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BODIPY类化合物的合成及其修饰方法概况 Synthesis of BODIPY Compounds and Their Modification Methods BODIPY类化合物的合成及其修饰方法概况 Synthesis of BODIPY Compounds and Their Modification Methods
Journal of Organic Chemistry Research Pub Date : 2017-03-08 DOI: 10.12677/JOCR.2017.51003
王南翔, 甄文
{"title":"BODIPY类化合物的合成及其修饰方法概况 Synthesis of BODIPY Compounds and Their Modification Methods","authors":"王南翔, 甄文","doi":"10.12677/JOCR.2017.51003","DOIUrl":"https://doi.org/10.12677/JOCR.2017.51003","url":null,"abstract":"近年来，氟硼二吡咯（BODIPY）类荧光化合物在生物标记、肿瘤光动力治疗（PDT）光敏剂、固态太阳能聚光器电致发光器件、荧光开光等不同领域中都成为了研究的焦点，特别是在传感器和生物探针方面。本文总结了BODIPY类化合物的多种合成及其修饰方法，希望对相关研究人员有所帮助。 In recent years, BODIPY (Boron-dipyrromethene complex) compounds have been the focus of many studies in diverse areas. BODIPYs are fully recognized as excellent fluorescent materials in tunable laser, biological labeling, photosensitizers and photodynamic therapy of tumor (PDT), solid-state solar concentrators, electroluminescent devices, on-off fluorescent switches etc., and in particular the fluorophores in sensors and probes. This paper summarizes the synthesis of BODIPY compounds and its modification methods, hoping to help the relevant researchers.","PeriodicalId":16596,"journal":{"name":"Journal of Organic Chemistry Research","volume":"42 1","pages":"15-20"},"PeriodicalIF":0.0,"publicationDate":"2017-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85466168","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Michael Addition Reaction of Indoles and α, β-Unsaturated Ketones Catalyzed by Br∅nsted Acidic Ionic Liquid 溴配置酸性离子液体催化吲哚与α， β-不饱和酮的Michael加成反应
Journal of Organic Chemistry Research Pub Date : 2017-01-01 DOI: 10.12677/JOCR.2017.52011
马 雪成
{"title":"The Michael Addition Reaction of Indoles and α, β-Unsaturated Ketones Catalyzed by Br∅nsted Acidic Ionic Liquid","authors":"马 雪成","doi":"10.12677/JOCR.2017.52011","DOIUrl":"https://doi.org/10.12677/JOCR.2017.52011","url":null,"abstract":"","PeriodicalId":16596,"journal":{"name":"Journal of Organic Chemistry Research","volume":"1 1","pages":"86-93"},"PeriodicalIF":0.0,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76336146","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on Synthesis, Crystal Structure and Fluorescence Properties of Schiff Base from 4-Aminoantipyrine 4-氨基安替比林席夫碱的合成、晶体结构及荧光性质研究
Journal of Organic Chemistry Research Pub Date : 2017-01-01 DOI: 10.12677/JOCR.2017.51001
刘 巧茹
{"title":"Study on Synthesis, Crystal Structure and Fluorescence Properties of Schiff Base from 4-Aminoantipyrine","authors":"刘 巧茹","doi":"10.12677/JOCR.2017.51001","DOIUrl":"https://doi.org/10.12677/JOCR.2017.51001","url":null,"abstract":"","PeriodicalId":16596,"journal":{"name":"Journal of Organic Chemistry Research","volume":"67 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84056602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Studies on the International Nomenclature of Organic Chemistry: (I) Functional Group and Characteristic Group 有机化学国际命名法研究:(一)官能团与特征团
Journal of Organic Chemistry Research Pub Date : 2017-01-01 DOI: 10.12677/JOCR.2017.53018
