{"title":"Conversion of hemicellulose from kenaf core fiber to xylose through dilute sulfuric acid hydrolysis","authors":"William Judiawan, Y. Sudiyani, E. Nurnasari","doi":"10.14203/JKTI.V21I1.412","DOIUrl":"https://doi.org/10.14203/JKTI.V21I1.412","url":null,"abstract":"Kenaf (Hibiscus cannabinus) is a lignocellulosic plant that is usually utilized as a fiber source for sack production. The core from kenaf fiber has not been utilized yet in Indonesia, therefore it is still considered as a waste. Hemicellulose from kenaf core can be hydrolyzed to xylose through dilute sulfuric acid hydrolysis in high temperature. Hydrolysis in this study was done by using autoclave at 121℃ and 10% (m/v) biomass: acid ratio for 15 and 45 minutes with a variation on acid concentration (2%, 4%, and 6% v/v). Xylose concentration in the hydrolyzate tends to increase with higher acid concentration and longer heating time. 6% (v/v) sulfuric acid concentration and 45 minutes of heating time produce the highest xylose concentration (20.53 gr/L) and yield (86.50%)","PeriodicalId":17694,"journal":{"name":"Jurnal Kimia Terapan Indonesia","volume":"26 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82508371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Irvan Maulana Firdaus, Tri Fitriany, M. N. Hidayah, A. Soleh, Khilman Husna Pratama, F. Febiyanto
{"title":"Use of Mg-Al/hydrotalcite Catalyst in Biodiesel Production from Avocado Seed Oils: A Preliminary Study","authors":"Irvan Maulana Firdaus, Tri Fitriany, M. N. Hidayah, A. Soleh, Khilman Husna Pratama, F. Febiyanto","doi":"10.14203/JKTI.V21I1.422","DOIUrl":"https://doi.org/10.14203/JKTI.V21I1.422","url":null,"abstract":"Biodiesel production of avocado seed oils has been carried out using the heterogeneous catalyst of Mg-Al/hydrotalcite. Transesterification process was conducted by varying temperature reaction and oil-methanol molar ratio. The reaction temperature was 30, 40, 50, and 60°C, whereas the oil-methanol molar ratio was 1:3, 1:6, 1:9, and 1:12, respectively. As-synthesized Mg-Al/hydrotalcite catalyst was characterized using X-ray diffraction and FTIR. Meanwhile, the biodiesel was analyzed their density, viscosity, water content and 1H-NMR analysis. The results showed that optimum condition in biodiesel production was oil-methanol molar ratio of 1:6 at a reaction temperature of 60°C for 60 minutes and catalyst quantity of 2% yielding biodiesel conversion percentage was approximately 15.90%. However, this preliminary findings showed that Mg-Al/hydrotalcite was able to convert the avocado seed oils into biodiesel even if still need further analysis and research so that produces a higher percentage of biodiesel conversion.","PeriodicalId":17694,"journal":{"name":"Jurnal Kimia Terapan Indonesia","volume":"147 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78292441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Esterification of Waste Cooking Oil Using Ultrasonic: Kinetic Study","authors":"E. Agustian, J. Jessica, P. Untoro, A. Sulaswatty","doi":"10.14203/JKTI.V20I2.397","DOIUrl":"https://doi.org/10.14203/JKTI.V20I2.397","url":null,"abstract":"Waste cooking oil (WCO) have a great potential as an alternative raw material for producing biodiesel. The literatures kinetic of the esterification of WCO in the presence of phosphoric acid catalyst with ultrasonic assisted are rare and most literatures used conventional method. This study aims to determine the optimum condition and the parameters of first and second order kinetics of the WCO esterification which was assisted by ultrasonic bath. Variables that used in this study are methanol/oil mole ratio, acid catalyst concentration and reaction temperature. The highest conversion was 42.08% with methanol/oil mole ratio of 15:1, a catalyst (phosphoric acid) concentration of 9% wt and temperature of 50oC within 90 minutes. The reaction time was reduced to 3 times (minute) compare to conventional method and fatty acid reduced 42%. Kinetic parameters were calculated with assumption that the esterification was the irreversible reaction. The reaction rate constant increasing with temperature. The value of activation energy for esterification of WCO is 42.94 kJ/mol for first order reaction and 35.30 kJ/mol for second order reaction.","PeriodicalId":17694,"journal":{"name":"Jurnal Kimia Terapan Indonesia","volume":"148 Pt 5 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84082501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nurul Azizah, Euis Filaila, S. Salahuddin, E. Agustian, A. Sulaswatty, N. Artanti
