{"title":"第一排过渡金属(π-环)M(CO)2X衍生物的金属-羰基弯曲振动的进一步研究","authors":"A. R. Manning","doi":"10.1039/J19710000106","DOIUrl":null,"url":null,"abstract":"The i.r. spectra of various (π-ring)M(CO)2X complexes of chromium, manganese, and iron have been investigated in the regions 225–700 and 1850–2100 cm–1. Absorption bands due to vibrations of the (π-ring)M(CO)2 moieties are reported and assigned. Trends in frequencies and relative intensities of those bands which are due largely to the δ(MCO) vibrations are discussed, and shown to depend on the ligand X.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":"151 1","pages":"106-110"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Further studies of the metal–carbonyl bending vibrations of (π-ring)M(CO)2X derivatives of the first-row transition metals\",\"authors\":\"A. R. Manning\",\"doi\":\"10.1039/J19710000106\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The i.r. spectra of various (π-ring)M(CO)2X complexes of chromium, manganese, and iron have been investigated in the regions 225–700 and 1850–2100 cm–1. Absorption bands due to vibrations of the (π-ring)M(CO)2 moieties are reported and assigned. Trends in frequencies and relative intensities of those bands which are due largely to the δ(MCO) vibrations are discussed, and shown to depend on the ligand X.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":\"151 1\",\"pages\":\"106-110\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710000106\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710000106","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Further studies of the metal–carbonyl bending vibrations of (π-ring)M(CO)2X derivatives of the first-row transition metals
The i.r. spectra of various (π-ring)M(CO)2X complexes of chromium, manganese, and iron have been investigated in the regions 225–700 and 1850–2100 cm–1. Absorption bands due to vibrations of the (π-ring)M(CO)2 moieties are reported and assigned. Trends in frequencies and relative intensities of those bands which are due largely to the δ(MCO) vibrations are discussed, and shown to depend on the ligand X.
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