{"title":"Diffusion and Thermal Shock Behaviour of Silicate Dental Ceramics","authors":"B. Ertuğ","doi":"10.5755/j02.ms.30414","DOIUrl":"https://doi.org/10.5755/j02.ms.30414","url":null,"abstract":"The purpose of this study is to examine the diffusion and thermal shock behaviour of the alternative dental silicates. The samples derived from BaO-SiO2 system have been produced by melting process and followed by the heat treatment. X-ray examinations have indicated that the amount of orthorhombic sanbornite phase rised due to treatment temperature as revealed by the peak intensities. The alteration of the morphology by treatment temperature was evident from scanning electron microscopy SEM images. Crystallization at low temperature produced small crystallites and coarsening was not observed with a rise in temperature. The failure of the dental samples after the thermal shock test was examined using SEM. A continuous crack geometry and very few crack branching were observed. Diffusivity constant (D) and diffusion rate were examined vs treatment temperature for the present system. Diffusion depth (L) was doubled when the crystallization treatment was applied. Based on the obtained results, these silicate samples might take part in the further characterization studies to be used as alternative dentistry materials.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44717546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Stress Field Simulation and its Experimental Verification of Carburizing-Quenching Process Performed on 18CrNiMo7-6 Steel","authors":"S. Qin, H. Ma, Lianxiang Wang","doi":"10.5755/j02.ms.30932","DOIUrl":"https://doi.org/10.5755/j02.ms.30932","url":null,"abstract":"The carburizing and quenching process of 18CrNiMo7-6 steel was performed through simulation methods and experiments. The study was carried out to accurately predict the residual stress distribution of carburized samples after the quenching process. The stress and retained-austenite amount were measured via X-ray diffraction. Similarly, the carbon content was determined using a carbon sulfur analyzer, respectively. A detailed model with the coupling of thermal, metallic, and mechanical fields was built to predict the evolution of the stress field during the quenching process. The carburized “thoroughly” specimens at different carbon potentials were used to obtain the required mechanical property parameters and dilatometric parameters for FEM simulation. According to the results, the martensite transformation kinetic parameters α value of 18CrNiMo7-6 alloy steel should be 0.0202. With the increase of carbon content, the changing trend of the transformation plasticity coefficient K appeared as a 'tick' shape. A compressive residual stress field was generated at the carburized layer surface after the quenching process, and the maximum value of 340 MPa occurred at ~ 0.9 mm below the surface. The carbon profile and residual stress fields predicted from the FEM simulation corresponded closely to the experimentally determined results.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43294957","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yu Zhang, Jiazhuo Lei, Z. Dan, Hui Chang, Lian Zhou
{"title":"Combinatorial Effects of the Recipes of the Initial Gas-atomized Powder Sizes on Microstructure and Passivation Characteristics of the SLM-ed Ti-6Al-4V Bulk Alloys","authors":"Yu Zhang, Jiazhuo Lei, Z. Dan, Hui Chang, Lian Zhou","doi":"10.5755/j02.ms.31220","DOIUrl":"https://doi.org/10.5755/j02.ms.31220","url":null,"abstract":"Bulk Ti-6Al-4V alloys have been fabricated by selective laser melting (SLM) in three recipes with different combinations of powder sizes. Combinatorial effects of initial gas-atomized powder sizes on microstructure and corrosion properties of SLM-ed Ti-6Al-4V alloys have been investigated by optical microscopy, X-ray diffraction, electrochemical measurements and surface free energy. The SLM-ed Ti-6Al-4V alloys are composed of acicular α' martensite and α phases. Many pinhole defects and twin boundaries exist in the SLM-ed Ti-6Al-4V alloys. According to electrochemical tests and surface free energy calculation, the SLM-ed Ti-6Al-4V alloys with 0 – 53 μm powders have the most positive corrosion potential, the lowest current density and the smallest surface free energy of 20.89 mJ m2. The passive film of SLM-ed Ti-6Al-4V alloys with 0 – 53 μm powders has superior protection ability due to their large thickness. The carrier concentration of SLM-ed Ti-6Al-4V alloys with 0 – 53 μm powders is the lowest by the Mott-Schottky curves. The SLM-ed samples with contact angles higher than 90º are hydrophobic, but the small contact angle of 46.98º reflects the hydrophilic features of as-rolled Ti-6Al-4V alloys. The combinatorial recipe of SLM-ed Ti-6Al-4V alloys with 0 – 53 μm powders is optimal for improvements on the corrosion resistance.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47534033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ting Wang, Qingshan Wang, Shenao Cui, Haihe Yi, Tian Su, Zhenyu Tan
