Journal of Rheology最新文献_第2页

A reexamination of the Cox–Merz rule through the lens of recovery rheology 从复原流变学的角度重新审视考克斯-梅尔兹法则

IF 3.3 2区工程技术

Journal of Rheology Pub Date : 2024-04-01 DOI: 10.1122/8.0000811

Y. Shim, James J. Griebler, Simon A. Rogers

{"title":"A reexamination of the Cox–Merz rule through the lens of recovery rheology","authors":"Y. Shim, James J. Griebler, Simon A. Rogers","doi":"10.1122/8.0000811","DOIUrl":"https://doi.org/10.1122/8.0000811","url":null,"abstract":"Empirical rules play a crucial role in industrial and experimental settings for efficiently determining the rheological properties of materials, thereby saving both time and resources. An example is the Cox–Merz rule, which equates the steady-shear viscosity with the magnitude of the complex viscosity obtained in oscillatory tests. This empirical rule provides access to the steady-shear viscosity that is useful for processing conditions without the instabilities associated with experiments at high shear rates. However, the Cox–Merz rule is empirical and has been shown to work in some cases and fail in others. The underlying connection between the different material functions remains phenomenological and the lack of a comprehensive understanding of the rheological physics allows for ambiguity to persist in the interpretation of material responses. In this work, we revisit the Cox–Merz rule using recovery rheology, which decomposes the strain into recoverable and unrecoverable components. When viewed through the lens of recovery rheology, it is clearly seen that the steady-shear viscosity comes from purely unrecoverable acquisition of strain, while the complex viscosity is defined in terms of contributions from both recoverable and unrecoverable components. With recovery tests in mind, we elucidate why the Cox–Merz rule works only in a limited set of conditions and present an approach that could allow for universal comparisons to be made. This work further highlights the significance of recovery rheology by showing how it is possible to extend beyond phenomenological approaches through clear rheophysical metrics obtained by decomposing the material response into recoverable and unrecoverable components.","PeriodicalId":16991,"journal":{"name":"Journal of Rheology","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140757949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Molecular rheology of nanoconfined oligomer melts 纳米固化低聚物熔体的分子流变学

IF 3.3 2区工程技术

Journal of Rheology Pub Date : 2024-03-21 DOI: 10.1122/8.0000751

A. B. Yıldırım, A. Erbaş, L. Biancofiore

引用次数: 1

Joncryl chain extender reactivity with polylactide: Effect of d-lactide content, Joncryl type, and processing temperature Joncryl 扩链剂与聚乳酸的反应性：d-内酯含量、Joncryl 类型和加工温度的影响

IF 3.3 2区工程技术

Journal of Rheology Pub Date : 2024-02-13 DOI: 10.1122/8.0000718

Yavuz Akdevelioğlu, M. Begum Alanalp, Ferit Siyahcan, J. Randall, Michael Gehrung, Ali Durmus, M. Nofar

{"title":"Joncryl chain extender reactivity with polylactide: Effect of d-lactide content, Joncryl type, and processing temperature","authors":"Yavuz Akdevelioğlu, M. Begum Alanalp, Ferit Siyahcan, J. Randall, Michael Gehrung, Ali Durmus, M. Nofar","doi":"10.1122/8.0000718","DOIUrl":"https://doi.org/10.1122/8.0000718","url":null,"abstract":"In this study, a highly crystallizable and an amorphous polylactide (i.e., cPLA and aPLA) with, respectively, low (0.5 mol. %) and high (12 mol. %) d-lactic acid contents and similar molecular weights were melt compounded with two different multifunctional epoxy-based Joncryl chain extenders (CEs, i.e., ADR 4400 and 4468) at 190 °C. Reactivity of Joncryl grades with aPLA was also explored at melt processing temperatures of 150, 170, and 210 °C. Small amplitude oscillatory shear rheological analysis was conducted to understand the extent of the Joncryl reaction with PLA molecules, and the results were confirmed with molecular weight determination using gel permeation chromatography. Extensional viscosity of the processed samples was also compared to control their strain hardening behavior. Results showed that the Joncryl reaction with cPLA and aPLA differs in terms of preference for chain extension or branching, indicating that molecular regularity affected the interactions with both Joncryl grades during reactive melt processing. Moreover, although the increase in processing temperature accelerated PLA degradation, it noticeably increased the reactivity of both Joncryl grades with aPLA. In all cases, ADR 4468 was more reactive in molecular chain extension/branching due to its higher functionality than ADR 4400. Differential scanning calorimetry results also revealed that the crystallization of cPLA was differently affected by the change in the Joncryl content and type.","PeriodicalId":16991,"journal":{"name":"Journal of Rheology","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139840405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Joncryl chain extender reactivity with polylactide: Effect of d-lactide content, Joncryl type, and processing temperature Joncryl 扩链剂与聚乳酸的反应性：d-内酯含量、Joncryl 类型和加工温度的影响

