Journal of energy storage最新文献

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High-entropy spinel-structured (VCrNiCoMn)3O4 anode for Li-ion batteries 用于锂离子电池的高熵尖晶石结构 (VCrNiCoMn)3O4 阳极
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-27 DOI: 10.1016/j.est.2024.114796
Mohammad Reza Esmaeili, Saba Noorsina, Sayed Khatiboleslam Sadrnezhaad
{"title":"High-entropy spinel-structured (VCrNiCoMn)3O4 anode for Li-ion batteries","authors":"Mohammad Reza Esmaeili,&nbsp;Saba Noorsina,&nbsp;Sayed Khatiboleslam Sadrnezhaad","doi":"10.1016/j.est.2024.114796","DOIUrl":"10.1016/j.est.2024.114796","url":null,"abstract":"<div><div>In the quest for improved battery performance, high entropy transition metal oxides (HEO-TM) have emerged as potential candidates for lithium-ion battery (LIB) anodes due to their high capacity resulting from multi-electron transfer redox reactions. This study a synthesized spinel high-entropy oxide (VCrNiCoMn)<sub>3</sub>O<sub>4</sub> using a surfactant-assisted hydrothermal method and subjected it to annealing at different temperatures. XRD analysis revealed that the stabilized spinel phase formed at 1223 K. The (VCrNiCoMn)<sub>3</sub>O<sub>4</sub> demonstrated a significant discharge capacity of 1269 mAh g<sup>−1</sup>, accompanied by a charge capacity of 1030 mAh g<sup>−1</sup>. After 1000 cycles, it achieved a reversible capacity of 733 mAh g<sup>−1</sup>. Furthermore, superior rate performance was observed, demonstrating a high reversible capacity of 394 mAh g<sup>−1</sup> at a scanning rate of 2 mV s<sup>−1</sup>. The superior performance was attributed to multivalent species, including vanadium, which stabilizes charge transfer, facilitates redox reactions, enhances electrical properties, and improves structural stability. Vanadium's ability to transition through multiple oxidation states reduce volume expansion, improve structural rigidity, and contribute to cycling stability. Moreover, Kinetic analysis showed that the lithiation reaction was dominated by the Faraday mechanism, while delithiation involved both capacitive and Faraday contributions. These results suggest that incorporating vanadium into high-entropy oxides can optimize electrochemical properties for long-life lithium-ion batteries.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"105 ","pages":"Article 114796"},"PeriodicalIF":8.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142723529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of urchin-like MnCo2O4 nanospheres as electrode material for supercapacitors 合成作为超级电容器电极材料的海胆状 MnCo2O4 纳米球
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-27 DOI: 10.1016/j.est.2024.114775
Ding Shen , Ran Zhang , Shuai Liu , Haoran Yu , Dong Xia , Jianqiang Niu , Youzhi Yang , Zhaoqi Ren , Wei Dong
{"title":"Synthesis of urchin-like MnCo2O4 nanospheres as electrode material for supercapacitors","authors":"Ding Shen ,&nbsp;Ran Zhang ,&nbsp;Shuai Liu ,&nbsp;Haoran Yu ,&nbsp;Dong Xia ,&nbsp;Jianqiang Niu ,&nbsp;Youzhi Yang ,&nbsp;Zhaoqi Ren ,&nbsp;Wei Dong","doi":"10.1016/j.est.2024.114775","DOIUrl":"10.1016/j.est.2024.114775","url":null,"abstract":"<div><div>The morphology of MnCo<sub>2</sub>O<sub>4</sub> has a significant effect on the electrochemical performance. In this paper, urchin-like MnCo<sub>2</sub>O<sub>4</sub> nanospheres was successfully fabricated by a simple hydrothermal process and post-annealing treatment. The effects of addition of surfactant (Hexadecy ltrimethyl ammonium bromide) on the crystal structure, surface morphology and electrochemical performance of MnCo<sub>2</sub>O<sub>4</sub> have been investigated. The results show that all the synthesized manganese cobalt oxides are composed of cubic spinel MnCo<sub>2</sub>O<sub>4</sub>. The addition of surfactant leads to the change of the morphology of MnCo<sub>2</sub>O<sub>4</sub> from nanoarray to urchin-like nanospheres and increases the specific surface area, which is beneficial to improve the electrochemical performance of the MnCo<sub>2</sub>O<sub>4</sub> electrode. The electrochemical test reveals that the urchin-like MnCo<sub>2</sub>O<sub>4</sub> nanospheres delivered a high specific capacity of 2019 F/g at a 1 A/g and 1144 F/g at 5 A/g, respectively. The specific capacity of MnCo<sub>2</sub>O<sub>4</sub> electrode reaches 512 F/g at 10 A/g and retains 96 % of the initial capacity after 2000 cycles at 10 A/g, which maintains an extraordinary cycling performance. In addition, an asymmetric supercapacitor (MnCo<sub>2</sub>O<sub>4</sub>//AC) with urchin-like MnCo<sub>2</sub>O<sub>4</sub> nanospheres as a cathode and activated carbon (AC) as an anode was also assembled. Impressively, the assembled MnCo<sub>2</sub>O<sub>4</sub>//AC asymmetric supercapacitor exhibits a high energy density of 69 Wh/kg at a power density of 793 W/kg. The above research shows that the urchin-like MnCo<sub>2</sub>O<sub>4</sub> nanospheres synthesized by adding surfactants are expected to be excellent high-performance energy storage electrode materials, which provides a new strategy for the synthesis of high-capacity nanoelectrode materials.