Chenjun Zhang, Xi Zhang, Xiaodan Liu, Yiheng Li, Xiaoqi Wang, Xu Jin, Man Shen, Lanqiong Zhang
{"title":"Modification Study of High-Temperature Resistant Rubber Based on Hydrogenated Nitrile Rubber (HNBR) / Polymide1212 (PA1212) Blend","authors":"Chenjun Zhang, Xi Zhang, Xiaodan Liu, Yiheng Li, Xiaoqi Wang, Xu Jin, Man Shen, Lanqiong Zhang","doi":"10.1002/masy.70085","DOIUrl":"https://doi.org/10.1002/masy.70085","url":null,"abstract":"<div>\u0000 \u0000 <p>Specialty engineering rubber has been put forward with more stringent requirements. In this paper, the material properties and reinforcing effects of several fillers were investigated, and polyamide was selected as the target reinforcing material to modify hydrogenated nitrile butadiene rubber (HNBR) in order to improve the temperature resistance of the system. It was concluded that the mechanical properties of PA1212/HNBR system were better than those of PC/HNBR system at 120°C. The optimum PA1212 additive amount was determined through the mechanical property test and dispersion state observation of the blended system, which proved that the PA1212 reinforcing system significantly improved the heat resistance and mechanical properties of HNBR. The modified HNBR has excellent tensile strength and elasticity, which effectively improves the reliability and service life of the sealing equipment under high temperature conditions, and provides experimental references and theoretical basis for the research and development of high-temperature resistant rubber.</p>\u0000 </div>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144910013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aman Rana, Nancy Jaswal, Sujeet Kumar Chaurasia, Manoj K. Singh, Pramod Kumar
{"title":"Microemulsion Mediated Organically Modified Silica-Based Sensors for Electrocatalysis","authors":"Aman Rana, Nancy Jaswal, Sujeet Kumar Chaurasia, Manoj K. Singh, Pramod Kumar","doi":"10.1002/masy.70096","DOIUrl":"https://doi.org/10.1002/masy.70096","url":null,"abstract":"<div>\u0000 \u0000 <p>Organically modified silica (ORMOSIL) is a class of novel materials that can host a variety of organic and inorganic substrates through chemical modification of silica using organic precursors. Silica-based nanoparticles are widely acknowledged for their structural robustness, resistance to biofouling, ease of synthesis, multimodality, and enhanced storage capacity. Materials composed of an ORMOSIL matrix exhibit enhanced activity in an array of photochemical processes, such as emission and absorption, electrochemical sensitivity, and the ability to sense gases, solvents, pH of solutions, and biomolecules. In this study, ORMOSIL nanoparticles were synthesized by microemulsion method. The formation of the as prepared sample was confirmed by x-ray diffraction analysis, EDS, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Further, the electrochemical activity of prepared materials was characterized by cyclic voltammetry (CV) techniques in different scan rates.</p>\u0000 </div>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144910300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Michele Perrella, Amedeo Di Marco, Matteo Bruno, Enrico Armentani
{"title":"Redesign of Structural Elements of Passenger Seat Based on Circular Economy Principles","authors":"Michele Perrella, Amedeo Di Marco, Matteo Bruno, Enrico Armentani","doi":"10.1002/masy.70063","DOIUrl":"https://doi.org/10.1002/masy.70063","url":null,"abstract":"<p>A product's environmental impact spans its entire lifecycle, from creation to disposal. The circular economy aims to eliminate this impact and resource waste by closing resource flow loops. In this perspective, circular design strategies are essential in achieving this goal. The end-of-life products should allow for easy material separation to enable reintegration into production cycles. In this work, design strategies that favor circularity, such as design for disassembly and design for recovery, were considered. The modular redesign of a passenger vehicle seat armrest was conducted with the purpose to achieve modularity, lightness, comfort improvement, easy maintenance, and reconfigurability of the armrest assembly. Finite element virtual tests were performed by using Ansys Workbench, in order to simulate, respectively, a loading condition according to NF F31-119 standard and an act of vandalism to separate the coupled parts of the new armrest. The results obtained in terms of strength and stiffness of the redesigned train seat armrest were considered satisfactory.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/masy.70063","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144309167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Petronela-Daniela Rusu (Ostahie), Simona-Nicoleta Mazurchevici, Catalin Tampu, Constantin Carausu, Ciprian Dumitru Ciofu, Dumitru Nedelcu
