羧甲基纤维素-丙烯酸酯OvPOSS接枝共聚物的合成及其在纸张防护中的应用

IF 0.8 4区材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Science-medziagotyra Pub Date : 2023-02-13 DOI:10.5755/j02.ms.29181

Jinjie Zhang, Yingping Qi, Yongfeng Shen, Hua Li

{"title":"羧甲基纤维素-丙烯酸酯OvPOSS接枝共聚物的合成及其在纸张防护中的应用","authors":"Jinjie Zhang, Yingping Qi, Yongfeng Shen, Hua Li","doi":"10.5755/j02.ms.29181","DOIUrl":null,"url":null,"abstract":"As an important part of cultural heritage, paper cultural relics have important historical, scientific and humanistic values. However, a large number of paper cultural relics are suffering from aging, mildew, yellowing, cracks, embrittlement and other threats, or are even completely damaged. To enhance the strength of paper cultural relics and prolong the life of paper cultural relics, a novel CMC-acrylate-OVPOSS graft copolymer was synthesized with carboxymethyl cellulose (CMC), methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA), octavinyl polyhedral oligomeric silsesquioxane (OVPOSS). The synthesized materials were analyzed by infrared spectroscopy, X-ray diffractometer, thermal analyzer and X-ray photoelectron spectroscopy. In addition, the reinforcement solution was coated on the surface of the paper, and the protective effect of the reinforcement solution on the paper was evaluated by testing the mechanical and optical properties of the paper. When the reinforcement solution with a mass concentration of 10 % was coated on the paper, the mechanical properties of the paper were greatly improved, and the gloss and whiteness were basically unchanged.","PeriodicalId":18298,"journal":{"name":"Materials Science-medziagotyra","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection\",\"authors\":\"Jinjie Zhang, Yingping Qi, Yongfeng Shen, Hua Li\",\"doi\":\"10.5755/j02.ms.29181\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"As an important part of cultural heritage, paper cultural relics have important historical, scientific and humanistic values. However, a large number of paper cultural relics are suffering from aging, mildew, yellowing, cracks, embrittlement and other threats, or are even completely damaged. To enhance the strength of paper cultural relics and prolong the life of paper cultural relics, a novel CMC-acrylate-OVPOSS graft copolymer was synthesized with carboxymethyl cellulose (CMC), methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA), octavinyl polyhedral oligomeric silsesquioxane (OVPOSS). The synthesized materials were analyzed by infrared spectroscopy, X-ray diffractometer, thermal analyzer and X-ray photoelectron spectroscopy. In addition, the reinforcement solution was coated on the surface of the paper, and the protective effect of the reinforcement solution on the paper was evaluated by testing the mechanical and optical properties of the paper. When the reinforcement solution with a mass concentration of 10 % was coated on the paper, the mechanical properties of the paper were greatly improved, and the gloss and whiteness were basically unchanged.\",\"PeriodicalId\":18298,\"journal\":{\"name\":\"Materials Science-medziagotyra\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2023-02-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Science-medziagotyra\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.5755/j02.ms.29181\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science-medziagotyra","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.5755/j02.ms.29181","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 1

摘要

纸质文物作为文化遗产的重要组成部分，具有重要的历史、科学和人文价值。然而，大量纸质文物正遭受着老化、霉变、发黄、开裂、脆化等威胁，甚至完全损毁。为了提高纸质文物的强度，延长纸质文物的使用寿命，以羧甲基纤维素（CMC）、甲基丙烯酸甲酯（MMA）、丙烯酸丁酯（BA）、甲基丙烯酸酯羟乙酯（HEMA）、甲基缩水甘油酯（GMA）、八乙烯基多面体低聚倍半硅氧烷（OVPOSS）为原料，合成了一种新型的CMC-丙烯酸酯OVPOSS接枝共聚物。用红外光谱、X射线衍射仪、热分析仪和X射线光电子能谱对合成的材料进行了分析。此外，将增强溶液涂覆在纸张表面，并通过测试纸张的机械和光学性能来评估增强溶液对纸张的保护作用。当质量浓度为10%的增强溶液涂布在纸上时，纸的机械性能大大提高，光泽度和白度基本不变。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection

As an important part of cultural heritage, paper cultural relics have important historical, scientific and humanistic values. However, a large number of paper cultural relics are suffering from aging, mildew, yellowing, cracks, embrittlement and other threats, or are even completely damaged. To enhance the strength of paper cultural relics and prolong the life of paper cultural relics, a novel CMC-acrylate-OVPOSS graft copolymer was synthesized with carboxymethyl cellulose (CMC), methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA), octavinyl polyhedral oligomeric silsesquioxane (OVPOSS). The synthesized materials were analyzed by infrared spectroscopy, X-ray diffractometer, thermal analyzer and X-ray photoelectron spectroscopy. In addition, the reinforcement solution was coated on the surface of the paper, and the protective effect of the reinforcement solution on the paper was evaluated by testing the mechanical and optical properties of the paper. When the reinforcement solution with a mass concentration of 10 % was coated on the paper, the mechanical properties of the paper were greatly improved, and the gloss and whiteness were basically unchanged.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Materials Science-medziagotyra 工程技术-材料科学：综合

CiteScore

1.70

自引率

10.00%

发文量

审稿时长

6-12 weeks

期刊介绍： It covers the fields of materials science concerning with the traditional engineering materials as well as advanced materials and technologies aiming at the implementation and industry applications. The variety of materials under consideration, contributes to the cooperation of scientists working in applied physics, chemistry, materials science and different fields of engineering.