Macromolecular Symposia最新文献

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Rapid Prototyping Process of Aerodynamic Components for a UAV 无人机气动部件快速成型工艺研究
Macromolecular Symposia Pub Date : 2025-06-18 DOI: 10.1002/masy.70041
Serafim Muntean, Sebastian Pop, Gheorghe Oancea
{"title":"Rapid Prototyping Process of Aerodynamic Components for a UAV","authors":"Serafim Muntean,&nbsp;Sebastian Pop,&nbsp;Gheorghe Oancea","doi":"10.1002/masy.70041","DOIUrl":"https://doi.org/10.1002/masy.70041","url":null,"abstract":"<p>The paper presents an application of the rapid prototyping process of the aerodynamic fiberglass and carbon fiber element for aeronautical vehicle systems without pilots, whose mold is made of extruded polyester foam or expanded polyester by hot wire cutting process. To manufacture an aerodynamic fiber element, usually a mold is required. In the case of traditional manufacturing or in the case of rapid manufacturing of a fiberglass and/or carbon fiber wing or empennage, both processes consist of layering the fiber and resin and polymerizing it in a mold, then finishing, painting, and coating, if necessary, with a protective layer. The traditional manufacturing of mold for the fiberglass or carbon fiber wing is expensive depending on the material used and is a time-consuming process. The process presented in the paper has a working time of 8 h in laboratory conditions for obtaining an aerodynamical element with dimensions up to 1000 × 500 × 300. This would mean a much shorter time to manufacture a mold compared to the obtaining of a mold for series, which can take from several weeks to several months. In the article, the steps of the rapid manufacturing of an aerodynamic element are described, and its practical implementation is discussed in detail. A comparison is made between the traditional process and the proposed rapid manufacturing process.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparison of Native and Modified Biopolymer Blends and Their Potential as Sustained Delivery System for Tolfenamic Acid 天然和改性生物聚合物共混物的比较及其作为甲苯胺酸持续递送系统的潜力
Macromolecular Symposia Pub Date : 2025-06-18 DOI: 10.1002/masy.70032
Sofia Milenkova, Asya Viraneva, Maria Marudova
{"title":"Comparison of Native and Modified Biopolymer Blends and Their Potential as Sustained Delivery System for Tolfenamic Acid","authors":"Sofia Milenkova,&nbsp;Asya Viraneva,&nbsp;Maria Marudova","doi":"10.1002/masy.70032","DOIUrl":"https://doi.org/10.1002/masy.70032","url":null,"abstract":"<p>Biocompatible and biodegradable polymers are becoming more and more attractive and desired platforms for the development of novel and composite materials. However, some of them are naturally insoluble in water, which is their main drawback and affects their whole behavior. To address this problem and make them porous and, therefore, more hydrophilic, different approaches have been proposed, such as plasma treatment, etching, and chemical modification. The present study is focused on the potential of poly (ethylene glycol) as pore-forming in casted films made out of poly(lactic acid), poly(ε-caprolactone), and their blends at three different ratios. These porous films were compared with the same blends but without modification. The effect of poly (ethylene glycol) on the general mechanical properties as Young modulus, load, stress, and strain at upper yield was evaluated. Additionally, the influence of the formed pores and the ability of the films to get charged was established, as they were corona treated with positive and negative polarity. After this treatment, all of the developed variations were used as a base for multilayer film formation between chitosan and casein. The release profiles out of the as formed layer-by-layer structures for active compound (tolfenamic acid) were investigated.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of 3D Printing Parameters For The Fabrication of Kinematic Elements In Mono-Mobile Robot Design 单移动机器人运动部件3D打印参数优化研究
Macromolecular Symposia Pub Date : 2025-06-18 DOI: 10.1002/masy.70049
Ileana Dugăeșescu, Angela-Miruna Neacșu-Pavel, Constantin Opran, Nicolae Tunsoiu, Cristian-Vasile Doicin