IF 3.3 2区工程技术

Journal of Rheology Pub Date : 2024-02-13 DOI: 10.1122/8.0000718

Yavuz Akdevelioğlu, M. Begum Alanalp, Ferit Siyahcan, J. Randall, Michael Gehrung, Ali Durmus, M. Nofar

{"title":"Joncryl chain extender reactivity with polylactide: Effect of d-lactide content, Joncryl type, and processing temperature","authors":"Yavuz Akdevelioğlu, M. Begum Alanalp, Ferit Siyahcan, J. Randall, Michael Gehrung, Ali Durmus, M. Nofar","doi":"10.1122/8.0000718","DOIUrl":"https://doi.org/10.1122/8.0000718","url":null,"abstract":"In this study, a highly crystallizable and an amorphous polylactide (i.e., cPLA and aPLA) with, respectively, low (0.5 mol. %) and high (12 mol. %) d-lactic acid contents and similar molecular weights were melt compounded with two different multifunctional epoxy-based Joncryl chain extenders (CEs, i.e., ADR 4400 and 4468) at 190 °C. Reactivity of Joncryl grades with aPLA was also explored at melt processing temperatures of 150, 170, and 210 °C. Small amplitude oscillatory shear rheological analysis was conducted to understand the extent of the Joncryl reaction with PLA molecules, and the results were confirmed with molecular weight determination using gel permeation chromatography. Extensional viscosity of the processed samples was also compared to control their strain hardening behavior. Results showed that the Joncryl reaction with cPLA and aPLA differs in terms of preference for chain extension or branching, indicating that molecular regularity affected the interactions with both Joncryl grades during reactive melt processing. Moreover, although the increase in processing temperature accelerated PLA degradation, it noticeably increased the reactivity of both Joncryl grades with aPLA. In all cases, ADR 4468 was more reactive in molecular chain extension/branching due to its higher functionality than ADR 4400. Differential scanning calorimetry results also revealed that the crystallization of cPLA was differently affected by the change in the Joncryl content and type.","PeriodicalId":16991,"journal":{"name":"Journal of Rheology","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139780419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hyperstretching in elongational flow of densely grafted comb and branch-on-branch model polystyrenes 密集接枝梳状聚苯乙烯和枝对枝模型聚苯乙烯伸长流动中的超拉伸现象