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"105 ","pages":"Article 114775"},"PeriodicalIF":8.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142723685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative study of methodologies for SOH diagnosis and forecast of LFP and NMC lithium batteries used in electric vehicles 电动汽车中使用的 LFP 和 NMC 锂电池 SOH 诊断和预测方法的比较研究
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-27 DOI: 10.1016/j.est.2024.114725
F.A. Vásquez, P. Sara Gaitán, Jorge A. Calderón
{"title":"Comparative study of methodologies for SOH diagnosis and forecast of LFP and NMC lithium batteries used in electric vehicles","authors":"F.A. Vásquez,&nbsp;P. Sara Gaitán,&nbsp;Jorge A. Calderón","doi":"10.1016/j.est.2024.114725","DOIUrl":"10.1016/j.est.2024.114725","url":null,"abstract":"<div><div>The exponential growth of electric mobility requires alternatives to extend the life of batteries in new applications and reduce the environmental impact of retired lithium batteries. The second life is an economic and environment-friendly alternative for battery management. The development of fast, low-cost, and reliable diagnostic methodologies makes it possible to increase the economic benefits and reduce the remanufacturing time of second-life batteries (SLBs). In the present work, battery state of health (SOH) distribution analysis, incremental capacity (IC), internal resistance (IR), and electrochemical impedance spectroscopy (EIS) were applied as diagnostic methodologies for two different chemistries of lithium-ion batteries previously used in electric vehicles (EV). In addition, module equalization in batteries was done in order to assess whether the state of module charge (SOC) variation affects the SOH. The results demonstrate that the diagnosis methodology depends on the chemistry of the battery, and that there is no single reliable diagnostic procedure that can be applied to all types of lithium-ion batteries. It was determined that the most adequate diagnostic method for LFP batteries (LiFePO<sub>4</sub> cathode) is the IC method, while for NMC batteries (LiNi<sub>0.33</sub>Mn<sub>0.33</sub>Co<sub>0.33</sub>O<sub>2</sub> cathode) the IR and EIS diagnostic methods are the most appropriate. Similarly, the present work proposed a simple methodology for IC capacity diagnosis and a general expression for SOH determination by IC and incremental voltage diagnosis of LFP batteries. Higher stability of LFP respect to NMC modules was observed during the SLBs performance, retaining &gt;99 % after 500 cycles for LFP, compared with 90.2 % for NMC. The remaining useful life (RUL) shows that there are kinetics and lithium inventory changes in the batteries temperature-dependent.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"105 ","pages":"Article 114725"},"PeriodicalIF":8.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142723124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Utilizing scenario-based multi-functional energy storage systems for optimal day-ahead operation of microgrid resources 利用基于场景的多功能储能系统优化微电网资源的日前运行
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-27 DOI: 10.1016/j.est.2024.114626
Ibrahim M. Ibrahim , Walid A. Omran , Almoataz Y. Abdelaziz