{"title":"Effects of Nanomaterials Reinforced Aggregate on Mechanical Properties and Microstructure of Recycled Brick Aggregate Concrete","authors":"Ting Wang, Qingshan Wang, Shenao Cui, Haihe Yi, Tian Su, Zhenyu Tan","doi":"10.5755/j02.ms.32715","DOIUrl":"https://doi.org/10.5755/j02.ms.32715","url":null,"abstract":"In this paper, the effects of nano-SiO2 and nano-Al2O3 on the brick aggregate properties, compressive strength of brick aggregate concrete at different ages, and microstructure of brick aggregate concrete are investigated. The results show that the water absorption of recycled brick aggregate decreases with the increase of nanomaterials solution concentrations, and the crush index of recycled brick aggregate decreases. Nano-SiO2 and nano-Al2O3 improve the compressive strength of recycled brick aggregate concrete at different ages, and the effect of nanomaterials on the early strength of concrete are more obvious. With the increase of nano-solution concentration, the compressive strength of nano-SiO2 reinforced brick aggregate concrete increases first and then decreases, while that of nano-Al2O3 reinforced brick aggregate concrete increases. The internal structure of nanomaterials reinforced brick aggregate is denser, micro cracks and pores are filled with hydration products, and the interfacial transition zone is more compact.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46538764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Calcium phosphate brushite cements made from substituted tricalcium phosphate Ca3(PO4)2 and reinforced with silicate glass fiber","authors":"Sharifjon A Musoev, A. Knotko, Y. Filippov","doi":"10.31044/1684-579x-2023-0-5-19-27","DOIUrl":"https://doi.org/10.31044/1684-579x-2023-0-5-19-27","url":null,"abstract":"The reinforcement of reaction hardening phosphate materials (phosphate cements) for bone implants, based on isomorphically cation- (Na+, K+) and anion- (SiO44-, SO42-) substituted tricalcium phosphate (β and α-TCP, Ca3(PO4)2), that are reinforced with silicate (basalt-based) fiberglass, is considered. The obtained materials were characterized by the XRD and SEM methods, mechanical compression tests were carried out, the setting times of cements were determined, changes in the pH of the aqueous medium in contact with the cements under study were measured. Microstructure analysis has been shown that the surface of the reinforcing fiber in contact with the matrix of hardening cement is partially corroded with the formation of phosphate microparticles on it. By pH-metry it was found that the samples during prolonged contact with water do not significantly change the pH value of the aquatic environment, which remains in the nearly neutral range from 5 to 7.5, favorable for further biological tests.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47794034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection","authors":"Jinjie Zhang, Yingping Qi, Yongfeng Shen, Hua Li","doi":"10.5755/j02.ms.29181","DOIUrl":"https://doi.org/10.5755/j02.ms.29181","url":null,"abstract":"As an important part of cultural heritage, paper cultural relics have important historical, scientific and humanistic values. However, a large number of paper cultural relics are suffering from aging, mildew, yellowing, cracks, embrittlement and other threats, or are even completely damaged. To enhance the strength of paper cultural relics and prolong the life of paper cultural relics, a novel CMC-acrylate-OVPOSS graft copolymer was synthesized with carboxymethyl cellulose (CMC), methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA), octavinyl polyhedral oligomeric silsesquioxane (OVPOSS). The synthesized materials were analyzed by infrared spectroscopy, X-ray diffractometer, thermal analyzer and X-ray photoelectron spectroscopy. In addition, the reinforcement solution was coated on the surface of the paper, and the protective effect of the reinforcement solution on the paper was evaluated by testing the mechanical and optical properties of the paper. When the reinforcement solution with a mass concentration of 10 % was coated on the paper, the mechanical properties of the paper were greatly improved, and the gloss and whiteness were basically unchanged.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42429516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Experimental Investigation on Evaporator Surface Modification for Hydrophobicity and Frost Resistance","authors":"Xingyuan Liang, Lijun Wu, Zeng Wei","doi":"10.5755/j02.ms.30986","DOIUrl":"https://doi.org/10.5755/j02.ms.30986","url":null,"abstract":"Frost accumulated on the surface of the evaporator leads to the increase of heat transfer resistance between the refrigerant and environmental medium, which reduces the system performance of cold storage and air source heat pump. To solve this problem, the surface-modified evaporator can achieve retardation of the frost formation, which greatly improves the heat exchange effect between the refrigerant and the external environment. In this paper, a novel coating sprayed on the evaporator was developed using the sol-gel method and the hydrophobicity, durability, and thermal conductivity were investigated. Moreover, a modified method of frost weight measurement under different temperatures and humidity was first proposed. The results showed that the coating has a favorable hydrophobic effect and thermal conductivity, and long service life. Under the standard experimental condition, the frost weight on the coating surface can be reduced up to 26.1 %. Additionally, the effect of coating composition ratio on its performance was further investigated. To sum up, this new coating has the potential for industrialized application.