Journal of Luminescence最新文献

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DFT and experimental investigation of nanostructured boron subphthalocyanine chloride-films based hybrid photodiodes: Bridging organic and inorganic materials for sustainable light detection 基于纳米结构亚酞菁氯硼薄膜的杂化光电二极管的DFT和实验研究:用于可持续光探测的桥接有机和无机材料
IF 3.6 3区 物理与天体物理
Journal of Luminescence Pub Date : 2026-05-01 Epub Date: 2026-01-21 DOI: 10.1016/j.jlumin.2026.121757
Ibtisam Alali , Nada Alhathlaul , Alaa Muqbil Alsirhani , Shimaa Abdel Halim , A.A.M. Farag
{"title":"DFT and experimental investigation of nanostructured boron subphthalocyanine chloride-films based hybrid photodiodes: Bridging organic and inorganic materials for sustainable light detection","authors":"Ibtisam Alali ,&nbsp;Nada Alhathlaul ,&nbsp;Alaa Muqbil Alsirhani ,&nbsp;Shimaa Abdel Halim ,&nbsp;A.A.M. Farag","doi":"10.1016/j.jlumin.2026.121757","DOIUrl":"10.1016/j.jlumin.2026.121757","url":null,"abstract":"<div><div>This study presents a comprehensive investigation of boron subphthalocyanine chloride (B-SubPcCl), combining computational and experimental approaches to reveal its unique structural, electronic, and optoelectronic characteristics. DFT calculations at the B3LYP/SDD level reveal that the molecule adopts a non-planar geometry and exhibits a ground-state energy gap of 2.68 eV, a substantial dipole moment of 8.19 D, and a first hyperpolarizability significantly exceeding that of urea, confirming its strong nonlinear optical (NLO) potential. Complementary NBO and MEP analyses demonstrate pronounced intramolecular charge transfer and clearly defined reactive regions, emphasizing the molecule's inherent electronic versatility and suitability for advanced optoelectronic applications. Experimentally, thermally evaporated thin films exhibit uniform nanocrystalline morphology with an average grain size of 27.1 nm and low RMS roughness (∼2.8 nm), as confirmed by HRTEM and AFM. Optical studies reveal multiple band gaps (1.35, 2.24, and 2.78 eV) with broad absorption spanning UV–visible–NIR regions. The Au/B-SubPcCl/n-Si/Al heterojunction shows strong rectifying behavior with a dark rectification ratio exceeding 10<sup>3</sup>, high responsivity, and detectivity, alongside fast, stable phototransient response and a light-dependent resistance ratio above 30 at −2 V. These results establish B-SubPcCl as a highly promising material for advanced optoelectronic and NLO devices, combining computational predictions with experimental validation to highlight its novel multifunctional performance.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"293 ","pages":"Article 121757"},"PeriodicalIF":3.6,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090335","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Peculiarities in the prompt isothermal luminescence decay of four feldspars 四种长石的快速等温发光衰减特性
IF 3.6 3区 物理与天体物理
Journal of Luminescence Pub Date : 2026-05-01 Epub Date: 2026-01-22 DOI: 10.1016/j.jlumin.2026.121777
Th. Lampoudi , P. Konstandinidis , G.S. Polymeris , G. Kitis
{"title":"Peculiarities in the prompt isothermal luminescence decay of four feldspars","authors":"Th. Lampoudi ,&nbsp;P. Konstandinidis ,&nbsp;G.S. Polymeris ,&nbsp;G. Kitis","doi":"10.1016/j.jlumin.2026.121777","DOIUrl":"10.1016/j.jlumin.2026.121777","url":null,"abstract":"<div><div>The prompt isothermal (PID) decay of luminescence at a stable temperature is defined as an specific stimulated luminescence effect. The PID stimulation mode is described by three types of analytical expressions: two derived from the one-trap-one-recombination model (OTOR) and another from the tunneling recombination model. These two families of models exhibit potentially significant differences. Specifically, the OTOR-based is expected to retain an exponential dependence of the decay on temperature, whereas the tunneling recombination model may exhibit temperature-independent behavior. The present work studies the PID of luminescence of four feldspar samples in order to investigate the delocalized or localized nature of the decay. The initial rise technique was applied in order to examine if the glow curve of