{"title":"Utilizing scenario-based multi-functional energy storage systems for optimal day-ahead operation of microgrid resources","authors":"Ibrahim M. Ibrahim ,&nbsp;Walid A. Omran ,&nbsp;Almoataz Y. Abdelaziz","doi":"10.1016/j.est.2024.114626","DOIUrl":"10.1016/j.est.2024.114626","url":null,"abstract":"<div><div>Single-functional battery units (BUs) are commonly utilized in most studies related to microgrids (MGs). This paper proposes efficient energy management of MG's resources including wind power turbines (WPTs), photovoltaic systems (PVs), BUs, and diesel generator units (DGUs). The proposed study aims to utilize the multi-functional capabilities of BUs to minimize the hourly costs of MG and thereby reduce the overall daily operating costs of MG. To achieve this, various potential scenarios are considered within the system policy to efficiently utilize the BUs for performing multiple functions including matching power generation from the renewable energy sources (RESs) with the demand (G/D) and performing energy arbitrage (EA). This work considers several factors, including two modes of MG operation (grid-connected mode and islanded mode), as well as demand-side management (DSM). Furthermore, the study addresses uncertainties associated with various parameters, affecting wind power and solar power, using the Latin Hypercube Sampling (LHS) approach. The metaheuristic technique known as Moth-Flame Optimization (MFO) is utilized to solve the formulated constrained nonlinear optimization problem. To verify the obtained optimal solutions, the Hybrid Firefly and Particle Swarm Optimization (HFPSO) technique is also utilized. Several case studies, considering various operating conditions, are done to investigate the proposed study. Finally, a comparison is made between four case studies to clarify the importance of the multi-functional BUs in achieving the objective of the proposed study. The results show that the multi-functional BUs case study achieves the lowest daily cost ($7701) compared to the single-functional BUs case studies ($8981.5 for EA and $9052 for G/D). The implementation and solutions of the proposed problem are done using MATLAB software.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"105 ","pages":"Article 114626"},"PeriodicalIF":8.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142723524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Designing novel Bi-metallic MOFs with optimized Ni and Co ions ratios for enhanced supercapacitor performance 设计新型双金属 MOFs,优化镍和钴离子比例,提高超级电容器性能
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-27 DOI: 10.1016/j.est.2024.114777
M.A. Deyab , Q. Mohsen , Omnia A.A. El-Shamy
{"title":"Designing novel Bi-metallic MOFs with optimized Ni and Co ions ratios for enhanced supercapacitor performance","authors":"M.A. Deyab ,&nbsp;Q. Mohsen ,&nbsp;Omnia A.A. El-Shamy","doi":"10.1016/j.est.2024.114777","DOIUrl":"10.1016/j.est.2024.114777","url":null,"abstract":"<div><div>The goal of this work is to assess the novel supercapacitors (Btc-Im-DMF-Ni<sub>x</sub>/Co<sub>y</sub>) by creating new bimetallic MOFs. The structure of novel bimetallic MOFs is based on the incorporation of varied Ni and Co ions ratios, as well as a large hetero-organic frame containing imidazole (Im), dimethyl formamide (DMF), and benzene tri carboxylic acid (BTC). Furthermore, the effect of the Ni<sub>x</sub>:Co<sub>y</sub> ratio on the performance of supercapacitors was investigated for Btc-Im-DMF-Ni<sub>2</sub>/Co<sub>1</sub> and Btc-Im-DMF-Ni<sub>1</sub>/Co<sub>2</sub>. The new materials were created to compensate for the conventional superapcitors' low energy density. The electrochemical performance of the novel materials is examined by a number of electrochemical studies, including galvanostatic charge/discharge (GSCD), cyclic voltammetry (CV), and surface analysis. The Btc-Im-DMF-Ni<sub>1</sub>/Co<sub>2</sub> has an optimum capacitance of 1640 F g<sup>−1</sup> at 1.0 A g<sup>−1</sup>, in contrast to Btc-Im-DMF-Ni<sub>2</sub>/Co<sub>1</sub>, which shows a capacitance of 1234 F g<sup>−1</sup> at 1.0 A g<sup>−1</sup>. After 5000 cycles, Btc-Im-DMF-Ni<sub>1</sub>/Co<sub>2</sub> has a greater cycling stability (91 %) than Btc-Im-DMF-Ni<sub>2</sub>/Co<sub>1</sub> (85.3 %). The Co to Ni ratio of the Btc-Im-DMF-Nix/Coy has a significant impact on the electrochemical activity of the supercapacitor. Within the MOFs network, Co and Ni have shown improved capacity and cycle stability due to their easier electron transport and lower deprotonation energy.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"105 ","pages":"Article 114777"},"PeriodicalIF":8.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142723601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Realization of nickel doped carbon enriched graphitic carbon nitride for diffusion controlled charge storage 实现用于扩散控制电荷存储的掺镍富碳氮化石墨碳
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-27 DOI: 10.1016/j.est.2024.114774
Malatesh S. Pujar , Sharanabasava Yalavara , Vidyalaxmi Wadeyar , Sudharani Khot , Nilesh Chougula , Smita Kalagi , Shidaling Matteppanavar , Sameer Kulkarni
