Journal of Environmental Sciences-china最新文献

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La replaced Bi3+ in BiO2-x for oxygen vacancies generation: degradation of antibiotics and biological toxicity elimination La取代Bi3+在BiO2-x中的氧空位生成:抗生素降解和生物毒性消除
IF 6.3 2区 环境科学与生态学
Journal of Environmental Sciences-china Pub Date : 2025-04-23 DOI: 10.1016/j.jes.2025.03.033
Jiangtao Niu , Jin Zhang , Xiaoxuan Song , Naif Abdullah Al-Dhabi , Wanhong He , Guihua Huang , Dujie Feng , Wanngwang Tang , Mingming Dang , Yi Zhou
{"title":"La replaced Bi3+ in BiO2-x for oxygen vacancies generation: degradation of antibiotics and biological toxicity elimination","authors":"Jiangtao Niu ,&nbsp;Jin Zhang ,&nbsp;Xiaoxuan Song ,&nbsp;Naif Abdullah Al-Dhabi ,&nbsp;Wanhong He ,&nbsp;Guihua Huang ,&nbsp;Dujie Feng ,&nbsp;Wanngwang Tang ,&nbsp;Mingming Dang ,&nbsp;Yi Zhou","doi":"10.1016/j.jes.2025.03.033","DOIUrl":"10.1016/j.jes.2025.03.033","url":null,"abstract":"<div><div>La-BiO<sub>2-x</sub> composite photocatalyst was successfully synthesized through a single-step hydrothermal strategy. The introduction of La<sup>3+</sup> into the BiO<sub>2-x</sub> lattice replaces the Bi<sup>3+</sup> in the BiO<sub>2-x</sub> lattice, resulting in a new defect level and oxygen vacancies (V<sub>o</sub>) generation. The ·O<sub>2</sub><sup>−</sup> generated in the surface of V<sub>o</sub>, which was converted into singlet oxygen (<sup>1</sup>O<sub>2</sub>) with the transformation of Bi<sup>5+</sup> to Bi<sup>3+</sup>. Upon visible (near-infrared) light irradiation, the removal rates of tetracycline (TC), oxytetracycline (OTC), and levofloxacin (LEV) by trace 5 % La-BiO<sub>2-x</sub> (0.1 g/L) reached 84.18 % (55.56 %), 78.85 % and 70.12 %, respectively. The Toxicity Estimation Software Tool (T.E.S.T) based on Quantitative Structure-Activity Relationship (QSAR) models illustrated that the biological toxicity of TC intermediates can be eliminated by 5 % La-BiO<sub>2-x</sub>. The green bean germination rates in 5 % La-BiO<sub>2-x</sub> treated TC solution was close to that in the tap water (100.0 %). The inorganic anion and humic acid (HA) exhibited almost no influence on the degradation of TC in lake water and river water. This study enhances the comprehension of biological toxicity elimination in antibiotics degradation process, providing the possibilities for actual applications of La-BiO<sub>2-x</sub>.</div></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"160 ","pages":"Pages 93-104"},"PeriodicalIF":6.3,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144925902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cathode catalyst-assisted microbial electrosynthesis of acetate from carbon dioxide: promising material selection 阴极催化剂辅助微生物从二氧化碳中电合成乙酸:有前途的材料选择
IF 6.3 2区 环境科学与生态学
Journal of Environmental Sciences-china Pub Date : 2025-04-17 DOI: 10.1016/j.jes.2025.04.038
Rujing Lin , Xiaomei Zheng , Huai Zhang , Yingying He , Mingxian Liu , Li Xie
{"title":"Cathode catalyst-assisted microbial electrosynthesis of acetate from carbon dioxide: promising material selection","authors":"Rujing Lin ,&nbsp;Xiaomei Zheng ,&nbsp;Huai Zhang ,&nbsp;Yingying He ,&nbsp;Mingxian Liu ,&nbsp;Li Xie","doi":"10.1016/j.jes.2025.04.038","DOIUrl":"10.1016/j.jes.2025.04.038","url":null,"abstract":"<div><div>As the core of cathode materials, sensitive metals play important roles in the optimization of acetate production from carbon dioxide (CO<sub>2</sub>) in microbial electrochemical system (MES). In this work, iron (Fe), copper (Cu), and nickel (Ni) as sensitive metal cathode materials were evaluated for CO<sub>2</sub> conversion in MES. The MES with Fe-electrode as a promising electrode material demonstrated a superior CO<sub>2</sub> reduction performance with a maximum acetate accumulation of 417.9 ± 39.2 mg/L, which was 1.5 and 1.7 folds higher than that in the Ni-electrode and Cu-electrode groups, respectively. Furthermore, an outstanding electron recovery efficiency of 67.7 % was shown in the Fe-electrode group. The electron transfer between electrode-suspended sludge was systematically cross-evaluated by the electrochemical behavior and extracellular polymeric substances. The Fe-electrode group had the highest electron transfer rate with 0.194 s<sup>-1</sup> (<em>k</em><sub>app</sub>), which