Mehrad Ahmadpour, M. Prete, Um Kanta Aryal, A. U. Petersen, Mariam Ahmad, H.-G. Rubahn, Malte F. Jespersen, K. Mikkelsen, V. Turkovic, M. Nielsen, M. Madsen
{"title":"Device engineering of organic solar cells based on a boron subphthalocyanine electron donor molecule","authors":"Mehrad Ahmadpour, M. Prete, Um Kanta Aryal, A. U. Petersen, Mariam Ahmad, H.-G. Rubahn, Malte F. Jespersen, K. Mikkelsen, V. Turkovic, M. Nielsen, M. Madsen","doi":"10.1088/2515-7639/acada2","DOIUrl":"https://doi.org/10.1088/2515-7639/acada2","url":null,"abstract":"A boron subphthalocyanine molecule has been employed as a novel electron donor in organic solar cells (OPVs), and optimized in terms of composition and device structure in small molecule solar cells. It is demonstrated that the power conversion efficiency (PCE) of the devices obtained by solution-processing in bulk heterojunction solar cells could be improved by one order of magnitude by changing the fabrication method to vacuum deposition, which promotes a better morphology in the OPV active layers. Importantly, upon insertion of an additional pristine C70 thin interlayer between the active layer and the hole transport layer the PCE was further improved, highlighting the importance of interfacial layer engineering in such subphthalocyanine small molecule OPVs.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"24 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82561337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
João Rocha Maia, R. Sobreiro‐Almeida, F. Cleymand, J. Mano
{"title":"Biomaterials of human source for 3D printing strategies","authors":"João Rocha Maia, R. Sobreiro‐Almeida, F. Cleymand, J. Mano","doi":"10.1088/2515-7639/acada1","DOIUrl":"https://doi.org/10.1088/2515-7639/acada1","url":null,"abstract":"Three-dimensional printing has risen in recent years as a promising approach that fast-tracked the biofabrication of tissue engineering constructs that most resemble utopian tissue/organ replacements for precision medicine. Additionally, by using human-sourced biomaterials engineered towards optimal rheological proprieties of extrudable inks, the best possible scaffolds can be created. These can encompass native structure and function with a low risk of rejection, enhancing overall clinical outcomes; and even be further optimized by engaging in information- and computer-driven design workflows. This paper provides an overview of the current efforts in achieving ink’s necessary rheological and print performance proprieties towards biofabrication from human-derived biomaterials. The most notable step for arranging such characteristics to make biomaterials inks are the employed crosslinking strategies, for which examples are discussed. Lastly, this paper illuminates the state-of-the-art of the most recent literature on already used human-sourced inks; with a final emphasis on future perspectives on the field.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"101 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77268990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Orthorhombic distortion and rectangular skyrmion crystal in a centrosymmetric tetragonal host","authors":"S. Hayami","doi":"10.1088/2515-7639/acab89","DOIUrl":"https://doi.org/10.1088/2515-7639/acab89","url":null,"abstract":"We theoretically investigate the stability of a rectangular skyrmion crystal without fourfold rotational symmetry under an orthorhombic distortion in centrosymmetric tetragonal magnets. The results are obtained by numerically simulated annealing for an effective spin model with competing interactions in momentum space and magnetic anisotropy. By constructing the low-temperature phase diagram while changing the interaction ratio arising from the orthorhombic distortion, we find that the rectangular skyrmion crystal remains stable in an external magnetic field against distortion. We show that the degree of fourfold rotational symmetry tends to recover when the magnetic field is increased. The relevance to the skyrmion-hosting material EuAl4 is also discussed.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"37 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81398044","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
G. Ciofani, M. Campisi, C. Mattu, R. Kamm, V. Chiono, A. M. Raynold, J. S. Freitas, Eugenio Redolfi Riva, S. Micera, C. Pucci, F. Novio, J. Lorenzo, D. Ruíz-Molina, Giulia Sierri, F. Re, Hannah Wunderlich, Prachi Kumari, K. Kozielski, Mounia Chami, Attilio Marino, Lino Ferreira
{"title":"Roadmap on nanomedicine for the central nervous system","authors":"G. Ciofani, M. Campisi, C. Mattu, R. Kamm, V. Chiono, A. M. Raynold, J. S. Freitas, Eugenio Redolfi Riva, S. Micera, C. Pucci, F. Novio, J. Lorenzo, D. Ruíz-Molina, Giulia Sierri, F. Re, Hannah Wunderlich, Prachi Kumari, K. Kozielski, Mounia Chami, Attilio Marino, Lino Ferreira","doi":"10.1088/2515-7639/acab88","DOIUrl":"https://doi.org/10.1088/2515-7639/acab88","url":null,"abstract":"In recent years, a great deal of effort has been undertaken with regards to treatment of pathologies at the level of the central nervous system (CNS). Here, the presence of the blood-brain barrier acts as an obstacle to the delivery of potentially effective drugs and makes accessibility to, and treatment of, the CNS one of the most significant challenges in medicine. In this Roadmap article, we present the status of the timeliest developments in the field, and identify the outstanding challenges and opportunities that exist. The format of the Roadmap, whereby experts in each discipline share their viewpoint and present their vision, reflects the dynamic and multidisciplinary nature of this research area, and is intended to generate dialogue and collaboration across traditional subject areas. It is stressed here that this article is not intended to act as a comprehensive review article, but rather an up-to-date and forward-looking summary of research methodologies pertaining to the treatment of pathologies at the level of the CNS.