IF 3.3 2区工程技术

Journal of Rheology Pub Date : 2024-02-08 DOI: 10.1122/8.0000781

V. Hirschberg, Lorenz Faust, Mahdi Abbasi, Qian Huang, Manfred Wilhelm, Manfred H. Wagner

{"title":"Hyperstretching in elongational flow of densely grafted comb and branch-on-branch model polystyrenes","authors":"V. Hirschberg, Lorenz Faust, Mahdi Abbasi, Qian Huang, Manfred Wilhelm, Manfred H. Wagner","doi":"10.1122/8.0000781","DOIUrl":"https://doi.org/10.1122/8.0000781","url":null,"abstract":"Strain hardening of long-chain branched polymers in elongational flow occurs due to the stretch of the backbone chain between branch points. With an increasing number of side arms, the length of the backbone chain segment between two branch points of a comb decreases. Of particular interest is the case when the number Nb of arms per entanglement length of the polymer is larger than one. This leads not only to larger strain hardening but also to hyperstretching, i.e., the elongational stress growth shows an enhanced increase with strain. We consider elongational data reported by Abbasi et al. [Macromolecules 50(15), 5964–5977 (2017)] and Faust et al. [Macromol. Chem. Phys. 224(1), 2200214 (2023)] on a series of comb and branch-on-branch polystyrene (PS) melts with the average number Nb of branches per entanglement segment of the backbone ranging from Nb = 0.2 to Nb = 9.5. In addition, we present measurements of the elongational viscosity of two PS combs with Nb = 4.7 as well as of blends consisting of 5 to 50 wt. % of a PS comb and a monodisperse linear PS. Analysis by the hierarchical multimode molecular stress function model shows that while backbone chains of loosely grafted combs with Nb < 1 are stretched affinely in elongational flow, backbone chains of more densely grafted combs with Nb > 1 show increasing hyperstretching with increasing Nb. The elongational data of the comb/linear blends confirm that hyperstretching is an intrinsic property of the comb macromolecule with Nb > 1, independent of its concentration in the blend. While this is of considerable interest from a modeling point of view, hyperstretching causing an enhanced increase of the elongational stress growth can also have a significant impact on the processability of polymers, and quantification of this effect is, therefore, important.","PeriodicalId":16991,"journal":{"name":"Journal of Rheology","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139793909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Creep and recovery in dense suspensions of smooth and rough colloids 光滑和粗糙胶体致密悬浮液中的蠕变和恢复

IF 3.3 2区工程技术

Journal of Rheology Pub Date : 2024-02-02 DOI: 10.1122/8.0000722

Y. Saraswat, Eli Kerstein, L. Hsiao

{"title":"Creep and recovery in dense suspensions of smooth and rough colloids","authors":"Y. Saraswat, Eli Kerstein, L. Hsiao","doi":"10.1122/8.0000722","DOIUrl":"https://doi.org/10.1122/8.0000722","url":null,"abstract":"We report the effect of particle surface roughness on creep deformation and subsequent strain recovery in dense colloidal suspensions. The suspensions are composed of hard-spherelike poly(methyl methacrylate) smooth (S) and rough (R) colloids with particle volume fractions ϕS = 0.64 ± 0.01 and ϕR = 0.56 ± 0.01, corresponding to a distance of 3.0% and 3.4% based on their jamming volume fractions (ϕJS=0.66±0.01, ϕJR=0.58±0.01). The suspensions are subject to a range of shear stresses (0.01–0.07 Pa) above and below the yield stress values of the two suspensions (σyS=0.035Pa, σyR=0.02Pa). During creep, suspensions of rough colloids exhibit four to five times higher strain deformation compared to smooth colloids, irrespective of the applied stress. The interlocking of surface asperities in rough colloids is likely to generate a heterogeneous microstructure, favoring dynamic particle activity and percolation of strain heterogeneities, therefore resulting in higher magnitude of strain deformation and an earlier onset of steady flow. Strain recovery after the cessation of stress reveals a nonmonotonic recoverable strain for rough colloids, where the peak recoverable strain is observed near the yield stress, followed by a steep decline with increasing stress. This type of response suggests that frictional constraints between geometrically frustrated interlocking contacts can serve as particle bonds capable of higher elastic recovery but only near the yield stress. Understanding how particle roughness affects macroscopic creep and recovery is useful in designing yield stress fluids for additive manufacturing and product formulations.","PeriodicalId":16991,"journal":{"name":"Journal of Rheology","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139809626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Creep and recovery in dense suspensions of smooth and rough colloids 光滑和粗糙胶体致密悬浮液中的蠕变和恢复