{"title":"Optimization of 3D Printing Parameters For The Fabrication of Kinematic Elements In Mono-Mobile Robot Design","authors":"Ileana Dugăeșescu,&nbsp;Angela-Miruna Neacșu-Pavel,&nbsp;Constantin Opran,&nbsp;Nicolae Tunsoiu,&nbsp;Cristian-Vasile Doicin","doi":"10.1002/masy.70049","DOIUrl":"https://doi.org/10.1002/masy.70049","url":null,"abstract":"<p><b>Summary</b>: The paper presents a comprehensive analysis of the Ultimaker S5 3D printer and its application in industrial environments. A systematic approach was employed to identify the most important features and parameters influencing the performance and efficiency of the printer. This involved analyzing its material compatibility to understand how these factors contribute to high quality prints. Critical parameters such as print speed, layer height, infill density, and material usage were studied to determine their impact on cost and durability. Various infill patterns and materials, including ABS, PLA, and PET-G were examined to optimize the printing process for both prototyping and functional part production. A multidisciplinary approach integrating mechanical properties, material science and production efficiency was used to assess the strengths and weaknesses of different parameters. The main considerations include material selection, print duration and cost, with particular focus on balancing strength and speed. The study proposes an optimized framework for utilizing the Ultimaker S5 in industrial applications, offering insights into how its advanced features can be leveraged to produce functional, durable, and cost-effective parts across sectors like academic, healthcare, aerospace, and automotive industries.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Buckling Behavior Of Tubular Parts Made of Polylactic Acid 聚乳酸管状件的屈曲行为
Macromolecular Symposia Pub Date : 2025-06-18 DOI: 10.1002/masy.70054
Adelina Hrițuc, Elisaveta Crăciun, Liviu Andrușcă, Andrei Marius Mihalache, Margareta Coteață, Vasile Ermolai, Gheorghe Nagîț, Laurențiu Slătineanu
{"title":"Buckling Behavior Of Tubular Parts Made of Polylactic Acid","authors":"Adelina Hrițuc,&nbsp;Elisaveta Crăciun,&nbsp;Liviu Andrușcă,&nbsp;Andrei Marius Mihalache,&nbsp;Margareta Coteață,&nbsp;Vasile Ermolai,&nbsp;Gheorghe Nagîț,&nbsp;Laurențiu Slătineanu","doi":"10.1002/masy.70054","DOIUrl":"https://doi.org/10.1002/masy.70054","url":null,"abstract":"<p>The development of 3D printing technologies allows the production of bars made of polymeric materials with equal areas of annular cross-sections. In this way, it becomes possible to establish a better justified determination of the dimensions of the cross-sections of the parts subject to buckling, for the same consumption of material required for the manufacture of the parts. The actual values of the stresses at which the tubular test samples of polymeric material fail are determined by experimental compression tests of the bars, carried out on a universal tensile-compression testing machine. The results are mathematically processed allowing the determination of a mathematical model that highlights the intensity of the influence exerted by the diametral dimensions of the cross-sections of equal areas on the buckling yield stress values in the case of tubular polylactic acid test samples manufactured by 3D printing.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Remanufacturing of Damaged Parts From a UAV 无人机损坏部件的再制造
Macromolecular Symposia Pub Date : 2025-06-18 DOI: 10.1002/masy.70042
MădălinaIoana Blaj, Gheorghe Oancea
{"title":"Remanufacturing of Damaged Parts From a UAV","authors":"MădălinaIoana Blaj,&nbsp;Gheorghe Oancea","doi":"10.1002/masy.70042","DOIUrl":"https://doi.org/10.1002/masy.70042","url":null,"abstract":"<p>In the ever-growing world of unmanned aerial vehicles (UAVs), also known as drones, keeping these machines operational can be a costly endeavor. Replacing damaged parts can be expensive, but a promising solution is emerging: remanufacturing considering additive manufacturing. This article explores the potential of the fused deposition modeling (FDM) process for remanufacturing damaged UAV parts, offering a sustainable and cost-effective approach to drone maintenance, considering also the current European Union Aviation Safety Agency (EASA) regulations. For a particular case, the parts are remanufactured with PET CF15 composite filament and tested for a loading case in the Z direction (vertical direction) in order to compare the behavior of the UAV with the original parts and the remanufactured parts in the original assembly.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
New Food Packaging Material Based on Modified Corn Oil 基于改性玉米油的新型食品包装材料
Macromolecular Symposia Pub Date : 2025-06-18 DOI: 10.1002/masy.70050
Federico Barrino, Giuseppe Mattia Lo Piccolo, Jaume Sempere-Torregrosa, Harrison De La Rosa-Ramírez, Maria Dolores Samper
