Journal of Luminescence最新文献

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Radio- and optically stimulated luminescence of Dy-doped MgB4O7 phosphor 掺镝MgB4O7荧光粉的无线电和光学激发发光
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-07-01 DOI: 10.1016/j.jlumin.2025.121390
A. Di Rocco , E. Cruz-Zaragoza , E. Camarillo-García , M. Lester , J. Marcazzó
{"title":"Radio- and optically stimulated luminescence of Dy-doped MgB4O7 phosphor","authors":"A. Di Rocco ,&nbsp;E. Cruz-Zaragoza ,&nbsp;E. Camarillo-García ,&nbsp;M. Lester ,&nbsp;J. Marcazzó","doi":"10.1016/j.jlumin.2025.121390","DOIUrl":"10.1016/j.jlumin.2025.121390","url":null,"abstract":"<div><div>The radioluminescence (RL) and optically stimulated luminescence (OSL) properties of dysprosium doped magnesium tetraborate have been investigated for the first time. MgB<sub>4</sub>O<sub>7</sub>:Dy<sup>3+</sup> was synthesized by ceramic and solution-assisted methods. X-ray diffraction (XRD) patterns corroborate the crystalline phase of MgB<sub>4</sub>O<sub>7</sub> obtained. Scanning electron microscopy revealed aggregates and porous regions in the MgB<sub>4</sub>O<sub>7</sub> phosphor. Radioluminescence showed an intrinsic emission band at approximately 370 nm and two other narrow bands at 480 nm and 575 nm associated to <sup>4</sup>F<sub>9/2</sub>→<sup>6</sup>H<sub>J</sub> transitions of the Dy<sup>3+</sup> ion, with J = 15/2 and J = 13/2, respectively. The optically stimulated luminescence properties after beta irradiation were analyzed, and the Dy-doped MgB<sub>4</sub>O<sub>7</sub> showed a linear dose response over the range studied.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"286 ","pages":"Article 121390"},"PeriodicalIF":3.3,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144548659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mn-Si Co-doping strategy for high-CRI and thermally stable Ce: YLuAG phosphor ceramics for laser-driven white light sources 用于激光驱动白光源的高显色比和热稳定Ce: YLuAG荧光粉陶瓷的锰硅共掺杂策略
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-07-01 DOI: 10.1016/j.jlumin.2025.121386
Shenghui Lin , Chang Min , Zitong Liu , Peng Wang , Jian Kang , Bingheng Sun , Yang Li , Enjin Liu , Tianyuan Zhou , Yanbin Li , Wieslaw Strek , Robert Tomala , Hao Chen , Le Zhang
{"title":"Mn-Si Co-doping strategy for high-CRI and thermally stable Ce: YLuAG phosphor ceramics for laser-driven white light sources","authors":"Shenghui Lin ,&nbsp;Chang Min ,&nbsp;Zitong Liu ,&nbsp;Peng Wang ,&nbsp;Jian Kang ,&nbsp;Bingheng Sun ,&nbsp;Yang Li ,&nbsp;Enjin Liu ,&nbsp;Tianyuan Zhou ,&nbsp;Yanbin Li ,&nbsp;Wieslaw Strek ,&nbsp;Robert Tomala ,&nbsp;Hao Chen ,&nbsp;Le Zhang","doi":"10.1016/j.jlumin.2025.121386","DOIUrl":"10.1016/j.jlumin.2025.121386","url":null,"abstract":"<div><div>The low color rendering index (CRI) of single-structured Ce: YAG phosphor ceramics (PCs) greatly limits their practical application in white laser-driven (LD) lighting due to the deficient red component. Traditional methods to enhance CRI often come at the expense of thermal stability, posing a challenge for widespread adoption. To address this issue, we proposed a multi-component co-doping strategy by incorporating Lu<sup>3+</sup> and Mn<sup>2+</sup>/Si<sup>4+</sup> into Ce: YAG PCs. Lu<sup>3+</sup> incorporation stabilized the crystal lattice, maintained the spatial separation between Ce<sup>3+</sup> and Mn<sup>2+</sup>, and reduced Ce<sup>3+</sup>-Mn<sup>2+</sup> energy transfer, thereby suppressing nonradiative transitions and ensuring excellent thermal stability. Additionally, Mn<sup>2+</sup>-Si<sup>4+</sup> co-doping achieved high-concentration incorporation through charge compensation, effectively sustaining strong