Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00783-w
Yu. H. Kvasnytska, L. M. Ivaskevych, A. I. Balitskii, H. P. Mialnitsa, K. H. Kvasnytska
{"title":"Evaluation of the Endurance Limit of Cooled Blades of Gas-Turbine Engines Made of Heat-Resistant Nickel Alloy","authors":"Yu. H. Kvasnytska, L. M. Ivaskevych, A. I. Balitskii, H. P. Mialnitsa, K. H. Kvasnytska","doi":"10.1007/s11003-024-00783-w","DOIUrl":"https://doi.org/10.1007/s11003-024-00783-w","url":null,"abstract":"<p>The characteristics of fatigue failure of the working blades of the first stage of the high-pressure turbine of the power gas-turbine engine were determined. Experimental studies were carried out on blades obtained according to the improved technology from the CM88Y alloy, which is used in the serial production of gas-turbine units. The blades withstood the test base of 1×10<sup>7</sup> cycles at a stress of 200–240 MPa. The established endurance limit corresponded to the given service life of blades of this type.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"152 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00778-7
O. I. Zvirko, M. I. Hredil, O. T. Tsyrulnyk, O. Z. Student, H. M. Nykyforchyn
{"title":"Mechanism of Development of Damage of Low-Strength Pipe Steel Due to Hydrogenation Under Operation","authors":"O. I. Zvirko, M. I. Hredil, O. T. Tsyrulnyk, O. Z. Student, H. M. Nykyforchyn","doi":"10.1007/s11003-024-00778-7","DOIUrl":"https://doi.org/10.1007/s11003-024-00778-7","url":null,"abstract":"<p>Resistance of pipe steels to hydrogen embrittlement is an important indicator of their serviceability. Pipes are manufactured from steels of a wide strength range. With the strength increase, a susceptibility to hydrogen embrittlement in general increases. This regularity is usually true for steels in the as-received state; however, the long-term operation can increase hydrogen susceptibility even of low- strength steels. This is caused by the development of damage dissipated in the metal bulk with the formation of voids due to deformation caused by high-pressure recombined hydrogen in them. Implementation of the hydrogen-induced damage mechanism, associated with the formation of deformation voids, extends the strength range of pipe steels, which become prone to operational hydrogen embrittlement.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"61 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00784-9
I. M. Pohrelyuk, M. M. Student, Kh.R. Zadorozhna, V. S. Trush, T. M. Kravchyshyn
{"title":"Surface Modification of Titanium by Oxidation Followed by Electrospark Alloying with a Graphite Electrode","authors":"I. M. Pohrelyuk, M. M. Student, Kh.R. Zadorozhna, V. S. Trush, T. M. Kravchyshyn","doi":"10.1007/s11003-024-00784-9","DOIUrl":"https://doi.org/10.1007/s11003-024-00784-9","url":null,"abstract":"<p>The characteristics of the modified layer of commercially pure BT1-0 titanium (c.p. BT1-0 titanium) after oxygen thermal diffusion saturation (oxidation) and subsequent electrospark alloying (ESA) with a graphite electrode were analyzed. The phase composition of surface layers, their hardness and tribological properties were studied. It was shown that both surface electrospark alloying of titanium with a graphite electrode and combined processing (oxidation followed by ESA) improve its tribological characteristics during friction without lubrication. As a result, the friction coefficient decreases from 0.4–0.5 to 0.15–0.17. At the same time, the wear resistance of titanium increases in 1.2–2.9 times.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"154 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140156943","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00786-7
O. O. Matviichuk, I. V. Andreiev, N. V. Litoshenko, M. O. Tsysar, V. A. Vynar, I. O. Hnatenko, S. A. Davydenko, I. V. Savchuk
{"title":"Peculiarities of Preparation and Properties of Cemented Carbide WC + 20 Mass% Ni with Ultra-Coarse-Grained Microstructure","authors":"O. O. Matviichuk, I. V. Andreiev, N. V. Litoshenko, M. O. Tsysar, V. A. Vynar, I. O. Hnatenko, S. A. Davydenko, I. V. Savchuk","doi":"10.1007/s11003-024-00786-7","DOIUrl":"https://doi.org/10.1007/s11003-024-00786-7","url":null,"abstract":"<p>The influence of the conditions of original components mixing and sintering temperatures on the peculiarities of microstructure formation of the cemented carbide WC + 20 mass% Ni prepared of ultra-coarse-grained (80/40 μm) tungsten carbide particles is investigated. The metallographic analysis shows that for the formation of such hard alloy microstructure, it is sufficient to use liquid phase sintering and preliminary economical wet mixing of WC with Ni powder. The strength under bending and compression is 1530 and 1720 MPa, respectively, the density is 13.51 g/cm<sup>3</sup>, and the hardness is 76 HRA. For the first time, the compressive stress-compression strain curve for this alloy with an average carbide grain size of 20 μm is experimentally obtained. The alloy plasticity is 6 times higher than that of the alloys prepared under other technological modes.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"7 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00780-z
I. O. Tsybailo, H. V. Krechkovska
{"title":"The Structural-Mechanical State of 12Kh1MF Steel of TPP Pipeline Bend after Long-Term Operation","authors":"I. O. Tsybailo, H. V. Krechkovska","doi":"10.1007/s11003-024-00780-z","DOIUrl":"https://doi.org/10.1007/s11003-024-00780-z","url":null,"abstract":"<p>The mechanical characteristics and structural features of the heat-resistant 12Kh1MF steel after long-term operation in a bend of the TPP (thermal power plants) steam pipelines were analyzed. The change in the technical state of the metal of different zones of the bend and the anisotropy of properties across the pipe wall thickness were established. It was found that in the stretched zone of the bend near the outer surface of the pipe the steel degraded more intense than in other zones, which was due to the most favorable operating conditions for creep.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"155 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00779-6
