{"title":"On the Impact of Cathodic Polarization on the Chloride Threshold of Carbon Steel in Alkaline Solutions","authors":"Konstantin Fache, Sylvia Keßler, Jörg Harnisch","doi":"10.1002/maco.202414601","DOIUrl":"10.1002/maco.202414601","url":null,"abstract":"<p>This study investigates the influence of cathodic polarization on the chloride threshold (<i>C</i><sub>T</sub>) for carbon steel in alkaline solutions, analogous to reinforcing steel embedded in concrete, with a focus on the electrochemical steel potential as a critical factor for corrosion initiation. The research, incorporating a literature review and potentiostatic tests, reveals that <i>C</i><sub>T</sub> shows potential independence at potentials more anodic than −200 mV<sub>SCE</sub> and increases for potentials more cathodic than −200 mV<sub>SCE</sub>. The observed increase in <i>C</i><sub>T</sub> under cathodic polarization is attributed to alterations in the passive layer composition, supporting the existence of distinct potential regions that govern the onset of corrosion.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 2","pages":"265-283"},"PeriodicalIF":1.6,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202414601","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142180245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Research on Pulse Current Cathodic Protection Technology for Long-Distance Pipeline: A Review","authors":"Qiudie Zhao, Hongfu Li, Xiaowu Luo, Yanjie Shi, Jian Li, Chen Wang, Yanming Liu, Xianghong Lv","doi":"10.1002/maco.202414557","DOIUrl":"10.1002/maco.202414557","url":null,"abstract":"<p>As an important infrastructure for oil and gas transportation, the safe and stable operation of long-distance pipelines is significant for guaranteeing national energy security and economic development. However, pipelines are susceptible to corrosion due to various factors. Therefore, it is crucial to take effective corrosion protection measures. Pulse current cathodic protection technology, as an advanced pipeline corrosion protection technology, is superior to traditional cathodic protection technology. This paper mainly summarizes the research progress of pulse current cathodic protection technology for long-distance pipelines in recent years. It briefly discusses the protection mechanism, characteristic parameters, challenges, and development trends of pulse current cathodic protection technology, which provides a useful reference for the further promotion and application of pulse current cathodic protection technology for long-distance transport pipelines.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 1","pages":"20-28"},"PeriodicalIF":1.6,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202414557","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142180244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Correction to “Carbon Steel Corrosion in a Bentonite Buffer: A Comparison Between In Situ Exposure and Lab Based Experiments”","authors":"","doi":"10.1002/maco.2024071011","DOIUrl":"10.1002/maco.2024071011","url":null,"abstract":"<p>J. Hesketh, H. Haynes, B. Reddy, et al., “Carbon Steel Corrosion in a Bentonite Buffer: A Comparison Between In Situ Exposure and Lab Based Experiments,” <i>Materials and Corrosion</i> 74(2023): 1728–1745, https://doi.org/10.1002/maco.202313767.</p><p>Where,</p><p>C is a constant (calculated as ~7 10<sup>−3</sup>°C<sup>−1</sup> from the gradient of the linear fit in Figure 14)</p><p>D is a constant (calculated as ~0.34 from the intercept of the linear fit in Figure 14)</p><p>T is the temperature in °C</p><p>The authors would like to mention that there are no changes in the results, interpretation, and final conclusion of the manuscript after this correction, and apologise for any confusion that these errors may have caused.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 11","pages":"1565"},"PeriodicalIF":1.6,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.2024071011","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142180246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ajmal T. S., Rahul Kumar Singh, Shashi Bhushan Arya, Satish Kumar D.
