Journal of energy storage最新文献

筛选
英文 中文
A comparison of the electrochemical performance between novel donut-like and rectangular-like supercapacitors made with La0.5Pr0.5Fe0.7Mn0.3O3 perovskite
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-29 DOI: 10.1016/j.est.2024.114628
M. Perez-Chavez , L.A. Garcés-Patiño , K.P. Padmasree , T.A. Esquivel-Castro , L. Ojeda , T. De la Torre , H. Chavez-Cardenas , M. Quevedo-Lopez , J. Oliva
{"title":"A comparison of the electrochemical performance between novel donut-like and rectangular-like supercapacitors made with La0.5Pr0.5Fe0.7Mn0.3O3 perovskite","authors":"M. Perez-Chavez ,&nbsp;L.A. Garcés-Patiño ,&nbsp;K.P. Padmasree ,&nbsp;T.A. Esquivel-Castro ,&nbsp;L. Ojeda ,&nbsp;T. De la Torre ,&nbsp;H. Chavez-Cardenas ,&nbsp;M. Quevedo-Lopez ,&nbsp;J. Oliva","doi":"10.1016/j.est.2024.114628","DOIUrl":"10.1016/j.est.2024.114628","url":null,"abstract":"<div><div>Novel donut-like supercapacitors (SCs) were fabricated from recycled plastics. To enhance their electrochemical performance, La<sub>0.5</sub>Pr<sub>0.5</sub>Fe<sub>0.7</sub>Mn<sub>0.3</sub>O<sub>3</sub> (LAFE) redox powder was added on their electrodes. This powder had an orthorhombic structure and was formed by porous grains with sizes of 40–120 nm according to the microscopy and X-ray diffraction analyses. Donut-like SCs (contained acidic electrolyte) made with and without LAFE had capacitances of 182.8 and 334.7 F g<sup>−1</sup>, respectively. Although the device made with LAFE had lower capacitance, it presented a battery component (prolonged discharge at a stable voltage of 1.2 V), which produced a high capacity of 1555 mAh g<sup>−1</sup>. In contrast, the donut-like SC made without LAFE had a lower capacity of 260 mAh g<sup>−1</sup>. Other donut-like SCs were made with an amber electrolyte derived from recycled lithium-ion battery (LIB) electrodes (collected from expired LIBs). Those devices had lower capacitances and energy-densities of 96–230 F g<sup>−1</sup> and 36–42 Wh kg<sup>−1</sup>, respectively. For comparison purposes, rectangular SCs were fabricated with and without LAFE redox powder and obtained capacitances/energy-densities of 970.8 F g<sup>−1</sup>/194.2 Wh kg<sup>−1</sup> and 562.5 F g<sup>−1</sup>/112.5 Wh kg<sup>−1</sup>, respectively. Thus, adding the LAFE powder to the rectangular SCs incremented their capacitance by ⁓73 %. Those rectangular devices were also immersed in water at room temperature or under cold water (5 °C); consequently, the capacitance decreased by 45–53 %. The analysis by Raman spectroscopy, optical-absorption, and XPS spectroscopy demonstrated the existence of Fe<sup>3+</sup>/Fe<sup>2+</sup> and Mn<sup>4+</sup>/Mn<sup>3+</sup> species as well as oxygen-vacancy defects on the SC electrodes made with LAFE. Those ones promoted the storage of charge by redox-reactions. Hence, the results of this work revealed that donut-like energy sources can be fabricated from recycled six-pack rings, which avoids the contamination of the environment by microplastics. We also demonstrated that electrolytes can be produced from recycled LIB electrodes and could be used to fabricate efficient SCs. Both, the novel electrolyte and donut-like devices pave the way for the design of low-cost energy sources that can be used in wearable electronics.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114628"},"PeriodicalIF":8.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the effect of magnesium oxide on electrochemical properties of polypyrrole encapsulated on graphitic carbon nitride for supercapacitors applications
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-29 DOI: 10.1016/j.est.2024.114698
Manisha , Monika Dhanda , Varij Panwar , Suman Lata , Harish Kumar , Anshu Sharma