IF 3.3 2区工程技术

Journal of Rheology Pub Date : 2024-02-02 DOI: 10.1122/8.0000722

Y. Saraswat, Eli Kerstein, L. Hsiao

{"title":"Creep and recovery in dense suspensions of smooth and rough colloids","authors":"Y. Saraswat, Eli Kerstein, L. Hsiao","doi":"10.1122/8.0000722","DOIUrl":"https://doi.org/10.1122/8.0000722","url":null,"abstract":"We report the effect of particle surface roughness on creep deformation and subsequent strain recovery in dense colloidal suspensions. The suspensions are composed of hard-spherelike poly(methyl methacrylate) smooth (S) and rough (R) colloids with particle volume fractions ϕS = 0.64 ± 0.01 and ϕR = 0.56 ± 0.01, corresponding to a distance of 3.0% and 3.4% based on their jamming volume fractions (ϕJS=0.66±0.01, ϕJR=0.58±0.01). The suspensions are subject to a range of shear stresses (0.01–0.07 Pa) above and below the yield stress values of the two suspensions (σyS=0.035Pa, σyR=0.02Pa). During creep, suspensions of rough colloids exhibit four to five times higher strain deformation compared to smooth colloids, irrespective of the applied stress. The interlocking of surface asperities in rough colloids is likely to generate a heterogeneous microstructure, favoring dynamic particle activity and percolation of strain heterogeneities, therefore resulting in higher magnitude of strain deformation and an earlier onset of steady flow. Strain recovery after the cessation of stress reveals a nonmonotonic recoverable strain for rough colloids, where the peak recoverable strain is observed near the yield stress, followed by a steep decline with increasing stress. This type of response suggests that frictional constraints between geometrically frustrated interlocking contacts can serve as particle bonds capable of higher elastic recovery but only near the yield stress. Understanding how particle roughness affects macroscopic creep and recovery is useful in designing yield stress fluids for additive manufacturing and product formulations.","PeriodicalId":16991,"journal":{"name":"Journal of Rheology","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139869583","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

In situ experimental investigation of fiber orientation kinetics during uniaxial extensional flow of polymer composites 聚合物复合材料单轴拉伸流动过程中纤维取向动力学的现场实验研究

IF 3.3 2区工程技术

Journal of Rheology Pub Date : 2024-01-23 DOI: 10.1122/8.0000749

Thijs R. N. Egelmeers, N. Jaensson, Patrick D. Anderson, R. Cardinaels

{"title":"In situ experimental investigation of fiber orientation kinetics during uniaxial extensional flow of polymer composites","authors":"Thijs R. N. Egelmeers, N. Jaensson, Patrick D. Anderson, R. Cardinaels","doi":"10.1122/8.0000749","DOIUrl":"https://doi.org/10.1122/8.0000749","url":null,"abstract":"The demand for fiber-filled polymers has witnessed a significant upswing in recent years. A comprehensive understanding of the local fiber orientation is imperative to accurately predict the mechanical properties of fiber-filled products. In this study, we experimentally investigated the fiber orientation kinetics in uniaxial extensional flows. For this, we equipped a rheometer with a Sentmanat extensional measurement device and with an optical train that allows us to measure the fiber orientation in situ during uniaxial extension using small angle light scattering. We investigated an experimental system with glass fibers for the suspended phase (L/D=8−15), and for the matrix either low density polyethylene, which shows strain hardening in extension, or linear low density polyethylene, which shows no strain hardening. For these two polymer matrices, the fiber orientation kinetics were investigated as a function of fiber volume fraction (ϕ=1%, 5%, and 10%) and Weissenberg number (by varying the Hencky strain rate, ϵ˙H=0.01−1s−1). We found that all these parameters did not influence the fiber orientation kinetics in uniaxial extension and that these kinetics can be described by a multiparticle model, based on Jeffery’s equation for single particles. Our results show that, in uniaxial extension, fiber orientation is solely determined by the applied strain and that, up to the concentrated regime (ϕ≈D/L), fiber-fiber interactions do not influence the fiber orientation. The extensional stress growth coefficient of these composites, which is measured simultaneously with the orientation, shows high agreement with Batchelor’s equation for rodlike suspensions.","PeriodicalId":16991,"journal":{"name":"Journal of Rheology","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139604367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

No yield stress required: Stress-activated flow in simple yield-stress fluids 无需屈服应力简单屈服应力流体中的应力激活流动