{"title":"New Food Packaging Material Based on Modified Corn Oil","authors":"Federico Barrino,&nbsp;Giuseppe Mattia Lo Piccolo,&nbsp;Jaume Sempere-Torregrosa,&nbsp;Harrison De La Rosa-Ramírez,&nbsp;Maria Dolores Samper","doi":"10.1002/masy.70050","DOIUrl":"https://doi.org/10.1002/masy.70050","url":null,"abstract":"<p>In this manuscript, we present novel bioplastics, which are completely biodegradable, for their potential use in food packaging to replace fossil-fuel-derived plastic films and slow food degradation due to oxidative processes or microbial contamination. In fact, the work analyzes the influence of modified corn oil as a plasticizing and/or compatibilizing agent in the polylactic acid (PLA) and polyhydroxybutyrate (PHB) blend. The films were obtained thanks to a blown film extruder. The low percentages of epoxidized (EPO) and maleinized (MAL) corn oil have been chosen to ensure the mixability and homogeneous distributions of the oil within the PLA–PHB matrix during processing and in the final films, and to avoid cost increases for the final material compared with the proposed material. The innovative contribution of this manuscript is the use of active films capable of slowing down the deterioration of food in order to avoid the waste of fruit and vegetables. In fact, a large amount of fruits and vegetables are thrown away because the consumer is unable to use them all before spoilage. For this reason, the materials obtained have the ability to wrap the cut and uneaten fruit so that it can be preserved and maintain its integrity over time, thus preventing it from being thrown away and wasted.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144309081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable Utilization of Industrial Waste in Metakaolin-Based Geopolymer Systems 偏高岭土聚合物体系中工业废弃物的可持续利用
Macromolecular Symposia Pub Date : 2025-06-18 DOI: 10.1002/masy.70020
Veronica Viola
{"title":"Sustainable Utilization of Industrial Waste in Metakaolin-Based Geopolymer Systems","authors":"Veronica Viola","doi":"10.1002/masy.70020","DOIUrl":"https://doi.org/10.1002/masy.70020","url":null,"abstract":"<p>The global demand for cement significantly contributes to greenhouse gas emissions and the unsustainable consumption of natural resources. Simultaneously, industrial waste poses disposal challenges and serious environmental and public health risks. This study addresses both issues by exploring the use of metakaolin-based geopolymers to incorporate 20% wt. of three types of industrial wastes: suction dust, red mud, and electro-filter dust. pH and conductivity measurements, along with FT-IR analysis, confirmed successful geo-polymerization. The leaching test revealed that only the geopolymer containing suction dust did not fully immobilize the waste. These analyses also provided insights into the compounds responsible for antibacterial properties, tested against <i>E. coli</i> and <i>S. aureus</i>. Finally, mechanical tests indicated their suitability for construction purposes, with compressive strength values ranging from 37–58 MPa, depending on the waste type.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/masy.70020","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144309083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preface Polcom 2024
Macromolecular Symposia Pub Date : 2025-06-18 DOI: 10.1002/masy.70069
Giuseppe Lamanna, Constantin G. Opran
{"title":"Preface Polcom 2024","authors":"Giuseppe Lamanna,&nbsp;Constantin G. Opran","doi":"10.1002/masy.70069","DOIUrl":"https://doi.org/10.1002/masy.70069","url":null,"abstract":"","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Moisture And Temperature Ageing On htpb Based Propellants Binder htpb基推进剂粘结剂的湿热老化研究
Macromolecular Symposia Pub Date : 2025-06-18 DOI: 10.1002/masy.70051
Théo Evrard, Julien Bonnet, Aude Vandenbroucke, Olivier Castelnau, Emmanuel Richaud
{"title":"Moisture And Temperature Ageing On htpb Based Propellants Binder","authors":"Théo Evrard,&nbsp;Julien Bonnet,&nbsp;Aude Vandenbroucke,&nbsp;Olivier Castelnau,&nbsp;Emmanuel Richaud","doi":"10.1002/masy.70051","DOIUrl":"https://doi.org/10.1002/masy.70051","url":null,"abstract":"<p>This study reports the impact of temperature, oxygen, and humidity ageing on the mechanical properties of a crosslinked hydroxy-terminated polybutadiene (HTPB) network. Its mechanical behavior is described using a classical Mooney-Rivlin model and shows a slight crosslinking reaction possibly due to oxidation of HTPB. Water presence is shown to have negligible effect during ageing and during the post ageing preconditioning step prior to mechanical tests.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/masy.70051","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Macromol. Symp. 414-3 絮凝。计算机协会414 - 3
Macromolecular Symposia Pub Date : 2025-06-18 DOI: 10.1002/masy.70072
{"title":"Macromol. Symp. 414-3","authors":"","doi":"10.1002/masy.70072","DOIUrl":"https://doi.org/10.1002/masy.70072","url":null,"abstract":"","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/masy.70072","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144309063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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