{"title":"Exploring the effect of magnesium oxide on electrochemical properties of polypyrrole encapsulated on graphitic carbon nitride for supercapacitors applications","authors":"Manisha ,&nbsp;Monika Dhanda ,&nbsp;Varij Panwar ,&nbsp;Suman Lata ,&nbsp;Harish Kumar ,&nbsp;Anshu Sharma","doi":"10.1016/j.est.2024.114698","DOIUrl":"10.1016/j.est.2024.114698","url":null,"abstract":"<div><div>This study addresses the facile synthesis of magnesium oxide/graphitic carbon nitride/Polpyrrole (MGP) composites by varying the concentration of magnesium oxide. These composites were synthesized via calcination route followed by in-situ polymerization reaction thus naming the composites as MGP0.5, MGP1, MGP2 and MGP3. The structural analysis of composites is done through X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR) and Raman spectroscopy while the morphology is analyzed through Field Emission Scanning Electron Microscopy (FESEM) and supported by Transmission Electron Microscopy (TEM). The MGP2 composite, assessed through multi-point BET theory, exhibits a specific surface area of 109.45 m<sup>2</sup> g<sup>−1</sup>, surpassing that of its precursor materials. This enhanced surface area facilitates a greater number of active sites for the adsorption-desorption of ions. The assessment of electrochemical properties is done through cyclic voltammetry (CV), galvanostatic charge discharge (GCD) and electrochemical impedance spectroscopy (EIS) in three-electrode setup in 1 M H<sub>2</sub>SO<sub>4</sub> which delivers a specific capacitance of 1132.12 F g<sup>−1</sup> at 5 mV s<sup>−1</sup> for MGP2 composite. The practical applicability of the electrode material was examined by fabricating an asymmetric supercapacitor device which delivers an energy density of 9.25 W h kg<sup>−1</sup> at a power density of 302.72 W kg<sup>−1</sup>. The supercapacitor device exhibited 94.03 % capacitance retention after 10,000 cycles demonstrating its potential to be used as a future supercapacitor applications.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114698"},"PeriodicalIF":8.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of binder-free MXene/reduced graphene oxide/W18O49 film electrode for flexible supercapacitors
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-29 DOI: 10.1016/j.est.2024.114741
Ruidong Li , Baoquan Liang , Hong Gao , Jie Li , Qianwen Liu , Lihua Chen , Shuxin Song , Bingyue Zheng , Tingxi Li , Yong Ma
{"title":"Fabrication of binder-free MXene/reduced graphene oxide/W18O49 film electrode for flexible supercapacitors","authors":"Ruidong Li ,&nbsp;Baoquan Liang ,&nbsp;Hong Gao ,&nbsp;Jie Li ,&nbsp;Qianwen Liu ,&nbsp;Lihua Chen ,&nbsp;Shuxin Song ,&nbsp;Bingyue Zheng ,&nbsp;Tingxi Li ,&nbsp;Yong Ma","doi":"10.1016/j.est.2024.114741","DOIUrl":"10.1016/j.est.2024.114741","url":null,"abstract":"<div><div>MXene nanosheets tend to aggregate during operation, significantly impeding their utility. Yet, the defect can be validly solved by incorporating intercalation substances. Herein, binder-free MXene/reduced graphene oxide/W<sub>18</sub>O<sub>49</sub> (MXene/rGO/W<sub>18</sub>O<sub>49</sub>) film is fabricated as supercapacitor electrode. W<sub>18</sub>O<sub>49</sub> and rGO can foster the formation of interlayer structure with MXene nanosheets. This enlarging of interlamellar spacing facilitates establishing multidirectional ion transport routes and exposing more active sites. MXene/rGO/W<sub>18</sub>O<sub>49</sub> manifests 581.2 F g<sup>−1</sup> specific capacitance at 1 A g<sup>−1</sup>. Moreover, the assembled asymmetric supercapacitor (ASC), comprising of MXene/rGO/W<sub>18</sub>O<sub>49</sub> and activated carbon (AC) as positive and negative electrodes, exhibits 1.6 V voltage window, along with 43.2 Wh kg<sup>−1</sup> energy density at 799.8 W kg<sup>−1</sup> power density. Notably, it retains 87.1 % capacitance after 10,000 cycles at 3 A g<sup>−1</sup>. Optimization strategy for MXene/rGO/W<sub>18</sub>O<sub>49</sub> film as electrode not only illustrates the viability of MXene advancement, but also offers significant technical backing for its utilization in the next generation of flexible devices.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114741"},"PeriodicalIF":8.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Physics-guided TL-LSTM network for early-stage degradation trajectory prediction of lithium-ion batteries
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-29 DOI: 10.1016/j.est.2024.114736
Qingqiang Liu , Zhiqing Shang , Shixiang Lu , Yuanhong Liu , Yuchao Liu , Sheng Yu
