Journal of Raman Spectroscopy最新文献

{"title":"Featured Cover","authors":"Henry Misoi,&nbsp;Jonas I. Hölzer,&nbsp;Thomas Seeger","doi":"10.1002/jrs.6771","DOIUrl":"https://doi.org/10.1002/jrs.6771","url":null,"abstract":"<p>The cover image is based on the article <i>Experimental Determination of the Temperature-Dependent Broadening Effect of Water Vapour on the S-Branch Raman Linewidths of Nitrogen</i> by Jonas Immanuel Hölzer et al., https://doi.org/10.1002/jrs.6742.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":16926,"journal":{"name":"Journal of Raman Spectroscopy","volume":"56 1","pages":"i"},"PeriodicalIF":2.4,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jrs.6771","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Applications of Raman Spectroscopy in Art and Archaeology","authors":"Anastasia Rousaki,&nbsp;Juan Manuel Madariaga","doi":"10.1002/jrs.6756","DOIUrl":"https://doi.org/10.1002/jrs.6756","url":null,"abstract":"&lt;p&gt;Raman spectroscopy is considered as one of the most valued and important techniques in the art and archaeology analysis field. Its increasing importance when the technique is applied on cultural heritage objects is reflected on the number of &lt;i&gt;peer reviewed&lt;/i&gt; papers published each year on a variety of journals regarding cultural heritage science, analytical chemistry and (vibrational) spectroscopy, among others. Moreover, the importance of the application Raman spectroscopy on works of art and archaeology together with its improvements and breakthroughs is underlined on dedicated international scientific conferences (and sessions) such as the International Conference on the Application of Raman Spectroscopy in Art and Archaeology (RAA).&lt;/p&gt;&lt;p&gt;The RAA conferences is a great gathering of scientists working on Raman spectroscopy and its instrumental developments and an excellent opportunity to be informed on the latest advances of the technique on Cultural Heritage studies. The first edition of the RAA conference was realized in London in 2001 [&lt;span&gt;1&lt;/span&gt;], followed by Ghent (2003) [&lt;span&gt;2&lt;/span&gt;] and then Paris (2005) [&lt;span&gt;3&lt;/span&gt;], Modena (2007) [&lt;span&gt;4&lt;/span&gt;], Bilbao (2009) [&lt;span&gt;5&lt;/span&gt;], Parma (2011) [&lt;span&gt;6&lt;/span&gt;], Ljubljana (2013) [&lt;span&gt;7&lt;/span&gt;], Wroclaw (2015) [&lt;span&gt;8&lt;/span&gt;], Évora (2017) [&lt;span&gt;9&lt;/span&gt;] and Potsdam (2019) [&lt;span&gt;10&lt;/span&gt;]. The 11&lt;sup&gt;th&lt;/sup&gt; edition of the RAA conference (RAA2023, 6 to 9 September 2023) was hosted by the National Gallery-Alexandros Soutsos Museum, located in Athens, Greece in collaboration with Ghent University, Ghent, Belgium. For the first time, the RAA2023 conference included a &lt;i&gt;two-day&lt;/i&gt; Raman spectroscopy training school (4 to 5 September 2023) on selected topics addressed to students and early career researchers.&lt;/p&gt;&lt;p&gt;As the previous editions, the scientific programme was focused on characterization of materials associated with cultural heritage research (natural and synthetic inorganic and organic materials including biological materials), degradation processes, conservation related themes and challenges, surface enhanced Raman spectroscopy (SERS), chemometrics, Raman spectroscopy related topics in paleontology, paleoenvironment and archaeology, the development and progresses of Raman techniques and the application, advantages and challenges of new Raman instrumentation. The aforementioned topics can be connected either to laboratory or in situ analysis, or both while Raman spectroscopy should act as a core technique in studies that include other analytical techniques. During the RAA2023, these type of studies were organized in 3 keynote and 1 plenary lectures, 30 oral presentations, 4 sponsor oral presentations and 37 poster presentations. The RAA2023 conference garnered 100 registries from 21 countries. There were 332 authors and co-authors in the studies of the conference's scientific programme.