拉曼光谱和FTIR-ATR光谱技术结合化学计量学:驴奶掺假的表征和比较

IF 2.4 3区 化学 Q2 SPECTROSCOPY
Sinem Çolak
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引用次数: 0

摘要

驴奶因其营养价值而成为一种新兴的流行食品。因为它有很高的附加值,它可能会掺假使用便宜的牛奶,如牛奶。本研究采用拉曼光谱法和FTIR-ATR光谱法对纯驴奶进行了快速鉴别,并进行了比较。对光谱进行了三种预处理方法。结果表明,与牛奶相比,驴奶的脂肪和蛋白质含量较低。值得注意的是,拉曼光谱根据β-胡萝卜素的存在与否成功地区分了驴奶和牛奶。主成分分析表明,牛、掺假驴和驴之间存在明显的分离。Raman数据的第一和第二pc的方差值为90.30% (PC1 = 72.76, PC2 = 17.53), FTIR数据的第一和第二pc的方差值为89.67% (PC1 = 65.25, PC2 = 24.41)。拉曼光谱数据可用于区分驴奶和牛奶,而红外光谱数据不足。用拉曼光谱和傅里叶红外光谱对掺假种属进行了分类。在FTIR光谱中,由于水存在一个宽峰,约占牛奶成分的87%,但这个水峰不包括在拉曼光谱中。结果表明,拉曼光谱是一种快速、可靠的分析方法,可作为驴奶中掺假的无损检测手段。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Simultaneous Raman and FTIR-ATR Spectroscopy Techniques Combined With Chemometrics: Characterization and Comparison of Donkey Milk Adulteration

Due to its nutritional qualities, donkey milk is a newly popular food. Because it has a high added value, it may be adulterated with using cheaper milks, like cow milk. This study has investigated a rapid method for the authentication of pure donkey milk using Raman and FTIR-ATR spectroscopy and comparison of the methods. Three preprocessing methods were applied to the spectra. The results show that donkey milk has lower fat and protein content compared with cow milk. Notably, Raman spectroscopy successfully distinguishes donkey and cow milk according to the presence and absence of β-carotene. Principal component analysis demonstrated a distinct separation between cow, adulterated donkey, and donkey. The variance value of 90.30% (PC1 = 72.76, PC2 = 17.53) is obtained from the first and second PCs for Raman data, and the variance value of 89.67% (PC1 = 65.25, PC2 = 24.41) is obtained from the first and second PCs for FTIR data. The Raman data could be used to separate donkey and cow milks, whereas the FTIR data were insufficient. It was observed that adulterated species could be separated between classes with Raman and FTIR. In the FTIR spectrum, there is a broad peak due to water, which accounts for about 87% of the milk composition, but this water peak is not included in the Raman spectrum. The results demonstrate the potential of Raman spectroscopy as a rapid and reliable method and suggest that it can be used as a nondestructive analytical tool for adulteration detection in donkey milk.

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来源期刊
CiteScore
5.40
自引率
8.00%
发文量
185
审稿时长
3.0 months
期刊介绍: The Journal of Raman Spectroscopy is an international journal dedicated to the publication of original research at the cutting edge of all areas of science and technology related to Raman spectroscopy. The journal seeks to be the central forum for documenting the evolution of the broadly-defined field of Raman spectroscopy that includes an increasing number of rapidly developing techniques and an ever-widening array of interdisciplinary applications. Such topics include time-resolved, coherent and non-linear Raman spectroscopies, nanostructure-based surface-enhanced and tip-enhanced Raman spectroscopies of molecules, resonance Raman to investigate the structure-function relationships and dynamics of biological molecules, linear and nonlinear Raman imaging and microscopy, biomedical applications of Raman, theoretical formalism and advances in quantum computational methodology of all forms of Raman scattering, Raman spectroscopy in archaeology and art, advances in remote Raman sensing and industrial applications, and Raman optical activity of all classes of chiral molecules.
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