{"title":"Enhancing the Flow-Accelerated Corrosion Resistance of X70 API Steel Through Laser Surface Melting in Synthetic Oilfield Water","authors":"Ajmal T. S., Rahul Kumar Singh, Shashi Bhushan Arya, Satish Kumar D.","doi":"10.1002/maco.202414456","DOIUrl":"10.1002/maco.202414456","url":null,"abstract":"<div>\u0000 \u0000 <p>Hydrodynamic flow conditions play a critical role in piping failure due to sharp variations of the Reynolds number in process and petrochemical industries. The current study aims to enhance flow-accelerated corrosion (FAC) resistance using metallurgy of the surface by utilizing the laser surface melting (LSM) technique. The FAC behavior of API X70 steel in simulated Indian synthetic oilfield water was studied by utilizing a closed-loop corrosion apparatus to simulate the pipeline flow. Electrochemical corrosion experiments (AC and DC methods) were conducted at a constant fluid velocity of 3 m/s in untreated and LSM-treated samples (at 2.5 and 3.0 kW) placed at a 90° pipe elbow. Experimental results showed that LSM-treated samples displayed enhanced resistance to FAC, attributed to changes in surface metallurgy. Additionally, it was observed that the corrosion rate varied within the pipe elbow for the different samples at different locations.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 1","pages":"175-187"},"PeriodicalIF":1.6,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142180255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Le Chen, Yanxia Du, Lei Guo, Zhenhong Zhu, Yi Liang, Lei Zhang
{"title":"Corrosion Behavior and Evaluation Method of Pipeline Steel Under Dynamic AC Interference: A Study","authors":"Le Chen, Yanxia Du, Lei Guo, Zhenhong Zhu, Yi Liang, Lei Zhang","doi":"10.1002/maco.202414607","DOIUrl":"10.1002/maco.202414607","url":null,"abstract":"<div>\u0000 \u0000 <p>Unlike the stable AC interference caused by AC transmission lines to buried pipelines, high-speed railways cause dynamic AC interference to nearby buried pipelines. The dynamic fluctuation characteristics of AC interference parameters of buried pipelines near high-speed railways with different traction power supply modes were obtained through the statistical analysis of field test data. The dynamic AC corrosion simulation experiments were conducted with different interference cycles and levels, as well as cathodic protection (CP) levels. The results show that the dynamic AC corrosion rate increases with the extension of the interference time within each interference cycle. After the <i>J</i><sub>AC</sub> ≥ 100 A/m<sup>2</sup>, the dynamic AC corrosion rate shows a three-stage change with a negative shift of CP potential, that is, first decreasing, then increasing, and then decreasing again. On the basis of the experimental results, the dynamic AC corrosion risk assessment criteria were proposed, which comprehensively considers the CP level and the proportion of interference time with different AC current densities.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 2","pages":"305-315"},"PeriodicalIF":1.6,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142180247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pranav Vivek Kulkarni, Meet Jaydeepkumar Oza, Anna Igual-Munoz, Jean-Michel Sallese, Moslem Shahverdi, Christian Leinenbach, Stefano Mischler
{"title":"Corrosion Behavior of Heat-Treated Fe-Based Shape Memory Alloys","authors":"Pranav Vivek Kulkarni, Meet Jaydeepkumar Oza, Anna Igual-Munoz, Jean-Michel Sallese, Moslem Shahverdi, Christian Leinenbach, Stefano Mischler","doi":"10.1002/maco.202414562","DOIUrl":"10.1002/maco.202414562","url":null,"abstract":"<p>The influence of various heat treatments on the corrosion behavior of a novel iron-based shape memory alloy (Fe-SMA), Fe-17Mn-6Si-10Cr-4Ni-1(V,C), used as prestressing elements in civil engineering was examined through electrochemical corrosion methods. SMAs were subjected to two different electrolytes: saturated Ca(OH)<sub>2</sub> solutions with and without chlorides to mimic the conditions in concrete. Two specific heat treatments were applied to the Fe-SMA, which resulted in a change in grain size and precipitation of secondary phases. Furthermore, conventional structural steel, B500B, was utilized as a reference material. The results reveal that the heat treatments did not significantly change the corrosion rates of these alloys in Ca(OH)<sub>2</sub> solution compared to B500B when chlorides were absent. However, the presence of chloride ions suppressed the passivity of B500B and promoted the localized corrosion (pitting and intergranular) of the Fe-SMAs, among which the solutionized alloy showed significantly higher resistance to the pitting. It was demonstrated that the heat treatments and, consequently, microstructural characteristics influence the pitting behavior of these alloys.