red emission to enhance the CRI. The optimized Mn10 sample demonstrated exceptional thermal stability, retaining 83.2 % of its emission intensity at 423 K. Moreover, the CRI of Ce,Mn-Si:YLuAG increased from 57.5 to 84.5, a 47 % improvement compared with Ce:YLuAG under high-power LED excitation. These results indicated that Ce, Mn-Si: YLuAG PC, with its excellent CRI and thermal stability, is a highly promising color converter for highpower white LEDs and LDs. <strong>Keywords</strong>: Ce: YAG phosphor ceramic; Ce<sup>3+</sup>-Mn<sup>2+</sup> codoping; white LDs; color rendering index; crystal-field splitting.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"286 ","pages":"Article 121386"},"PeriodicalIF":3.3,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144548660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel green-emitting phosphor Na4Zr2Si3O12:Eu2+ for unimodal sensing and light-emitting diodes 用于单峰传感和发光二极管的新型绿色发光荧光粉Na4Zr2Si3O12:Eu2+
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-06-30 DOI: 10.1016/j.jlumin.2025.121387
Ya Zheng , Yaping You , Tianrui Zhou , Zesheng Pan , Yunluo Wang , Minghui Wang , Haijie Chen , Lianjun Wang , Wan Jiang
{"title":"A novel green-emitting phosphor Na4Zr2Si3O12:Eu2+ for unimodal sensing and light-emitting diodes","authors":"Ya Zheng ,&nbsp;Yaping You ,&nbsp;Tianrui Zhou ,&nbsp;Zesheng Pan ,&nbsp;Yunluo Wang ,&nbsp;Minghui Wang ,&nbsp;Haijie Chen ,&nbsp;Lianjun Wang ,&nbsp;Wan Jiang","doi":"10.1016/j.jlumin.2025.121387","DOIUrl":"10.1016/j.jlumin.2025.121387","url":null,"abstract":"<div><div>Temperature sensors typically use dual-rare-earth-doped dual-emission phosphors. Here, an innovated single-emission green phosphor Na<sub>4</sub>Zr<sub>2</sub>Si<sub>3</sub>O<sub>12</sub>: <em>x</em>Eu<sup>2+</sup> is proposed, which has the characteristics of simple structure and high temperature sensitivity. Under 325 nm excitation, the Na<sub>4</sub>Zr<sub>2</sub>Si<sub>3</sub>O<sub>12</sub>: <em>x</em>Eu<sup>2+</sup> phosphor exhibits a broad green emission peak at 512 nm. Na<sub>4</sub>Zr<sub>2</sub>Si<sub>3</sub>O<sub>12</sub>: <em>x</em>Eu<sup>2+</sup> phosphors show asymmetrical emission peaks due to the fact that Eu<sup>2+</sup> occupies two types of Na<sub>1</sub> and Na<sub>2</sub> in different environments. The energy transfer between Eu<sup>2+</sup> belongs to the dipole-dipole interaction. In particular, the unimodal emission characteristics of Na<sub>4</sub>Zr<sub>2</sub>Si<sub>3</sub>O<sub>12</sub>: <em>x</em>Eu<sup>2+</sup> phosphor under near-ultraviolet (NUV) excitation give it a unique advantage in unimodal sensing applications, with an absolute sensitivity of 0.00738 K<sup>-1</sup> (300 K–425 K). The color saturation (Rg) of green LED device prepared with 365 nm ultraviolet chips can reach 96.2, and the related color temperature (CCT) is 6074K. Moreover, the phosphor has stable weather resistance after 72 h of storage at 85 °C and 85 % humid heat and water environment, and the luminous intensity is maintained at 83.6 % and 82.1 % at room temperature. These characteristics indicate that Na<sub>4</sub>Zr<sub>2</sub>Si<sub>3</sub>O<sub>12</sub>: <em>x</em>Eu<sup>2+</sup> phosphors have important application value in the field of fluorescent lighting and temperature sensing technology.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"286 ","pages":"Article 121387"},"PeriodicalIF":3.3,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144534989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Machine-learning assisted prediction of peak wavelengths in four-primary light-emitting diode displays with arbitrary Rec. 2020 机器学习辅助四基色发光二极管显示峰值波长预测与任意Rec. 2020