was 17.6 and 21.5 times higher than that of the Cu- and Ni-electrode groups, respectively. Fe-electrode was beneficial for reducing electrochemical impedance between the electrode and suspended sludge. Additionally, redox substances in extracellular polymeric substances of the Fe-electrode group were increased, implying more favorable electron transport dynamics. Simultaneously, enrichments of functional bacteria <em>Acetoanerobium</em> and increased key enzymes involved in the carbonyl pathway of the Fe-electrode group were observed, which also promoted CO<sub>2</sub> conversion in MES. This study provides a perspective on evaluating the promising sensitive metal electrode material for the process of CO<sub>2</sub> valorization in MES and offers a reference for the subsequent electrode modification.</div></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"160 ","pages":"Pages 394-404"},"PeriodicalIF":6.3,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145154307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adaptation of microbial gene polymorphisms of the partial nitritation-anammox process for maintaining denitrification performance and robustness under salinity stress 部分硝化-厌氧氨氧化过程微生物基因多态性对维持盐度胁迫下反硝化性能和稳健性的适应性研究
IF 6.3 2区 环境科学与生态学
Journal of Environmental Sciences-china Pub Date : 2025-04-17 DOI: 10.1016/j.jes.2025.04.028
Risen Yang , Yanxiao Wei , Jianhong Jiang , Xinying Kong , Sha Wu , Qingchang Tang , Yangkai Liu , Le Luo , E.A.E. Ali , Hong Chen
{"title":"Adaptation of microbial gene polymorphisms of the partial nitritation-anammox process for maintaining denitrification performance and robustness under salinity stress","authors":"Risen Yang ,&nbsp;Yanxiao Wei ,&nbsp;Jianhong Jiang ,&nbsp;Xinying Kong ,&nbsp;Sha Wu ,&nbsp;Qingchang Tang ,&nbsp;Yangkai Liu ,&nbsp;Le Luo ,&nbsp;E.A.E. Ali ,&nbsp;Hong Chen","doi":"10.1016/j.jes.2025.04.028","DOIUrl":"10.1016/j.jes.2025.04.028","url":null,"abstract":"<div><div>To explore the adaptive mechanisms of the partial nitritation-anammox (PNA) process under high salinity stress during kitchen wastewater treatment, focusing on their physiological and molecular responses through metagenomic analysis. An airlift inner-circulation partition bioreactor (AIPBR) was developed, featuring an inner cylinder and a flow guide tube to create distinct oxygen gradients, facilitating the study of microbial adaptation under varying salt conditions. The AIPBR was operated with synthetic wastewater containing ammonium concentrations of 1800 ± 100 mg/L and salinity gradients ranging from 1 to 10 g/L, followed by a fixed salinity period at 6 g/L, with ammonium concentrations approximately 850 mg/L. High-throughput metagenomic analysis revealed shifts in functional genes and metabolic pathways in response to salinity stress. Anammox bacteria adapted by enriching genes involved in the synthesis of osmoprotective compounds and activating energy-producing pathways like the tricarboxylic acid cycle (TCA). These adaptations, along with modifications in membrane composition, were essential for sustaining system stability under elevated salinity. Under prolonged high salinity stress, anaerobic ammonium oxidizing (AnAOB) exhibited improved salt tolerance, maintaining a total nitrogen removal efficiency above 85 % and stabilizing after an adaptation phase. The metagenomic data revealed a marked enrichment of genes associated with ion transport, stress response mechanisms, and DNA repair pathways. Changes in microbial community composition favored salt-tolerant species, supporting system stability. These findings highlight the applicability of the developed bioreactor for scaling up the PNA process to handle high-salinity wastewater, providing a promising avenue for sustainable nitrogen removal in challenging environments.</div></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"160 ","pages":"Pages 39-50"},"PeriodicalIF":6.3,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144885721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effects of bisphenol compounds on endocrine disruption and reproductive function from epidemiological analysis to animal exposure: A mixture analysis 从流行病学分析到动物接触双酚类化合物对内分泌干扰和生殖功能的影响:混合分析
IF 6.3 2区 环境科学与生态学