{"title":"Realization of nickel doped carbon enriched graphitic carbon nitride for diffusion controlled charge storage","authors":"Malatesh S. Pujar ,&nbsp;Sharanabasava Yalavara ,&nbsp;Vidyalaxmi Wadeyar ,&nbsp;Sudharani Khot ,&nbsp;Nilesh Chougula ,&nbsp;Smita Kalagi ,&nbsp;Shidaling Matteppanavar ,&nbsp;Sameer Kulkarni","doi":"10.1016/j.est.2024.114774","DOIUrl":"10.1016/j.est.2024.114774","url":null,"abstract":"<div><div>Here in this communication we report synthesis of Nickel doped carbon enriched graphitic carbon nitride for supercapacitor applications. Although the FTIR spectra of carbon enriched gC<sub>3</sub>N<sub>4</sub> indicates the destruction of out of plane heptazine ring but simultaneously shows the preservation of tri – s - triazine structure of gC<sub>3</sub>N<sub>4</sub>. There is a blue shift in absorption peak resulting in the widening of the band gap by doping the carbon enriched gC<sub>3</sub>N<sub>4</sub> with nickel. In XRD spectrum the peak shift towards lower angle with decrease in the intensity is observed indicating widening in in-plane stacking of <em>s</em>- triazine rings. The cyclic voltammetry studies show increase in the specific capacitance from 91.5F/g for gC<sub>3</sub>N<sub>4</sub> to as high as 226F/g @ 10 mV/s for nickel doped carbon enriched gC<sub>3</sub>N<sub>4</sub> (NiCgC<sub>3</sub>N<sub>4</sub>). This increase in the charge storage can be attributed to the increase in the diffusion of electrons aided by doping of carbon enriched graphitic carbon nitride by nickel as suggested by Randles Sevick calculation. The Lindstrom &amp; Dunn's methods points out that the charge storage is by faradaic diffusion controlled processes at the electrode and electrolyte interface. Furthermore NiCgC<sub>3</sub>N<sub>4</sub> electrode exhibits a good stability of 79.5 % up to 4000 cycles. The as synthesized electrode material NiCgC<sub>3</sub>N<sub>4</sub> basically shows the psuedocapacitive nature. The asymmetric two electrode device showed a specific capacitance of 119F/g @ 1 A/g. A maximum energy density of 214 Wh/Kg with power density of 1800 W/Kg is achieved for 1 A/g current density. Overall the synthesized NiCgC<sub>3</sub>N<sub>4</sub> has shown good diffusion controlled charge storage material qualities.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"105 ","pages":"Article 114774"},"PeriodicalIF":8.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142723602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Solar-powered compact thermal energy storage system with rapid response time and rib-enhanced plate via techniques of CFD, ANN, and GA 通过 CFD、ANN 和 GA 技术实现具有快速响应时间和肋增强板的太阳能紧凑型热能储存系统
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-27 DOI: 10.1016/j.est.2024.114807
Gongxing Yan , Jialing Li , Rebwar Nasir Dara , Mohamed Shaban , Raymond GHANDOUR , Fahad M. Alhomayani , Ahmad Almadhor , Ahmed Hendy , Mohammad Nadeem Khan , Nidhal Becheikh
{"title":"Solar-powered compact thermal energy storage system with rapid response time and rib-enhanced plate via techniques of CFD, ANN, and GA","authors":"Gongxing Yan ,&nbsp;Jialing Li ,&nbsp;Rebwar Nasir Dara ,&nbsp;Mohamed Shaban ,&nbsp;Raymond GHANDOUR ,&nbsp;Fahad M. Alhomayani ,&nbsp;Ahmad Almadhor ,&nbsp;Ahmed Hendy ,&nbsp;Mohammad Nadeem Khan ,&nbsp;Nidhal Becheikh","doi":"10.1016/j.est.2024.114807","DOIUrl":"10.1016/j.est.2024.114807","url":null,"abstract":"<div><div>Reducing carbon emissions is a vital approach to combat the global threat of climate change. As energy consumption continues to grow on a global scale, the shift towards renewable energy is crucial for maintaining sustainable development. Solar power, in particular, has emerged as a leading renewable resource due to its widespread availability and the potential to cover a significant portion of global energy demand. Nonetheless, the variability of solar energy poses challenges for ensuring a steady power supply. To overcome this, efficient energy storage systems, such as advanced batteries and thermal energy storage (TES) systems are essential. There is growing attention on solar energy storage, with a particular focus on phase change material (PCM) and TES systems. Here, a compact thermal energy storage (CTES) system with two heat transfer fluid plates and one rib-enhanced PCM plate was investigated to minimize the response time. RT42 was employed as the PCM within the plate. Selected for its suitable melting temperature range of 311.15–315.15 K, RT42 