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-06-28 DOI: 10.1016/j.jlumin.2025.121388
Shanrong Ke, Linyu Ye, Xiujia Yin, Qiuxue Kuang, Yi Lin, Ziheng Li, Yuanyu Zheng, Zhong Chen, Ziquan Guo
{"title":"Machine-learning assisted prediction of peak wavelengths in four-primary light-emitting diode displays with arbitrary Rec. 2020","authors":"Shanrong Ke,&nbsp;Linyu Ye,&nbsp;Xiujia Yin,&nbsp;Qiuxue Kuang,&nbsp;Yi Lin,&nbsp;Ziheng Li,&nbsp;Yuanyu Zheng,&nbsp;Zhong Chen,&nbsp;Ziquan Guo","doi":"10.1016/j.jlumin.2025.121388","DOIUrl":"10.1016/j.jlumin.2025.121388","url":null,"abstract":"<div><div>The color gamut is an important quality evaluation metric for LED (Light-Emitting Diode, LED) displays. Based on GA (Genetic Algorithm, GA) and LM-BP (Levenberg-Marquardt Back-Propagation, LM-BP) neural network model, this paper proposes an effective method for the precise prediction of peak wavelengths in four-primary RYGB-LED displays (Red-R, Yellow-Y, Green-G, and Blue-B LEDs or QDs (Quantum Dots, QDs) with arbitrary values of color gamut. The GA is applied to optimize the CIE (Commission Internationale de l’Eclairage, CIE) chromaticity coordinates in consideration of specific color gamut thresholds, and the LM-BP neural network model is applied to predict the peak wavelengths of four-primary RYGB-LED displays based on the optimal CIE chromaticity coordinates, which enables the spectral design from color gamut to peak wavelengths of LEDs. The spectral power distribution of four-primary RYGB-LED displays is simulated using double-Gaussian functions. A total of 2000 spectral datasets for each color are divided into training sets, validation sets, and test sets in a ratio of 8:1:1. The K-fold cross-validation is used to determine the hyperparameters in LM-BP neural network model, and the optimal model is tested in the test sets, recording mean square error to assess the overfitting. Results indicate that the LM-BP neural network model exhibits excellent performances and generalization capabilities, and this model is applied to CIE chromaticity coordinate sets to design peak wavelengths of LED displays from the color gamut, guiding the manufacturing of high-quality four-primary RYGB-LED displays consisting of LEDs and QDs.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"286 ","pages":"Article 121388"},"PeriodicalIF":3.3,"publicationDate":"2025-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144518981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in zirconium-based metal-organic frameworks for fluorescence detection 荧光检测用锆基金属有机骨架的研究进展
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-06-24 DOI: 10.1016/j.jlumin.2025.121372
Enai Dai , Lin Xu , Pengxiang Dong , Hao Zhang , Feifan Lang , Tianxin Zhang , Zhen Fan , Houping Xia , Jiandong Pang
{"title":"Advances in zirconium-based metal-organic frameworks for fluorescence detection","authors":"Enai Dai ,&nbsp;Lin Xu ,&nbsp;Pengxiang Dong ,&nbsp;Hao Zhang ,&nbsp;Feifan Lang ,&nbsp;Tianxin Zhang ,&nbsp;Zhen Fan ,&nbsp;Houping Xia ,&nbsp;Jiandong Pang","doi":"10.1016/j.jlumin.2025.121372","DOIUrl":"10.1016/j.jlumin.2025.121372","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) are widely acknowledged as the optimal choice for sensing materials due to their high surface area, structural tunability, and ease of modification of functional sites. In particular, zirconium-based MOFs (Zr-MOFs) have garnered significant attention owing to their exceptional crystallinity and unparalleled stability. The applications of fluorescent sensors based on Zr-MOFs have been extensively investigated. This article reviews the recent research advancements in Zr-MOF fluorescent sensors concerning synthesis strategies, detection mechanisms, and practical applications across various fields including biomarker detection, food safety assessment, environmental monitoring, among others. Furthermore, this article highlights the current challenges faced in Zr-MOF sensor research and outlines future directions aimed at providing comprehensive guidance for the design, synthesis, and practical application of Zr-MOF fluorescent sensors. Ultimately, this review seeks to broaden their scope of application and promote their pivotal role in related domains.