Amadeu Concustell, Alejandro Pérez-Alonso, Marc Bahillo, Sílvia Molas, Raül Bonet, Jordi Orrit-Prat, Jaume Caro, Joan Muñoz
{"title":"Corrosion Behavior of Bactericidal Surfaces Based on Silver and Copper Ion Implantation","authors":"Amadeu Concustell, Alejandro Pérez-Alonso, Marc Bahillo, Sílvia Molas, Raül Bonet, Jordi Orrit-Prat, Jaume Caro, Joan Muñoz","doi":"10.1002/maco.202414581","DOIUrl":"https://doi.org/10.1002/maco.202414581","url":null,"abstract":"<div>\u0000 \u0000 <p>Titanium is a commonly used material in biomedical applications due to its excellent biocompatibility and mechanical properties. In addition, the surface incorporation of metal ions with bactericidal behavior proves to be very interesting in preventing bacterial colonization in biomedical titanium implants. This study investigates the corrosion resistance and stability of a series of Ti substrates implanted with Ag and Cu ions, as well as a combination of both. Characterization results indicate that the dense native oxide layer naturally present in Ti may contain more defects in the implanted materials due to the implantation process, especially when Ag is implanted. The material co-implanted with Ag and Cu presents an outer oxide layer with Ag and Cu nanoparticles which are the source of ions that can act as bactericidal agents. Finally, the study shows that the implantation of Ag and/or Cu ions does not lead to a deterioration of the corrosion resistance of Ti under simulated physiological conditions.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 4","pages":"591-603"},"PeriodicalIF":1.6,"publicationDate":"2024-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Optimize the Corrosion and Mechanical Performance of Additive-Manufactured Nano-Size WC-Reinforced Stainless Steel Matrix Composites by Heat Treatments","authors":"Yiqi Zhou, Xiaochang Xu, Shuoyang Wang, Decheng Kong, Fan Zhang, Lili Li, Tingting Liu, Xiaogang Li, Xuanhui Qu, Yu Yan, Chaofang Dong","doi":"10.1002/maco.202414705","DOIUrl":"https://doi.org/10.1002/maco.202414705","url":null,"abstract":"<div>\u0000 \u0000 <p>Adding 200 nm WC can dramatically increase the mechanical properties of laser powder bed fusion (LPBF) 420 stainless steel, whereas the evolution of the microstructure, corrosion resistance, wear resistance, and tensile performance in LPBF 420 + 2 wt% WC MMCs is not researched yet. WC increases the hardness of the LPBF MMCs. WC offers W and C to the matrix during laser scanning, with C diffusing to the matrix to form austenite and Cr-rich carbides. The austenite content increases with higher tempering temperatures by up to 22% after heat treatment at 400°C. However, more numbers and large size Cr-rich carbides are formed after being tempered at 600°C. Austenite increases pitting corrosion resistance by a higher critical pitting potential and lower pit growth kinetics. Wear resistance is linearly related to the hardness value, with smaller grain and more austenite improving ductility without sacrificing tensile strength. Overall, LPBF 420 + 2 wt% WC MMCs has the best corrosion in 0.1 M NaCl, with optimized mechanical properties.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 5","pages":"620-639"},"PeriodicalIF":1.6,"publicationDate":"2024-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Juan Du, Qi Zou, Pengfei Chen, Yiquan Shi, Pingli Liu, Jinming Liu, Yaoshun Yuan, Xiang Chen, Hui Shu
{"title":"Corrosion Behavior of 110SS Steel in Self-Generated Acid at High Temperature","authors":"Juan Du, Qi Zou, Pengfei Chen, Yiquan Shi, Pingli Liu, Jinming Liu, Yaoshun Yuan, Xiang Chen, Hui Shu","doi":"10.1002/maco.202414624","DOIUrl":"https://doi.org/10.1002/maco.202414624","url":null,"abstract":"<div>\u0000 \u0000 <p>The corrosion behavior of hydrogen sulfide corrosion-resistant alloy steel 110SS in the self-generated acid system at (ultra-) high temperature was studied. The results of the weight loss experiment showed that the corrosion rate of 110SS steel decreased with the increase of temperature at 120°C–200°C. The comprehensive study of SEM-EDS and XPS showed that FeCO<sub>3</sub> was formed on the surface of 110SS steel. With the increase in temperature, FeCO<sub>3</sub> became dense, and the corrosion rate of self-generated acid decreased. In addition, when the temperature is 120°C, the results of weight loss experiment and 3D laser scanning show that the corrosion of 110SS steel is strong, and the corrosion phenomenon is inhibited after adding oleic imidazoline. SEM and electrochemical experiments show that the oleic imidazoline corrosion inhibitor can be stably adsorbed on the surface of 110SS steel and reduce its corrosion in the self-generated acid.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 4","pages":"557-571"},"PeriodicalIF":1.6,"publicationDate":"2024-12-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Alexandr S. Kuprin, Hanna Y. Rostova, Elena N. Reshetnyak, Bogdan Warcholinski, Adam Gilewicz, Ilya O. Klimenko, Konrad Trzciński, Maria Gazda, Jacek Ryl, Miroslaw Sawczak
