{"title":"Contents: Materials and Corrosion. 8/2024","authors":"","doi":"10.1002/maco.202470083","DOIUrl":"10.1002/maco.202470083","url":null,"abstract":"","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 8","pages":"946-949"},"PeriodicalIF":1.6,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202470083","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141947246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Masthead: Materials and Corrosion. 8/2024","authors":"","doi":"10.1002/maco.202470082","DOIUrl":"10.1002/maco.202470082","url":null,"abstract":"","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 8","pages":"945"},"PeriodicalIF":1.6,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202470082","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141947249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Maria Asuncion Valiente Bermejo, Alice Moya Núñez, Rikard Norling
{"title":"Cover Picture: Materials and Corrosion. 8/2024","authors":"Maria Asuncion Valiente Bermejo, Alice Moya Núñez, Rikard Norling","doi":"10.1002/maco.202470081","DOIUrl":"10.1002/maco.202470081","url":null,"abstract":"<p><b>Cover:</b></p><p>SEM-EDS analysis of edge section of tube # 9 (Kanthal ® APMT). A type of grain boundary related attack is observed in this specimen. The bright spots correspond to RE elements.</p><p>More detailed information can be found in: <i>Maria Asuncion Valiente Bermejo, Alice Moya Núñez, Rikard Norling</i>, Metal loss and corrosion attack of FeCrAl overlay welds on evaporator tube shields of a waste-fi red power plant, <i>Materials and Corrosion</i> <b>2024</b>, <i>75</i>, 950.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 8","pages":"943"},"PeriodicalIF":1.6,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202470081","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141947248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fang Cao, Alexander Donchev, Mathias Galetz, Michael Myers, Ning Ma, Charlie Chun
{"title":"Effect of CO on the corrosion behavior of 304 stainless steel in wet CO2 gas at 710°C","authors":"Fang Cao, Alexander Donchev, Mathias Galetz, Michael Myers, Ning Ma, Charlie Chun","doi":"10.1002/maco.202414312","DOIUrl":"10.1002/maco.202414312","url":null,"abstract":"<p>The corrosion behavior of 304 stainless steel in wet CO<sub>2</sub> gas with or without CO and CO plus 400 ppmv SO<sub>2</sub> was investigated in this study. Corrosion kinetics was studied by thermogravimetric analysis at 710°C for 100 h under three gas conditions. After isothermal exposure, the corroded coupons were characterized in detail by X-ray diffraction, scanning electron microscopy, an electron probe microanalyzer, and transmission electron microscopy. CO addition to wet CO<sub>2</sub> resulted in lower oxygen partial pressure and lower oxide growth kinetics. It also suppressed iron-rich oxide nodule formation, as compared to the wet CO<sub>2</sub> gas environment. A Cr-depletion zone was observed underneath the oxide scale in the substrate, but no obvious internal carburization was observed in all three gas environments. A thin, protective oxide scale consisting of an outer layer of a Cr-rich spinel and an inner Cr-rich chromia layer was developed in CO-containing gas conditions, with or without SO<sub>2</sub>. The effect of CO on oxidation and scale formation is discussed in comparison with that in wet CO<sub>2</sub> conditions.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 12","pages":"1652-1660"},"PeriodicalIF":1.6,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202414312","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141869950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Suzue Yoneda, Takashi Kogin, Eiji Ishikawa, So Murasue, Shigenari Hayashi
{"title":"Effect of Fe addition on corrosion behavior of Ni–xFe–5Cr alloys at 570°C in air containing salt vapor","authors":"Suzue Yoneda, Takashi Kogin, Eiji Ishikawa, So Murasue, Shigenari Hayashi","doi":"10.1002/maco.202414399","DOIUrl":"10.1002/maco.202414399","url":null,"abstract":"<p>The high-temperature corrosion behavior of Ni–<i>x</i>Fe–5Cr alloys (<i>x</i> = 0, 10, or 30 wt.