Journal of Nonlinear Optical Physics & Materials最新文献

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Unusually large magnetic moment and tricritical behavior of the CMR compound NaCr2O4 revealed with high resolution neutron diffraction and μ+ SR 高分辨中子衍射和μ+ SR分析表明,CMR化合物NaCr2O4具有异常大的磁矩和三临界行为
IF 2.7 4区 物理与天体物理
Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-11-24 DOI: 10.1088/2515-7639/acdf21
E. Nocerino, O. K. Forslund, H. Sakurai, A. Hoshikawa, N. Matsubara, D. Andreica, A. Zubayer, Federico Mazza, T. Saito, J. Sugiyama, I. Umegaki, Y. Sassa, M. Månsson
{"title":"Unusually large magnetic moment and tricritical behavior of the CMR compound NaCr2O4 revealed with high resolution neutron diffraction and μ+ SR","authors":"E. Nocerino, O. K. Forslund, H. Sakurai, A. Hoshikawa, N. Matsubara, D. Andreica, A. Zubayer, Federico Mazza, T. Saito, J. Sugiyama, I. Umegaki, Y. Sassa, M. Månsson","doi":"10.1088/2515-7639/acdf21","DOIUrl":"https://doi.org/10.1088/2515-7639/acdf21","url":null,"abstract":"The mixed valence Cr3+/Cr4+ compound NaCr2O4, hosts a plethora of unconventional electronic properties. In the present study, muon spin rotation/relaxation ( μ+ SR) and high-resolution time-of-flight neutron powder diffraction measurements were carried out on high-quality samples to clarify the complex magnetic ground state of this unique material. We identified a commensurate canted antiferromagnetic order (C-AFM) with a canting angle of the Cr spin axial vector equal to θc=(8.8±0.5)∘ , and an estimated Cr moment μCrC∼(4.30±0.01)μB . Such an unusually large value of μCrC is compatible with the existence of high-spin Cr sites created by the presence of an unconventional negative charge transfer state in NaCr2O4. In addition to the C-AFM structure, a novel magnetic supercell was also revealed. Such supercell display an incommensurate (IC)-AFM propagation vector (0 0 12−δ ), having a Cr moment μCrIC=(2.20±0.03)μB . It is suggested that the C-AFM and IC-AFM modulations have two different electronic origins, being due to itinerant and localized contributions to the magnetic moment respectively. Finally, the direct measurement of the magnetic order parameter for the C-AFM structure provided a value of the critical exponent β=0.245≈14 , suggesting a non conventional critical behavior for the magnetic phase transition in NaCr2O4.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"14 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84066958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Solution-based fullerene-free route enables high-performance green-selective organic photodetectors 基于溶液的无富勒烯路线实现高性能绿色选择有机光电探测器
IF 2.7 4区 物理与天体物理
Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-11-11 DOI: 10.1088/2515-7639/aca222
Yang Cao, J. Mei, Kai Xia, Ting Zhao, Jing Zhao, N. Gasparini, V. Pecunia
{"title":"Solution-based fullerene-free route enables high-performance green-selective organic photodetectors","authors":"Yang Cao, J. Mei, Kai Xia, Ting Zhao, Jing Zhao, N. Gasparini, V. Pecunia","doi":"10.1088/2515-7639/aca222","DOIUrl":"https://doi.org/10.1088/2515-7639/aca222","url":null,"abstract":"Ongoing developments in machine vision, wearables, and the Internet of Things have led to strong demand for easy-to-fabricate, color-selective photodetectors. Narrowband-absorption-type (NBA) printable organic photodetectors provide an attractive solution, given their spectral robustness and fabrication simplicity. However, a key remaining challenge to realizing their potential is to concurrently achieve high photoconversion efficiency and spectral selectivity. Herein, this challenge is tackled by investigating a non-fullerene-based route to green-selective, solution-based photodetectors. Soluble phthalocyanine acceptor PhO-Cl6BsubPc is considered due to its high absorption selectivity to green photons. Blends with soluble quinacridones are pursued to realize the ideal of a donor:acceptor layer selectively absorbing the target photons throughout its volume. A latent-pigment route to the solution-based deposition of linear trans-quinacridone (QA) enables well-intermixed QA:PhO-Cl6BsubPc layers. Green-selective photodetectors with cutting-edge performance are thus realized, achieving a 25% increase in external quantum efficiency compared to all prior solution-based NBA implementations, as well as a nearly five-fold enhancement of the green-to-blue spectral rejection ratio. The merit of this approach is further illustrated by comparison with the corresponding fullerene-based photodetectors. By demonstrating an approach to solution-based NBA photodetectors with cutting-edge photoconversion efficiency and spectral selectivity, this study represents an important step toward printable, high-performance organic color sensors and imagers.