{"title":"Laser Surface Texturing of Biodegradable Polymers","authors":"Petronela-Daniela Rusu (Ostahie), Simona-Nicoleta Mazurchevici, Catalin Tampu, Constantin Carausu, Ciprian Dumitru Ciofu, Dumitru Nedelcu","doi":"10.1002/masy.70053","DOIUrl":"https://doi.org/10.1002/masy.70053","url":null,"abstract":"<p>Surface modification through forming, micro grooving, micro dimples, and microchannel is known as surface texturing. In addition to other related techniques on the substrate surface, laser and micromachining are used to accomplish this. The surface properties of the Arbofill Fichte biodegradable polymer with four and six passes, hexagonal and square patterns, and laser texturing are presented in this study. The results were focused on surface microscopy and topography of the four textured samples. Based on the acquired results, it is also possible to replace non-biodegradable polymers from other areas of activity.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nicolae Tunsoiu, Andrei Staicu, Daniela Tunsoiu, Mihaela-Elena Ulmeanu, Cristian-Vasile Doicin
{"title":"Optimization of Real-Time Monitoring and Control of Industrial Conveyor Systems Using Vision Automated Identification Methods","authors":"Nicolae Tunsoiu, Andrei Staicu, Daniela Tunsoiu, Mihaela-Elena Ulmeanu, Cristian-Vasile Doicin","doi":"10.1002/masy.70037","DOIUrl":"https://doi.org/10.1002/masy.70037","url":null,"abstract":"<p>The integration of new technologies such as the internet of things and artificial intelligence in industrial automation represents the next stages of development in industrial engineering. This paper focuses on studying two automated control methods for recognizing a part on an industrial conveyor belt, enabling remote monitoring of the entire belt's operation. The main objective of this study is to monitor and regulate the functioning of a conveyor in a virtual environment by analyzing parameters resulting from the comparison of the two methods. Identifying the primary object on the conveyor and analyzing data in real time are key aspects of the entire process of simulating automation. Developing applications for identifying parts on the industrial conveyor can enhance the speed of real-time information analysis. Upon identifying a missing object or a nonconformity, an alert system notifies the responsible personnel who can take immediate action.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Donato Perfetto, Nima Rezazadeh, Mario Munno, Stefano Beneduce
{"title":"Predicting the Residual Life of Spur Gears Using the SED Method","authors":"Donato Perfetto, Nima Rezazadeh, Mario Munno, Stefano Beneduce","doi":"10.1002/masy.70056","DOIUrl":"https://doi.org/10.1002/masy.70056","url":null,"abstract":"<p>Ensuring sustainability in the industrial sector is a global priority, encompassing environmental, economic, and social dimensions. Achieving this objective requires the development of efficient strategies for product value retention, including numerical finite element (FE) models to predict component life and optimize resource utilization. For spur gears, as an example, accurate FE models are essential to replicate experimental behavior and estimate the number of cycles to failure (<i>N<sub>f</sub></i>) under operational loads. This study applies the local average strain energy density (SED) method to predict the residual life, that is, <i>N<sub>f</sub></i>, of a spur gear under varying operational loads ranging from 68 kN to 95 kN. A systematic approach was adopted: (i) developing geometric and FE model (using 2-D plane strain elements) of the gear to replicate an existing experimental setup, (ii) determining a suitable control radius <i>R</i><sub>0</sub> to define the control volume for SED calculation, and (iii) validating the FE model against experimental data. The use of <i>R</i><sub>0</sub> was instrumental in accurately capturing the energy density distribution, enabling precise residual life predictions. Results showed good agreement between SED values and experimental data, confirming that higher load levels led to increased SED values, which in turn resulted in lower <i>N<sub>f</sub></i>.