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44337035","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Investigation of Vortex Motion in the YBCO Devices Manufactured Utilizing a Gaussian-shaped Optical Spot from a Continuous-wave Laser","authors":"A. Jukna","doi":"10.5755/j02.ms.31099","DOIUrl":"https://doi.org/10.5755/j02.ms.31099","url":null,"abstract":"The current report focuses on the analysis of the investigation results of the Abrikosov vortex motion in the YBa2Cu3O7-d (YBCO) device, which is a c-axis textured 0.3 ´ 50 ´ 100 µm3 (thickness ´ width ´ length) stripe of YBCO superconductor deposited on a LaAlO3 substrate. A laser beam focused in a Gaussian-shape optical spot of 5 mm in diameter modifies the stripe, initiating the oxygen out-diffusion and its uneven distribution in illuminated areas and in this way causing the appearance of a higher level of deoxygenation in the spot center and a lower level at its edges (slopes of weak superconductivity region). At temperatures below the temperature of the superconducting transition Tc, the current-self-produced magnetic field penetrates the optically modified area of the stripe in a form of Abrikosov magnetic vortices, and due to the current-self-produced Lorentz force, the vortices move toward their annihilation line resulting in energy dissipation. The vortices pinned on the slopes experience strong pinning and exert a magnetic drag force on moving vortices, which is confirmed by the stepped current-voltage dependences of the YBCO devices measured at temperatures 0.933·Tc £ T £ 0.958·Tc. Our results demonstrate the advantages of partially deoxygenated YBCO material for the development of superconducting electronic devices with electronic properties controlled by the motion of Abrikosov vortices at temperatures below Tc of the superconductor.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42035191","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Di Ma, Shuying Li, Xinyu Lyu, Shu-bai Li, Yang Cao
{"title":"Electrochemical Impedance Spectroscopy Study of Porous Anodic Alumina Films Fabricated at Low Temperature","authors":"Di Ma, Shuying Li, Xinyu Lyu, Shu-bai Li, Yang Cao","doi":"10.5755/j02.ms.30047","DOIUrl":"https://doi.org/10.5755/j02.ms.30047","url":null,"abstract":"A method of fabrication of AAO film in 0.3 mol/L H2C2O4 by adding 1,2-propanediol(PROH) and at sub-zero temperature has been proposed. The electrochemical characteristics of the barrier and porous layers of AAO films before and after pore-filling are examined using electrochemical impedance spectroscopy (EIS). It is shown that the high and medium frequency range corresponds to the barrier layer properties and the low frequency ranges reflect the sealed porous layer properties. The calculated thickness of the barrier layer is in the range of 1 ~ 18 nm. The resistance (Rb) and the thickness (δb) of the barrier layer increase and the capacitance of the barrier layer (CPEb) decrease with the volume percentage of PROH increasing from in electrolyte from 25 % to 75 %. The surface non-homogeneity of AAO film goes better by pore-filling, leading to a decrease in the capacitance of the porous layer (CPEp) and an increase in the porous layer thickness.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48661383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Vicen, O. Bokůvka, F. Nový, R. Nikolić, L. Trško, Z. Florková
{"title":"Analysis of the Low Service Life of a Planing Knife – A Case Study","authors":"M. Vicen, O. Bokůvka, F. Nový, R. Nikolić, L. Trško, Z. Florková","doi":"10.5755/j02.ms.31109","DOIUrl":"https://doi.org/10.5755/j02.ms.31109","url":null,"abstract":"The presented work deals with an analysis of causes of the very low service life of the new version of hand woodworking planing knife, which has replaced the original version of a planing knife. Based on the performed experimental works, chemical analysis, macroscopic and microscopic observation, SEM, diffractometric analysis, and Vickers hardness test it was concluded that the cause for the very low service life (practically the nonexistent one) of the new version of a planing knife are significant features of overheating. During the heating to the hardening temperature used steel was overheated, the cementite carbides dissolved, and the austenitic grains became coarse. The final microstructure of the used steel after hardening and tempering consists of brittle coarse martensitic needles, without any presence of the fine globular cementite carbides, accompanied by a very high amount of retained austenite. Thus, the chipping of the knife's cutting edge took place and the planer was unusable.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46358234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}