Journal of Luminescence最新文献

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Camphor-modified porphyrins: Near-infrared CPL emission at aggregation states
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-04-11 DOI: 10.1016/j.jlumin.2025.121250
Liangbin Lin , Sining Zheng , Yun Li , Hongyu Guo , Fafu Yang
{"title":"Camphor-modified porphyrins: Near-infrared CPL emission at aggregation states","authors":"Liangbin Lin ,&nbsp;Sining Zheng ,&nbsp;Yun Li ,&nbsp;Hongyu Guo ,&nbsp;Fafu Yang","doi":"10.1016/j.jlumin.2025.121250","DOIUrl":"10.1016/j.jlumin.2025.121250","url":null,"abstract":"<div><div>The near-infrared dyes with high CPL properties in aggregated state were important but rarely reported. In this work, two camphor-modified porphyrins were designed and synthesized in high yields by the simple procedures. They exhibited good CPL properties in both solution and aggregation states. The absolute fluorescence quantum yields attained 0.16 and 0.18 in solid films. The biggest g<sub>lum</sub> values of were as high as 2.08 × 10<sup>−2</sup> at 758 nm in THF/H<sub>2</sub>O (5/95) and 1.70 × 10<sup>−2</sup> at 736 nm in solid state. This work suggested that the large volume chiral camphor groups not only have good chiral transfer effect for producing CPL emission for porphyrin moieties, but also possess large steric hindrance to reduce ACQ effect for achieving excellent CPL luminescence in aggregated states.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"282 ","pages":"Article 121250"},"PeriodicalIF":3.3,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Ca content on optical, scintillation and thermoluminescence performance of LuAG:Ce ceramic scintillators
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-04-10 DOI: 10.1016/j.jlumin.2025.121245
Chen Hu , Danyang Zhu , Yanbin Wang , Romana Kucerkova , Alena Beitlerova , Martin Nikl , Jiang Li
{"title":"Effect of Ca content on optical, scintillation and thermoluminescence performance of LuAG:Ce ceramic scintillators","authors":"Chen Hu ,&nbsp;Danyang Zhu ,&nbsp;Yanbin Wang ,&nbsp;Romana Kucerkova ,&nbsp;Alena Beitlerova ,&nbsp;Martin Nikl ,&nbsp;Jiang Li","doi":"10.1016/j.jlumin.2025.121245","DOIUrl":"10.1016/j.jlumin.2025.121245","url":null,"abstract":"<div><div>Ce doped Lu<sub>3</sub>Al<sub>5</sub>O<sub>12</sub> (LuAG:Ce) is a scintillator that attracts attention due to its high light yield, fast scintillation response, and excellent radiation resistance. In this study, optical and scintillation performance of Ca<sup>2+</sup> co-doped LuAG:Ce ceramics, fabricated by two-step sintering combined with air annealing, was investigated. In addition, thermoluminescence (TSL) of these LuAG:Ce,Ca ceramics was studied. Decrease of TSL glow curve intensity was observed with increasing Ca<sup>2+</sup> content. In particular, the TSL signal becomes hard to detect when Ca<sup>2+</sup> content is higher than 0.1 at.%. Ca<sup>2+</sup> co-doping is also beneficial for suppressing the slow scintillation component. Sample with Ca<sup>2+</sup> co-doping level of 0.1 at.% shows an optimized light yield of 11 700 ph/MeV with scintillation decay showing a high fast component/total intensity ratio of 98.3 %, which is the highest value ever reported in the Ca<sup>2+</sup> co-doped LuAG:Ce.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"282 ","pages":"Article 121245"},"PeriodicalIF":3.3,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Achieving tunable dual-bands self-trapped excitons emission in Sb3+/Bi3+- codoped Cs2ZrCl6 by modulating the excitation wavelength
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-04-10 DOI: 10.1016/j.jlumin.2025.121243
Weifeng Zhao , Feifei Ma , Tingting Zhang , Tianfu Gao , Haiyi Luo , Lanting Huang , Qingping Li , Bing Xu , Qinghua Li