facilitates efficient thermal management, enabling effective storage and release of latent heat. Eight aluminum-made ribs were embedded to allow heat to penetrate deeper into the storage container. According to the several geometric parameters of the ribs such as angle of lower ribs, angle of upper ribs, and the distance between ribs, different configurations of ribbed CTES systems were introduced. Additionally, an artificial neural network-based anticipation model was introduced to predict system's melting performance, facilitating faster and more accurate optimization of design parameters. This innovative approach aids researchers in accelerating their future work on similar energy storage systems. Eventually, an optimal configuration (OC) was derived from the genetic algorithm and the anticipation model. Based on the results, the rib-less specimen took 19,648 s to melt completely, which was 118.2 % longer compared to the OC. This indicated a difference of nearly 3 h between the two systems, underscoring the effectiveness of the optimal configuration in conserving thermal energy throughout the day. Moreover, the rib-less system needed 130.5 % more time to melt 50 % of the PCM and 129.4 % more time to melt 80 % of the material. This stark difference further emphasized the efficiency of the OC in the entire stages of the charging in the CTES system. Among the ribbed specimens, there was a difference of about 41 min in the melting time, which highlights the importance of optimizing the geometric design in TES systems.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"105 ","pages":"Article 114807"},"PeriodicalIF":8.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142723531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Supported bimetallic Pt-Pd/ZrVFeTi catalyst for H2 oxidation and its enhanced catalytic hydrogen elimination performance 用于 H2 氧化的负载型双金属 Pt-Pd/ZrVFeTi 催化剂及其增强的催化消氢性能
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-27 DOI: 10.1016/j.est.2024.114731
Yong Liu , He Zhang , Aimin Ju , Ping Li , Xuanhui Qu
{"title":"Supported bimetallic Pt-Pd/ZrVFeTi catalyst for H2 oxidation and its enhanced catalytic hydrogen elimination performance","authors":"Yong Liu ,&nbsp;He Zhang ,&nbsp;Aimin Ju ,&nbsp;Ping Li ,&nbsp;Xuanhui Qu","doi":"10.1016/j.est.2024.114731","DOIUrl":"10.1016/j.est.2024.114731","url":null,"abstract":"<div><div>The deflagration of hydrogen in confined spaces is a significant safety concern. To eliminate hydrogen for ensuring safety, we study catalysts for catalytic oxidation of hydrogen at room temperature. Bimetallic Pt<img>Pd catalyst is prepared on the hydrogen storage alloy ZrVFeTi by the chemical reduction method. The structure, composition, morphology and elemental analyses are characterized using XRD, HR-TEM, XPS and ICP-AES, and its hydrogen elimination performance is also studied. The obtained results show that Pt-Pd/ZrVFeTi bimetallic catalyst displays superior catalytic performance toward H<sub>2</sub> oxidation reaction than monometallic Pt/ZrVFeTi or Pd/ZrVFeTi catalyst, which can be attributed to the presence of the PtPd alloyed structures. The Pt-Pd/ZrVFeTi bimetallic catalyst exhibits a high hydrogen conversion of 98.8 % when the hydrogen inlet concentration is 4 vol%, which is higher than 94.3 % for Pd/ZrVFeTi and 91.3 % for Pt/ZrVFeTi. Furthermore, it maintains excellent catalytic activity over 120 mins of the testing experiments, demonstrating remarkable stability. The synergistic effect between Pt and Pd proves beneficial for H<sub>2</sub> oxidation reaction.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"104 ","pages":"Article 114731"},"PeriodicalIF":8.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142721335","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Neural network controller for hybrid energy management system applied to electric vehicles 应用于电动汽车的混合能源管理系统神经网络控制器
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-27 DOI: 10.1016/j.est.2024.114502
Alex N. Ribeiro , Daniel M. Muñoz