曹 忠民
{"title":"Studies on the International Nomenclature of Organic Chemistry: (I) Functional Group and Characteristic Group","authors":"曹 忠民","doi":"10.12677/JOCR.2017.53018","DOIUrl":"https://doi.org/10.12677/JOCR.2017.53018","url":null,"abstract":"","PeriodicalId":16596,"journal":{"name":"Journal of Organic Chemistry Research","volume":"96 1","pages":"137-141"},"PeriodicalIF":0.0,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77327232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
4-甲基-2-[(3,5-二甲基-4-甲氧基-2-吡啶基)甲硫基]-嘧啶的合成与分析 Synthesis and Analysis of 4-Methyl-2-[(3,5-Dimethyl-4-Methoxy-2-Pyridine)Methylmercapto]-Pyrimidine 4-甲基-2-[(3,5-二甲基-4-甲氧基-2-吡啶基)甲硫基]-嘧啶的合成与分析 Synthesis and Analysis of 4-Methyl-2-[(3,5-Dimethyl-4-Methoxy-2-Pyridine)Methylmercapto]-Pyrimidine
Journal of Organic Chemistry Research Pub Date : 2016-12-02 DOI: 10.12677/JOCR.2016.44015
陈向莹, 范芳芳, 夏佳美, 张千峰
{"title":"4-甲基-2-[(3,5-二甲基-4-甲氧基-2-吡啶基)甲硫基]-嘧啶的合成与分析 Synthesis and Analysis of 4-Methyl-2-[(3,5-Dimethyl-4-Methoxy-2-Pyridine)Methylmercapto]-Pyrimidine","authors":"陈向莹, 范芳芳, 夏佳美, 张千峰","doi":"10.12677/JOCR.2016.44015","DOIUrl":"https://doi.org/10.12677/JOCR.2016.44015","url":null,"abstract":"以2-巯基-4-甲基嘧啶盐酸盐为原料，与2-氯甲基-4-甲氧基-3,5-二甲基吡啶盐酸盐、甲醇钠反应，合成4-甲基-2-[(3,5-二甲基-4-甲氧基-2-吡啶基)甲硫基]-嘧啶。并通过1H NMR、FT-IR表征手段，对产物4-甲基-2-[(3,5-二甲基-4-甲氧基-2-吡啶基)甲硫基]-嘧啶进行谱学分析。 4-Methyl-2-[(3,5-dimethyl-4-methoxy-2-pyridine)methylmercapto]-pyrimidine was efficiently synthesized by reaction of 2-mercapto-4-methylpyrimidine hydrochloride and 2-chloromethyl-3,5- dimethyl-4-methoxypyridine hydrochloride in the presence of sodium methoxide. The product was well characterized by 1H NMR and FT-IR spectroscopies.","PeriodicalId":16596,"journal":{"name":"Journal of Organic Chemistry Research","volume":"95 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2016-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78080344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
磷钨酸促进的酰肼与查尔酮缩合反应的研究 Study on the Condensation Reaction of Hydrazide with Benzylideneacetophenone Catalyzed by Phosphotungstic Acid 磷钨酸促进的酰肼与查尔酮缩合反应的研究 Study on the Condensation Reaction of Hydrazide with Benzylideneacetophenone Catalyzed by Phosphotungstic Acid
Journal of Organic Chemistry Research Pub Date : 2016-12-02 DOI: 10.12677/JOCR.2016.44013
吴阳, 邢雪建, 邢刘桩, 侯亚东, 杨敬辉, 惠永海
{"title":"磷钨酸促进的酰肼与查尔酮缩合反应的研究 Study on the Condensation Reaction of Hydrazide with Benzylideneacetophenone Catalyzed by Phosphotungstic Acid","authors":"吴阳, 邢雪建, 邢刘桩, 侯亚东, 杨敬辉, 惠永海","doi":"10.12677/JOCR.2016.44013","DOIUrl":"https://doi.org/10.12677/JOCR.2016.44013","url":null,"abstract":"本文以杂多酸–磷钨酸为催化剂，对酰肼与查尔酮的缩合反应进行了研究。经过一系列反应条件的筛选，确立了最佳反应条件，并对底物的普适性进行了考察，得到了一系列高产率的酰腙类目标产物，最高产率达到99%。本反应操作简单，条件温和，为查尔酮酰腙合成提供了一种新的方法。 The condensation of hydrazide with benzylideneacetophenone was studied by using phospho-tungstic acid as catalyst. After a series of reaction conditions, the optimal reaction conditions were established, and the universality of the substrate was investigated. A series of acylhydrazones were obtained with the high yields, up to 99%. The reaction was simple and mild, which provided a new method for the synthesis of chalcone hydrazone.","PeriodicalId":16596,"journal":{"name":"Journal of Organic Chemistry Research","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2016-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82181715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
