Macromolecular Materials and Engineering最新文献_第8页

Quantification of Airborne Concentrations of Nanoscale Dusts by Particle Gravimetry Using Ionic-Liquid Modified Polymeric Electrospun Fibers 利用离子液体改性聚合物电纺纤维的粒子重力测量法量化空气中的纳米级粉尘浓度

IF 4.2 3区材料科学

Macromolecular Materials and Engineering Pub Date : 2024-05-23 DOI: 10.1002/mame.202400062

Zeki Tok, Kadriye Ertekin

{"title":"Quantification of Airborne Concentrations of Nanoscale Dusts by Particle Gravimetry Using Ionic-Liquid Modified Polymeric Electrospun Fibers","authors":"Zeki Tok, Kadriye Ertekin","doi":"10.1002/mame.202400062","DOIUrl":"10.1002/mame.202400062","url":null,"abstract":"In this work, functional polymeric filters are prepared by electrospinning using four different non-ionic polymers or their blends together with deliberately selected additives, and then tested for quantification of the nano-sized powders. Particle gravimetry is used for the quantitative determination of the dusts. Validation studies are carried out using the ICP-OES technique. The polymeric fibers prepared with different contents consist of PS/PMMA, PVDF/EC/PMMA, chitosan, chitosan/PMMA and PMMA/PVDF, respectively. The ionic liquids of tetra-n-butylammonium tetrafluoroborate, 1-ethyl-3-methylimidazolium hexafluorophosphate and hexadecyltrimethylammonium bromide are used as additives for the preparation of the functional polymeric fibers. The prepared nanoscale dusts and electrospun fibers are characterized by SEM, XRD, XPS, and size distribution analysis techniques, respectively. Among them, the CTAB-modified chitosan fibers exhibit the highest dust retention efficiency. This study introduces a new approach to the quantification of nano-sized powders. In addition, it is concluded that the proposed method can be used in pre-concentration before testing, cleaning powders from the working environment and quantitative analysis of nanoscale powders. The presented materials can also be used to improve indoor air quality and potential worker exposure in workplaces.","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":"309 7","pages":""},"PeriodicalIF":4.2,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202400062","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141103698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Review on Processing, Flame-Retardant Properties, and Applications of Polyethylene Composites with Graphene-Based Nanomaterials 石墨烯基纳米材料聚乙烯复合材料的加工、阻燃性能和应用综述

IF 4.2 3区材料科学

Macromolecular Materials and Engineering Pub Date : 2024-05-23 DOI: 10.1002/mame.202400104

Lesego Tabea Temane, Suprakas Sinha Ray, Jonathan Tersur Orasugh

{"title":"Review on Processing, Flame-Retardant Properties, and Applications of Polyethylene Composites with Graphene-Based Nanomaterials","authors":"Lesego Tabea Temane, Suprakas Sinha Ray, Jonathan Tersur Orasugh","doi":"10.1002/mame.202400104","DOIUrl":"10.1002/mame.202400104","url":null,"abstract":"This paper presents recent developments in graphene-based nanomaterial (GNM)-containing flame-retardant (FR) polyethylene (PE) composites for advanced applications and introduces knowledge gaps and potential solutions. Various nanomaterials have been used to improve the FR properties of PEs. Among these, GNMs score highly because of their superior performance and multifunctional characteristics. By offering a holistic overview of the fundamentals of the FR characteristics of GNMs, the processing and characterization of PE/GNM composites, and the critical aspects related to the development of FR PE/GNM composites for advanced applications, this review provides insights into advances in this area as well as prospects. Furthermore, the kinetics of the FR characteristics of PE and PE/GNM composites are critically discussed in the context of how the FR properties of PE/GNM composites can be tailored by modifying either the surface of the GNM, PE or both, an area seldom discussed in the literature. Moreover, the FR performance of PE/GNM composites is compared with PE/Expandable Graphite (EG) composites because EG has been recognized as a highly efficient and eco-friendly intumescent FR. In summary, this review offers new insights into the design of advanced PE/GNM composites for automotive, construction, aerospace, and electronic packaging applications.","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":"309 8","pages":""},"PeriodicalIF":4.2,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202400104","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141106614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design and Fabrication of Fibrous Spindle-Like Constructs Using a Melt Electrohydrodynamic Writing Process 利用熔体电流体动力写入工艺设计和制造纤维状纺锤形构件

