Application of 3D Raman Mapping on Complex Inclusions: A Case Study of the Styrian Basin Mantle Xenoliths (W-Carpathian Pannonian Region)

IF 2.4 3区 化学 Q2 SPECTROSCOPY
Justine L. Myovela, László E. Aradi, Tamás Spránitz, Zoltán Taracsák, Máté Hegedűs, Patrik Konečný, János Kovács, Márta Berkesi
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Abstract

Fluid and melt inclusions trapped in mantle xenoliths provide direct insights into the metasomatic agent in the lithospheric mantle, including its volatile content. We conducted 3D Raman mapping on fluid and melt inclusions in modally metasomatized mantle xenoliths from the Styrian Basin (W-Carpathian Pannonian Region) to explore how this method can be utilized to study the role of fluids and melts in the upper mantle. 3D Raman mapping revealed complex phase assemblages of coexisting fluid and solid phases in the inclusions. Fluid phases are CO2 (49.2–98.4 mol%, 19.1–61.0 vol%) and H2O (1.5–50.8 mol%, 8.6–35.3 vol%). This H2O concentration range is considerably higher than in most mantle fluids (∼10–15 mol%). Solid phases are silicates, carbonates, sulfides, and sulfates present in varying volume% (vol%). 3D Raman mapping shows that liquid H2O wets other phases in the mapped fluid inclusions and may be preferentially lost compared to the CO2-rich phase during inclusion decrepitation. The accuracy of CO2-H2O mol ratios from Raman 3D mapping in fluid inclusions can be affected by variable Raman cross-sections of trapped phases. Therefore, thermodynamic modeling is recommended to validate measured CO2-H2O mol ratios. 3D Raman mapping may underestimate low Raman scatterers like silicate glass in fluid inclusions, but their volumes can be corrected based on FIB-SEM analyses. Thermodynamic modeling suggests that the fluid compositions in the Raman-mapped fluid inclusions may reflect non-equilibrium entrapment, whereas those in the melt inclusions reflect equilibrium entrapment in this mantle portion. The discovered C-O-H fluids provide new information on fluid-rock reactions in the lithospheric mantle.

Abstract Image

三维拉曼制图在复杂包裹体中的应用——以西喀尔巴阡潘诺尼亚盆地地幔包体为例
地幔捕虏体中的流体和熔体包裹体提供了对岩石圈地幔交代介质及其挥发性含量的直接认识。本文对Styrian盆地(W-Carpathian Pannonian Region)模态交代地幔包体中的流体和熔体进行了三维拉曼制图,探讨如何利用该方法研究流体和熔体在上地幔中的作用。三维拉曼图揭示了包裹体中流体和固相共存的复杂相组合。流体相为CO2 (49.2-98.4 mol%, 19.1-61.0 vol%)和H2O (1.5-50.8 mol%, 8.6-35.3 vol%)。这个水的浓度范围远高于大多数地幔流体(~ 10-15 mol%)。固相是硅酸盐、碳酸盐、硫化物和硫酸盐,以不同的体积% (vol%)存在。三维拉曼图显示,在绘制的流体包裹体中,液态水湿润了其他相,与富co2相相比,在包裹体剥蚀过程中,液态水可能优先丢失。流体包裹体拉曼三维制图中CO2-H2O摩尔比的准确性会受到捕获相拉曼截面变化的影响。因此,建议使用热力学建模来验证测量的CO2-H2O摩尔比。3D拉曼映射可能会低估低拉曼散射体,如流体包裹体中的硅酸盐玻璃,但它们的体积可以根据FIB-SEM分析进行校正。热力学模拟表明,拉曼图流体包裹体中的流体成分反映了地幔部分的非平衡包裹体,而熔体包裹体中的流体成分反映了地幔部分的平衡包裹体。发现的C-O-H流体为岩石圈地幔中流体-岩石反应提供了新的信息。
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来源期刊
CiteScore
5.40
自引率
8.00%
发文量
185
审稿时长
3.0 months
期刊介绍: The Journal of Raman Spectroscopy is an international journal dedicated to the publication of original research at the cutting edge of all areas of science and technology related to Raman spectroscopy. The journal seeks to be the central forum for documenting the evolution of the broadly-defined field of Raman spectroscopy that includes an increasing number of rapidly developing techniques and an ever-widening array of interdisciplinary applications. Such topics include time-resolved, coherent and non-linear Raman spectroscopies, nanostructure-based surface-enhanced and tip-enhanced Raman spectroscopies of molecules, resonance Raman to investigate the structure-function relationships and dynamics of biological molecules, linear and nonlinear Raman imaging and microscopy, biomedical applications of Raman, theoretical formalism and advances in quantum computational methodology of all forms of Raman scattering, Raman spectroscopy in archaeology and art, advances in remote Raman sensing and industrial applications, and Raman optical activity of all classes of chiral molecules.
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