%) was investigated in air containing alkali salt vapor at 570°C to clarify the effect of Fe on the corrosion resistance. Fe addition to Ni–5Cr was found to improve the corrosion resistance under the present conditions. In the case of Ni–5Cr, NiCl<sub>2</sub> was formed beneath the NiO scale during the initial stage of corrosion, and it grew thicker over time and then evaporated. The formation and evaporation of NiCl<sub>2</sub> resulted in a porous scale that underwent spallation resulting in mass loss. In the Fe-containing alloys, (Fe, Ni, Cr)<sub>3</sub>O<sub>4</sub> spinel and Fe<sub>3</sub>O<sub>4</sub> decreased the partial pressures of oxygen and chlorine and thus prevented the generation of NiO and NiCl<sub>2</sub>, leading to superior corrosion resistance compared with Ni–5Cr.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 12","pages":"1628-1638"},"PeriodicalIF":1.6,"publicationDate":"2024-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141869951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kateřina Kolomá, Václava Havlová, Anna Pecková, Šárka Šachlová, Vlastislav Kašpar, Diana Tkachenok, Alžběta Danielisová, Drahomíra Malyková, Helena Březinová, Ludmila Barčáková, Saqib Mukhtar, Richard Bureš, Jan Stoulil
{"title":"Archaeological analogues for the lifetime prediction of the canister for spent nuclear fuel in the deep geological repository: Part I. Composition of pore water and corrosion products","authors":"Kateřina Kolomá, Václava Havlová, Anna Pecková, Šárka Šachlová, Vlastislav Kašpar, Diana Tkachenok, Alžběta Danielisová, Drahomíra Malyková, Helena Březinová, Ludmila Barčáková, Saqib Mukhtar, Richard Bureš, Jan Stoulil","doi":"10.1002/maco.202414516","DOIUrl":"10.1002/maco.202414516","url":null,"abstract":"<p>This work focuses on archaeological analogues as a way of obtaining long-term data for assessing the lifetime of a spent nuclear fuel canister. An analysis of the environment around the excavated artefacts is presented, followed by geochemical modelling of the likely corrosion products and subsequent comparison with real phases in the corrosion layer estimated by X-ray diffraction. A total of 16 archaeological sites with fine clay soils and the potential for long-term flooding were evaluated. Although the soil pore solution contained high levels of silicates, no such phases with iron in the corrosion products were confirmed. Carbonate corrosion products, typical of bentonite environments, were also not observed. Although oxygen access is very limited in the environments of all sites, even low concentrations shifted the equilibrium of corrosion products formed in favour of (hydroxy)oxides.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 1","pages":"137-154"},"PeriodicalIF":1.6,"publicationDate":"2024-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141784166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Preparation and characterisation of black conversion coating of Cr(NO3)3–CoCl2–NiCl2 of Zn–Ni alloy electroplated on 2024 aluminium alloy surface","authors":"Tingyi Chen, Qiming Huang, Hongtao Zhu, Yaqi Ma","doi":"10.1002/maco.202414414","DOIUrl":"10.1002/maco.202414414","url":null,"abstract":"<p>To meet the application requirements of electronic connectors, a trivalent chromium process (TCP) conversion coating was prepared on the Zn–Ni alloy plating of 2024 aluminium alloy. The composition of the TCP solution was as follows: 45 g/L Cr(NO<sub>3</sub>)<sub>3</sub>, 14 g/L CoCl<sub>2</sub>, 1.3 g/L NiCl<sub>2</sub>, 10 g/L citric acid, 10 g/L succinic acid and 1 g/L sodium dodecyl sulphate. The properties of TCP were characterised by a range of techniques, including macroscopic observations, scanning electron microscope, energy-dispersive X-ray spectrometer, three-dimensional (3D) morphometry, electrochemical impedance spectroscopy, polarisation curves and conductivity tests. The TCP prepared in this experiment exhibits a uniform black colour and bright appearance, predominantly composed of Zn, Ni, O, Cr and Co. The TCP enhances the impedance of Zn–Ni alloys, reduces the corrosion current to 1.99 × 10<sup>−5 </sup>A/cm<sup>2</sup> and maintains a flatter surface 3D morphology and less surface roughness following electrochemical testing. It has better corrosion resistance. Following the preparation of the TCP on a suitably sized shell sample, the shell resistance was 1.2 mVDC with good electrical conductivity, which meets the requirements for electrical connector applications.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 11","pages":"1463-1471"},"PeriodicalIF":1.6,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141743157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Isehaq Al-Nafai, Katarzyna Rzeszutek, Stuart Lyon, Christopher Jones, Douglas Beaumont