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"1 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90234407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Anisotropic Rashba coupling to polar modes in KTaO3 kta3中各向异性Rashba耦合与极模
IF 2.7 4区 物理与天体物理
Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-11-09 DOI: 10.1088/2515-7639/acb017
G. Venditti, M. Temperini, P. Barone, J. Lorenzana, M. Gastiasoro
{"title":"Anisotropic Rashba coupling to polar modes in KTaO3","authors":"G. Venditti, M. Temperini, P. Barone, J. Lorenzana, M. Gastiasoro","doi":"10.1088/2515-7639/acb017","DOIUrl":"https://doi.org/10.1088/2515-7639/acb017","url":null,"abstract":"Motivated by the discovery of superconductivity in KTaO3-based heterostructures, we study a pairing mechanism based on spin-orbit assisted coupling between the conduction electrons and the ferroelectric (FE) modes present in the material. We use ab initio frozen-phonon computations to show a linear-in-momentum Rashba-like coupling with a strong angular dependence in momentum for the lower j=3/2 manifold, deviating from the conventional isotropic Rashba model. This implies the Rashba-like interaction with the polar modes has substantial L = 3 cubic harmonic corrections, which we quantify for each electronic band. The strong anisotropy of the Rashba interaction is captured by a microscopic toy model for the t2g electrons. We find its origin to be the angular dependence in electronic momentum imposed by the kinetic term on the degenerate j=3/2 manifold. A comparison between the toy model and ab initio results indicates that additional symmetry allowed terms beyond odd-parity spin-conserving inter-orbital hopping processes are needed to describe the Rashba-like polar interaction between the electrons and the soft FE mode.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"1 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76365811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Spin-orbit torques due to extrinsic spin-orbit scattering of topological insulator surface states: out-of-plane magnetization 拓扑绝缘体表面态的外部自旋轨道散射引起的自旋轨道力矩:面外磁化
IF 2.7 4区 物理与天体物理
Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-11-02 DOI: 10.1088/2515-7639/ac9f6e
Mohsen Farokhnezhad, R. Asgari, D. Culcer
{"title":"Spin-orbit torques due to extrinsic spin-orbit scattering of topological insulator surface states: out-of-plane magnetization","authors":"Mohsen Farokhnezhad, R. Asgari, D. Culcer","doi":"10.1088/2515-7639/ac9f6e","DOIUrl":"https://doi.org/10.1088/2515-7639/ac9f6e","url":null,"abstract":"The origins of the spin-orbit torque (SOT) at ferromagnet/topological insulator interfaces are incompletely understood. The theory has overwhelmingly focussed on the Edelstein effect due to the surface states in the presence of a scalar scattering potential. We investigate here the contribution to the SOT due to extrinsic spin-orbit (SO) scattering of the surface states, focusing on the case of an out-of-plane magnetization. We show that SO scattering brings about a sizable renormalization of the field-like SOT, which exceeds 20 % at larger strengths of the extrinsic SO parameter. The resulting SOT exhibits a maximum as a function of the Fermi energy, magnetization, and extrinsic SO strength. The field-like SOT decreases with increasing disorder strength, while the damping-like SOT is independent of the impurity density. With experimental observation in mind we also determine the role of extrinsic SO scattering on the anomalous Hall effect. Our results suggest extrinsic SO scattering is a significant contributor to the surface SOT stemming from the Edelstein effect when the magnetization is out of the plane.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"25 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87777580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Advanced characterization of organic–metal and organic–organic interfaces: from photoelectron spectroscopy data to energy-level diagrams 有机-金属和有机-有机界面的高级表征:从光电子能谱数据到能级图