{"title":"Antibacterial and Antioxidant activities of Indonesian ginger (jahe emprit) essential oil extracted by hydrodistillation","authors":"Nurul Azizah, Euis Filaila, S. Salahuddin, E. Agustian, A. Sulaswatty, N. Artanti","doi":"10.14203/JKTI.V20I2.401","DOIUrl":"https://doi.org/10.14203/JKTI.V20I2.401","url":null,"abstract":"The rhizome of ginger is commonly used as a spice, food, beverage as well as medicine. Plant essential oils including from ginger have been widely used for food preservation, pharmaceutical and alternative medicines. Currently there are growing interest of consumer for natural sources such as essential oils for natural antibacterial and antioxidant. Jahe emprit (Zingiber officinale var. Amarum) is one of Indonesian ginger variety used to obtain ginger essential oil. The objective of current study was to investigate the effect of solvent to feed (SF) ratio in hydrodistillation process on yield, chemicals content, antibacterial and antioxidant activities of ginger essential oils from jahe emprit. SF ratio used in this study is 0.7: 1, 1.7: 1, 2.7: 1. Chemicals content was conducted using GCMS analysis. Antibacterial assay was conducted using disc diffusion method against Escherichia coli and Staphylococcus aureus. Antioxidant assay was conducted using DPPH free radical scavenging assay. The results show that the highest essential oil yield was obtained from SF ratio 1.7:1 which gave yield of 3.7%. GCMS analysis shows that camphene was always the major compound present in those 3 SF ratio, although the amount present was differed. Besides, 4 other major compounds present were varied. Antibacterial assay using 1% concentration showed ginger oil obtained from SF 0.7:1 and 2.7:1 have the same activities for S. aureus, whereas SF ratio 1.7:1 has the lowest activities. However for E. coli, all SF ratio gave same results. For antioxidant activities at 1000 ppm concentration, the highest activity was obtained from SF ratio 2.7:1","PeriodicalId":17694,"journal":{"name":"Jurnal Kimia Terapan Indonesia","volume":"43 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90672469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
I. Nurjaya, M. Hanafi, P. Lotulung, T. Ernawati, S. Mursiti
{"title":"The Synthesis of Quinidine Salicylate Ester Compound","authors":"I. Nurjaya, M. Hanafi, P. Lotulung, T. Ernawati, S. Mursiti","doi":"10.14203/JKTI.V20I2.403","DOIUrl":"https://doi.org/10.14203/JKTI.V20I2.403","url":null,"abstract":"Quinidine a compound isolated from quinine plants, one of the species of quinine plants is (Chincona ledgereriana) From PT SIL Lembang. The purpose of this study was obtain quinidine salicylate ester through esterification reaction. In this study, the synthesis of quinidine ester compound by esterification reaction was conducted. Esterification reaction was conducted by using DCC activator and DMAP catalyst with one carboxylic acid namely salicylate acid producing new compound namely quinidine salicylate, Subsequent Quinidine salicylate was obtained in the form of oil with 97% yield. The compound obtained from the synthesis was then identified using Thin Layer Chromatography continue analyzed using with Spectrophotometer, LC-ESI-MS spectroscopy. Results show that the target compound has been successfully synthesized.","PeriodicalId":17694,"journal":{"name":"Jurnal Kimia Terapan Indonesia","volume":"56 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87067353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Management of Technology Transfer in the Traditional Tempeh and Tofu Industries","authors":"I. Suharto, Y. A. Miryanti, Lita Wijaya","doi":"10.14203/JKTI.V20I2.398","DOIUrl":"https://doi.org/10.14203/JKTI.V20I2.398","url":null,"abstract":"The objective is to study the screening of Rhizopus