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"1985 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90326374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fabrication of high-surface-area, SiO2 supported polyimide carbon aerogel microspheres: electrochemical application","authors":"Shin-Chih Liu, Jianqi Ji, Yixing Wang, Cenqi Yan, Huitao Bai, Jiaqiang Qin, Pei Cheng","doi":"10.1088/2515-7639/acaa59","DOIUrl":"https://doi.org/10.1088/2515-7639/acaa59","url":null,"abstract":"A series of polyimide (PI)/SiO2 aerogel microspheres were prepared by using polyamide acid salt and hydrolyzed tetraethyl orthosilicate based on the reverse-phase emulsion method. Then, PI/SiO2 aerogel microspheres were carbonized and etched to obtain carbon aerogel microspheres (CAMs). Scanning electron microscope, transmission electron microscope and nitrogen isothermal adsorption were used to characterize the micro-morphology and pore structure of the microspheres; and electrochemical workstation was used to test the electrochemical performance of the CAMs. The results showed that CAMs with different pore structures and specific surface area were obtained by adjusting the content of SiO2. Highest specific surface area of 1166.9 m2 g−1 and a total pore volume of 1.2369 cm3 g−1 were achieved at a SiO2 content of 50%. When used as the electrode materials for supercapacitors, these CAMs demonstrated a maximum specific capacitance of 125.1 F g−1 in a three-electrode system and a maximum capacitance of 53.3% at 30 A g−1. This article provides a new strategy for the preparation of CAMs with high specific surface area by using linear PI precursor and SiO2 support skeleton.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"20 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81178581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Hidding, Sytze H Tirion, J. Momand, A. Kaverzin, M. Mostovoy, B. V. van Wees, B. Kooi, M. Guimarães
{"title":"Corrigendum: Interfacial spin–orbit torques and magnetic anisotropy in WSe2/permalloy bilayers (2021 J. Phys. Mater. 4 04LT01)","authors":"J. Hidding, Sytze H Tirion, J. Momand, A. Kaverzin, M. Mostovoy, B. V. van Wees, B. Kooi, M. Guimarães","doi":"10.1088/2515-7639/aca71c","DOIUrl":"https://doi.org/10.1088/2515-7639/aca71c","url":null,"abstract":"Upon further analysis of the data","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"8 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87513633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Constructing hierarchical porous structure in microsized silicon/carbon nanotubes composite anode with LiF-rich solid-electrolyte interfaces for highly stable lithium-ion batteries","authors":"Meiying Liang, Ji Liu, Ailis O'Shea, V. Nicolosi","doi":"10.1088/2515-7639/aca936","DOIUrl":"https://doi.org/10.1088/2515-7639/aca936","url":null,"abstract":"Lithium-ion batteries (LIBs) with silicon microparticle anodes provide a high capacity, low cost, low environmental impact, and ease of production. However, the rapid capacity degradation and low Coulombic efficiency (CE) are impediments to their further development and commercialization, which are mainly caused by large volume variation and unstable solid–electrolyte interface (SEI) of silicon. To break this bottleneck, here, we demonstrate that designing silicon microparticles with nanoporous structure (PSi) and confining the PSi in the carbon nanotube (CNT) segregated network can effectively suppress the volume expansion of silicon, enabling the fabrication of high-performance electrodes. The rate capability and cycling performance of the electrode are further improved by creating a hierarchical open porous structure for the PSi-CNT composite anodes via freeze drying. In addition, the mixTHF electrolyte was employed to get a thin and uniform SEI, which can reduce the breakage of SEI during cycling and improve the CE and stability of the LIBs. As a result, the PSi-CNT composite anode delivers a high specific capacity of 3210.1 mAh g−1 at 1/15 °C rate and an initial Coulombic efficiency of 87.3%. After 100 cycles, the capacity could be maintained at over 2000 mAh g−1 with 99.5% CE. In addition, hierarchical porous structured PSi-CNT composites exhibit excellent rate performance, the specific capacity could reach 2264.5 mAh g−1 at 5 °C rate. The work suggests several effective solutions that could be used to facilitate the future commercialization of silicon anodes.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"15 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75443777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jakob Lenz, M. Statz, K. Watanabe, T. Taniguchi, F. Ortmann, R. Weitz