IF 3.3 2区工程技术

Journal of Rheology Pub Date : 2024-01-23 DOI: 10.1122/8.0000748

G. Pagani, M. Hofmann, L. E. Govaert, T. Tervoort, J. Vermant

{"title":"No yield stress required: Stress-activated flow in simple yield-stress fluids","authors":"G. Pagani, M. Hofmann, L. E. Govaert, T. Tervoort, J. Vermant","doi":"10.1122/8.0000748","DOIUrl":"https://doi.org/10.1122/8.0000748","url":null,"abstract":"An elastoviscoplastic constitutive equation is proposed to describe both the elastic and rate-dependent plastic deformation behavior of Carbopol® dispersions, commonly used to study yield-stress fluids. The model, a variant of the nonlinear Maxwell model with stress-dependent relaxation time, eliminates the need for a separate Herschel–Bulkley yield stress. The stress dependence of the viscosity was determined experimentally by evaluating the steady-state flow stress at a constant applied shear rate and by measuring the steady-state creep rate at constant applied shear stress. Experimentally, the viscosity’s stress-dependence was confirmed to follow the Ree–Eyring model. Furthermore, it is shown that the Carbopol® dispersions used here obey time-stress superposition, indicating that all relaxation times experience the same stress dependence. This was demonstrated by building a compliance mastercurve using horizontal shifting on a logarithmic time axis of creep curves measured at different stress levels and by constructing mastercurves of the storage- and loss-modulus curves determined independently by orthogonal superposition measurements at different applied constant shear stresses. Overall, the key feature of the proposed constitutive equation is its incorporation of a nonlinear stress-activated change in relaxation time, which enables a smooth transition from elastic to viscous behavior during start-up flow experiments. This approach bypasses the need for a distinct Herschel–Bulkley yield stress as a separate material characteristic. Additionally, the model successfully replicates the observed steady-state flow stress in transient-flow scenarios and the steady-state flow rate in creep experiments, underlining its effectiveness in capturing the material’s dynamic response. Finally, the one-dimensional description is readily extended to a full three-dimensional finite-strain elastoviscoplastic constitutive equation.","PeriodicalId":16991,"journal":{"name":"Journal of Rheology","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2024-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139603469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Spreading ceramic stereolithography pastes: Insights from shear- and orthogonal-rheology 陶瓷立体光刻浆料的铺展：剪切流变学和正交流变学的启示

IF 3.3 2区工程技术

Journal of Rheology Pub Date : 2023-12-21 DOI: 10.1122/8.0000688

Sylvain Fournier, Jérôme Chevalier, Saray Pérez-Robles, C. Carotenuto, M. Minale, H. Reveron, G. Baeza

{"title":"Spreading ceramic stereolithography pastes: Insights from shear- and orthogonal-rheology","authors":"Sylvain Fournier, Jérôme Chevalier, Saray Pérez-Robles, C. Carotenuto, M. Minale, H. Reveron, G. Baeza","doi":"10.1122/8.0000688","DOIUrl":"https://doi.org/10.1122/8.0000688","url":null,"abstract":"We study the shear rheological behavior of a commercial stereolithography paste containing ≈50 vol. % of zirconia particles (diameter ≈ 100 nm) with the aim to clarify physical mechanisms occurring during the “scraping” step of this yield stress fluid. Beyond a flow curve characterized by a high zero-shear viscosity accompanied with an overall shear-thinning behavior, we investigate in a systematic way the transient regime through start-up experiments. We demonstrate that a structural transition occurs between 10−2 and 10−1 s−1, resulting in an apparent interruption of the shear-thinning. The corresponding transient response presents a pronounced extra-growth of the shear stress before to stabilize at high strain amplitude and a negative first normal stress difference peak, both effects become stronger at higher shear rates. These observations are rationalized based on the high interparticle friction owing to the polyhedral shape and the roughness of the particles. In addition, relaxation tests following the start-up experiments reveal that the samples submitted to shear rates higher than 10−1 s−1 cannot relax the shear stress to the same level as in low shear rate experiments, suggesting a durable structural modification likely to impact the quality of the parts prior to their debinding and densification. Finally, we utilize orthogonal superposition rheology to illustrate how the application of an oscillatory deformation during the scraping procedure could help to reduce the shear-thinning interruption and improve the stereolithography processing as already observed empirically during scraping.","PeriodicalId":16991,"journal":{"name":"Journal of Rheology","volume":null,"pages":null},"PeriodicalIF":3.3,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138949235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0