all feldspar are due to discrete or continuous energy levels. All PID curves obtained were fitted by three analytical expressions derived from OTOR delocalized and localized models as well as from a tunneling (localized) recombination model. The results showed that the PID effect presents a weak dependence of decay temperature yielding activation energy values much lower that the values of initial rise. Special attention was given to fitting parameters which are microscopic quantities characteristic of the trapping and recombination systems. The basic question arisen from this work is why in the framework of the same measurement the TL during linear heating is due to delocalized transitions whereas the TL from decay at stable temperature is due to localized transitions.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"293 ","pages":"Article 121777"},"PeriodicalIF":3.6,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrafast carrier dynamics related to energy transfer and hole transfer in (PEA)2PbI4/MoS2 heterostructure (PEA)2PbI4/MoS2异质结构中与能量转移和空穴转移相关的超快载流子动力学
IF 3.6 3区 物理与天体物理
Journal of Luminescence Pub Date : 2026-05-01 Epub Date: 2026-02-11 DOI: 10.1016/j.jlumin.2026.121798
Meng Xue , Shuwen Zheng , Zhongpo Zhou , Jian Song , Zhaoyong Jiao , Shuhong Ma , Guangrui Jia , Chaochao Qin
{"title":"Ultrafast carrier dynamics related to energy transfer and hole transfer in (PEA)2PbI4/MoS2 heterostructure","authors":"Meng Xue ,&nbsp;Shuwen Zheng ,&nbsp;Zhongpo Zhou ,&nbsp;Jian Song ,&nbsp;Zhaoyong Jiao ,&nbsp;Shuhong Ma ,&nbsp;Guangrui Jia ,&nbsp;Chaochao Qin","doi":"10.1016/j.jlumin.2026.121798","DOIUrl":"10.1016/j.jlumin.2026.121798","url":null,"abstract":"<div><div>The emergence of van der Waals heterostructures based on two-dimensional (2D) transition metal dichalcogenides (TMDs) and perovskites has provided a good basis for the study of high-performance photodetectors, light-emitting diodes, and other optoelectronic devices in recent years. This study focuses on the heterostructure formed by two-dimensional perovskite (PEA)<sub>2</sub>PbI<sub>4</sub> and monolayer MoS<sub>2</sub>. The interface transfer behavior of the heterostructure was obtained using femtosecond transient absorption spectra at different excitation wavelengths. The research results show that there are both hole transfer and energy transfer within the (PEA)<sub>2</sub>PbI<sub>4</sub>/MoS<sub>2</sub> heterostructure. The hole transfer rate constant is 2 × 10<sup>11</sup> s<sup>−1</sup>. However, due to the large band gap of the organic spacer layer of (PEA)<sub>2</sub>PbI<sub>4</sub>, the direct electron transfer process is blocked. This discovery provides a reference for in-depth exploration of the potential applications in the field of optoelectronic devices.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"293 ","pages":"Article 121798"},"PeriodicalIF":3.6,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146190491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction of dynamic lighting system based on chlorophyll absorption efficacy and its regulation effect on lettuce growth 基于叶绿素吸收效应的动态照明系统构建及其对生菜生长的调节作用
IF 3.6 3区 物理与天体物理
Journal of Luminescence Pub Date : 2026-05-01 Epub Date: 2026-02-05 DOI: 10.1016/j.jlumin.2026.121792
Lili Zheng , Ziquan Guo
{"title":"Construction of dynamic lighting system based on chlorophyll absorption efficacy and its regulation effect on lettuce growth","authors":"Lili Zheng ,&nbsp;Ziquan Guo","doi":"10.1016/j.jlumin.2026.121792","DOIUrl":"10.1016/j.jlumin.2026.121792","url":null,"abstract":"<div><div>In response to the need for optimizing the light quality of artificial lighting in indoor agriculture, this study proposes an adaptive plant illumination system based on chlorophyll absorption efficacy (CAE), using loose-leaf lettuce as the subject. The system utilizes a five-channel light-emitting diode (LED) array—comprising red (640 nm, 660 nm), green (540 nm), and blue (430 nm, 470 nm) wavelengths—to dynamically simulate the spectral variations of natural light across different seasons and times of day. This is achieved through a combination of a pre-programmed spectral recipe