{"title":"Charge transport in single polymer fiber transistors in the sub-100 nm regime: temperature dependence and Coulomb blockade","authors":"Jakob Lenz, M. Statz, K. Watanabe, T. Taniguchi, F. Ortmann, R. Weitz","doi":"10.1088/2515-7639/aca82f","DOIUrl":"https://doi.org/10.1088/2515-7639/aca82f","url":null,"abstract":"Even though charge transport in semiconducting polymers is of relevance for a number of potential applications in (opto-)electronic devices, the fundamental mechanism of how charges are transported through organic polymers that are typically characterized by a complex nanostructure is still open. One of the challenges which we address here, is how to gain controllable experimental access to charge transport at the sub-100 nm lengthscale. To this end charge transport in single poly(diketopyrrolopyrrole-terthiophene) fiber transistors, employing two different solid gate dielectrics, a hybrid Al2O3/self-assembled monolayer and hexagonal boron nitride, is investigated in the sub-50 nm regime using electron-beam contact patterning. The electrical characteristics exhibit near ideal behavior at room temperature which demonstrates the general feasibility of the nanoscale contacting approach, even though the channels are only a few nanometers in width. At low temperatures, we observe nonlinear behavior in the current–voltage characteristics in the form of Coulomb diamonds which can be explained by the formation of an array of multiple quantum dots at cryogenic temperatures.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"115 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80858186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hannes Hase, Melissa Berteau-Rainville, Somaiyeh Charoughchi, W. Bodlos, E. Orgiu, I. Salzmann
{"title":"Critical dopant concentrations govern integer and fractional charge-transfer phases in doped P3HT","authors":"Hannes Hase, Melissa Berteau-Rainville, Somaiyeh Charoughchi, W. Bodlos, E. Orgiu, I. Salzmann","doi":"10.1088/2515-7639/aca71e","DOIUrl":"https://doi.org/10.1088/2515-7639/aca71e","url":null,"abstract":"The conjugated polymer poly(3-hexylthiophene) (P3HT) p-doped with the strong acceptor tetrafluorotetracyanoquinodimethane (F4TCNQ) is known to undergo ion-pair (IPA) formation, i.e. integer-charge transfer, and, as only recently reported, can form ground state charge-transfer complexes (CPXs) as a competing process, yielding fractional charge transfer. As these fundamental charge-transfer phenomena differently affect doping efficiency and, thus, organic-semiconductor device performance, possible factors governing their occurrence have been under investigation ever since. Here, we focus on the role of a critical dopant concentration deciding over IPA- or CPX-dominated regimes. Employing a broad, multi-technique approach, we compare the doping of P3HT by F4TCNQ and its weaker derivatives F2TCNQ, FTCNQ, and TCNQ, combining experiments with semi-classical modeling. IPA, CPX, and neutral-dopant ratios (estimated from vibrational absorption spectroscopy) together with electron affinity and ionization energy values (deduced from cyclic voltammetry) allow calculating the width of a Gaussian density of states (DOS) relating to the highest occupied molecular orbital in P3HT. While a broader DOS indicates energetic disorder, we use grazing-incidence x-ray diffraction to assess spatial order. Our findings consider the proposal of nucleation driving IPA formation and we hypothesize a certain host-dopant stoichiometry to be key for the formation of a crystalline CPX phase.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"23 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82062530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Meinero, F. Caglieris, A. Leveratto, L. Repetto, M. Fujioka, Y. Takano, U. Zeitler, I. Pallecchi, M. Putti
{"title":"Magnetotransport as a probe for the interplay between Sm and Fe magnetism in SmFeAsO","authors":"M. Meinero, F. Caglieris, A. Leveratto, L. Repetto, M. Fujioka, Y. Takano, U. Zeitler, I. Pallecchi, M. Putti","doi":"10.1088/2515-7639/aca71d","DOIUrl":"https://doi.org/10.1088/2515-7639/aca71d","url":null,"abstract":"The complex magnetic ordering of parent compounds of most unconventional superconductors is crucial for the understanding of high-temperature superconductivity (SC). Within this framework, we have performed temperature-dependent magnetotransport experiments on a single crystal of SmFeAsO, a parent compound of iron pnictide superconductors. We observe multiple features in the measured transport properties at temperatures below the antiferromagnetic (AFM) ordering of Sm, T<TNSm , which evolve with in-plane magnetic field, suggesting a rich variety of metamagnetic transitions never before observed in this compound. Considering that transport mainly involves Fe d orbitals at the Fermi level, these findings suggest that the features originate from magnetic transitions of the Fe moments sublattice, which in turn may be induced by magnetic transitions of the Sm moments sublattice via the interaction between Fe and Sm moments. We outline a possible scenario in which the Fe moments, strongly affected by the Sm ordering below T NSm, reorder to an in-plane canted AFM structure, which is washed out by the application of an in-plane magnetic field up to 9 T. Our work shows that transport properties are a valuable tool for investigating magnetic ordering in iron pnictide parent compounds, where the interplay of magnetism and SC is believed to be the origin of high-temperature SC.","PeriodicalId":16520,"journal":{"name":"Journal of Nonlinear Optical Physics & Materials","volume":"41 1","pages":""},"PeriodicalIF":2.7,"publicationDate":"2022-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88027344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}