Journal of Environmental Sciences-china Pub Date : 2025-04-17 DOI: 10.1016/j.jes.2025.04.042
Peiyun Jiang , Weiwei Wang , Jiande Li , Yating Li , Xiaotong Ji , Huifeng Yue
{"title":"The effects of bisphenol compounds on endocrine disruption and reproductive function from epidemiological analysis to animal exposure: A mixture analysis","authors":"Peiyun Jiang ,&nbsp;Weiwei Wang ,&nbsp;Jiande Li ,&nbsp;Yating Li ,&nbsp;Xiaotong Ji ,&nbsp;Huifeng Yue","doi":"10.1016/j.jes.2025.04.042","DOIUrl":"10.1016/j.jes.2025.04.042","url":null,"abstract":"<div><div>Bisphenol F (BPF) and Bisphenol S (BPS) are widely used substitutes for Bisphenol A (BPA). However, growing evidence indicated that BPF and BPS may induce physiological effects similar to those of BPA. Furthermore, chemical management and control is primarily focus on the risk assessment of individual compounds, often overlooking the implications of chemical mixtures. We hypothesize that exposure to a mixture of BPA and its substitutes will enhance their endocrine-disruptive effects, disrupt steroid hormone homeostasis, and further impair reproductive system functionality. In the animal study, both female and male mice were exposed to 333 μg/kg of BPA, BPF, BPS, their mixture (333 μg/kg (MIXL), and 1 mg/kg (MIXH)) via gavage daily for four weeks. The study demonstrated that bisphenols (BPs) affected the expression of genes related to steroid hormone synthesis. The MIXL group of female mice exhibited an increasing trend in estradiol (E2) levels and a decreasing trend in progesterone (Pg) and testosterone (TT) levels. Additionally, follicular development was impacted, resulting in an increased number of atretic follicles. In contrast, a significant increase in E2 concentration and disruption of testicular morphology were observed in the MIXH group of male mice, accompanied by a decline in sperm quality. Importantly, these results were corroborated by a population-based investigation. Collectively, the animal experiments indicate that mixed exposure to BPs disrupts hormone levels and adversely affects reproductive function, while epidemiological evidence further establishes correlative links between bisphenols and hormone levels. These findings underscore the necessity of considering chemical mixtures during testing and risk assessment.</div></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"160 ","pages":"Pages 537-547"},"PeriodicalIF":6.3,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145220029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Far-UVC-driven Cr(VI) reduction in alkaline solution: Synergistic effects of iodide and sulfite 远紫外驱动碱性溶液中Cr(VI)的还原:碘化物和亚硫酸盐的协同效应
IF 6.3 2区 环境科学与生态学
Journal of Environmental Sciences-china Pub Date : 2025-04-17 DOI: 10.1016/j.jes.2025.04.047
Yida Huang , Min Zhao , Guoxin Li , Yan Lin , Lei Wang
{"title":"Far-UVC-driven Cr(VI) reduction in alkaline solution: Synergistic effects of iodide and sulfite","authors":"Yida Huang ,&nbsp;Min Zhao ,&nbsp;Guoxin Li ,&nbsp;Yan Lin ,&nbsp;Lei Wang","doi":"10.1016/j.jes.2025.04.047","DOIUrl":"10.1016/j.jes.2025.04.047","url":null,"abstract":"<div><div>Hexavalent chromium (Cr(VI)) is an extremely toxic pollutant in aqueous environment. Chemical reduction is the most employed method in decontamination of Cr(VI). However, the chemical reduction was usually conducted in acidic media, resulting in considerable waste of acid reagents and the following neutralizing agents. In this study, kinetics and mechanisms of Cr(VI) reduction by sulfite in alkaline conditions (pH: 7–10) were investigated. It reveals that Cr(VI) reduction follows pseudo-zero-order kinetics, where the rate constants increased markedly with an <em>in situ</em> irradiation of Far-UVC (UV<sub>222</sub>). Decreasing pH levels slightly favored the reduction. Iodide ion displayed a notable accelerating effect, which not only save the energy input but also minimize the reductant usage. Chloride, sulfate, and carbonate ions exhibit little effect on the reduction, whereas nitrate and nitrite ions, dissolved oxygen as well as Cu(II) suppressed the reduction significantly, implying that hydrated electrons produced by UV<sub>222</sub> played the most important role in the reaction. Compared to the UV<sub>254</sub>/sulfite/iodide process, UV<sub>222</sub>/sulfite/iodide demonstrates clear advantages in the reduction kinetics and the sulfite utilization efficiency, underscoring its potential for effective Cr(VI) remediation in various environmental settings.</div></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"160 ","pages":"Pages 405-413"},"PeriodicalIF":6.3,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145154434","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nutrient accumulation and eutrophication restricted CO2 emissions in the two backwater bays in the Three Gorges Reservoir (TGR), China 三峡库区两个回水湾的养分积累和富营养化限制了CO2的排放