database and real-time clock control. Experimental results indicate that the system can accurately replicate the diurnal variation trend of natural light CAE, with Pearson correlation coefficients exceeding 0.97 across all four seasons and an average relative error below 1.04%. Further cultivation validation experiments demonstrate that, compared to a fixed red-blue spectrum, lettuce grown under CAE dynamic spectra exhibited significant advantages during the mid-to-late growth stages. At harvest, plant width, height, leaf number, and individual fresh weight were notably increased, with fresh weight rising by approximately 21.5%. This study confirms the effectiveness of the dynamic lighting system based on CAE in both spectral simulation accuracy and plant growth promotion, offering a reliable technical approach for intelligent light environment management and enhanced light energy utilization efficiency in plant factories.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"293 ","pages":"Article 121792"},"PeriodicalIF":3.6,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146190493","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stairstep Cu4I4 cluster with n-butyldimethylsilyl thiophenyl triphosphine: Structure and photophysical properties 含正丁基二甲基硅基噻吩三膦的阶梯Cu4I4簇:结构和光物理性质
IF 3.6 3区 物理与天体物理
Journal of Luminescence Pub Date : 2026-05-01 Epub Date: 2026-02-06 DOI: 10.1016/j.jlumin.2026.121789
Han Yang , Ruiqin Zhu , Li Liu , Xin-Xin Zhong , Fa-Bao Li , Guijiang Zhou , Hai-Mei Qin
{"title":"Stairstep Cu4I4 cluster with n-butyldimethylsilyl thiophenyl triphosphine: Structure and photophysical properties","authors":"Han Yang ,&nbsp;Ruiqin Zhu ,&nbsp;Li Liu ,&nbsp;Xin-Xin Zhong ,&nbsp;Fa-Bao Li ,&nbsp;Guijiang Zhou ,&nbsp;Hai-Mei Qin","doi":"10.1016/j.jlumin.2026.121789","DOIUrl":"10.1016/j.jlumin.2026.121789","url":null,"abstract":"<div><div>Highly efficient OLEDs fabricated with mononuclear Cu(I) halide complexes containing rigid aryl triphosphine ligands have attracted much attention. However, there are no reports on copper halide clusters containing rigid triphosphine ligands. Here, one rigid triphosphine ligand <strong>L1</strong> and one tetranuclear copper(I) iodide stairstep cluster <strong>1</strong> [Cu<sub>4</sub>I<sub>4</sub>(<strong>L1</strong>)<sub>2</sub>, <strong>L1</strong> = (2-PPh<sub>2</sub>-5-Si(<em>n</em>-Bu)Me<sub>2</sub>-C<sub>4</sub>HS)<sub>2</sub> (3-PPh)], were successfully synthesized. At room temperature, cluster <strong>1</strong> in powder emits yellow green delayed fluorescence (<em>λ</em><sub>em</sub> = 554 nm, <em>τ</em> = 4.9 μs, <em>Φ</em> = 0.25), and at 77 K, it emits yellow green phosphorescence (<em>λ</em><sub>em</sub> = 543 nm, <em>τ</em> = 104 μs). Based on the TDDFT calculations, the emission of cluster <strong>1</strong> mainly originates from metal-to-ligand charge transfer (MLCT) and halogen-to-ligand charge transfer (XLCT). Cluster <strong>1</strong> shows good thermal stability with the onset decomposition temperature (<em>T</em><sub>dec</sub>) of 421 °C. Cluster <strong>1</strong>-based solution-processed devices exhibit greenish yellow light with the highest EQE of 2.30% and the maximum luminance of 1661 cd m<sup>−2</sup>.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"293 ","pages":"Article 121789"},"PeriodicalIF":3.6,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146189986","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Defect–phonon mediated anti-stokes white emission in carbon materials 碳材料中缺陷声子介导的抗斯托克斯白发射
IF 3.6 3区 物理与天体物理
Journal of Luminescence Pub Date : 2026-05-01 Epub Date: 2026-02-10 DOI: 10.1016/j.jlumin.2026.121801
S. Rekhviashvili , D. Gaev , Z. Margushev