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 1","pages":"10-19"},"PeriodicalIF":1.6,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202414562","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142180249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lekan Taofeek Popoola, Alfred Ogbodo Agbo, Usman Taura, Adeyinka Sikiru Yusuff, Yuli Panca Asmara, Olusegun A. Olagunju, Onyemaechi Melford Chima
{"title":"Corrosion Behavior of Aluminum in Fossil Diesel Fuel and Biodiesel From Chicken Eggshell-Alumina-Catalyzed Waste Cooking Oil","authors":"Lekan Taofeek Popoola, Alfred Ogbodo Agbo, Usman Taura, Adeyinka Sikiru Yusuff, Yuli Panca Asmara, Olusegun A. Olagunju, Onyemaechi Melford Chima","doi":"10.1002/maco.202414510","DOIUrl":"10.1002/maco.202414510","url":null,"abstract":"<p>To curb environmental pollution emanating from the exhausts of engines using fossil diesel fuel (DF), studies on the use of biodiesel from renewable energy source are ongoing. However, engine components have been observed to corrode easily in biodiesels. In this study, a comparative study of the corrosion rate of aluminum coupon (AC) in biodiesel from waste cooking oil over chicken eggshell-supported alumina catalyst (WCOB) and fossil DF was executed. Weight loss method was used to examine the corrosion rate. Highest corrosion rates of 0.0381 and 0.0052 mm year<sup>−1</sup> were recorded for AC in WCOB and DF, respectively. The developed mathematical models proved effective for corrosion rate prediction. At optimum prediction, the minimum corrosion rates for the AC in WCOB and DF were 1.822 × 10<sup>−3</sup> and 1.222 × 10<sup>−3</sup> mm year, respectively. Characterization revealed pits formation and presence of oxygen and carbon on AC surface with loss of Al ions from the AC surface into WCOB and DF after corrosion. In conclusion, all results revealed high corrosion rates of AC in WCOB than DF.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 1","pages":"122-136"},"PeriodicalIF":1.6,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202414510","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142180256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Cover Picture: Materials and Corrosion. 9/2024","authors":"Bin Xie, Hongwei Shi, Yingwei Song, En-Hou Han","doi":"10.1002/maco.202470091","DOIUrl":"https://doi.org/10.1002/maco.202470091","url":null,"abstract":"<p><b>Cover:</b></p><p>The morphology (SEM image) of the urea-formaldehyde-alkyd resin microcapsules. The microcapsules were regularly globular in shape.</p><p>More detailed information can be found in: <i>Bin Xie, Hongwei Shi, Yingwei Song, En-Hou Han</i>, Self-healing polyurethane anticorrosive coatings based on alkyd resin microcapsules, <i>Materials and Corrosion</i> <b>2024</b>, <i>75</i>, 1090.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 9","pages":"1083"},"PeriodicalIF":1.6,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202470091","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142123298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Masthead: Materials and Corrosion. 9/2024","authors":"","doi":"10.1002/maco.202470092","DOIUrl":"https://doi.org/10.1002/maco.202470092","url":null,"abstract":"","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 9","pages":"1085"},"PeriodicalIF":1.6,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202470092","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142123299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Contents: Materials and Corrosion. 9/2024","authors":"","doi":"10.1002/maco.202470093","DOIUrl":"https://doi.org/10.1002/maco.202470093","url":null,"abstract":"","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 9","pages":"1086-1089"},"PeriodicalIF":1.6,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202470093","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142123132","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}