IF 2.7 4区 物理与天体物理
Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-11-02 DOI: 10.1088/2515-7639/ac9f6f
Qi Wang, Jiacheng Yang, A. Gerlach, F. Schreiber, S. Duhm
{"title":"Advanced characterization of organic–metal and organic–organic interfaces: from photoelectron spectroscopy data to energy-level diagrams","authors":"Qi Wang, Jiacheng Yang, A. Gerlach, F. Schreiber, S. Duhm","doi":"10.1088/2515-7639/ac9f6f","DOIUrl":"https://doi.org/10.1088/2515-7639/ac9f6f","url":null,"abstract":"Organic–metal and organic–organic interfaces account for the functionality of virtually all organic optoelectronic applications and the energy-level alignment is of particular importance for device performance. Often the energy-level alignment is simply estimated by metal work functions and ionization energies and electron affinities of the organic materials. However, various interfacial effects such as push back, mirror forces (also known as screening), electronic polarization or charge transfer affect the energy-level alignment. We perform x-ray and ultraviolet photoelectron spectroscopy (XPS and UPS) measurements on copper-hexadecafluorophthalocyanine (F16CuPc) and titanyl-phthalocyanine (TiOPc) thin films on Ag(111) and use TiOPc bilayers to decouple F16CuPc layers from the metal substrate. Even for our structurally well-characterized model interfaces and by stepwise preparation of vacuum-sublimed samples, a precise assignment of vacuum-level and energy-level shifts remains challenging. Nevertheless, our results provide guidelines for the interpretation of XPS and UPS data of organic–metal and organic–organic interfaces.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"289 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77904334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Accelerated design of chalcogenide glasses through interpretable machine learning for composition–property relationships 通过可解释的机器学习来加速设计硫系玻璃的组成-性质关系
IF 2.7 4区 物理与天体物理
Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-11-01 DOI: 10.1088/2515-7639/acc6f2
Sayam Singla, Sajid Mannan, Mohd Zaki, N. Krishnan
{"title":"Accelerated design of chalcogenide glasses through interpretable machine learning for composition–property relationships","authors":"Sayam Singla, Sajid Mannan, Mohd Zaki, N. Krishnan","doi":"10.1088/2515-7639/acc6f2","DOIUrl":"https://doi.org/10.1088/2515-7639/acc6f2","url":null,"abstract":"Chalcogenide glasses (ChGs) possess various outstanding properties enabling essential applications, such as optical discs, infrared cameras, and thermal imaging systems. Despite their ubiquitous usage, these materials’ composition–property relationships remain poorly understood, impeding the pace of their discovery. Here, we use a large experimental dataset comprising ∼24 000 glass compositions made of 51 distinct elements from the periodic table to develop machine learning (ML) models for predicting 12 properties, namely, annealing point, bulk modulus, density, Vickers hardness, Littleton point, Young’s modulus, shear modulus, softening point, thermal expansion coefficient, glass transition temperature, liquidus temperature, and refractive index. These models are the largest regarding the compositional space and the number of properties covered for ChGs. Further, we use Shapley additive explanations, a game theory-based algorithm, to explain the properties’ compositional control by quantifying each element’s role toward model predictions. This work provides a powerful tool for interpreting the model’s prediction and designing new ChG compositions with targeted properties. Finally, using the trained ML models, we develop several glass-selection charts that can potentially aid in the rational design of novel ChGs for various applications.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"20 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90840861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Photonics design theory enhancing light extraction efficiency in quantum dot light emitting diodes 提高量子点发光二极管光提取效率的光子设计理论