IF 4.2 3区材料科学

Macromolecular Materials and Engineering Pub Date : 2024-05-20 DOI: 10.1002/mame.202400080

Ahmadreza Zaeri, Kai Cao, Fucheng Zhang, Ralf Zgeib, Robert C. Chang

{"title":"Design and Fabrication of Fibrous Spindle-Like Constructs Using a Melt Electrohydrodynamic Writing Process","authors":"Ahmadreza Zaeri, Kai Cao, Fucheng Zhang, Ralf Zgeib, Robert C. Chang","doi":"10.1002/mame.202400080","DOIUrl":"10.1002/mame.202400080","url":null,"abstract":"Advanced manufacturing of 3D-structured materials enables the production of biomimetic muscle tissues. While models of muscle tissue exist, current approaches possess a limited ability to capture essential elements of the muscle tissue microarchitecture. Therefore, this paper aims to engineer the intrinsically complex muscle spindle-like ellipsoid geometry using a polymer melt-based electrohydrodynamic (EHD) printing system. EHD systems have conventionally reported fiber deposition in a layerwise fashion. However, without mitigation, the observed fiber sagging and residual charge phenomena for the melt electrowriting (MEW) process limit the ability to produce layered fibrous 3D constructs with in-plane fiber alignment. However, in this work, fiber sagging and residual charge phenomena are leveraged as part of the design intent to deposit nonoverlapping suspended fibers between two stationary walls toward spindle-like construct fabrication. Specifically, herein the structural and mechanical properties of the MEW-enabled spindle-like constructs are analyzed as a function of the process and design parameters that govern control over fiber sagging and residual charge. The results indicate that the collector speed and wall-to-wall distance are the key parameters for tuning the spindle morphology. Moreover, cycle number and fiber diameter are identified as effective parameters for tuning the spindle mechanical properties.","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":"309 11","pages":""},"PeriodicalIF":4.2,"publicationDate":"2024-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202400080","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141122551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Masthead: Macromol. Mater. Eng. 5/2024 刊头：Macromol.Mater.Eng.5/2024

IF 3.9 3区材料科学

Macromolecular Materials and Engineering Pub Date : 2024-05-16 DOI: 10.1002/mame.202470010

引用次数: 0

Ion-Mediated Gelation of Thermo-Responsive Cellulose Nanofibril/Poly(N-isopropylacrylamide) Hybrid Hydrogels with Tunable De-Swelling Kinetics 离子介导的热响应性纤维素纳米纤维/聚（N-异丙基丙烯酰胺）混合水凝胶的可调谐溶胀动力学

IF 4.2 3区材料科学

Macromolecular Materials and Engineering Pub Date : 2024-05-16 DOI: 10.1002/mame.202300457

Bennie Motloung, Rueben Pfukwa, Bert Klumperman

{"title":"Ion-Mediated Gelation of Thermo-Responsive Cellulose Nanofibril/Poly(N-isopropylacrylamide) Hybrid Hydrogels with Tunable De-Swelling Kinetics","authors":"Bennie Motloung, Rueben Pfukwa, Bert Klumperman","doi":"10.1002/mame.202300457","DOIUrl":"10.1002/mame.202300457","url":null,"abstract":"The tunability of the lower critical solution temperature (LCST) of poly(N-isopropylacrylamide) (PNIPAM) to lower or higher temperatures, as well as the ease of modulation of the LCST phase transition kinetics broadens the scope of application of PNIPAM-based materials in biomedical fields. This work reports a facile approach to formulate a smart, injectable cellulose nanofibril (CNF)/PNIPAM hybrid gel. Hofmeister salts are used to induce ion-mediated gelation of the nanofibrils and PNIPAM chains, resulting in an interpenetrating network (IPN) structure. From rheological measurements, the hybrid material displays excellent structural integrity at room temperature and tunable thermo-stiffening around body temperature. De-swelling kinetics can be modulated by varying the nature and concentration of the Hofmeister ion used. The successful realization of the IPN hybrid gel structure is dependent on the molecular weight of PNIPAM used. Moreover, the hybrid gels show good thermo-reversibility during thermal cycling, as well as excellent injectability and remarkable self-healing post-injection, owing to shear-thinning and thixotropic characters. Since rheology is a crucial technique in the analysis of soft matter and flow behavior is fundamental for the design and synthesis of application-specific viscoelastic materials, the work reported herein provides a rheological basis for careful design and synthesis of smart gels.","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":"309 8","pages":""},"PeriodicalIF":4.2,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202300457","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140967112","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High Power Sunlight-Simulated UV-Induced Radical Polymerization: Self-Initiation and Self-Crosslinking 大功率太阳光模拟紫外线诱导的自由基聚合：自引发和自交联