&lt;/p&gt;&lt;p&gt;This special issue includes 14 selected manuscripts reflecting th","PeriodicalId":16926,"journal":{"name":"Journal of Raman Spectroscopy","volume":"55 12","pages":"1218-1223"},"PeriodicalIF":2.4,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jrs.6756","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142851383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Complementary Use of Raman, ATR-FTIR Spectroscopy, and Chemometrics for Investigating the Deterioration of Artificially Aged Parchment","authors":"Ekaterini Malea,&nbsp;Stamatis C. Boyatzis,&nbsp;Dimitris Karlis,&nbsp;Dimitrios Palles,&nbsp;Soghomon Boghosian,&nbsp;Spiros Zervos","doi":"10.1002/jrs.6755","DOIUrl":"https://doi.org/10.1002/jrs.6755","url":null,"abstract":"<p>Among the materials constituting our cultural heritage, parchment has a significant role as the substrate of many archival documents. The assessment of its state of preservation has an important benefit to conservation and delineates the adequate preventive measures that would lead to better-controlled storage and exhibition conditions in museums and libraries worldwide. In the framework of this project, artificial aging of 48 new goat parchment samples was performed to induce deterioration similar to naturally aged parchment exposed to atmospheric pollutants. Five factors have been examined: relative humidity; NO₂; SO₂; exposure time, and the order of sequential exposure to NO₂ and SO₂. Temperature was kept constant at 25°C, while the effect of the above-mentioned factors was examined at two levels (low and high). Statistics was involved in advance in the experimental design. Raman spectroscopy along with attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy were used to investigate the condition of collagen in parchment. The entire set of environmental factors along with detected changes in the spectra were investigated through a chemometrics scheme involving analysis of variance (ANOVA). According to the results, the onset of collagen's secondary structure decomposition was observed. Statistical elaboration of data reveals that the two analytical methods (Raman and ATR-FTIR) function in a complementary manner related to the molecular changes and the chemical reactions that happen. In conclusion, both methods can increase their impact on the investigation of parchment degradation if they are combined with other analytical methods and chemometric applications.</p>","PeriodicalId":16926,"journal":{"name":"Journal of Raman Spectroscopy","volume":"55 12","pages":"1266-1280"},"PeriodicalIF":2.4,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jrs.6755","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142851384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Archaeometric Study of the Colorants in the Finds From the 4th Century BC Cist Tomb at Lakkoma, Chalcidice","authors":"Svetlana Vivdenko,&nbsp;Athina Vasileiadou,&nbsp;Maria Tsimbidou-Avlonitou,&nbsp;Alexandros Konstanta,&nbsp;Lydia Avlonitou,&nbsp;Nikolaos Zacharias","doi":"10.1002/jrs.6754","DOIUrl":"https://doi.org/10.1002/jrs.6754","url":null,"abstract":"<div>\u0000 \u0000 <p>The analytical findings concerning the red pigments used on various decorative features originating from a Macedonian, as well as the purple dye from the deceased's attire, are presented. The cist tomb, discovered in 1987 at the area of Lakkoma Chalcidice (Macedonia, Greece), dated to the 4th century <span>bc</span> and featured a wooden funeral couch with intricate ornaments, such as clay “eyes,” colored plaster, and clay gorgoneions. Vermilion and red ochre served as the main pigments of these decorative features. The pigments were applied in various combinations to produce a range of red hues, from deep to bright red. Furthermore, the precious vermilion was also used in every element of the couch. The stucco on the decoration was gypsum, whereas the preparation layers over clay and stucco elements consisted of calcite and lead white, respectively. The cloth covering the deceased was dyed with the most expensive organic dye of antiquity, the Tyrian (shellfish) purple. In this research, the preliminary identification of the chromophoric minerals in the colors of the samples was carried out with the examination of their optical characteristics in thin sections using polarizing light microscope (PLM) and with portable XRF. Physicochemical techniques, Raman and HPLC, were also used to definitively identify the pigments. Portable Raman spectrometer was used for the in situ analysis of the inorganic colorants of the decorative materials, whereas laboratory Raman spectrometer served for the identification of inorganic and organic colorants of the grain samples and the dye. High-pressure liquid chromatography with diode array detector (HPLC-DAD) was applied for the identification of the coloring components of the purple organic dye from the deceased's clothes. The samples examined (0.5- to 1.5-mm diameter) were collected during the initial cleaning of the surface.