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"286 ","pages":"Article 121372"},"PeriodicalIF":3.3,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144513518","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Highly efficient white OLEDs based on bipolar interface exciplex interlayer architecture 基于双极接口外加层间结构的高效白光oled
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-06-24 DOI: 10.1016/j.jlumin.2025.121382
Jun Sun , Jintao Wang , Xiaoqing Jing , Erdong Zhang , Duxu Yan , Jihua Tang , Qingxiang Wang , Fankang Kong , Yongan Zhang , Lingcong Lv , Ren Sheng , Ping Chen
{"title":"Highly efficient white OLEDs based on bipolar interface exciplex interlayer architecture","authors":"Jun Sun ,&nbsp;Jintao Wang ,&nbsp;Xiaoqing Jing ,&nbsp;Erdong Zhang ,&nbsp;Duxu Yan ,&nbsp;Jihua Tang ,&nbsp;Qingxiang Wang ,&nbsp;Fankang Kong ,&nbsp;Yongan Zhang ,&nbsp;Lingcong Lv ,&nbsp;Ren Sheng ,&nbsp;Ping Chen","doi":"10.1016/j.jlumin.2025.121382","DOIUrl":"10.1016/j.jlumin.2025.121382","url":null,"abstract":"<div><div>White organic light-emitting diodes (WOLEDs) with ultrathin layer structure still suffer from inefficient exciton utilization and unstable spectra. Herein, high-performance WOLED is realized by inserting a bipolar interlayer between the blue exciplex-hosted layer and ultrathin orange layer to construct additional reverse intersystem crossing (RISC) channels. By elaborately modulating the exciton behavior in the emission layer, the device achieves maximum current efficiency of 48.54 cd/A and maximum power efficiency of 50.84 lm/W with Commission Internationale de l'Éclairage coordinates variation of (0.019, 0.011) from 1295 cd/m<sup>2</sup> to 20,886 cd/m<sup>2</sup>. The superior performance of the device is attributed to enhanced Fӧster energy transfer from host to dopant via the double RISC channel and regulation of the charge carrier behavior. Our results demonstrate a promising approach for developing high-performance WOLEDs based on an ultrathin layer structure.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"286 ","pages":"Article 121382"},"PeriodicalIF":3.3,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144501661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrafast energy transfer between all-inorganic tin-based perovskite nanocrystals and RhB chromophore 全无机锡基钙钛矿纳米晶体与RhB发色团之间的超快能量转移
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-06-24 DOI: 10.1016/j.jlumin.2025.121383
Zhaoyong Jiao, Zhiheng Shang, Minghuan Cui, Shuwen Zheng, Pan Song, Haiying Wang, Jicai Zhang, Jian Song, Shuhong Ma, Guangrui Jia, Zhongpo Zhou, Chaochao Qin
{"title":"Ultrafast energy transfer between all-inorganic tin-based perovskite nanocrystals and RhB chromophore","authors":"Zhaoyong Jiao,&nbsp;Zhiheng Shang,&nbsp;Minghuan Cui,&nbsp;Shuwen Zheng,&nbsp;Pan Song,&nbsp;Haiying Wang,&nbsp;Jicai Zhang,&nbsp;Jian Song,&nbsp;Shuhong Ma,&nbsp;Guangrui Jia,&nbsp;Zhongpo Zhou,&nbsp;Chaochao Qin","doi":"10.1016/j.jlumin.2025.121383","DOIUrl":"10.1016/j.jlumin.2025.121383","url":null,"abstract":"<div><div>This study explores the energy transfer mechanisms through visible-light excitation of hybrids based on CsSnBr<sub>3</sub> nanocrystals