IF 3.9 3区材料科学

Macromolecular Materials and Engineering Pub Date : 2024-05-16 DOI: 10.1002/mame.202470009

Wenqing Yan, Jimena de la Vega, Özen Eroğlu, Lavinia Heisenberg, Deyi Wang

引用次数: 0

Advancing Surface-Enhanced Electrospun Nanofiber Membranes: Customizing Properties for Enhanced Performance in Membrane Distillation 推进表面增强电纺纳米纤维膜：定制特性以提高膜蒸馏性能

IF 4.2 3区材料科学

Macromolecular Materials and Engineering Pub Date : 2024-05-14 DOI: 10.1002/mame.202300461

Michaela Olisha S. Lobregas, Ratthapol Rangkupan, David Riassetto, Chalida Klaysom

{"title":"Advancing Surface-Enhanced Electrospun Nanofiber Membranes: Customizing Properties for Enhanced Performance in Membrane Distillation","authors":"Michaela Olisha S. Lobregas, Ratthapol Rangkupan, David Riassetto, Chalida Klaysom","doi":"10.1002/mame.202300461","DOIUrl":"10.1002/mame.202300461","url":null,"abstract":"Electrospun nanofiber membranes (ENMs) have emerged as a cutting-edge solution for membrane distillation (MD), recognized for their highly porous and interconnected architecture. This distinctive structure enables them to offer minimal mass transfer resistance, making them exceptionally suited for high-efficiency membrane-based separation processes. However, the very porosity that defines their strength also renders them vulnerable to fouling, scaling, and wetting during operation, which in turn compromises their performance. Current research efforts are geared toward overcoming these obstacles by refining the surface design and characteristics of ENMs. This review delves into the latest advancements in surface-enhanced electrospun nanofiber membranes tailored for MD applications. It discusses the existing gaps in research and provides forward-looking insights into the future of ENMs, spotlighting the development of membranes with precisely tunable surface attributes for optimized performance.","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":"309 7","pages":""},"PeriodicalIF":4.2,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202300461","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140981259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Experimental Evaluation of Mechanical Properties, Thermal Analysis, Morphology, Printability, and Shape Memory Performance of the Novel 3D Printed PETG-EVA Blends 对新型 3D 打印 PETG-EVA 混合物的机械性能、热分析、形态、可打印性和形状记忆性能的实验评估

IF 4.2 3区材料科学

Macromolecular Materials and Engineering Pub Date : 2024-05-14 DOI: 10.1002/mame.202400069

Saeed J. A. Ali, Davood Rahmatabadi, Mostafa Baghani, Majid Baniassadi

{"title":"Experimental Evaluation of Mechanical Properties, Thermal Analysis, Morphology, Printability, and Shape Memory Performance of the Novel 3D Printed PETG-EVA Blends","authors":"Saeed J. A. Ali, Davood Rahmatabadi, Mostafa Baghani, Majid Baniassadi","doi":"10.1002/mame.202400069","DOIUrl":"10.1002/mame.202400069","url":null,"abstract":"Polyethylene terephthalate glycol (PETG) is a novel amorphous shape memory polymer with excellent printability for 4D printing. In this article, ethylene-vinyl acetate (EVA) is used as a biocompatible and non-toxic copolymer to improve plasticity and shape memory performance of PETG. PETG-EVA blends are prepared and 3D printed using a melt mixing method and an upgraded fused deposition modeling (FDM) with a pneumatic feeding system. The results of the thermal analysis show that the blends exhibit two tan-delta peaks, each related to their components, and morphology images confirm that they are biphasic and immiscible with good compatibility. The morphology of both EVA10 and EVA30 matrix droplets is observed, with the droplets being larger for EVA30. The use of a pneumatic feeding system, along with the ability to control the output melt flow, results in the best printing ability for EVA30, with minimal microholes between the grids and interlayer cracks. The tensile strength of PETG-EVA blends ranged from 25.38 to 20.14 MPa, with the highest tensile strength achieved for EVA30. The shape memory performance of all three blends is similar; with shape recovery exceeding 90% in 20 s. Blends with higher EVA content exhibited faster shape recovery within the first 10 s.","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":"309 10","pages":""},"PeriodicalIF":4.2,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202400069","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140981850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Simulation-Guided Design of Gradient Multilayer Microwave Absorber with Tailored Absorption Performance 仿真引导设计具有定制吸收性能的梯度多层微波吸收器