</p>\u0000 </div>","PeriodicalId":16926,"journal":{"name":"Journal of Raman Spectroscopy","volume":"55 12","pages":"1322-1332"},"PeriodicalIF":2.4,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142851581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Characterization of the Lattice Vibrations of Ammonium Nitrate in ANFO Mixture After Authentic Detonations Using Confocal Raman Microscopy and Single Crystal X-Ray Diffraction","authors":"Jared Estevanes,&nbsp;Nicholas Jernigan,&nbsp;Christopher Zall,&nbsp;Geraldine Monjardez","doi":"10.1002/jrs.6752","DOIUrl":"https://doi.org/10.1002/jrs.6752","url":null,"abstract":"<div>\u0000 \u0000 <p>This study aimed to characterize ammonium nitrate lattice vibrations in an ammonium nitrate and fuel oil mixture (ANFO) following authentic explosive events using confocal Raman microscopy and single-crystal X-ray diffraction (XRD). Two simulated IEDs were constructed and detonated, consisting of several different substrate materials, using ANFO as the main charge. Crystalline material was observed to be growing on several of the postblast substrates. Microscopical examination revealed the crystalline material to have isotropic and anisotropic characteristics. Following recrystallization from water, the material was identified as ammonium nitrate. Single-crystal X-ray diffraction enabled the identification of the unit cells and molecular structures of the crystals formed after the blast. The values corresponded to the known Phase IV structure of recrystallized ammonium nitrate; however, there were minor yet statistically significant variations in the distances in the unit cell dimensions and O–N–O angles. Ex situ analysis of isotropic crystalline fragment using confocal Raman microscopy determined that lattice vibrations within the material were different than the ANFO intact reference, with the blue shifting of several bands, the emergence of new bands, and the loss of other characteristic bands. It was determined that the isotropic crystalline material observed in the postblast residue consisted of stressed state Phase IV AN. This suggests that a thermal change of AN can be observed in the microscopical characteristics and Raman spectrum of the crystals, demonstrating the importance of low frequency Raman spectroscopy (10–250 cm⁻¹), which allows the identification of distinct spectral features of crystalline salts.</p>\u0000 </div>","PeriodicalId":16926,"journal":{"name":"Journal of Raman Spectroscopy","volume":"56 2","pages":"146-154"},"PeriodicalIF":2.4,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Raman Spectroscopy Reveals Microparticles in Synovial Fluids of Patients With Suspected Implant-Related Complications","authors":"Tom Niessink,&nbsp;Jorrit W. A. Schoenmakers,&nbsp;Matthijs Janssen,&nbsp;Marjan Wouthuyzen-Bakker,&nbsp;Sjouke Piersma,&nbsp;Marleen van Oosten,&nbsp;Jan Maarten van Dijl,&nbsp;Cees Otto,&nbsp;Tim L. Jansen","doi":"10.1002/jrs.6753","DOIUrl":"https://doi.org/10.1002/jrs.6753","url":null,"abstract":"<p>Prosthetic implant-associated inflammation and failure can be caused by bacterial infections and mechanical wear of the prosthesis. Currently, there is no diagnostic modality that allows simultaneous identification of both causes of implant failure. Here, we present a proof-of-principle study to assess whether Raman spectroscopy can be applied to diagnose implant failure. Synovial fluids from 10 patients with a clinical suspicion of implant-related complications were previously collected and cultured to determine the presence of bacteria. The presence of microparticles in these synovial fluids was assessed by Raman spectroscopy and