and Rhodamine B (RhB) chromophores. The ability of RhB dyes to donate energy to CsSnBr<sub>3</sub> is comprehensively investigated with steady-state and time-resolved photoluminescence, as well as femtosecond transient absorption spectroscopy. The Förster resonance energy transfer (FRET) dominates (85.1 %) the photosensitization of the singlet excited state of RhB in the nanocrystal-chromophore hybrids with a rate constant of 4.3 × 10<sup>9</sup> s<sup>−1</sup>. These findings reveal the energy transfer mechanism and highlight the design of light-harvesting devices based on CsSnBr<sub>3</sub> nanocrystals and organic chromophores.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"286 ","pages":"Article 121383"},"PeriodicalIF":3.3,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144491813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient near-infrared emission and imaging of lead-free double perovskite Cs2TeCl6 by Mo4+ doping Mo4+掺杂无铅双钙钛矿Cs2TeCl6的高效近红外发射和成像
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-06-24 DOI: 10.1016/j.jlumin.2025.121381
Chao Wang , Junlin Wang , Dongting Wang , Linli He
{"title":"Efficient near-infrared emission and imaging of lead-free double perovskite Cs2TeCl6 by Mo4+ doping","authors":"Chao Wang ,&nbsp;Junlin Wang ,&nbsp;Dongting Wang ,&nbsp;Linli He","doi":"10.1016/j.jlumin.2025.121381","DOIUrl":"10.1016/j.jlumin.2025.121381","url":null,"abstract":"<div><div>In this work, we successfully synthesized a novel lead-free perovskite material Cs<sub>2</sub>TeCl<sub>6</sub>: xMo<sup>4+</sup>(x = 0.02,0.06,0.1,0.2) and conducted in-depth research on its near-infrared emission characteristics. The morphology of the material was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results confirmed that the synthesized Cs<sub>2</sub>TeCl<sub>6</sub>: xMo<sup>4+</sup> exhibited excellent crystallinity and high phase purity. And it exhibits efficient luminescence performance in the near-infrared region, with a maximum emission wavelength of 900 nm and a full width at half maximum of 100 nm. The photoluminescence quantum yield (PLQY) in the near-infrared region (750–1100 nm) measured at an excitation wavelength of 450 nm is as high as 29 %. The temperature-dependent (80–480K) near-infrared PL spectra also exhibit good thermal stability at low and high temperatures. Near infrared phosphor converted LEDs (pc-LEDs) made from this material exhibit excellent stability in the range of 100 mÃ500 mA. The pc-LEDs based on Cs<sub>2</sub>TeCl<sub>6</sub>: 0.1Mo<sup>4+</sup> material exhibit efficient near-infrared emission in the near-infrared region, demonstrating excellent performance in applications such as venous photography, night vision and drug impurity detection. In addition, the excellent performance of this material not only provides new insights for the application of perovskite materials in near-infrared luminescence, but also provides important theoretical and experimental basis for the development of new and efficient near-infrared luminescent materials.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"286 ","pages":"Article 121381"},"PeriodicalIF":3.3,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144470630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photoluminescence characteristics and Judd–Ofelt analysis of YBa3(BO3)3:Tb3+ phosphors co-doped with Li+, Na+, and K+ Li+、Na+、K+共掺杂YBa3(BO3)3:Tb3+荧光粉的光致发光特性及Judd-Ofelt分析
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-06-23 DOI: 10.1016/j.jlumin.2025.121380
Abeer S. Altowyan , U.H. Kaynar , Cem Gök , H. Aydin , Jabir Hakami , M.B. Coban , A. Canimoglu , N. Can