O. P. Kononiuk, I. Yu. Zavaliy, V. V. Berezovets, A. R. Kytsia, I. V. Borukh
{"title":"Hydrogen Generation by Hydrolysis of Magnesium Hydride Composites with TiFe/Ti3Fe3O Additives and Graphite","authors":"O. P. Kononiuk, I. Yu. Zavaliy, V. V. Berezovets, A. R. Kytsia, I. V. Borukh","doi":"10.1007/s11003-024-00779-6","DOIUrl":"https://doi.org/10.1007/s11003-024-00779-6","url":null,"abstract":"<p>Hydrides of magnesium composites with additives of intermetallic TiFe and suboxide Ti<sub>3</sub>Fe<sub>3</sub>O were synthesized by mechanical milling in a hydrogen atmosphere. The addition of graphite reduces the particle size of the composites. The influence of catalytic additives and graphite on the hydrolysis of magnesium hydride was studied. The dependence of the amount of hydrogen obtained by hydrolysis on the time of composite milling was found.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"90 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155583","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00788-5
T. V. Humenetskyi, A. S. Masiuk, V. Ye. Levitskyi, L. M. Bilyi
{"title":"The Influence of Polyvinylpyrrolidone as a Polymer Modifier on the Morphology and Properties of Copolyamide","authors":"T. V. Humenetskyi, A. S. Masiuk, V. Ye. Levitskyi, L. M. Bilyi","doi":"10.1007/s11003-024-00788-5","DOIUrl":"https://doi.org/10.1007/s11003-024-00788-5","url":null,"abstract":"<p>Peculiarities of copolyimide modification by polyvinylpyrrolidone in a viscous state were studied. The differential scanning calometry revealed changes in the morphology and phase transitions of modified copolyamide materials. The increased technological compatibility between the components of copolyamide-polyvinyl pyrrolidone mixture was established. The effect of the modifier on the strength and thermophysical properties of the studied thermoplastic was found. Introduction of polyvinylpyrrolidone contributes to the growth of copolyamide strength under rupture and relative elongation and leads to a certain decrease in Vicat softening point and change of copolyamide technological properties.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"32 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00776-9
I. V. Kravchenko, O. V. Suvorin, H. O. Tatarchenko
{"title":"Corrosion Activity of Low-Carbon Steel Under the Action of Multi-Component Anti-Icing Reagent","authors":"I. V. Kravchenko, O. V. Suvorin, H. O. Tatarchenko","doi":"10.1007/s11003-024-00776-9","DOIUrl":"https://doi.org/10.1007/s11003-024-00776-9","url":null,"abstract":"<p>Corrosion activity of a multi-component solution, namely, distiller liquid previously clarified and strengthened to 20 wt% by CaCl<sub>2</sub> including the addition of corrosion inhibitors at –5°C to low-carbon 08kp steel is studied by the gravimetric method. The holding time of the specimens is 500–650 h. In distiller liquid corrosion rate is 0.111 g/(m<sup>2</sup>×h), corrosion depth is 0.12 mm/year, steel resistance refers to the IV group (relatively resistant). When adding the hexamethylenetetramine, triethanolamine, trilon B corrosion inhibitors or their mixture in the amount of 0.5 wt% the corrosion resistance of steel improves, and the best results are achieved by adding hexamethylenetetramine with triethanolamine. The obtained results indicate the possibility of using the distiller liquid from sludge accumulator of JSC “Lysychanska Soda” with additives of such corrosion inhibitors as reagents for preventing highway surface against icing.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"26 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155439","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00787-6
V. YA. Suprun, V. I. Marukha, V. P. Sylovanyuk
{"title":"Use of Polyols of Petroleum Chemical Processing as Raw Materials for the Synthesis of Polyurethanes","authors":"V. YA. Suprun, V. I. Marukha, V. P. Sylovanyuk","doi":"10.1007/s11003-024-00787-6","DOIUrl":"https://doi.org/10.1007/s11003-024-00787-6","url":null,"abstract":"<p>Polyurethanes (PU) are unique heteropolymers with a wide range of physicomechanical properties, fields of use and high development potential. PU is obtained by condensation of diisocyanate and various polyol compounds. The peculiarities of the structure and synthesis of commercial polyols based on the products of secondary oil processing, namely oligomeric glycols, oxides and dicarboxylic acids are presented.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"61 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00785-8
{"title":"The Influence of the Initial Clearance on the Fracture of Bolted Joints of Composite Materials","authors":"","doi":"10.1007/s11003-024-00785-8","DOIUrl":"https://doi.org/10.1007/s11003-024-00785-8","url":null,"abstract":"<p>The results of experiments studying the dependence of contact angles for different initial clearances in a bolted joint on loading are presented. Considering the change of the interacting surface area of the composite plates with a pin, the bearing capacity of the hole is determined. The modified correlation algorithm for digital image processing is used to obtain the experimental results.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"6 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140156941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}