{"title":"Neural network controller for hybrid energy management system applied to electric vehicles","authors":"Alex N. Ribeiro ,&nbsp;Daniel M. Muñoz","doi":"10.1016/j.est.2024.114502","DOIUrl":"10.1016/j.est.2024.114502","url":null,"abstract":"<div><div>Hybrid energy storage systems based on batteries and supercapacitors can mitigate the aging of electric vehicle batteries aging by avoiding high currents and rapid discharge cycles. This system requires energy management systems that efficiently split the power during real driving cycles. This paper outlines a design methodology for creating a Multilayer Perceptron neural controller that governs the power distribution between the storage system components. In parallel, a Proportional-Integral-Derivative controller was implemented to ensure voltage regulation in the primary DC bus, ensuring stable operation of the entire system and providing flexibility to the neural design. The controller was tuned using particle swarm optimization, hippopotamus optimization, and differential evolution algorithms, designed to minimize the battery root-mean-square current in a comprehensive vehicle simulation. The training was structured into layers to approach the physical problem and controller optimization facets. The controller’s primary goal is to minimize the battery strain, mitigating stress events and prolonging its lifespan. The energy management neural controller was designed using a simple drive cycle and later validated with a realistic cycle. The findings demonstrate the feasibility of achieving a significant reduction in current, both in peak value and on average, especially when compared to basic energy management strategies. The process uncovered a strategy that prioritizes the use of the supercapacitor in power balance, with this effect being more pronounced during critical load events. The main bus voltage remained stable, with no deviations exceeding 5%, owing to the voltage regulator’s stability. Additionally, the particle swarm optimization and the hippopotamus optimization techniques exhibited notable performance compared to the differential evolution algorithm for this problem. Subsequently, the design was evaluated in a more complex cycle, revealing a slight decrease in average battery current performance. However, it still maintained a significant reduction in peak battery current compared to traditional controllers. Nevertheless, this methodology demonstrated power management optimization efficacy and can be extended to more complex scenarios.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"104 ","pages":"Article 114502"},"PeriodicalIF":8.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142721171","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Commercial operation mode of shared energy storage system considering power transaction satisfaction of renewable energy power plants 考虑可再生能源发电厂电力交易满意度的共享储能系统商业运营模式
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-27 DOI: 10.1016/j.est.2024.114738
Hejun Yang , Zhaochen Yang , Mengchao Gong , Ke Tang , Yuming Shen , Dabo Zhang
{"title":"Commercial operation mode of shared energy storage system considering power transaction satisfaction of renewable energy power plants","authors":"Hejun Yang ,&nbsp;Zhaochen Yang ,&nbsp;Mengchao Gong ,&nbsp;Ke Tang ,&nbsp;Yuming Shen ,&nbsp;Dabo Zhang","doi":"10.1016/j.est.2024.114738","DOIUrl":"10.1016/j.est.2024.114738","url":null,"abstract":"<div><div>The sharing economy mode can promote an optimal allocation and utilization of resources, and its integration with the energy storage and renewable energy can improve their utilization rate and reduce the dispatching deviation. In order to reduce the renewable energy dispatching deviation and improve profits of shared energy storage, this paper proposes a shared energy storage commercial operation mode considering the power transaction satisfaction of renewable energy plants. Firstly, in order to promote the participation of renewable energy plants in the commercial mode, a power transaction satisfaction mode is proposed, and a multilateral bidding transaction mode based on power transaction satisfaction is established. Secondly, in order to further compensate the dispatching deviation, a deviation elimination model through jointing multiple shared energy storages and renewable energy plant clusters is established, and the advantages of renting multiple shared energy storages are analyzed. Thirdly, in order to quantify the profits of each participant in the commercial mode, a shared profit and settlement cost model is developed. Finally, the correctness of the above proposed model is verified by analyzing the case study.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"105 ","pages":"Article 114738"},"PeriodicalIF":8.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142723126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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