{"title":"Defect–phonon mediated anti-stokes white emission in carbon materials","authors":"S. Rekhviashvili ,&nbsp;D. Gaev ,&nbsp;Z. Margushev","doi":"10.1016/j.jlumin.2026.121801","DOIUrl":"10.1016/j.jlumin.2026.121801","url":null,"abstract":"<div><div>Broadband anti-Stokes emission is observed in various carbon-based materials, including polycrystalline graphite, fullerenes, carbon nanotubes, and graphene foams. Despite numerous reports, a comprehensive microscopic understanding remains elusive. Here, we present a model in which laser-excited electron–hole pairs localized at structural defects interact with a thermal vibrational reservoir, enabling phonon-assisted anti-Stokes recombination. The model reproduces key spectral features, including a central peak and its equidistant phonon sidebands. Comparative measurements indicate that highly ordered pyrolytic graphite exhibits negligible anti-Stokes emission, highlighting the essential role of structural disorder and defect-mediated vibrational coupling. These results provide a unified framework for interpreting broadband anti-Stokes emission in defected sp<sup>2</sup>-carbon networks and suggest strategies for controlled generation of high-energy photons via defect engineering.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"293 ","pages":"Article 121801"},"PeriodicalIF":3.6,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146189996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electroluminescence of 1.65 μm near-infrared wavelength quantum cascade lasers using Si/CaF2 heterostructures 基于Si/CaF2异质结构的1.65 μm近红外量子级联激光器的电致发光研究
IF 3.6 3区 物理与天体物理
Journal of Luminescence Pub Date : 2026-05-01 Epub Date: 2026-01-29 DOI: 10.1016/j.jlumin.2026.121786
Zhiyuan Fan, Haibo Wang, Hyuma Suzuki, Masahiro Watanabe
{"title":"Electroluminescence of 1.65 μm near-infrared wavelength quantum cascade lasers using Si/CaF2 heterostructures","authors":"Zhiyuan Fan,&nbsp;Haibo Wang,&nbsp;Hyuma Suzuki,&nbsp;Masahiro Watanabe","doi":"10.1016/j.jlumin.2026.121786","DOIUrl":"10.1016/j.jlumin.2026.121786","url":null,"abstract":"<div><div>We have demonstrated a room temperature near-infrared electroluminescence (EL) at a wavelength of λ = 1.65 μm from Si/CaF<sub>2</sub> quantum cascade laser structure. Five periods of the active layer were epitaxially grown on an n-Si (111) layer of a silicon-on-insulator (SOI) substrate, forming a single-mode propagation waveguide in transverse magnetic (TM) mode grown by molecular beam epitaxy (MBE). The active layer structure consists of a 5-monolayer (ML) transition layer quantum well, double-injector-barrier and a 4-ML blocking layer. EL spectra exhibiting multiple peaks in the near-infrared region were obtained at room temperature, and the dependence of EL intensity on the injection current clearly confirmed that the emission originated from carrier injection. Moreover, a peak shift toward longer wavelengths was observed with increasing applied voltage, and preliminary estimates confirm that the magnitude of the shift is consistent with an interpretation based on the Stark effect, strongly suggesting that the emission originates from inter subband transition of intended design.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"293 ","pages":"Article 121786"},"PeriodicalIF":3.6,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146189998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optical and electronic properties of zero-dimensional-type lithium hafnium iodide scintillator 零维型碘化铪锂闪烁体的光学和电子性质
IF 3.6 3区 物理与天体物理
Journal of Luminescence Pub Date : 2026-05-01 Epub Date: 2026-02-03 DOI: 10.1016/j.jlumin.2026.121784
Chihaya Fujiwara , Shunsuke Kurosawa , Akihiro Yamaji , Akira Yoshikawa , Nishiki Matsubayashi , Takushi Takata , Hiroki Tanaka
{"title":"Optical and electronic properties of zero-dimensional-type lithium hafnium iodide scintillator","authors":"Chihaya Fujiwara ,&nbsp;Shunsuke Kurosawa ,&nbsp;Akihiro Yamaji ,&nbsp;Akira Yoshikawa ,&nbsp;Nishiki Matsubayashi ,&nbsp;Takushi Takata ,&nbsp;Hiroki Tanaka","doi":"10.1016/j.jlumin.2026.121784","DOIUrl":"10.1016/j.jlumin.2026.121784","url":null,"abstract":"<div><div>Zero-dimensional (0D) halides with the general formula A<sub>2</sub>BX<sub>6</sub> (such as Cs<sub>2</sub>HfI<sub>6</sub>) have emerged as a promising class of next-generation scintillator materials characterized by their high luminescence efficiency. This study investigated the novel 0D halide Li<sub>2</sub>HfI<sub>6</sub>, where A-site Li<sup>+</sup> substitution induces a structural transition to a rhombohedral structure. Comprehensive experimental