sp inoculum, the utilization of this inoculum for a solid substrate soybean fermentation, to study the trial run of peeling machine and a fluidized bed reactor for the separation of soybean skin and soybean meat, to compare a manual cotton cloth bag filter and a manual rotary filter to separate soybean slurry, to run vertical technology transfer of a manual rotary filter into small scale tofu industry according to hygiene control and education skill training . The benefit of this research is to create a new business and to absorb manpower. The method used is a preparation of Rhizopus sp inoculum for fermentation. Trial run of the peeling machine and three phase fluidized bed reactor for the production of cleaned soybean. Cleaned soybeans are delivered to the production of a cake like fermented soybean , soy milk and tofu. Vertical transfer of technology of a manual rotary filter based on technometric approaches to soy milk and tofu industries. Education skill training was attended by 60 participants. The research results can be shown that the utilization of Rhizopus oligoporus and Rhizopus oryzae inoculum for soybean fermentation into a cake like fermented soybean can be accepted by the 60 panelists and local market. The trial run of peeling machine has a capacity of 30 kg per hour, the trial of three phase fluidized bed reactor can produce cleaned soybean after the total weight of soybean skin of about 35% from the total feed. Technology transfer of a manual rotary filter to the small scale of tofu industries can increase an efficiency of 66.37% for 25 minutes is better than a manual a cotton cloth bag filter with an efficiency of 62.62% for 36 minutes in tofu industry according to the hygiene control. This manual rotary filter can be scale-up into a larger scale. Education skill training was attended by 60 participants of a low income group people in rural areas in order to show how of the know how to do something better according to the hygiene control.","PeriodicalId":17694,"journal":{"name":"Jurnal Kimia Terapan Indonesia","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84273607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
T. B. Bardant, M. S. Haq, Arief Amier Rahman Setiawan, S. Harianto, J. Waluyo, Adhi Irianto Mastur, Annisa Dieni Lestari, A. Sulaswatty, S. Sujarwo, N. Rinaldi, E. Wiloso
{"title":"The Renewability Indicator and Cumulative Degree of Perfection for Gamboeng Tea; Part.2, Exergy Calculation of Tea Factory","authors":"T. B. Bardant, M. S. Haq, Arief Amier Rahman Setiawan, S. Harianto, J. Waluyo, Adhi Irianto Mastur, Annisa Dieni Lestari, A. Sulaswatty, S. Sujarwo, N. Rinaldi, E. Wiloso","doi":"10.14203/JKTI.V20I2.400","DOIUrl":"https://doi.org/10.14203/JKTI.V20I2.400","url":null,"abstract":"Renewability Indicator (RI) and Cumulative Degree of Perfection (CDP) were used to observe sustainability of Gamboeng Tea. The assessment then compared with black tea process in Black Sea Region in Turkey from the previous study. Calculation of exergy for Gamboeng fresh tea leaf had already described in Part.1. Since the main process for both production was drying, then tropical humid climate in Gamboeng is the main challenge to increase efficiency, and thus, renewability. This second part described the significant improvement of renewability had applied in Gamboeng by using wood pellet in rotary pannier. Further recommended improvement were by installing better humidity detector and connected to the process control so the process can adapt the ambient change which the relative humidity can be varied from 65% and up to 92%.","PeriodicalId":17694,"journal":{"name":"Jurnal Kimia Terapan Indonesia","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82338013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mechanical and Barrier Properties of PVP-Carbon Dot Nanocomposite Films","authors":"A. Sjahriza, Z. A. Mas’ud, Komar Sutirah","doi":"10.14203/JKTI.V20I2.392","DOIUrl":"https://doi.org/10.14203/JKTI.V20I2.392","url":null,"abstract":"This research reported carbon dot were synthesized form citric acid and urea through a single step microwave process and Poly Vinyl Pirrolidone (PVP) films composited