IF 2.7 4区 物理与天体物理
Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-10-28 DOI: 10.1088/2515-7639/ac9e77
Diyar Mousa Othman, Julia A Weinstein, Quan Lyu, Bo Hou
{"title":"Photonics design theory enhancing light extraction efficiency in quantum dot light emitting diodes","authors":"Diyar Mousa Othman, Julia A Weinstein, Quan Lyu, Bo Hou","doi":"10.1088/2515-7639/ac9e77","DOIUrl":"https://doi.org/10.1088/2515-7639/ac9e77","url":null,"abstract":"The external quantum efficiency (EQE) of quantum dot light emitting diodes (QLEDs) needs improvement for more power-efficient devices. One of the main limitations is the low light extraction efficiency (LEE). Generally, only 20% of the light that is generated inside the emissive layer makes its way out of the device into air, with the rest being lost to waveguide and substrate modes and surface plasmon polaritons. Different photonics structures have been previously tested to help extract the light that is trapped inside the device. Here we report a photonics design which is a combination of nanopillars and grating structures for improving the LEE of QLEDs. The effect of changing the nanopillar height, radius and material has been studied. It was found that ZnO nanopillars of 500 nm pitch, 200 nm height and 400 nm width alongside 150 nm width and pitch grating structure can increase the LEE at 460 nm by 50% and at 640 nm by 20%. It was also found that different materials can help extract light at different wavelengths. TiO2 nanopillars increased the extraction efficiency at ∼590 nm region which was not observed by the other materials. As around 19% of the world’s electricity consumption is due to lighting applications, increasing the LEE can significantly reduce the power consumption.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"2007 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82473425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Impact of atomic defects in the electronic states of FeSe 1−x S x superconducting crystals 原子缺陷对FeSe 1−x sx超导晶体电子态的影响
IF 2.7 4区 物理与天体物理
Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-10-26 DOI: 10.1088/2515-7639/ac9dc1
Jazmín Aragón Sánchez, M. L. Amigó, C. H. Belussi, M. V. Ale Crivillero, S. Suarez, J. Guimpel, G. Nieva, J. Esteban Gayone, Y. Fasano
{"title":"Impact of atomic defects in the electronic states of FeSe 1−x S x superconducting crystals","authors":"Jazmín Aragón Sánchez, M. L. Amigó, C. H. Belussi, M. V. Ale Crivillero, S. Suarez, J. Guimpel, G. Nieva, J. Esteban Gayone, Y. Fasano","doi":"10.1088/2515-7639/ac9dc1","DOIUrl":"https://doi.org/10.1088/2515-7639/ac9dc1","url":null,"abstract":"The electronic properties of Fe-based superconductors are drastically affected by deformations on their crystal structure introduced by doping and pressure. Here we study single crystals of FeSe 1−x S x and reveal that local crystal deformations such as atomic-scale defects impact the spectral shape of the electronic core level states of the material. By means of scanning tunneling microscopy we image S-doping induced defects as well as diluted dumbbell defects associated with Fe vacancies. We have access to the electronic structure of the samples by means of x-ray photoemission spectroscopy (XPS) and show that the spectral shape of the Se core levels can only be adequately described by considering a principal plus a minor component of the electronic states. We find this result for both pure and S-doped samples, irrespective that in the latter case the material presents extra crystal defects associated to doping with S atoms. We argue that the second component in our XPS spectra is associated with the ubiquitous dumbbell defects in FeSe that are known to entail a significant modification of the electronic clouds of surrounding atoms.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"25 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82233987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Anomalous Hall effect and two-dimensional Fermi surfaces in the charge-density-wave state of kagome metal RbV3Sb5 kagome金属RbV3Sb5电荷密度波态的反常霍尔效应和二维费米面