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/masy.70056","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Recyclable Composite Materials for the Upholstered Furniture Industry","authors":"Cornel Ciupan, Emilia Ciupan, Mihai Ciupan","doi":"10.1002/masy.70039","DOIUrl":"https://doi.org/10.1002/masy.70039","url":null,"abstract":"<p>The furniture industry is one of the world's most important sectors, but due to the scarcity of wood and its high-cost companies have to look for alternatives. Natural fiber composites represent one alternative because many fibrous plants are easy to cultivate and generate high yields. The purpose of this work is to present formulations of materials that use short fibers such as poplar and willow. The paper presents five formulations of composite materials using willow, poplar, and hemp fibers, mixed with thermoplastic fibers, in different percentages. The consolidation in the form of a fibrous layer is done by Carding Airlaid Fusion Technology (CAFT). From the S5 material (20% willow, 20% poplar, 20% hemp, 5% bicomponent, and 35% polypropylene) twelve boards (marked S5.1–S5.12) are thermoformed by setting-up different parameters. This material was characterized, and the results are presented in the paper.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144308860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"3D Printed Materials with Electrical Properties Tailored for Thermal Management","authors":"Marialuigia Raimondo, Francesca Aliberti, Elisa Calabrese, Roberto Pantani, Teresa Rosaria Verde, Andrea Sorrentino, Liberata Guadagno","doi":"10.1002/masy.70030","DOIUrl":"https://doi.org/10.1002/masy.70030","url":null,"abstract":"<p>FDM (fused deposition modeling) 3D-printed parts, based on acrylonitrile butadiene styrene (ABS) with multi-walled carbon nanotubes (MWCNTs), are manufactured to obtain different multi-scale configurations of the internal conductive pathways. By appropriately selecting materials and printing parameters, it is possible to align MWCNTs along the printing direction, leading to an increase of electrical conductivity from 6.88 × 10<sup>−2</sup> S/m before printing to 1.19 × 10<sup>1</sup> S/m of a single printed filament. Consequently, the conductive network arrangement through the sample justifies the higher electrical conductivity parallel to the printing direction (1.22 S/m) than its value perpendicularly measured (7.34 × 10<sup>−2</sup> S/m) in 3D-printed samples. This approach, together with a suitable choice of the electrical contact position, allows controlling the flow of the electrical current, conferring parts the ability to heat up when subjected to an electrical source selectively. This energy-saving strategy can be advantageously applied to print quickly, in a single step, electronic devices, thermistors capable of converting electrical energy into thermal energy, heat exchangers, and electromagnetic interference (EMI) and radio frequency interference (RFI) shielding.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/masy.70030","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144309077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Luigi Vertuccio, Francesca Aliberti, Raffaele Longo, Liberata Guadagno
{"title":"Electrical Behavior of Nanocomposites Exposed to Water Sorption","authors":"Luigi Vertuccio, Francesca Aliberti, Raffaele Longo, Liberata Guadagno","doi":"10.1002/masy.70027","DOIUrl":"https://doi.org/10.1002/masy.70027","url":null,"abstract":"<p>The present study examines the electrical response of nanocomposites to water uptake. Specifically, an electrical signal was employed to detect the amount of water absorbed in a carbon nanotube-based epoxy composite. The investigation focused on changes in the electrical resistance of the composite with a filler content (0.1% by weight) near the electrical percolation threshold. Water penetration results in “non-Fickian” diffusion behavior due to the composite's viscoelastic nature and plasticization effects. The variation in time of the resistance change ratio, similar to that of water absorption, allows associating the electrical resistance measurement for the amount of the absorbed water by the use of a sensitivity factor.</p>","PeriodicalId":18107,"journal":{"name":"Macromolecular Symposia","volume":"414 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144309084","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}