{"title":"Physics-guided TL-LSTM network for early-stage degradation trajectory prediction of lithium-ion batteries","authors":"Qingqiang Liu ,&nbsp;Zhiqing Shang ,&nbsp;Shixiang Lu ,&nbsp;Yuanhong Liu ,&nbsp;Yuchao Liu ,&nbsp;Sheng Yu","doi":"10.1016/j.est.2024.114736","DOIUrl":"10.1016/j.est.2024.114736","url":null,"abstract":"<div><div>Predicting early degradation trajectories of lithium-ion batteries is crucial in enhancing system reliability and promoting battery technology advancement. Existing data-driven methods often require large amounts of historical data and similar cycle information, which are not easily accessible in real-world applications. To this end, a physics-guided TL-LSTM network is proposed for degradation trajectory prediction, which integrates the physical degradation property into a transfer learning framework. Specifically, we first build a backbone network that combines a Long Short-Term Memory (LSTM) module and a Fully Connected (FC) module to perform fine-grained model training on the source domain. Then, the well-trained LSTM module is frozen and transferred to the target domain, and the FC module is fine-tuned using 30% of its early-cycle data. The entire network optimization process is guided by two inherent properties of battery degradation. Extensive comparative analysis demonstrates that our proposed approach outperforms existing methods in predicting early degradation trajectories.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114736"},"PeriodicalIF":8.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research and optimization of slit issues in the kW-scale redox flow batteries stack
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-29 DOI: 10.1016/j.est.2024.114703
Yingchun Niu, Shengwei Yuan, Ziyu Liu, Ali Heydari, Yinping Liu, Wei Qiu, Chunming Xu, Quan Xu
{"title":"Research and optimization of slit issues in the kW-scale redox flow batteries stack","authors":"Yingchun Niu,&nbsp;Shengwei Yuan,&nbsp;Ziyu Liu,&nbsp;Ali Heydari,&nbsp;Yinping Liu,&nbsp;Wei Qiu,&nbsp;Chunming Xu,&nbsp;Quan Xu","doi":"10.1016/j.est.2024.114703","DOIUrl":"10.1016/j.est.2024.114703","url":null,"abstract":"<div><div>The assembly of the frame and bipolar plates in redox flow batteries (RFBs) often results in assembly gaps, forming ‘slit.’ Due to differing coefficients of thermal expansion between the plate frame and bipolar plates, thermal expansion and contraction occur under the influence of assembly environment temperatures and operational temperatures of RFBs, exacerbating the ‘slit’ issue. The presence of ‘slits’ can reduce the utilization rate of the electrolyte and decrease mass transfer efficiency during the battery cycling process. However, the flow channel design for kilowatt (kW)-scale stacks often overlooks the impact of these slits. Therefore, this paper examines the influence of ‘slit’ structures on the flow characteristics of electrolytes within carbon cloth using kW-scale stacks with interdigitated flow channel structures as an example, and optimizes the interdigitated flow field with slits. The study analyzes the flow characteristics of electrolytes on carbon cloth in flow field structures with no slits, slits at both ends and slits on three sides. It further investigates the effects of slit width and the length of interdigitated flow channels on the flow patterns of electrolytes on carbon cloth when slits are present. Through numerical simulation, velocity and pressure distribution maps at the center of the carbon cloth, as well as velocity distributions at various positions, are obtained. The results show that slits affect the position and extent of the low-speed zone on the carbon cloth. As slit width increases, the resistance of the slit decreases, gradually increasing the flow velocity of the electrolyte towards the carbon cloth. However, when the slit width exceeds 0.5 mm, the impact of the slit on flow over the carbon cloth remains largely unchanged. With a fixed slit width of 0.5 mm, increasing the length of the interdigitated flow channels reduces the flow velocity and pressure within the carbon cloth but significantly improves the uniformity of the carbon cloth. Extending the interdigitated flow channel length by 15 mm demonstrates the best overall effect.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114703"},"PeriodicalIF":8.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746477","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamic programming-based energy storage siting and sizing: Application to enhance flexibility of large-scale power grid