by carbon dot were prepared. The effects of different composition carbon dots on mechanical strength of films and water vapour barrier were evaluated. Highest mechanical yielded composite film were analyzed their thermal stability. Average of carbon dot diameter was found 90.61 nm and polydispersity indice 0.396. Different composition carbon dot exhibit significant improvement in tensile strength and modulus. Water permeablity of films varieate with content of carbon dot. The presence of carbon dot had a negligible effect on Tg of film and show melting process.","PeriodicalId":17694,"journal":{"name":"Jurnal Kimia Terapan Indonesia","volume":"208 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83536994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. W. Indrianingsih, A. I. Prihantini, S. Tachibana
{"title":"Isolation of Endophytic Fungi QPS 05 from Quercus phillyraeoides A. Gray and Its Potential for α-Glucosidase Inhibitory Activity","authors":"A. W. Indrianingsih, A. I. Prihantini, S. Tachibana","doi":"10.14203/JKTI.V20I1.372","DOIUrl":"https://doi.org/10.14203/JKTI.V20I1.372","url":null,"abstract":"AbstractEndophytic fungi are the microorganisms that spend all or part of their life cycles within plant tissue without causing harmful effects on the plant. In this study, 14 endophytic fungus from Quercus phillyraeoides A. Gray were isolated. Alternaria sp. QPS 05, an endophytic fungi which was isolated from the stem of Q. phillyraeoides A. Gray showed the highest α-glucosidase inhibitory activity. Further separation of ethyl acetate extract from the fungus led to the isolation of active substance from hexane-soluble fraction which give fatty acids mixture consist of palmitic acid, oleic acid, linoleic acid and linolenic acid (1) strong inhibitory activity against α-glucosidase. Isolated fatty acids (1) had inhibitory concentration (IC50) values against Saccharomyces cerevisiae was 12.10 μg/mL. The results of the present study showed that endophytic fungus from Alternaria sp. QPS 05 potentially contained a rich source of natural antidiabetic medicine.","PeriodicalId":17694,"journal":{"name":"Jurnal Kimia Terapan Indonesia","volume":"47 7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82783341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Ratnakomala, N. F. Sari, F. Fahrurrozi, P. Lisdiyanti
{"title":"Antimicrobial Activity of Selenium Nanoparticles Synthesized by Actinomycetes Isolated from Lombok Island Soil Samples","authors":"S. Ratnakomala, N. F. Sari, F. Fahrurrozi, P. Lisdiyanti","doi":"10.14203/JKTI.V20I1.374","DOIUrl":"https://doi.org/10.14203/JKTI.V20I1.374","url":null,"abstract":"AbstractA total of 98 actinomycetes were isolated from the soil and litter samples collected from the cacao and coffee plantation in Lombok Island, West Nusa Tenggara, Indonesia. These isolates were screened for their antimicrobial activity. Among 98 isolated strains, only 24 isolates showed antimicrobial activity against test microorganisms of which 20.4% were active against Bacillus subtilis BTCC B-612, 14.3% against Staphylococcus aureus BTCC B-611, and 5.1% against Escherichia coli BTCC B-609. Out of these 24 isolates, 3 were found to be able to grow in medium containing 3 mM Selenium oxide of which the culture were changed color to red. Two of the best strains, L-155 and L-156, were selected for assessing production of Selenium nanoparticles. Bioreduction of selenium nanoparticles was confirmed by UV–visible spectrophotometer which showed peak between 300 and 320 nm. Biosynthesized selenium nanoparticle from isolate actinomycetes L-155 and L-156 were found to have a broad spectrum of activity against the tested microorganisms: Bacillus subtilis, Staphylococcus aureus, Escherichia coli, Micrococcus luteus, and Candida albicans. This study showed rapid and eco-friendly synthesis of selenium nanoparticles from soil actinomycetes. Most of these active isolates revealed to possess antibacterial property.","PeriodicalId":17694,"journal":{"name":"Jurnal Kimia Terapan Indonesia","volume":"116 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73533139","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}