{"title":"How aluminium additions improve the performance of zinc-rich organic coatings","authors":"Isehaq Al-Nafai, Katarzyna Rzeszutek, Stuart Lyon, Christopher Jones, Douglas Beaumont","doi":"10.1002/maco.202414529","DOIUrl":"10.1002/maco.202414529","url":null,"abstract":"<p>Novel sacrificial zinc-rich organic coatings, with varying additions of aluminium, were prepared and tested for anticorrosion performance. Electrochemical measurements (potential vs. time and electrochemical impedance spectroscopy) were carried out to investigate cathodic protection and barrier performance while neutral salt spray and immersion experiments tested long-term performance. Analytical scanning electron microscopy and X-ray diffraction were used to characterize coatings before and after testing. Formulations containing aluminium significantly outperformed the standard 100% zinc-rich coating with the greatest improvement occurring at 10%–15% aluminium by volume in the dry film. This improvement was caused by the dispersal of aluminium between zinc particles, which improved packing and enabled greater efficiency in zinc consumption resulting in extended galvanic protection times for steel substrates. The expected zinc corrosion product (basic zinc chloride, simonkolleite) was present within the coating as well as a Zn–Al layered doubled hydroxide. The latter's presence demonstrates that dissolution of aluminium contributed to the longevity of the galvanic action. The new Zn–Al formulations are extremely promising alternatives to standard zinc-rich epoxy coatings, significantly reducing zinc loading and increasing the sacrificial lifetime.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 1","pages":"53-70"},"PeriodicalIF":1.6,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202414529","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141743162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Michael Schneider, Ulrike Langklotz, Laurence Kühne, Claudia Kutzer-Schulze
{"title":"Influence of mechanical grinding on the formation of native passive layers on aluminum alloys","authors":"Michael Schneider, Ulrike Langklotz, Laurence Kühne, Claudia Kutzer-Schulze","doi":"10.1002/maco.202414503","DOIUrl":"10.1002/maco.202414503","url":null,"abstract":"<p>Mechanical grinding creates mechanical as well as thermal stress in treated material and the so-called Beilby layer is formed. The present work investigates the influence of abrasive coarse grain size on the thickness and electrochemical behavior of the native oxide layer formed after the grinding process by using cyclovoltammetry. The difference in the native oxide layer thickness amounts to Δ<i>d</i> ≈ 0.5 nm under the surface conditions investigated. Additionally, an experimental design is introduced and tested, which allows the <i>operando</i> measuring of the temperature of the material during the grinding process. Estimates result in a thermal stress Δ<i>σ</i> between 0.8 and 1.3 MPa depending on the chosen grinding parameters and influence the subsequently formed oxide layer thickness.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"76 1","pages":"43-52"},"PeriodicalIF":1.6,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/maco.202414503","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141743160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Accelerated microbiologically influenced corrosion of copper by sulfate-reducing bacterium Desulfovibrio desulfovibrio","authors":"Lijuan Chen, Jialin Li, Bo Wei, Jin Xu, Cheng Sun","doi":"10.1002/maco.202414451","DOIUrl":"10.1002/maco.202414451","url":null,"abstract":"<p>The corrosion behavior and electrochemical damage mechanisms induced by sulfate-reducing bacteria (SRB) on copper (Cu) were investigated in this study. Electrochemical impedance spectroscopy revealed that SRB accelerated the corrosion of Cu, albeit with a mitigating effect observed due to the formation of a protective and dense biofilm. However, upon the rupture of this protective film, the corrosion tendency of Cu significantly increased. Surface analysis corroborated these findings, with the predominant corrosion product identified as Cu2S, a result further supported by thermodynamic calculations. The accelerated corrosion of Cu was primarily attributed to the physiological metabolism of SRB, which generates hydrogen sulfide as the principal agent driving corrosion processes.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 11","pages":"1495-1505"},"PeriodicalIF":1.6,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141743159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}