{"title":"Achieving tunable dual-bands self-trapped excitons emission in Sb3+/Bi3+- codoped Cs2ZrCl6 by modulating the excitation wavelength","authors":"Weifeng Zhao ,&nbsp;Feifei Ma ,&nbsp;Tingting Zhang ,&nbsp;Tianfu Gao ,&nbsp;Haiyi Luo ,&nbsp;Lanting Huang ,&nbsp;Qingping Li ,&nbsp;Bing Xu ,&nbsp;Qinghua Li","doi":"10.1016/j.jlumin.2025.121243","DOIUrl":"10.1016/j.jlumin.2025.121243","url":null,"abstract":"<div><div>Lead-free perovskites exhibit excellent photoelectric properties, making them widely concerned in optoelectronic and photovoltaic fields. The broadband emission and self-absorption-free properties of lead-free perovskites-derived self-trapped excitons (STEs) are broadly applied in lighting, display, radiation detection and etc. Herein, Sb<sup>3+</sup>/Bi<sup>3+</sup> codoped Cs<sub>2</sub>ZrCl<sub>6</sub> perovskites with dual-band STEs emission are synthesized through thermal precipitation method. Optimizing excitation wavelength and ion doping amounts assisted in the precise adjustment of the intensity ratio with regard to the emission bands. Specially, the study acquired a white light emission with CIE (Commission Internationale de l'Éclairage) coordinates of (0.33, 0.34) and color rendering index (CRI) (Ra) value of 83. Time-resolved and temperature-dependent fluorescence spectra served for ascertaining the interactions between the dual-bands emission. This work reveals the luminescent mechanism underlying the dual-bands STEs emission and demonstrates its large value in versatile lighting applications.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"282 ","pages":"Article 121243"},"PeriodicalIF":3.3,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative studies of Er3+/Yb3+ co-doped GdCa4O(BO3)3, Gd0.5Y0.5Ca4O(BO3)3 and YCa4O(BO3)3 crystals as 1.55 μm laser materials
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-04-10 DOI: 10.1016/j.jlumin.2025.121246
Chenglong Wang , Xilei Cao , Xinghong Gong , Jianhua Huang , Yanfu Lin , Yidong Huang , Yujin Chen
{"title":"Comparative studies of Er3+/Yb3+ co-doped GdCa4O(BO3)3, Gd0.5Y0.5Ca4O(BO3)3 and YCa4O(BO3)3 crystals as 1.55 μm laser materials","authors":"Chenglong Wang ,&nbsp;Xilei Cao ,&nbsp;Xinghong Gong ,&nbsp;Jianhua Huang ,&nbsp;Yanfu Lin ,&nbsp;Yidong Huang ,&nbsp;Yujin Chen","doi":"10.1016/j.jlumin.2025.121246","DOIUrl":"10.1016/j.jlumin.2025.121246","url":null,"abstract":"<div><div>Er<sup>3+</sup> (1 at%) and Yb<sup>3+</sup> (20 at%) co-doped GdCa<sub>4</sub>O(BO<sub>3</sub>)<sub>3</sub>, Gd<sub>0.5</sub>Y<sub>0.5</sub>Ca<sub>4</sub>O(BO<sub>3</sub>)<sub>3</sub>, and YCa<sub>4</sub>O(BO<sub>3</sub>)<sub>3</sub> crystals were successfully grown by the Czochralski method. Their thermal, spectral, and 1.55 μm laser properties were investigated and compared. The thermal expansion anisotropy of the Er<sup>3+</sup>/Yb<sup>3+</sup>:Gd<sub>0.5</sub>Y<sub>0.5</sub>Ca<sub>4</sub>O(BO<sub>3</sub>)<sub>3</sub> crystal is the weakest among the three crystals. The Er<sup>3+</sup>/Yb<sup>3+</sup>:Gd<sub>0.5</sub>Y<sub>0.5</sub>Ca<sub>4</sub>O(BO<sub>3</sub>)<sub>3</sub> crystal has the larger absorption cross section at 976 nm and emission cross section at 1545 nm than those of the other two crystals. Caused by the high maximum phonon energy close to 1260 cm<sup>−1</sup>, the Yb<sup>3+</sup>→Er<sup>3+</sup> energy transfer efficiency in all crystals is higher than 90 %. Under the identical experimental conditions, 1548 nm continuous-wave laser performance obtained in the Er<sup>3+</sup>/Yb<sup>3+</sup>:Gd<sub>0.5</sub>Y<sub>0.5</sub>Ca<sub>4</sub>O(BO<sub>3</sub>)<sub>3</sub> crystal is superior to those of the other two crystals. The results show that the Er<sup>3+</sup>/Yb<sup>3+</sup>:Gd<sub>0.5</sub>Y<sub>0.5</sub>Ca<sub>4</sub>O(BO<sub>3</sub>)<sub>3</sub> crystal may be a better 1.55 μm laser gain medium compared with the Er<sup>3+</sup>/Yb<sup>3+</sup> co-doped GdCa<sub>4</sub>O(BO<sub>3</sub>)<sub>3</sub> and YCa<sub>4</sub>O(BO<sub>3</sub>)<sub>3</sub> crystals.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"282 ","pages":"Article 121246"},"PeriodicalIF":3.3,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143816855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced interfacial engineering with Poly-TPD for CsPbBr3-based perovskite light emitting diodes 利用 Poly-TPD 对基于 CsPbBr3 的过氧化物发光二极管进行先进的界面工程设计
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-04-09 DOI: 10.1016/j.jlumin.2025.121241