IF 6.3 2区 环境科学与生态学
Journal of Environmental Sciences-china Pub Date : 2025-04-16 DOI: 10.1016/j.jes.2025.04.043
Chen Jian , Xiaofeng Wang , Tingting Liu , Yuewei Zhang , Lijun Wang , Honglin Chen , Dongfeng Li , Yixin He
{"title":"Nutrient accumulation and eutrophication restricted CO2 emissions in the two backwater bays in the Three Gorges Reservoir (TGR), China","authors":"Chen Jian ,&nbsp;Xiaofeng Wang ,&nbsp;Tingting Liu ,&nbsp;Yuewei Zhang ,&nbsp;Lijun Wang ,&nbsp;Honglin Chen ,&nbsp;Dongfeng Li ,&nbsp;Yixin He","doi":"10.1016/j.jes.2025.04.043","DOIUrl":"10.1016/j.jes.2025.04.043","url":null,"abstract":"<div><div>Reservoir is an important source of CO<sub>2</sub> emissions. The backwater bay is a distinct hydrological unit formed in the open channel of canyon-reservoir as a result of impoundment. It is characterized by efficient nutrients retention and a propensity for frequent eutrophication. However, the spatio-temporal dynamics of CO<sub>2</sub> emissions in these backwater bays remain unclear. This study investigated CO<sub>2</sub> fluxes (<em>f</em>CO<sub>2</sub>) in two different backwater bays (Hanfeng Lake and Gaoyang Lake) within the Three Gorges Reservoir (TGR), to reveal the spatio-temporal dynamics and driving factors of CO<sub>2</sub> emissions. The two backwater bays serve as minor sources of CO<sub>2</sub> emissions, exhibiting lower <em>f</em>CO<sub>2</sub> compared to other water areas within the TGR. In the subsiding and low water level periods of the TGR, the <em>f</em>CO<sub>2</sub> in the two backwater bays were significantly lower, with some areas even converting into CO<sub>2</sub> sinks due to extensive eutrophication. However, the water flow backward caused by the TGR water level elevation simultaneously enhances CO<sub>2</sub> emissions by diluting algae density and constraining primary production. We highlighted that nutrients enrichment, eutrophication, and water level fluctuations co-dominate the temporal dynamics of CO<sub>2</sub> emissions from backwater bays in the TGR. The CO<sub>2</sub> fluxes decreased from upstream to downstream in the two backwater bays. The spatial distribution of nutrients and related algal density are critical factors driving this pattern. The key factors influencing CO<sub>2</sub> emissions in the backwater bays diversified with water level fluctuations. Our findings contribute to a better understanding of CO<sub>2</sub> emissions in large reservoirs with varying hydrological habitats.</div></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"160 ","pages":"Pages 656-669"},"PeriodicalIF":6.3,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145220111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effective recovering Pd(II) ions via tuning the Lewis basicity of nanofiber capture vacancy 通过调整纳米纤维捕获空位的路易斯碱度,有效地回收Pd(II)离子
IF 6.3 2区 环境科学与生态学
Journal of Environmental Sciences-china Pub Date : 2025-04-16 DOI: 10.1016/j.jes.2025.04.044
Nianshou Cheng , Mingyue Wang , Lu Wang , Lin Zhang , Chuanbin Li , Yu Guo , Bo Xing , Haichao Wang , Min Li