{"title":"Corrosion Resistance and Structure of Cr−O−N Coatings Formed in Vacuum Arc Plasma Fluxes With PIIID","authors":"Alexandr S. Kuprin, Hanna Y. Rostova, Elena N. Reshetnyak, Bogdan Warcholinski, Adam Gilewicz, Ilya O. Klimenko, Konrad Trzciński, Maria Gazda, Jacek Ryl, Miroslaw Sawczak","doi":"10.1002/maco.202414543","DOIUrl":"https://doi.org/10.1002/maco.202414543","url":null,"abstract":"<div>\u0000 \u0000 <p>Cr−O−N-based vacuum arc coatings are very promising for the wear and corrosion protection of various steel parts. The aim of the work was to determine the effect of frequency and amplitude of the pulsed bias voltage (U<sub>B</sub>) on the elemental and phase composition, mechanical, and corrosion properties of Cr−O−N coatings. They have an amorphous structure with embedded nanosized solid solution crystallites based on CrN with a cubic structure and Cr<sub>2</sub>O<sub>3</sub> with a rhombohedral structure. The increase in the bias voltage results in a reduction in the grain size of the Cr<sub>2</sub>O<sub>3</sub> and CrN phases by about four times to about 5 nm, as well as a change in the CrN phase content in the coating. The lattice parameter increases slightly for the Cr<sub>2</sub>O<sub>3</sub> phase but decreases for the CrN phase. The increase in the pulse frequency results in an increase in the CrN phase content in the coating and the lattice constant of both phases and a slight decrease in the crystallite size. The hardness of Cr−O−N coatings slightly increased with the U<sub>B</sub> from 26 ± 1 GPa (DC) to 28 ± 1 GPa (−300 V, pulsed), and the elastic modulus ranges from 290 to 310 GPa. The greatest changes were observed in corrosion resistance. With an increase in the bias voltage and pulse frequency, the corrosion current of Cr−O−N coatings on steel in 3% NaCl solution decreased by three orders of magnitude compared to coatings deposited at DC voltage and by five orders of magnitude compared to the base steel. Therefore, the use of a pulsed bias voltage with a frequency of at least 10 kHz and an amplitude of 700 V can significantly increase the corrosion resistance of Cr−O−N coatings on steel substrates.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 4","pages":"542-556"},"PeriodicalIF":1.6,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143809926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The High Temperature Corrosion and Oxidation 2023 Workshop","authors":"","doi":"10.1002/maco.202470118","DOIUrl":"https://doi.org/10.1002/maco.202470118","url":null,"abstract":"","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 12","pages":"1582"},"PeriodicalIF":1.6,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142868104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Katharina Beck, Till König, Ekin Senvardarli, Frauke Hinrichs, Martin Heilmaier, Mathias C. Galetz
{"title":"Cover Picture: Materials and Corrosion. 12/2024","authors":"Katharina Beck, Till König, Ekin Senvardarli, Frauke Hinrichs, Martin Heilmaier, Mathias C. Galetz","doi":"10.1002/maco.202470115","DOIUrl":"https://doi.org/10.1002/maco.202470115","url":null,"abstract":"<p><b>Cover:</b></p><p>BSE image of the oxides and corrosion products formed on the eutectoid alloy Mo-21.0Si-34.0Ti after hot corrosion at 700 in synthetic air + 0.1% SO<sub>2</sub> for 24 h.</p><p>More detailed information can be found in:</p><p><i>Katharina Beck, Till König, Ekin Senvardarli, Frauke Hinrichs, Martin Heilmaier, Mathias C. Galetz</i>, Hot Corrosion Behavior of Mo-Si-Ti Alloys, <i>Materials and Corrosion</i> <b>2024</b>, <i>75</i>, 1610.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 12","pages":"1575"},"PeriodicalIF":1.6,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202470115","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142868101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Contents: Materials and Corrosion. 