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-29 DOI: 10.1016/j.est.2024.114734
Yucan Zhao , Yue Bi , Yao Xu , Yuan Gao , Sile Hu , Yu Guo , Jiaqiang Yang
{"title":"Dynamic programming-based energy storage siting and sizing: Application to enhance flexibility of large-scale power grid","authors":"Yucan Zhao ,&nbsp;Yue Bi ,&nbsp;Yao Xu ,&nbsp;Yuan Gao ,&nbsp;Sile Hu ,&nbsp;Yu Guo ,&nbsp;Jiaqiang Yang","doi":"10.1016/j.est.2024.114734","DOIUrl":"10.1016/j.est.2024.114734","url":null,"abstract":"<div><div>To address the issues of limited Energy Storage System (ESS) locations and the flexibility unevenly distributed in the large-scale power grid planning, this paper introduces the Dynamic Programming (DP) theory into flexibility planning, and proposes a DP-based ESS siting and sizing method. This method reduces the computational complexity of siting and sizing to ensure a sufficient number of ESSs allocated. It provides each partitioning area with a certain degree of flexible ramping capability so that the flexibility is evenly distributed in the large-scale grid.</div><div>The proposed method starts with a high-voltage pruning partition algorithm to hierarchically partition the large-scale grid, with the partitioning outcomes serving to divide the various DP stages. Then a state transition equation is established with the ESS rated power as the state variable, considering all nodes which satisfy the voltage level requirements as potential ESS sites to ensure a sufficient number of locations. Following this, a DP basic equation is formulated with the ESS capacity as the decision variable, setting flexibility constraints for all partitioning areas to achieve an even distribution of grid flexibility. By combining the state transition equation and the DP basic equation, the proposed method culminates in the energy storage allocation dynamic programming model, which determines the optimal locations, capacities, and rated powers of ESSs, along with the construction cost.</div><div>This paper further explores the development of the Flexible Resource Allocation Intelligent Decision Software (FRAIDS) building upon the proposed method. Case analysis in an actual grid verifies that the calculations from FRAIDS significantly enhance the entire grid flexibility. Additionally, day-ahead dispatching results indicate that, following ESS allocation, net load fluctuates between 15,295.5 MW and 17,794.9 MW with the conventional method, compared to a more stable range of 16,309.8 MW to 17,417.4 MW with the proposed method. This shows that the proposed method effectively reduces net load fluctuations, thereby significantly alleviating flexible ramping pressure on thermal units.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114734"},"PeriodicalIF":8.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142747284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogen bond cross-linked photo-healable multifunctional phase change materials for thermal management
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-29 DOI: 10.1016/j.est.2024.114821
Fang Wei , Yongpeng Wu , Mingjie Li , Danfeng Pei , Chaoxu Li
{"title":"Hydrogen bond cross-linked photo-healable multifunctional phase change materials for thermal management","authors":"Fang Wei ,&nbsp;Yongpeng Wu ,&nbsp;Mingjie Li ,&nbsp;Danfeng Pei ,&nbsp;Chaoxu Li","doi":"10.1016/j.est.2024.114821","DOIUrl":"10.1016/j.est.2024.114821","url":null,"abstract":"<div><div>Phase change materials (PCMs) are extensively employed in the realm of electronic device thermal management due to their remarkable ability to absorb heat while maintaining temperature stability. However, the lack of versatility has greatly hindered their applications in flexible wearable electronics and similar fields. Herein, we designed a dynamic, flexible, anti-flaming, ultrafast healable and recyclable supramolecular poly(urethane-urea) phase change material (PUSePCM). The synergistic effects of dynamic hydrogen-bond network and rapid diselenide metathesis endowed a rapid self-healing within 30 s and recycle capability. The PUSePCM could also attach to various metal surfaces and was further used as flexible interface materials in thermal management applications. With the silver microparticles content of ≥30 vol%, the resultant composite can significantly reduce the work temperature of a chip by about 10 °C. This research not only provides a new approach for creating phase-change materials with dynamic, flexible, self-healing, and recyclable performance, but also offers the applications for damage tolerable thermal management interface.