and density functional theory (DFT) analyses reveal that Li<sup>+</sup> substitution facilitates carrier delocalization. Temperature-dependent photoluminescence identified a shallow 17 meV de-trapping barrier from the self-trapped exciton (STE) to the free exciton (FE) state. This thermally induced transition, paralleling phenomena well-observed in 2D perovskites, results in a coexistence of high-energy FE and low-energy STE emissions at room temperature. The emergence of the FE component enables a rapid scintillation decay time of less than 100 ns. In addition, Li<sub>2</sub>HfI<sub>6</sub> achieves a high thermal neutron light yield of 17,000 photons/neutron, which is approximately three times higher than commercial <sup>6</sup>Li-glass. These characteristics demonstrate that Li<sub>2</sub>HfI<sub>6</sub> is a promising candidate for <sup>3</sup>He-alternative technologies. This work establishes A-site cation engineering as an effective design principle for controlling the structure and luminescence properties of 0D halide neutron scintillators.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"293 ","pages":"Article 121784"},"PeriodicalIF":3.6,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146190495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intense green upconversion and temperature sensing properties of GdAl3(BO3)4: Er3+ and Er3+/Yb3+ phosphors GdAl3(BO3)4: Er3+和Er3+/Yb3+荧光粉的强绿色上转换和温度传感性能
IF 3.6 3区 物理与天体物理
Journal of Luminescence Pub Date : 2026-05-01 Epub Date: 2026-01-19 DOI: 10.1016/j.jlumin.2026.121763
Venkata Surya Bhagavan Netheti , Bungala Chinna Jamalaiah , Pidaparthy Lalitha Saranya , Guddety Ramachandra Reddy , Mangali Madhu Sekhar
{"title":"Intense green upconversion and temperature sensing properties of GdAl3(BO3)4: Er3+ and Er3+/Yb3+ phosphors","authors":"Venkata Surya Bhagavan Netheti ,&nbsp;Bungala Chinna Jamalaiah ,&nbsp;Pidaparthy Lalitha Saranya ,&nbsp;Guddety Ramachandra Reddy ,&nbsp;Mangali Madhu Sekhar","doi":"10.1016/j.jlumin.2026.121763","DOIUrl":"10.1016/j.jlumin.2026.121763","url":null,"abstract":"<div><div>GdAl<sub>3</sub>(BO<sub>3</sub>)<sub>4</sub>: Er<sup>3+</sup> and Er<sup>3+</sup>/Yb<sup>3+</sup> phosphors were prepared through solid state reaction method and characterized. The crystalline phase was studied by powder X-ray diffraction technique, the occurrence of several vibrational bonds was recognized by Fourier transform infrared spectroscopy and the surface morphology was verified by scanning electron microscopy. The down and up conversion emission spectra reveal three emission bands related to <sup>2</sup>H<sub>11/2</sub> → <sup>4</sup>I<sub>15/2</sub> (∼521 nm), <sup>4</sup>S<sub>3/2</sub> → <sup>4</sup>I<sub>15/2</sub> (∼547 nm) and <sup>4</sup>F<sub>9/2</sub> → <sup>4</sup>I<sub>15/2</sub> (∼658 nm) transitions up on 377 nm and 980 nm excitation, respectively. An effective sensitization of Yb<sup>3+</sup> ions improves the intensity of green emission upon 980 nm upconversion. The GdAl<sub>3</sub>(BO<sub>3</sub>)<sub>4</sub>: 1 %Er<sup>3+</sup>/3 %Yb<sup>3+</sup> phosphor exhibited a noteworthy thermal stability with an activation energy of 0.314 eV. The same was more potential for not only the design of green LEDs, but also for non-contact temperature sensing devices. It possesses an absolute sensitivity of 0.00415 K<sup>−1</sup> at 473 K and relative sensitivity of 0.576 % K<sup>−1</sup> at 373 K with an excellent thermal cycling repeatability.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"293 ","pages":"Article 121763"},"PeriodicalIF":3.6,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145996490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Surface-passivated (GA)xK2-xSiF6: Mn4+ organic-inorganic hybrid red phosphor: Enhanced stability and promising utilization in WLEDs 表面钝化(GA)xK2-xSiF6: Mn4+有机-无机杂化红色荧光粉:增强稳定性和在wled中的应用前景
IF 3.6 3区 物理与天体物理
Journal of Luminescence Pub Date : 2026-05-01 Epub Date: 2026-02-07 DOI: 10.1016/j.jlumin.2026.121785
Wenjing Han , Ying Jin , Xiaoyi Liu , Zhe Qiu , Shengda Liu , Jiayin Zhan , Jinxian Wang , Xiangting Dong , Guixia Liu
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