2-氯甲基-3,5-二甲基-4-甲氧基吡啶的合成及分析 Synthesis and Analysis of 2-Chloromethyl-3,5-Dimethyl-4-Methoxypyridine 2-氯甲基-3,5-二甲基-4-甲氧基吡啶的合成及分析 Synthesis and Analysis of 2-Chloromethyl-3,5-Dimethyl-4-Methoxypyridine
Journal of Organic Chemistry Research Pub Date : 2016-12-02 DOI: 10.12677/JOCR.2016.44014
陈向莹, 范芳芳, 夏佳美, 张千峰
{"title":"2-氯甲基-3,5-二甲基-4-甲氧基吡啶的合成及分析 Synthesis and Analysis of 2-Chloromethyl-3,5-Dimethyl-4-Methoxypyridine","authors":"陈向莹, 范芳芳, 夏佳美, 张千峰","doi":"10.12677/JOCR.2016.44014","DOIUrl":"https://doi.org/10.12677/JOCR.2016.44014","url":null,"abstract":"以2,3,5-三甲基吡啶为起始原料，经N-氧化、硝化、亲核取代、重排水解和氯甲基化等五大步骤而制得2-氯甲基-3,5-二甲基-4-甲氧基吡啶的合成与工艺。并通过1HNMR、FT-IR、HPLC等测试手段对2-氯甲基-3,5-二甲基-4-甲氧基吡啶产品进行定性和定量分析。 2-Chloromethyl-3,5-dimethyl-4-methoxypyridine was synthesized by use of 2,3,5-trimethylpyridine as the starting material. The synthetic route contains five steps including N-oxidation, nitration, nu-cleophilic substitution, alcoholation and chloromethylation. The target product was qualitatively and quantitatively analyzed using 1H NMR, FT-IR, and HPLC testing methods.","PeriodicalId":16596,"journal":{"name":"Journal of Organic Chemistry Research","volume":"48 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2016-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90745116","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Decoloring Research on Sweet Potato Leaf 甘薯叶片脱色研究
Journal of Organic Chemistry Research Pub Date : 2016-09-09 DOI: 10.12677/JOCR.2016.43012
粉玲 李
{"title":"Decoloring Research on Sweet Potato Leaf","authors":"粉玲 李","doi":"10.12677/JOCR.2016.43012","DOIUrl":"https://doi.org/10.12677/JOCR.2016.43012","url":null,"abstract":"以番薯叶为原料，采用超声波辅助提取精制多糖，通过高岭土、活性炭、过氧化氢设置各个量进行脱色反应，以及采用分光光度法测定脱色后的吸光度，计算脱色率。研究结果表明番薯叶在高岭土、活性炭、过氧化氢溶液中，在适宜条件下均有较好的脱色效果，其中，活性炭的脱色效果最好。 With sweet potato leaves as raw material, the ultrasonic assisted extraction has been used to refine polysaccharide through setting the kaolin clay, activated carbon and hydrogen peroxide amount to carry on the decolorizing reaction, using spectrophotometry after decolorizing absorbance, and decoloring rate calculation. Some research results show that the sweet potato leaves have good decolorization effect in kaolin clay, activated carbon, hydrogen peroxide solution, under appropriate conditions.","PeriodicalId":16596,"journal":{"name":"Journal of Organic Chemistry Research","volume":"8 1","pages":"82-92"},"PeriodicalIF":0.0,"publicationDate":"2016-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78316837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Synthesis and In Vitro Antitumor Activities of Lupanol Gallate 没食子酚酸酯的合成及体外抗肿瘤活性研究
Journal of Organic Chemistry Research Pub Date : 2016-09-09 DOI: 10.12677/JOCR.2016.43011