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114821"},"PeriodicalIF":8.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The enhanced cooling effect and critical control capability of nanofluids on suppressing thermal runaway of lithium-ion batteries
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-29 DOI: 10.1016/j.est.2024.114733
Jun Deng , Zhen Hu , Jian Chen , Tianyang Deng , Yanni Zhang , Zujin Bai , Luoxin Huang , Fenfen He
{"title":"The enhanced cooling effect and critical control capability of nanofluids on suppressing thermal runaway of lithium-ion batteries","authors":"Jun Deng ,&nbsp;Zhen Hu ,&nbsp;Jian Chen ,&nbsp;Tianyang Deng ,&nbsp;Yanni Zhang ,&nbsp;Zujin Bai ,&nbsp;Luoxin Huang ,&nbsp;Fenfen He","doi":"10.1016/j.est.2024.114733","DOIUrl":"10.1016/j.est.2024.114733","url":null,"abstract":"<div><div>Lithium-ion batteries (LIBs) thermal runaway (TR) has been highly concerned by society and scholars due to its tendency to cause considerable disasters and accidents, such as fire and explode. Rapid cooling and effective control methods play an important role in mitigating the development of disasters caused by TR of LIBs. In the present study, three types of nanofluids namely Boron nitride, Aluminum oxide and Titanium dioxide dispersed in distilled water, have been used with single concentration; 0.1 % by volume, to investigate cooling effect and critical control capacity by spray cooling in mitigation TR of LIBs. The results show that water mist containing nanoparticles can enhance cooling rate. The nanofluids can quickly reduce the temperature from maximum temperature during thermal runaway to below 100 °C in the cooling experiment, and the cooling times of 11 s, which was 45 % shorter than that of water mist. The maximum cooling rate can reach 127.4 °C/s, which is 61.29 % higher than water mist. Compared with the critical suppression temperature of water mist at 160 °C, nanofluid spray can inhibit thermal runaway at a higher temperature, and can increase the critical suppression temperature by nearly 40 °C at most. The maximum heat dissipation rate of the nanofluid spray is 6067.4 W. However, Nanofluids are difficult to suppress the rapid rise in battery temperature during TR. In addition, the cooling rate of nanofluids is closely related to their own thermal conductivity. These results demonstrate that a higher cooling rate of nanofluid spray can help firefighters quickly control TR accidents and strive for sufficient time for personnel evacuation, which may provide a reference for the suppressing disasters caused by TR.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114733"},"PeriodicalIF":8.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Implementation of phosphonium salt for high-performance supercapacitors from room to ultra-low temperature conditions
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-29 DOI: 10.1016/j.est.2024.114750
Hoai Van T. Nguyen , Hee Jin Han , Euna Choi , Yong Ho Lee , Kyung-Koo Lee
{"title":"Implementation of phosphonium salt for high-performance supercapacitors from room to ultra-low temperature conditions","authors":"Hoai Van T. Nguyen ,&nbsp;Hee Jin Han ,&nbsp;Euna Choi ,&nbsp;Yong Ho Lee ,&nbsp;Kyung-Koo Lee","doi":"10.1016/j.est.2024.114750","DOIUrl":"10.1016/j.est.2024.114750","url":null,"abstract":"<div><div>Conventional supercapacitors encounter limitations in operating voltage and performance at low temperatures due to poor ionic conductivity and diminished interfacial dynamics in electrolytes. In this study, we synthesized the phosphonium salt 5-phosphinaspiro[4.4] nonane tetrafluoroborate (PSNBF<sub>4</sub>) for the first time. We extensively characterized the physical and electrochemical properties of