IF 4.2 3区材料科学

Macromolecular Materials and Engineering Pub Date : 2024-05-11 DOI: 10.1002/mame.202400015

Ye Wang, Chunzheng Lv, Xuan Zhang, Xingang Liu, Chuhong Zhang

{"title":"Simulation-Guided Design of Gradient Multilayer Microwave Absorber with Tailored Absorption Performance","authors":"Ye Wang, Chunzheng Lv, Xuan Zhang, Xingang Liu, Chuhong Zhang","doi":"10.1002/mame.202400015","DOIUrl":"10.1002/mame.202400015","url":null,"abstract":"Flexible microwave absorber (MAR), vital in advanced applications such as wearable electronics and precision devices, are highly valued for their lightweight, exceptional electromagnetic waves (EWs), and ease of fabrication. However, optimizing the electromagnetic parameters of microwave absorption materials (MAMs) to enhance absorption ability and expand effective absorption broadband (EAB, reflection loss (RL) <−10 dB) is a considerable challenge. Herein, a permittivity-attenuation evaluation diagram (PAED) is constructed using parameter scanning based on the Materials Genome Initiative to determine the ideal electromagnetic parameters and thickness, optimize absorption efficiency, and obtain highly efficient absorbers. Guided by the PAED, a multilayer MAR consisting of a “matching-absorption-reflection layer” and a dielectric loss gradient aligned with the direction of EWs propagation is developed. This design significantly enhances the EWs penetration and ensures effective absorption, attributed to the well-matched impedance and attenuation characteristics. As anticipated, the microwave absorption of the absorber (density = 0.063 g cm−3) is optimized, with an RL of −34 dB at d = 4 mm and an EAB covering the entire X-band (8.2–12.4 GHz). This study presents a novel approach for establishing a material database for MAMs and developing high-performance absorbers characterized by thinness, lightness, broad operational frequency range, and robust absorption capacity.","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":"309 9","pages":""},"PeriodicalIF":4.2,"publicationDate":"2024-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202400015","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140928592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design of Reversible Adhesives by Using a Triple Function of Ionic Liquids 利用离子液体的三重功能设计可逆粘合剂

IF 4.2 3区材料科学

Macromolecular Materials and Engineering Pub Date : 2024-05-02 DOI: 10.1002/mame.202400011

Florian Wanghofer, Matthias Kriehuber, David Reisinger, Florian Floh, Markus Wolfahrt, Sandra Schlögl

{"title":"Design of Reversible Adhesives by Using a Triple Function of Ionic Liquids","authors":"Florian Wanghofer, Matthias Kriehuber, David Reisinger, Florian Floh, Markus Wolfahrt, Sandra Schlögl","doi":"10.1002/mame.202400011","DOIUrl":"10.1002/mame.202400011","url":null,"abstract":"Reversible adhesives are crucial for a circular economy of composites as they play a key role for rework, repair, and recycling of adhesively bonded components. Herein, electrically debondable adhesives are prepared by introducing ionic liquids in dynamic thiol–epoxy networks. The function of the ionic liquid in the networks is threefold as it accelerates the curing reaction between thiol and epoxy monomers, facilitates electrical debonding, and catalyzes thermoactivated transesterification reactions, required for rebonding at elevated temperature. A library of 1,3-dibutylimidazolium-based ionic liquids with varying anions is synthetized and it is found that 1,3-dibutyl-1H-imidazol-3-ium dicyanamide (DiButIm─N(CN)2) is superior in accelerating bond-exchange reactions between hydroxy and ester moieties at elevated temperature. Thus, a thiol–epoxy resin containing 20 wt% of DiButIm─N(CN)2 is used to impregnate glass fiber mats yielding adhesive connections for aluminum substrates with 10.2 MPa pull-off strength. The adhesive connections are successfully debonded at the metal–adhesive interface by applying 120 V. The samples are then rebonded via the thermoactivated change in the networks’ viscoelastic properties and ≈80% (8.1 MPa) of their original bond strength can be regained. By providing a simple strategy to synthetize reversible adhesives, this approach paves a way toward improved recyclability and repairability of adhesively bonded structures.","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":"309 9","pages":""},"PeriodicalIF":4.2,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202400011","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140828307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0