12/2024","authors":"","doi":"10.1002/maco.202470117","DOIUrl":"https://doi.org/10.1002/maco.202470117","url":null,"abstract":"","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 12","pages":"1578-1580"},"PeriodicalIF":1.6,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202470117","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142868102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Masthead: Materials and Corrosion. 12/2024","authors":"","doi":"10.1002/maco.202470116","DOIUrl":"https://doi.org/10.1002/maco.202470116","url":null,"abstract":"","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 12","pages":"1577"},"PeriodicalIF":1.6,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202470116","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142868103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Janusz Kamiński, Bogusława Adamczyk-Cieślak, Mateusz Kopec, Andrzej Kosiński, Ryszard Sitek
{"title":"Effects of Reduction-Oxidation Cycles on the Structure, Heat and Corrosion Resistance of Haynes 282 Nickel Alloy Manufactured by Using Powder Bed Fusion-Laser Beam Method","authors":"Janusz Kamiński, Bogusława Adamczyk-Cieślak, Mateusz Kopec, Andrzej Kosiński, Ryszard Sitek","doi":"10.1002/maco.202414477","DOIUrl":"https://doi.org/10.1002/maco.202414477","url":null,"abstract":"<div>\u0000 \u0000 <p>The study investigated the effect of the oxidation–reduction cycles on the structure and corrosion resistance of the Haynes 282 nickel superalloy at ambient and elevated temperatures. The comparative studies were performed on specimens produced by the Powder Bed Fusion-Laser Beam (PBF-LB) process and those in the as-received state. The microstructure of the PBF-LB specimens was studied using optical and scanning electron microscopy, whereas the chemical composition of the scale formed after isothermal oxidation in an air atmosphere at 750°C was analysed using energy-dispersive X-ray spectroscopy and X-ray Photoelectron Spectroscopy. The phase composition of the formed scale was determined by X-ray diffraction. Laboratory-induced hydrogen atmosphere was adopted through cathodic charging. A comparison of corrosion resistance was carried out on two types of Haynes 282 specimens, before and after the oxidation and cathodic charging processes. It was found that PBF-LB process could be effectively used to manufacture Haynes 282 nickel superalloy with low porosity and a fine crystalline microstructure. The low-porous, fine-crystalline microstructure of the tested specimens produced by the PBF-LB technique exhibited good resistance to electrochemical corrosion, slightly lower than wrought Haynes 282 nickel superalloy specimens.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 3","pages":"354-367"},"PeriodicalIF":1.6,"publicationDate":"2024-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143554994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yazan Meri, Osman Siddiqui, Ihsan ulhaq Toor, Afaque Shams
{"title":"A Detailed Review of Numerical Modeling of Flow Accelerated Corrosion: Challenges and Opportunities for the Future","authors":"Yazan Meri, Osman Siddiqui, Ihsan ulhaq Toor, Afaque Shams","doi":"10.1002/maco.202414625","DOIUrl":"https://doi.org/10.1002/maco.202414625","url":null,"abstract":"<div>\u0000 \u0000 <p>Flow-accelerated corrosion (FAC) is a complex phenomenon that poses a significant threat to the integrity of piping and fittings in power plants, affecting infrastructure protection and power production reliability. The presence of corrosive substances in the fluid and elevated flow velocity and temperature leads to increased material loss in piping and equipment. Understanding the intricate relationship among the contributing factors such as flow dynamics, environmental factors, and corrosion reactions is essential for developing effective prediction and mitigation strategies. This review discusses the recent advancements in the numerical modeling of FAC using computational fluid dynamics (CFD). The numerical models presented show abilities to predict FAC profiles across multiple power plant components, and a review was conducted on the evaluation of these predictions with experimental measurements. Notably, increased turbulence in the flow significantly contributed to prediction errors, emphasizing the need for advanced turbulence models in numerical simulations of FAC. Addressing these challenges is crucial for maintaining sustainable infrastructure and reducing industrial risks through enhanced predictive maintenance strategies.</p></div>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 3","pages":"368-385"},"PeriodicalIF":1.6,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143555202","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}