PSNBF<sub>4</sub> in acetonitrile (AN) and propionitrile (PN) as electrolytes, assessing their performance in supercapacitors at room temperature and − 40 °C. The results demonstrate PSNBF<sub>4</sub> electrolytes exhibit high solubility, outstanding ionic conductivity (1 M PSNBF<sub>4</sub>/AN: 49.8 mS cm<sup>−1</sup>; 1 M PSNBF<sub>4</sub>/PN: 27.5 mS cm<sup>−1</sup>), and high electrochemical stability, contributing to good capacitance retention after 500 h of floating tests at 25 °C. Supercapacitors using PSNBF<sub>4</sub>/AN retained 78 % of their capacitance at 3.1 V, whereas those with PSNBF<sub>4</sub>/PN maintained 68 % at 3.2 V. Impressively, these supercapacitors performed exceptionally well at −40 °C, displaying excellent cycle stability and high capacitance retention at elevated voltages. Supercapacitors with PSNBF<sub>4</sub>/AN retain 96.6 % of their capacitance at 3.2 V, while PSNBF<sub>4</sub>/PN retained 93.4 % of their capacitance at 3.4 V after floating for 500 h. These results demonstrate PSNBF<sub>4</sub>-based supercapacitors can operate effectively at high voltages in both room and extremely low temperatures, addressing a significant challenge in commercial supercapacitor applications.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114750"},"PeriodicalIF":8.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparing experimental designs for parameterizing semi-empirical and deep learning-based lithium-ion battery aging models
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-29 DOI: 10.1016/j.est.2024.114702
Thomas Kröger , Sven Maisel , Georg Jank , Kareem Abo Gamra , Tobias Brehler , Markus Lienkamp
{"title":"Comparing experimental designs for parameterizing semi-empirical and deep learning-based lithium-ion battery aging models","authors":"Thomas Kröger ,&nbsp;Sven Maisel ,&nbsp;Georg Jank ,&nbsp;Kareem Abo Gamra ,&nbsp;Tobias Brehler ,&nbsp;Markus Lienkamp","doi":"10.1016/j.est.2024.114702","DOIUrl":"10.1016/j.est.2024.114702","url":null,"abstract":"<div><div>Design of Experiment (DOE) methods can be applied to optimize test plans of cycle life aging studies with the aim to efficiently parameterize lithium-ion battery aging models. Since different DOEs exist and their effect on the prediction performance of battery aging models has not yet been investigated, we conducted a cycle life aging study with six commonly used DOEs (One-factor-at-a-time, Taguchi, Box–Behnken, Central Composite, Full Factorial, and D-optimal) and compare their influence on the prediction performance of a semi-empirical and a deep learning-based battery aging model. The results show that the semi-empirical model benefits the most from statistically optimized test plans. Compared to randomly selecting test plans, applying DOE methods helps to consistently achieve one of the lowest possible prediction errors for a given number of test points. Furthermore, it is shown that a D-optimal test plan and the test plans obtained from response surface methods (Box–Behnken and Central Composite) require only half as many test points as a Full Factorial test design, but still result in semi-empirical models with a high prediction accuracy that is similar to the Full Factorial test design. In contrast, deep learning-based battery aging models benefit significantly less from statistically optimized test plans. The highest prediction accuracy is achieved by the Full Factorial test plan and all other DOEs result in higher prediction errors and are even outperformed by several randomly defined test plans. Instead of using static designs, deep-learning-based models profit from a dynamic test optimization, which reduces the number of tested batteries during cycle life testing based on their information gain. We demonstrate that with our proposed dynamic test reduction algorithm, which analyzes the information gain based on aging features extracted after 100 EFC of cycling, up to 50% of all tested batteries of a Full Factorial test plan can be excluded from the cycle life study without deteriorating the prediction accuracy of the resulting deep learning-based battery aging model.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114702"},"PeriodicalIF":8.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信