Lalita , Ashish Kumar , Harshit Sharma , Vidya Nand Singh , Ritu Srivastava
{"title":"Advanced interfacial engineering with Poly-TPD for CsPbBr3-based perovskite light emitting diodes","authors":"Lalita ,&nbsp;Ashish Kumar ,&nbsp;Harshit Sharma ,&nbsp;Vidya Nand Singh ,&nbsp;Ritu Srivastava","doi":"10.1016/j.jlumin.2025.121241","DOIUrl":"10.1016/j.jlumin.2025.121241","url":null,"abstract":"<div><div>Perovskite based light-emitting diodes are showing significant potential for next-generation displays and lighting applications as a result of easy solvent-based manufacture, high photoluminescence quantum efficiency, and tunable electronic bandgaps. Despite these advantages, morphological defects, unbalanced charge transport, and stability challenges hinder its broad applications in light-emitting devices. Herein, we introduce a simple and affordable approach to address these challenges; we fabricated the device having structure ITO/PEDOT:PSS/poly-TPD/CsPbBr<sub>3</sub>-Poly-TPD/BCP/TPBi/LiF/Al by spin coating and thermal deposition technique. To improve the morphology of the CsPbBr<sub>3</sub> active layer, encapsulate QDs using poly-TPD for fabrication of LEDs. The interfacial chemistry of nanocrystals was tuned to obtain moderately enhanced luminescence and efficient charge transport in the perovskite layer by adjusting the concentration of the hole transport layer beneath the active layer, which is CsPbBr<sub>3</sub> QDs mixed with the poly-TPD matrix. Full-width half maxima within 20 ± 0.5 nm after mixing with poly-TPD in the emissive layer, indicating a high degree of color purity; this type of material is well-suited for an expanded color gamut in display applications. We demonstrated a device with better surface morphology, shown by atomic force microscopy with the optimized hole transport layer concentration. The study could open the door for perovskite polymer union for better optoelectronic devices such as large-scale production of LEDs, flexible display, and stability in the air.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"282 ","pages":"Article 121241"},"PeriodicalIF":3.3,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nonstoichiometric cation engineering in SrGaxO4:Nd for near-infrared persistent luminescence
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-04-09 DOI: 10.1016/j.jlumin.2025.121225
Jian-An Zeng , Qiang Tang , Zi-Hao Chen , Weijiang Gan , Rongfu Zhou , Jing Wang , Bo-Mei Liu
{"title":"Nonstoichiometric cation engineering in SrGaxO4:Nd for near-infrared persistent luminescence","authors":"Jian-An Zeng ,&nbsp;Qiang Tang ,&nbsp;Zi-Hao Chen ,&nbsp;Weijiang Gan ,&nbsp;Rongfu Zhou ,&nbsp;Jing Wang ,&nbsp;Bo-Mei Liu","doi":"10.1016/j.jlumin.2025.121225","DOIUrl":"10.1016/j.jlumin.2025.121225","url":null,"abstract":"<div><div>Persistent luminescence (PersL) plays an important role in applications such as display, optical information storage, bioimaging, and bead assays for personalized medicine. To date, the development of PersL materials with excellent performance in the second near-infrared (NIR) window (1000–1700 nm) is a challenging but urgent task that can provide high resolution and deep tissue penetration for bioimaging and biosensing. Here, A strategy for creating novel PersL materials by introducing quantitative cationic vacancies is presented. Hence, a tailored NIR PersL SrGa<em><sub>x</sub></em>O<sub>4</sub>:Nd<sup>3+</sup> (<em>x</em> &lt; 2) bearing Ga cation vacancies was synthesized by continuously introducing nonstoichiometric defects. Moreover, this design ideal guided by utilizing cation-deficient materials as PersL hosts can be used as a powerful guide to accelerate the discovery of novel PersL materials with much clearer mechanisms. Our discovery of this NIR PersL material offers prospects for potential applications in bioimaging and biosensing and beyond.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"282 ","pages":"Article 121225"},"PeriodicalIF":3.3,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143820538","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Red-emitting LiAlSiO4:Eu3+ nanophosphors: A versatile material for lighting, forensic and anti-counterfeiting technologies