verified by scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (SEM-EDX). For control, the possibility to detect in vitro<i>-</i>cultured <i>Staphylococcus aureus</i> by Raman spectroscopy was investigated. Raman spectroscopy revealed that all 10 synovial fluid samples contained microparticles: eight contained microplastics (polyethylene, polypropylene, and polystyrene), and nine contained titanium dioxide nanoparticles (anatase and rutile) as verified by SEM-EDX. There was no clear difference in the microparticle content of synovial fluids with or without bacteria. Raman signals relating to individual bacteria and clusters of bacteria were detectable in in vitro cultures of <i>S. aureus</i>, but it was not possible to demonstrate the presence of bacteria in synovial fluids by Raman spectroscopy. Raman spectroscopy is a potential tool for characterizing microparticles in synovial fluids from patients with implant-related complications. This is of clinical relevance as these microparticles can cause joint inflammation. The identification of bacteria by Raman spectroscopy is feasible, but further research is needed before clinical implementation.</p>","PeriodicalId":16926,"journal":{"name":"Journal of Raman Spectroscopy","volume":"56 2","pages":"127-134"},"PeriodicalIF":2.4,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jrs.6753","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Determination of Size, Size Distribution, and Concentration of Nanoparticles Using ICP-MS in the Context of SERS Substrates","authors":"Julie Horne,&nbsp;Pierre Beckers,&nbsp;Kevser Kemik,&nbsp;Charlotte De Bleye,&nbsp;Pierre-Yves Sacré,&nbsp;Nicolas Thelen,&nbsp;Philippe Hubert,&nbsp;Eric Ziemons,&nbsp;Cédric Hubert","doi":"10.1002/jrs.6746","DOIUrl":"https://doi.org/10.1002/jrs.6746","url":null,"abstract":"<div>\u0000 \u0000 <p>Surface enhanced Raman scattering (SERS) is a widely used vibrational spectroscopic technique employing metallic nanostructures to enhance an inherent Raman signal. This study aimed to develop a method for the characterization of SERS substrates in a single analysis by inductively coupled plasma mass spectrometry (ICP-MS) equipped with the single particle module (spICP-MS). For this development, the well-known Lee-Meisel protocol was selected as starting point to synthesize gold nanoparticles (AuNps) and silver nanoparticles (AgNps). A spICP-MS method was successfully developed and gave the mean size, size distribution, and concentration of nanoparticles in only one single analysis. Reference techniques were used to confirm these results namely dynamic light scattering, transmission electron microscopy, and UV–Visible spectroscopy. Thanks to the ICP-MS characterization, it was observed that AgNps synthesized by chemical reduction presented more variability than the AuNps. The dissolved elements concentration in the suspension was investigated. It appeared that reaction yields were close to 100% for the six syntheses. This analysis may be repeated over time to evaluate the suspension stability and monitor any potential degradation of Nps. To conclude, ICP-MS is a powerful technique to characterize SERS substrates and could be an interesting alternative to other characterization techniques.</p>\u0000 </div>","PeriodicalId":16926,"journal":{"name":"Journal of Raman Spectroscopy","volume":"56 2","pages":"117-126"},"PeriodicalIF":2.4,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143363030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Raman Spectra of \u0000\u0000 \u0000 \u0000 α\u0000 \u0000 $$ alpha $$\u0000 - and \u0000\u0000 \u0000 \u0000 β\u0000 \u0000 $$ beta $$\u0000 -Si3N4 and Si2N2O Determined Experimentally and by Density Functional Theory","authors":"Johannes T. Kehren,&nbsp;Michael Fischer,&nbsp;Olaf Krause","doi":"10.1002/jrs.6749","DOIUrl":"https://doi.org/10.1002/jrs.6749","url":null,"abstract":"<p>High-quality Raman spectra of the two silicon nitride polymorphs \u0000<span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>α</mi>\u0000 </mrow>\u0000 <annotation>$$ alpha $$</annotation>\u0000 </semantics></math>- and \u0000<span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>β</mi>\u0000 </mrow>\u0000 <annotation>$$ beta $$</annotation>\u0000 </semantics></math>-Si₃N₄ as well as of Si₂N₂O are presented here. This work significantly extends the previously available data on the Raman spectra of all three phases. For \u0000<span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>α</mi>\u0000 </mrow>\u0000 <annotation>$$ alpha $$</annotation>\u0000 </semantics></math>-Si₃N₄, a total of 34 Raman bands were confirmed, and for Si₂N₂O, a total of 19 Raman bands were observed for the first time. In the case of \u0000<span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>β</mi>\u0000 </mrow>\u0000 <annotation>$$ beta $$</annotation>\u0000 </semantics></math>-Si₃N₄, all 11 known Raman modes were confirmed. For further accuracy and comparison, the spectra of the three phases were also calculated with different density functional theory functionals. Good agreement between the experimental data and the calculated vibrational modes is shown. Between the different DFT functionals, the rSCAN functional had the best agreement with the experimental data, clearly outperforming the PBEsol functional.</p>","PeriodicalId":16926,"journal":{"name":"Journal of Raman Spectroscopy","volume":"56 2","pages":"155-164"},"PeriodicalIF":2.4,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jrs.6749","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Assessment of Time-Gated Raman Spectroscopy for Online Mineralogy of a Spodumene Ore","authors":"Teemu Laitinen,&nbsp;Marc Legault,&nbsp;Satu Ojala,&nbsp;Jean-François Boulanger","doi":"10.1002/jrs.6748","DOIUrl":"https://doi.org/10.1002/jrs.6748","url":null,"abstract":"<p>This paper investigates the applicability of time-gated Raman spectroscopy (TRS) for online mineralogy identification, focusing on a Li-bearing spodumene ore. The study provides an overview of existing online mineralogy tools and points out some limitations of elemental analysis techniques. Dense media separation concentrate and tailing samples used originated from a deposit in Quebec, Canada. Various techniques, including ICP-AES, XRD, laser diffraction, and specific gravity determination, were used for detailed sample characterization. Samples and their mixtures at known ratios were prepared as powder and slurries, before being analyzed using TRS, followed by spectrum quantitative analysis. Results show a linear correlation between spodumene percentage by weight and the main Raman peak height or area, in both dry and slurry form, with a higher determination coefficient in slurry form. TRS also provided indications as to the gangue minerals present in the samples. This study shows the potential for TRS as a tool for online mineralogical assessment of spodumene ores, and further work should target the determination of detection limits and quantification of both valuable and gangue minerals.</p>","PeriodicalId":16926,"journal":{"name":"Journal of Raman Spectroscopy","volume":"56 2","pages":"135-145"},"PeriodicalIF":2.4,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jrs.6748","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Particle Size on Raman Signal Strength of Silicate Minerals","authors":"Laura B. Breitenfeld,&nbsp;M. Darby Dyar,&nbsp;Elizabeth C. Sklute,&nbsp;Carey Legett","doi":"10.1002/jrs.6745","DOIUrl":"https://doi.org/10.1002/jrs.6745","url":null,"abstract":"<div>\u0000 \u0000 <p>Understanding the effects of particle size is necessary for quantifying minerals in mixtures using Raman spectroscopy. Raman signal intensity is evaluated using six common silicate minerals (two olivines, two pyroxenes, and two feldspars) at 10 particle size ranges. For olivines and feldspars, the highest peak intensities are observed in samples with 38–63 and 63–106 μm particle sizes. There is no such consistent trend for the pyroxene samples, although the overall low signal strength complicates those measurements. Raman spectra of samples with varying particle sizes appear to be influenced by two competing effects: scattering from particle boundaries and effective sampling volume.</p>\u0000 </div>","PeriodicalId":16926,"journal":{"name":"Journal of Raman Spectroscopy","volume":"56 2","pages":"184-187"},"PeriodicalIF":2.4,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143362864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}