李 伟杰
{"title":"Synthesis and In Vitro Antitumor Activities of Lupanol Gallate","authors":"李 伟杰","doi":"10.12677/JOCR.2016.43011","DOIUrl":"https://doi.org/10.12677/JOCR.2016.43011","url":null,"abstract":"在缩合剂N,N'-二环己基碳二亚胺(DCC)和催化剂4-二甲氨基吡啶(DMAP)的作用下，羽扇烷醇与过量的没食子酸在二氯甲烷中回流10 h，合成了新化合物没食子酸羽扇烷醇酯，产率为69.6%。研究了没食子酸羽扇烷醇酯体外对肿瘤细胞株A549、LAC和HepG2的抑制活性。结果表明，羽扇烷醇和顺铂作为阳性对照物，它们对上述3株肿瘤细胞株的增殖没有抑制作用，没食子酸羽扇烷醇酯对A549、LAC和HepG2的IC50值分别是51.71、62.16和64.34 μM，其对肿瘤细胞株A549和LAC增殖的抑制作用不及阿霉素，而对HepG2增殖的抑制作用比阿霉素的强。 Under the presence of N,N'-dicyclohexylcarbodiimide (DDC) as dehydrating agent and 4-dimethyl- aminopyridine (DMAP) as catalyst, lupanol was refluxed with excessive gallic acid for 10 h in di-chloromethane to give lupanol gallate as a new compound at 69.6% yield. The latter was explored for in vitro antitumor activities against A549, LAC and HepG2 cell lines. The results showed that lupanol and cisplatin as positive control compounds had no inhibitory abilities against the above three tested tumor cell lines. The IC50 values of lupanol gallate against A549, LAC and HepG2 cells were 51.71 μM, 62.16 μM and 64.34 μM respectively. The antitumor activities of lupanol gallate against A549 and LAC cells were inferior to those of adriamycin, however its antitumor activity against HepG2 cell exceeded that of adriamycin.","PeriodicalId":16596,"journal":{"name":"Journal of Organic Chemistry Research","volume":"19 1","pages":"77-81"},"PeriodicalIF":0.0,"publicationDate":"2016-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75641739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical Constituents Pre-Analysis and Antioxidant Activity of the Puffball Calvatia candida from Foshan 佛山白念珠球化学成分分析及抗氧化活性研究
Journal of Organic Chemistry Research Pub Date : 2016-09-09 DOI: 10.12677/JOCR.2016.43010
吴 静姝
{"title":"Chemical Constituents Pre-Analysis and Antioxidant Activity of the Puffball Calvatia candida from Foshan","authors":"吴 静姝","doi":"10.12677/JOCR.2016.43010","DOIUrl":"https://doi.org/10.12677/JOCR.2016.43010","url":null,"abstract":"在综述秃马勃属真菌化学成分研究的基础上，通过多种指示剂和显色剂的显色反应或沉淀反应对佛山白秃马勃化学成分进行了预分析，并通过羟自由基(•OH)和1,1-二苯基-2-苦肼基(DPPH)清除试验评价了其甲醇提取物的体外抗氧化活性。结果表明，佛山白秃马勃含有生物碱、甾体和萜类化合物，具有有效的抗氧化活性，对•OH和DPPH自由基的半数清除浓度(IC50)分别为241.55和418.63 μg/mL。 Based on review of chemical composition of the genus of Calvatia sp., the chemical constituents of the puffball Calvatia candida from Foshan were analyzed by pre-test tube method, and its antioxi-dant activities were evaluated by the biochemical assay of hydroxyl and DPPH radicals scavenging activity in vitro. The results show that, the puffball Calvatia candida from Foshan contain alkaloids, steroids and terpenoids, and have potent antioxidant activities with IC50 values of 241.55 (for •OH) and 418.63 (for DPPH) μg/mL, respectively.","PeriodicalId":16596,"journal":{"name":"Journal of Organic Chemistry Research","volume":"22 1","pages":"69-76"},"PeriodicalIF":0.0,"publicationDate":"2016-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75302322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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