{"title":"Effective recovering Pd(II) ions via tuning the Lewis basicity of nanofiber capture vacancy","authors":"Nianshou Cheng ,&nbsp;Mingyue Wang ,&nbsp;Lu Wang ,&nbsp;Lin Zhang ,&nbsp;Chuanbin Li ,&nbsp;Yu Guo ,&nbsp;Bo Xing ,&nbsp;Haichao Wang ,&nbsp;Min Li","doi":"10.1016/j.jes.2025.04.044","DOIUrl":"10.1016/j.jes.2025.04.044","url":null,"abstract":"<div><div>Recovery of palladium from spent catalysts is of great practical significance for the construction of ecological civilization and resource recycling. However, for environmentally friendly adsorption methods, designing specialized capture vacancies with high capacity and precise selectivity for Pd(II) ions remains a challenge. Herein, a salicylic acid-modified nanofiber (SANF), exhibiting specific spatial configuration and constructing a capture vacancy by “O<img>O” of hard bases, was designed and employed for recovering and separating palladium. The adsorption results indicated that the SANF exhibited a fast capture rate (reaching adsorption equilibrium within 60 min) and a large capture capacity (about 170 mg/g) for Pd(II) ions, and the capture process was exothermic and spontaneous. Additionally, the Lewis basicity of the capture vacancy after tuning better matches the Lewis acidity of Pd(II) ions, which achieves a high-selectivity separation of Pd(II) ions (selectivity coefficient for K(I), Na(I) Ca(II), Mg(II) and Al(III) ions are 1505.2, 10,536.7, 1128.9, 2634.2 and 2873.6, respectively). Practical applications showed that SANF was enabled to recover Pd(II) ions from spent catalyst leachate and achieved four time adsorption-desorption cycles, possessing some industrial promise. Furthermore, the matching mechanism between the Lewis basicity of the capture vacancy and the Lewis acidity of the Pd(II) ions was revealed through series characterization and theoretical calculations. Finally, it is proposed a Lewis basicity tuning strategy founded on a specific spatial structure, provides a new insight for the design and construction of a capture vacancy for Pd(II) ions in the future.</div></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"160 ","pages":"Pages 690-699"},"PeriodicalIF":6.3,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145220057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recovery nitrogen and phosphorus from source-separated urine by polytetrafluoroethylene-polypropylene membrane distillation 聚四氟乙烯-聚丙烯膜蒸馏法从源分离尿液中回收氮磷
IF 6.3 2区 环境科学与生态学
Journal of Environmental Sciences-china Pub Date : 2025-04-15 DOI: 10.1016/j.jes.2025.04.036
Yuanyang Lv , Haoyang Song , Wei Tan , Ke Chen , Yajun Li , Jinyuan Jiang , Yanmei Yang
{"title":"Recovery nitrogen and phosphorus from source-separated urine by polytetrafluoroethylene-polypropylene membrane distillation","authors":"Yuanyang Lv ,&nbsp;Haoyang Song ,&nbsp;Wei Tan ,&nbsp;Ke Chen ,&nbsp;Yajun Li ,&nbsp;Jinyuan Jiang ,&nbsp;Yanmei Yang","doi":"10.1016/j.jes.2025.04.036","DOIUrl":"10.1016/j.jes.2025.04.036","url":null,"abstract":"<div><div>Urine consists of approximately 95 % water, 3.5 % organic matter, and 1.5 % inorganic salts. Membrane distillation (MD) offers a potential approach for urine resource utilization. To some extent, it reduces the loss of nitrogen and phosphorus resources. However, MD is also accompanied by problems such as high membrane cost, membrane fouling and membrane wetting. In light of these issues, this study employs polytetrafluoroethylene (PTFE) as the separation layer and polypropylene (PP) as the support layer to make a distillation membrane. The feasibility and efficiency of the PTFE-PP membrane in intercepting and recovering nitrogen and phosphorus from source-separated urine were investigated. Results obtained through 14 days of continuous operation demonstrated that the recovery rates of nitrogen and phosphorus were 95 % and 99 %, respectively. The dissolved organic carbon recovery rate was 95 %, and urea as well as the macromolecular organic matter in dissolved organic matter were significantly intercepted. The phosphorus content in the permeate was 0.022 mg/L, which met the Ⅱ class standard of China's surface water and the basic water use standard of the United States Environmental Protection Agency. This finding reduces the pressure on sewage treatment plants. PTFE-PP distillation membrane has important potential in recovering nitrogen and phosphorus from urine and alleviating global water shortage.</div></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"160 ","pages":"Pages 713-721"},"PeriodicalIF":6.3,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145220171","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Mn-ion reconstructed lattice on lead-free halide perovskite Cs3Bi2-XMnxCl9 Anode in Li-ion batteries 锰离子重构晶格对锂离子电池无铅卤化物钙钛矿Cs3Bi2-XMnxCl9负极的影响
IF 6.3 2区 环境科学与生态学
Journal of Environmental Sciences-china Pub Date : 2025-04-15 DOI: 10.1016/j.jes.2025.04.030
