{"title":"Kompleks Besi(II) dengan ligan 3-bpp: review","authors":"F. Fitriani, Djulia Onggo, Irma Mulyani","doi":"10.26874/JKK.V4I1.74","DOIUrl":"https://doi.org/10.26874/JKK.V4I1.74","url":null,"abstract":"The change of two different spin electronic states under the influence of temperature, pressure and light irradiation is known as the Spin Transition or Spin Crossover (SCO) phenomenon. Spin transition exists on octahedral complexes with an intermediate ligand field, one of the ligands is 2,6-bis (pyrazol-3-yl)pyridine or 3-bpp. Spin transition complexes were intensively investigated because they are highly potential candidates for electronic materials, such as sensors, molecular switches and information storages. The iron(II) complex with 3-bpp ligand has shown SCO characteristics including different transition pattern and transition temperature which were influenced by type of the counter anions. The iron(II) complexes with different types of counter anions have exhibited SCO phenomenon, due to the effect of temperature with abrupt transition. However, the presence of hydrate water in the iron(II) complex results in the higher temperature transition. In addition of that, the transition pattern has changed from the abrupt transition into the gradual transition types. Several studies of SCO properties of the complex Fe(II)-3-bpp reported that the transition type and the temperature transition were influenced by the type of counter anion and the amount of hydrate molecules. With various transition patterns and transition temperatures, the potential of Fe(II)-bpp complexes as SCO materials is more interesting to explored. \u0000 \u0000Keywords: Iron(II) Complex, 3-bpp Ligand, Spin Crossover","PeriodicalId":17768,"journal":{"name":"Jurnal Kartika Kimia","volume":"71 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85481857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Sintesis kitosan-lignin dengan reaksi Mannich dan karakterisasinya","authors":"N. T. Berghuis, M. Wahid","doi":"10.26874/JKK.V4I1.77","DOIUrl":"https://doi.org/10.26874/JKK.V4I1.77","url":null,"abstract":"Lignin and chitosan compounds are abundant biopolymers that occur in nature. However, the use aspect of this biopolymer is still very minimal and only becomes waste in the environment. The synthesis of lignin-chitosan using the Mannich reaction can be an alternative to be able to use this waste to become useful material in the future. The chitosan used was commercial chitosan with% DD (percent deacetylation) of 71.57%. The characterization used is FTIR and TGA. The success of lignin-chitosan synthesis is indicated by the appearance of peaks in the FTIR spectrum at wavenumbers 3300 - 3500 cm-1. TGA analysis is used to determine the thermal degradation properties of lignin-chitosan compounds which are thought to be new biopolymer compounds. \u0000 \u0000Keywords: Chitosan, Lignin, Mannich Reaction","PeriodicalId":17768,"journal":{"name":"Jurnal Kartika Kimia","volume":"18 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85084264","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
I. B. Rachman, Hunumi Oktiyani Rusdi, E. Ciptawati, Daratu Eviana Kusuma Puteri, R. Retnosari, Aman Santosa
{"title":"Thermodynamic and Infrared Spectroscopy Analysis of Tert-butyl Chloride and Hydroxide Nucleophilic Substitution Reaction Using Computational Method","authors":"I. B. Rachman, Hunumi Oktiyani Rusdi, E. Ciptawati, Daratu Eviana Kusuma Puteri, R. Retnosari, Aman Santosa","doi":"10.26874/jkk.v3i2.60","DOIUrl":"https://doi.org/10.26874/jkk.v3i2.60","url":null,"abstract":"Reaksi substitusi nukleofilik adalah salah satu reaksi yang penting dan umum dipelajari pada kimia organik. Mekanisme bagaimana reaksi sebenarnya berlangsung dan spesi apa yang berperan pada sistem sehingga terbentuk produk, diulas pada penelitian ini. Pada penelitian ini, dimodelkan reaksi substitusi nukleofilik senyawa tersier butil klorida oleh ion hidroksida. Pemodelan komputasi pada penelitian ini, digunakan software Putty, Marvin, NWChem, Avogadro, dan ECCE Viewer. Hasil akhir perhitungan komputasi, didapatkan besaran termodinamika berupa energi aktivasi 230.9478 kcal mol-1, entalpi reaksi -7101.74808 kcal mol-1, entropi reaksi -40.178 cal/mol-K dan energi bebas Gibbs sebesar 4877.32262 kcal mol-1. Lebih lanjut, kestabilan dan reaktivitas molekul pada reaksi ini, dianalisis menggunakan pemodelan molekul dan spektroskopi infra merah. \u0000 \u0000Kata kunci: kimia komputasi, substitusi nukleofilik, tersier butil klorida","PeriodicalId":17768,"journal":{"name":"Jurnal Kartika Kimia","volume":"46 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85312950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jasmansyah Jasmansyah, Pipit Fitriyani, Hernandi Sujono, L. Aisyah
{"title":"Uji Aktivitas Antimikroba Minyak Atsiri Tanaman Pegagan\u0000(Centella asiatica (L.) Urb)","authors":"Jasmansyah Jasmansyah, Pipit Fitriyani, Hernandi Sujono, L. Aisyah","doi":"10.26874/jkk.v3i1.54","DOIUrl":"https://doi.org/10.26874/jkk.v3i1.54","url":null,"abstract":"Pegagan (Centella asiatica (L.) Urb) merupakan salah satu tanaman obat yang memiliki khasiat seperti mengatasi demam, antialergi, anti inflamasi, dan stimulan sistem syaraf pusat. Kandungan senyawa kimia yang terdapat dalam minyak atsiri tanaman pegagan (C. asiatica) diketahui berperan sebagai antibakteri. Penelitian ini adalah untuk mengetahui aktivitas antimikroba dari minyak atsiri tanaman pegagan (C.asiatica) terhadap pertumbuhan bakteri Staphylococcus epidermidis, Pseudomonas aeruginosa, dan jamur Candida albicans. Metode yang digunakan metode destilasi uap-air, hasil destilat dilakukan uji Gas Chromatography – Mass Spectrometry dan aktivitas antimikroba dengan metode mikrodilusi. Hasil penelitian menunjukkan bahwa rendemen minyak sebesar 0,01% dan dengan 37 komponen senyawa, 5 komponen senyawa utama dengan konsentrasi tertinggi yaitu (E)-β-farnesen (17,85%), Kariofilen (13,55%), Germacrene-D (9,61%), α-Humulene (9,54%), β-Elemen (7,80%). Hasil uji aktivitas antimikroba minyak atsiri tanaman pegagan terhadap bakteri S.epidermidis dengan KHM dan KBM ≤ 0,2 %, bakteri P.aeruginosa dengan nilai KHM dan KBM berturut-turut sebesar 50 % dan 100% dan jamur C.albicans dengan nilai KHM dan KBM 100 %. Hasil menunjukkan bahwa minyak atsiri tanaman pegagan lebih berpengaruh dan berpotensi dalam menghambat pertumbuhan bakteri Gram positif dibandingkan dengan perhambatan terhadap bakteri Gram negatif dan jamur. \u0000Kata Kunci : Centella asiatica (L.) Urb, Minyak Atsiri, Antimikroba","PeriodicalId":17768,"journal":{"name":"Jurnal Kartika Kimia","volume":"13 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73481369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}