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-04-09 DOI: 10.1016/j.jlumin.2025.121240
T.N. Megharaj , B.R. Radha Krushna , G.R. Mamatha , B. Bommalingaiah , S.C. Sharma , Subhashree Ray , V.J. Subha , Augustine George , K. Manjunatha , Sheng Yun Wu , R. Arunakumar , G. Ramakrishna , H. Nagabhushana
{"title":"Red-emitting LiAlSiO4:Eu3+ nanophosphors: A versatile material for lighting, forensic and anti-counterfeiting technologies","authors":"T.N. Megharaj ,&nbsp;B.R. Radha Krushna ,&nbsp;G.R. Mamatha ,&nbsp;B. Bommalingaiah ,&nbsp;S.C. Sharma ,&nbsp;Subhashree Ray ,&nbsp;V.J. Subha ,&nbsp;Augustine George ,&nbsp;K. Manjunatha ,&nbsp;Sheng Yun Wu ,&nbsp;R. Arunakumar ,&nbsp;G. Ramakrishna ,&nbsp;H. Nagabhushana","doi":"10.1016/j.jlumin.2025.121240","DOIUrl":"10.1016/j.jlumin.2025.121240","url":null,"abstract":"<div><div>High-performance red-emitting LiAlSiO<sub>4</sub>:Eu<sup>3+</sup> (0–11 mol%) nanophosphors (LASO:Eu<sup>3+</sup> NPs) are successfully synthesized via an eco-friendly, low-temperature solution combustion method, employing mushroom extract as a green fuel for the first time. These NPs are developed for applications in white light-emitting diodes (w-LEDs) and latent fingerprints (LFPs) visualization. Under 393 nm excitation (<sup><em>7</em></sup><em>F</em><sub><em>0</em></sub> <em>→</em> <sup><em>5</em></sup><em>L</em><sub><em>6</em></sub> transition), LASO:Eu<sup>3+</sup> NPs exhibit a prominent emission peak at 616 nm, corresponding to the <sup><em>5</em></sup><em>D</em><sub><em>0</em></sub> <em>→</em> <sup><em>7</em></sup><em>F</em><sub><em>2</em></sub> transition. The optimal doping concentration is determined to be 7 mol%, with concentration quenching primarily influenced by neighbouring ion interactions. The Commission Internationale de l’Éclairage (CIE) chromaticity coordinates of LASO:7Eu<sup>3+</sup> NPs are determined to be (0.616, 0.377), with a color purity (CP) of 98.3 % and an average correlated color temperature (CCT) of 1832 K. Furthermore, the phosphors are evaluated for temperature-sensing capabilities based on the fluorescence intensity ratio (FIR) technique. The phosphor retains ∼86.10 % PL intensity at 423 K and exhibits internal quantum yield (<em>I</em><sub><em>QE</em></sub>) of 65.20 %. Relative sensitivity is assessed using two different peak ratios, yielding maximum values at 303 K of 0.45 % K<sup>−1</sup> for I<sub>537</sub>/I<sub>592</sub> and 1.04 % K<sup>−1</sup> for I<sub>537</sub>/I<sub>616</sub>. The suitability of the phosphor for the powder dusting method in fingerprints (FPs) detection on various surfaces is also assessed. Under 365 nm UV light, the LASO:7Eu<sup>3+</sup> NPs clearly reveals the level I–III features of LFPs. A new anti-counterfeiting (AC) material utilizing LASO:7Eu<sup>3+</sup> phosphor has been developed, showcasing intense red luminescence under UV light and offering distinctive optical features for secure and dependable authentication in advanced security systems. Overall, LASO:7Eu<sup>3+</sup> NPs showing excellent red emission, thermal stability, and quantum efficiency. Their multifunctionality makes them promising candidates for w-LEDs, optical thermometry, and high-resolution LFPs detection.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"282 ","pages":"Article 121240"},"PeriodicalIF":3.3,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Achieving blue light excitation and broadband NIR-II region emission regulation of ALaMgSbO6: Ni2+ (A=Ca, Sr, Ba) phosphors
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-04-08 DOI: 10.1016/j.jlumin.2025.121237
Wei Wang , Shikun Su , Hui Xu , Wenhua Yang , Lizhen Zhao , Wenying Teng , Xiaowei Yang , Xun Sun , Haiyang Zhang , Jialin Cui , Yangkai Zhang , Bing Teng , Degao Zhong