Wei Jia , Jianxun Bao , Hebi Zhang , Min Wu , Jianbei Qiu , Hao Wu , Yingjie Zhang
{"title":"Effect of Mn-ion reconstructed lattice on lead-free halide perovskite Cs3Bi2-XMnxCl9 Anode in Li-ion batteries","authors":"Wei Jia ,&nbsp;Jianxun Bao ,&nbsp;Hebi Zhang ,&nbsp;Min Wu ,&nbsp;Jianbei Qiu ,&nbsp;Hao Wu ,&nbsp;Yingjie Zhang","doi":"10.1016/j.jes.2025.04.030","DOIUrl":"10.1016/j.jes.2025.04.030","url":null,"abstract":"<div><div>Halide perovskite materials have received considerable attention for solar cells, LEDs, lasers etc. owing to their controllable physicochemical properties and structural advantages. However, little research has focused on energy storage and conversion applications, such as use as anodes in lithium-ion batteries. In this paper, all-inorganic lead-free halide perovskite Cs<sub>3</sub>Bi<sub>2</sub>Cl<sub>9</sub> powders were synthesized by the grinding method, and the lattice was successfully adjusted via introducing Mn<sup>2+</sup>. The characterization results show that Mn-ion substitution can cause local lattice distortion to restructure the lattice, which will cause a mixed arrangement of [BiCl<sub>6</sub>] octahedra to improve the performance of the anode material. This new material can provide a feasible solution for solving the problem of low specific capacity anode materials caused by unstable crystal structures, and also indicates that such perovskites with unique crystal structures and lattice tunability have broad application prospects in lithium-ion batteries.</div></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"159 ","pages":"Pages 154-165"},"PeriodicalIF":6.3,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144739003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The path to carbon neutral shipping: A comparative analysis of low carbon technologies 碳中和航运之路:低碳技术的比较分析
IF 6.3 2区 环境科学与生态学
Journal of Environmental Sciences-china Pub Date : 2025-04-15 DOI: 10.1016/j.jes.2025.04.034
Zhengang Zhou , Zhicheng Wu , Chang Liu , Lingyu Shao , You Zhang , Weijie Liu , Haitao Shen , Dongwei Yao , Haidong Fan , Chenghang Zheng , Xiang Gao
{"title":"The path to carbon neutral shipping: A comparative analysis of low carbon technologies","authors":"Zhengang Zhou ,&nbsp;Zhicheng Wu ,&nbsp;Chang Liu ,&nbsp;Lingyu Shao ,&nbsp;You Zhang ,&nbsp;Weijie Liu ,&nbsp;Haitao Shen ,&nbsp;Dongwei Yao ,&nbsp;Haidong Fan ,&nbsp;Chenghang Zheng ,&nbsp;Xiang Gao","doi":"10.1016/j.jes.2025.04.034","DOIUrl":"10.1016/j.jes.2025.04.034","url":null,"abstract":"<div><div>Ship operations are crucial to global trade, and their decarbonization is essential to mitigate climate change. This study evaluates the economic viability of existing and emerging decarbonization technologies in maritime shipping using the levelized cost of energy methodology. It includes a detailed comparative analysis based on essential criteria and sensitivity assessments to highlight the economic impacts of technological advancements. Key factors influencing total costs include fuel costs, carbon pricing, and energy demands for carbon capture. The findings reveal that methanol is more cost-effective than heavy fuel oil (HFO) when priced below 3000 CNY/t, assuming HFO costs 4400 CNY/t. Additionally, methanol with post-combustion carbon capture is less expensive than pre-combustion carbon capture. When carbon prices rise above 480 CNY/t, carbon capture technologies prove more economical than purchasing carbon emission allowances for HFO and liquefied natural gas. Enhancing the use of exhaust gas waste heat is recommended for cost savings. Post-combustion carbon capture also shows greater efficiency, requiring about 1.1 GJ/t less energy than pre-combustion methods, leading to lower overall costs. Future research should focus on market mechanisms to stabilize fuel prices and develop less energy-intensive carbon capture technologies. This study offers critical insights into effective decarbonization strategies for advancing global maritime trade in the present and future.</div></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"159 ","pages":"Pages 606-616"},"PeriodicalIF":6.3,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144830782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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