IF 2.7 4区 物理与天体物理
Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-10-24 DOI: 10.1088/2515-7639/acba46
Lingfei Wang, Wei Zhang, Zheyu Wang, Tsz Fung Poon, Wenyan Wang, Chun Wai Tsang, Jianyu Xie, Xuefeng Zhou, Yusheng Zhao, Shanmin Wang, K. Lai, S. Goh
{"title":"Anomalous Hall effect and two-dimensional Fermi surfaces in the charge-density-wave state of kagome metal RbV3Sb5","authors":"Lingfei Wang, Wei Zhang, Zheyu Wang, Tsz Fung Poon, Wenyan Wang, Chun Wai Tsang, Jianyu Xie, Xuefeng Zhou, Yusheng Zhao, Shanmin Wang, K. Lai, S. Goh","doi":"10.1088/2515-7639/acba46","DOIUrl":"https://doi.org/10.1088/2515-7639/acba46","url":null,"abstract":"AV3Sb5 (A = Cs, K, Rb) is a recently discovered superconducting system ( Tc∼0.9 –2.5 K) in which the vanadium atoms adopt the kagome structure. Intriguingly, these systems enter a charge-density-wave (CDW) phase ( TCDW∼80 –100 K), and further evidence shows that the time-reversal symmetry is broken in the CDW phase. Concurrently, the anomalous Hall effect (AHE) has been observed in KV3Sb5 and CsV3Sb5 inside the novel CDW phase. Here, we report a comprehensive study of a high-quality RbV3Sb5 single crystal with magnetotransport measurements. Our data demonstrate the emergence of the AHE in RbV3Sb5 when the CDW state develops. The magnitude of the anomalous Hall resistivity in the low temperature limit is comparable to the reported values in KV3Sb5 and CsV3Sb5. The magnetoresistance channel further reveals a rich spectrum of quantum oscillation frequencies, many of which have not been reported before. In particular, a large quantum oscillation frequency (2235 T), which occupies ∼56% of the Brillouin zone area, was recorded. For the quantum oscillation frequencies with sufficient signal-to-noise ratio, we further perform field angle-dependent measurements, and our data indicate two-dimensional Fermi surfaces in RbV3Sb5. Our results provide indispensable information for understanding the AHE and band structure in kagome metal AV3Sb5.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"18 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72942047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Anisotropic magnetic and transport properties of orthorhombic o-Pr2Co3Ge5 正交型o-Pr2Co3Ge5的各向异性磁性和输运性质
IF 2.7 4区 物理与天体物理
Journal of Nonlinear Optical Physics & Materials Pub Date : 2022-10-17 DOI: 10.1088/2515-7639/ac9ad9
Trent M Kyrk, Ellis Kennedy, Jorge R. Galeano-Cabral, Kaya Wei, G. McCandless, M. Scott, R. Baumbach, J. Chan
{"title":"Anisotropic magnetic and transport properties of orthorhombic o-Pr2Co3Ge5","authors":"Trent M Kyrk, Ellis Kennedy, Jorge R. Galeano-Cabral, Kaya Wei, G. McCandless, M. Scott, R. Baumbach, J. Chan","doi":"10.1088/2515-7639/ac9ad9","DOIUrl":"https://doi.org/10.1088/2515-7639/ac9ad9","url":null,"abstract":"The crystal structure, electron energy-loss spectroscopy (EELS), heat capacity, and anisotropic magnetic and resistivity measurements are reported for Sn flux grown single crystals of orthorhombic Pr2Co3Ge5 (U2Co3Si5-type, Ibam). Our findings show that o-Pr2Co3Ge5 hosts nearly trivalent Pr ions, as evidenced by EELS and fits to temperature dependent magnetic susceptibility measurements. Complex magnetic ordering with a partially spin-polarized state emerges near T sp = 32 K, with a spin reconfiguration transition near T M = 15 K. Heat capacity measurements show that the phase transitions appear as broad peaks in the vicinity of T sp and T M. The magnetic entropy further reveals that crystal electric field splitting lifts the Hund’s rule degeneracy at low temperatures. Taken together, these measurements show that Pr2Co3Ge5 is an environment for complex f state magnetism with potential strongly correlated electron states.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"2 1 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72501982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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