Journal of The Chemical Society A: Inorganic, Physical, Theoretical最新文献_第6页

Preparation and properties of a but-2-enyl butadiene complex of cobalt and of an analogous complex from isoprene 钴的2-烯基丁二烯配合物及异戊二烯类似配合物的制备及性质

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI: 10.1039/J19710003246

G. Vitulli, L. Porri, A. Segre

引用次数: 10

Magnetic and spectroscopic studies of some lutidine complexes of cobalt(II) and nickel(II) 钴(II)和镍(II)配合物的磁性和光谱学研究

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI: 10.1039/J19710000658

D. Machin, J. Sullivan

引用次数: 4

Further studies of the metal–carbonyl bending vibrations of (π-ring)M(CO)2X derivatives of the first-row transition metals 第一排过渡金属(π-环)M(CO)2X衍生物的金属-羰基弯曲振动的进一步研究

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI: 10.1039/J19710000106

A. R. Manning

引用次数: 6

Alkali-metal complexes. Part VI. Crystal and molecular structure of a complex formed from isonitrosoacetophenone and potassium o-nitrophenolate 碱金属配合物。第六部分:异硝基苯乙酮和邻硝基酚酸钾形成的络合物的晶体和分子结构

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI: 10.1039/J19710000745

M. Bush, M. Truter

{"title":"Alkali-metal complexes. Part VI. Crystal and molecular structure of a complex formed from isonitrosoacetophenone and potassium o-nitrophenolate","authors":"M. Bush, M. Truter","doi":"10.1039/J19710000745","DOIUrl":"https://doi.org/10.1039/J19710000745","url":null,"abstract":"The crystal structure of a complex formed from isonitrosoacetophenone and potassium o-nitrophenolate having the formula KC6H4(NO2)OHONCHC(O)C6H5 has been determined. The crystals are monoclinic and have space group P21/c with Z= 4, a= 10·826(4), b= 5·581(3), c= 24·559(10)A, and β= 102°4′(1′). 1557 independent reflections collected on an automatic diffractometer were used to refine the structure by full-matrix least-squares methods to a conventional R of 0·053.The potassium is surrounded by eight electron-rich atoms of the ligands. Seven of these are oxygen atoms and one is the oxime-nitrogen atom. The two ligands may be regarded as chelates; the o-nitrophenol forms a six-membered ring and the isonitrosoacetophenone ligand makes a five-membered ring by the interaction of the potassium ion with the keto-oxygen atom and the oxime-nitrogen atom. Two oxygen atoms from the o-nitrophenolate interact with two symmetry-related potassium ions and thereby form a polymeric sequence parallel to the b-axis. The o-nitrophenolate is connected to the isonitrosoacetophenone by an apparently symmetrical hydrogen bond of length 2·51 A. The dimensions of the o-nitrophenolate ligand indicate a significant contribution of a quinonoid form.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":"16 1","pages":"745-750"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76009288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 12

Infrared spectra of trimetal dodecacarbonyl species in frozen gas matrices at 20 K 20 K冷冻气体基质中三金属十二羰基的红外光谱

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI: 10.1039/J19710000654

M. Poliakoff, J. J. Turner

引用次数: 16

Metal complex formazans. Part II. The reaction of copper salts with certain tetradentate formazans 金属络合物。第二部分。铜盐与某些四齿甲酸盐的反应

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI: 10.1039/J19710003385

R. Price

引用次数: 5

Steric effects and five-co-ordination in first-row transition-metal compounds. Compounds with a linear tetra-amine ligand 第一排过渡金属化合物中的立体效应和五配位。具有线性四胺配体的化合物

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI: 10.1039/J19710001029

J. G. Gibson, E. Mckenzie

{"title":"Steric effects and five-co-ordination in first-row transition-metal compounds. Compounds with a linear tetra-amine ligand","authors":"J. G. Gibson, E. Mckenzie","doi":"10.1039/J19710001029","DOIUrl":"https://doi.org/10.1039/J19710001029","url":null,"abstract":"Compounds of MnII, CoII, NiII, CuII and ZnII of the type M(chelate)X2[where chelate =NN′-di-(3-aminopropyl)piperazine; X = one of a variety of anions] are reported. Square-pyramidal five-co-ordinate cations in the compounds [M(chelate)X]X and [M(chelate)X]Y are characterised for the following: where M = CoII, X = Br and I; where M = NiII, X = Cl, Br and possibly NCS; and where M = CuII, X = Cl, Br, I, NCS, and Y = ClO4, PF6. In addition, a five-co-ordinate species Cu(chelate)Cl2 in which the ligand is only terdentate with a free NH2, also is characterised. Four co-ordinate planar [MN4]2+ species also are characterised for NiII, CuII and perhaps CoII. No significant structural data is available for the MnII, FeII, or ZnII species. The structural assignments for the solid compounds rely on X-ray data (powder-pattern correlations with a known three-dimensional structure), i.r. and electronic spectra, and magnetic measurements. Structural studies of solutions in non-aqueous solvents also are reported. These rely on electronic spectra. Specific ion-pairing limits the use of conductivity data. The origin of the five-co-ordinate structures in these compounds is discussed in terms of the peculiar steric effects of the ligand, which is the precursor of a class of homologous ligands, each of which is expected to give five-co-ordinate compounds of these metals.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":"9 1","pages":"1029-1038"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87159578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 10

Antimony-121 Mössbauer spectroscopy of some chloro-complexes of antimony 锑-121 Mössbauer一些锑的氯络合物的光谱

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI: 10.1039/J19710001855

T. Birchall, B. Valle, E. Martineau, J. Milne

引用次数: 9

Single-crystal electronic and electron spin resonance spectra of thiocyanatotriethylenetetraminecopper(II) thiocyanate 硫氰酸三乙四铜(II)的单晶电子和电子自旋共振谱

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI: 10.1039/J19710001442

R. J. Dudley, B. Hathaway

引用次数: 7

Preparation and infrared spectra of some Group IV metal–tricarbonylnitrosyliron derivatives 一些IV族金属-三羰基亚硝基吡啶衍生物的制备及其红外光谱

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI: 10.1039/J19710000256

M. Casey, A. R. Manning

引用次数: 11