{"title":"Achieving blue light excitation and broadband NIR-II region emission regulation of ALaMgSbO6: Ni2+ (A=Ca, Sr, Ba) phosphors","authors":"Wei Wang ,&nbsp;Shikun Su ,&nbsp;Hui Xu ,&nbsp;Wenhua Yang ,&nbsp;Lizhen Zhao ,&nbsp;Wenying Teng ,&nbsp;Xiaowei Yang ,&nbsp;Xun Sun ,&nbsp;Haiyang Zhang ,&nbsp;Jialin Cui ,&nbsp;Yangkai Zhang ,&nbsp;Bing Teng ,&nbsp;Degao Zhong","doi":"10.1016/j.jlumin.2025.121237","DOIUrl":"10.1016/j.jlumin.2025.121237","url":null,"abstract":"<div><div>Obtaining broadband near-infrared (NIR) II region phosphors that can be effectively excited by blue light chips remains a significant challenge in the current construction of compact NIR light sources. In this work, a novel series of Ni<sup>2+</sup>-activated ALaMgSbO<sub>6</sub> (A = Ca, Sr, Ba) double perovskite phosphors were designed and synthesized. By substituting the A-site ions, tunable broadband emission of Ni<sup>2+</sup> in the NIR-II region was achieved. Experiments and theoretical calculations show that A-site substitution and Ni<sup>2+</sup> doping have a certain impact on the luminescence performance. When the A-site was occupied by Ca<sup>2+</sup>, the CaLaMgSbO<sub>6</sub>: 1.2 % Ni<sup>2+</sup> phosphor showed the highest emission intensity. Under 440 nm blue light excitation, CaLaMgSbO<sub>6</sub>: 1.2 % Ni<sup>2+</sup> achieved long-wavelength broadband NIR emission centered at 1546 nm with a full width at half maximum (FWHM) of 229 nm and photoluminescence quantum yield of 32.94 %. Finally, CaLaMgSbO<sub>6</sub>: 1.2 % Ni<sup>2+</sup> phosphor was coated on a 440 nm blue light chip to package NIR-LED, verifying its feasibility in material detection and night vision. These results have opened up new ways to develop efficient broadband NIR-II region LED light sources.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"282 ","pages":"Article 121237"},"PeriodicalIF":3.3,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143807348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synchronous realization of green upconversion emission enhancement and optical temperature sensitivity improvement in phosphors NaYF4: Yb, Ho via Mn doping
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-04-08 DOI: 10.1016/j.jlumin.2025.121239
Zhuoyue Li , Zhenlong Cheng , Maoxiu Huang , Qingkai Chen , Yuanli Liu , Zhiyi He , Jun Ou
{"title":"Synchronous realization of green upconversion emission enhancement and optical temperature sensitivity improvement in phosphors NaYF4: Yb, Ho via Mn doping","authors":"Zhuoyue Li ,&nbsp;Zhenlong Cheng ,&nbsp;Maoxiu Huang ,&nbsp;Qingkai Chen ,&nbsp;Yuanli Liu ,&nbsp;Zhiyi He ,&nbsp;Jun Ou","doi":"10.1016/j.jlumin.2025.121239","DOIUrl":"10.1016/j.jlumin.2025.121239","url":null,"abstract":"<div><div>In this paper, highly fluorescent, structurally homogeneous, and small-sized NaYF<sub>4</sub> upconversion nanoparticles were synthesized via the hydrothermal method, Yb/Ho/Mn co-doping altered the local symmetry of the crystals, slightly deforming their structure and enhancing the fluorescence intensity of the nanocrystals. The strong green light emission from the synthesized samples was mechanistically explained by energy transfer upconversion combined with excited state absorption process involving Yb-Mn dimers. The highest fluorescence intensity was observed with 15 mol% Mn<sup>2+</sup>, which increased the fluorescence intensity by a factor of approximately 10.88 compared to the undoped sample. Furthermore, this work explored the optical temperature-sensing properties of these upconversion fluorescent nanocrystals for non-contact temperature measurement, leveraging thermal and non-thermal coupling mechanisms. It provided a promising strategy for developing high-performance optical temperature sensors using other transition metal-doped lanthanide materials.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"282 ","pages":"Article 121239"},"PeriodicalIF":3.3,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143820537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient management of excitons in near-infrared organic light-emitting diodes employing interlayer sensitization strategy
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-04-07 DOI: 10.1016/j.jlumin.2025.121238
Jie Hua , Zhuolin Zhan , Wenbo Song , Kuiyuan Gao , Chunyu Wei , Haipeng Jiang , Jianan Dai , Yuan Chai , He Dong , Jin Wang
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