{"title":"Photoluminescence characteristics and Judd–Ofelt analysis of YBa3(BO3)3:Tb3+ phosphors co-doped with Li+, Na+, and K+","authors":"Abeer S. Altowyan ,&nbsp;U.H. Kaynar ,&nbsp;Cem Gök ,&nbsp;H. Aydin ,&nbsp;Jabir Hakami ,&nbsp;M.B. Coban ,&nbsp;A. Canimoglu ,&nbsp;N. Can","doi":"10.1016/j.jlumin.2025.121380","DOIUrl":"10.1016/j.jlumin.2025.121380","url":null,"abstract":"<div><div>This study presents a systematic investigation of the photoluminescent properties of Tb<sup>3+</sup>-doped YBa<sub>3</sub>(BO<sub>3</sub>)<sub>3</sub> (YBBO) phosphors, synthesized via a microwave-assisted sol-gel combustion (MA-SG) method and co-doped with monovalent alkali ions (Li<sup>+</sup>, Na<sup>+</sup>, K<sup>+</sup>). Structural, vibrational, and morphological analyses were performed using XRD with Rietveld refinement, Raman and FTIR spectroscopy, and SEM–EDS. These analyses confirmed the successful incorporation of dopants without compromising the borate lattice. Photoluminescence (PL) measurements under near-UV excitation (377 nm) showed intense green emission attributed to the <sup>5</sup>D<sub>4</sub> → <sup>7</sup>F<sub>5</sub> transition of Tb<sup>3+</sup>, with Li<sup>+</sup> co-doping producing the greatest enhancement (∼2.7 × ) in emission intensity. Lifetime measurements revealed longer decay times with co-doping, suggesting reduced non-radiative relaxation processes. Judd–Ofelt (J–O) analysis confirmed strong radiative transitions and high internal quantum efficiency (η ≈ 48.4 %). The internal quantum efficiency (IQE) of 48.4 % was estimated using Judd–Ofelt theory, which is based on radiative transition probabilities derived from emission spectra. This method, while theoretical, is widely accepted for powdered phosphors and provides insight into the intrinsic radiative efficiency of the activator ions. Although absolute quantum yield (QY) measurements are typically obtained using integrating sphere systems to account for all optical losses, in this study, such measurements were not performed. Nonetheless, the strong agreement between radiative parameters and observed photoluminescence behavior supports the reliability of the calculated efficiency. In this study, J–O parameters were derived from the integrated emission spectra of Tb<sup>3+</sup> transitions, following an emission-based approach that has been increasingly employed for powdered phosphors due to its experimental feasibility. Colorimetric analysis using CIE chromaticity diagrams validated the tunable green emission behaviour of the phosphors. Minor deviations from ideal green were linked to background blue emission from the host matrix, a feature that may offer spectral advantages in multifunctional optical applications. Furthermore, the phosphor exhibited a rare negative thermal quenching (NTQ) behavior, maintaining or enhancing emission intensity up to 550 K, which is superior to many commercial green phosphors.These results highlight the crucial role of alkali ion co-doping in tuning the local crystal field, enhancing emission efficiency, and paving the way for the development of efficient green-emitting phosphors for solid-state lighting applications.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"286 ","pages":"Article 121380"},"PeriodicalIF":3.3,"publicationDate":"2025-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144470627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-precision machine learning analysis of photoluminescence and I-V measurements in SiNWs-based Schottky diodes 基于sinws的肖特基二极管的光致发光和I-V测量的高精度机器学习分析
IF 3.3 3区 物理与天体物理
Journal of Luminescence Pub Date : 2025-06-21 DOI: 10.1016/j.jlumin.2025.121379
Radhouane Laajimi , Kawther Laajimi , Mehdi Rahmani
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