Yosuke Matsuo, Kentaro Takahara, Hidemi Hatabayashi, H. Nakagawa
{"title":"Detection of N-(1-deoxy-D-fructos-1-yl) Fumonisin C1, C2 and C3 in Corn Powder by LC - Orbitrap MS","authors":"Yosuke Matsuo, Kentaro Takahara, Hidemi Hatabayashi, H. Nakagawa","doi":"10.4172/2161-0525.1000536","DOIUrl":"https://doi.org/10.4172/2161-0525.1000536","url":null,"abstract":"Detection of N-(1-deoxy-D-fructos-1-yl) fumonisin C1, C2 and C3 (NDfrc-FCs) in a reference material of corn powder were performed with LC-Orbitrap MS. The peaks of NDfrc-FCs were eluted 0.1 ~ 0.3 min earlier than those of fumonisin C1, C2 and C3 (FCs), from the C18 column, probably due to their hydrophilic structures having the carbohydrate residues. At negative ionization mode scan with LC-MS analysis, the fragment ions of the tricarballylic acid (TCA) and characteristic fumonisin ions lacking TCA were detected at the identical retention times with those of respective parent NDfrc-FCs. Mass fragmentation patterns of NDfrc-FCs were confirmed to be almost in consistent with those of FCs. This study is the first report of natural occurrence of NDfrc-FC1, FC2, and FC3 in corn powder.","PeriodicalId":15742,"journal":{"name":"Journal of Environmental and Analytical Toxicology","volume":"20 1","pages":"1-11"},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86268217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mohamed Ho, Al-Ansari Emas, Aliyu Aa, O. Yigiterhan, I. Al-maslamani
{"title":"Monitoring and Comparison of Methylmercury Bioaccumulation between Lightly and Heavily Contaminated Sites in the Arabian Gulf","authors":"Mohamed Ho, Al-Ansari Emas, Aliyu Aa, O. Yigiterhan, I. Al-maslamani","doi":"10.4172/2161-0525.1000593","DOIUrl":"https://doi.org/10.4172/2161-0525.1000593","url":null,"abstract":"","PeriodicalId":15742,"journal":{"name":"Journal of Environmental and Analytical Toxicology","volume":"99 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76463588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tadele Eticha, Hiyaw Getachew, G. Kahsay, H. Gebretsadik
{"title":"Metals Contamination in Face Powders and their Associated Health Risks to the Users in Mekelle, Ethiopia","authors":"Tadele Eticha, Hiyaw Getachew, G. Kahsay, H. Gebretsadik","doi":"10.4172/2161-0525.1000547","DOIUrl":"https://doi.org/10.4172/2161-0525.1000547","url":null,"abstract":"The presence of heavy metals has been reported in cosmetics and their assessment in these products is of significantly important to protect the users. The objective of this study was to assess the levels of cadmium, lead and zinc in face powders and provide information on the risk associated with human exposure to these heavy metals in the products. The samples were pretreated using dry ashing technique and analyzed by flame atomic absorption spectrophotometer. The level of lead in face powders was below the detection limit while the concentrations of cadmium and zinc ranged from 0.13 to 0.215 mg/kg and not detected to 7.05 mg/kg, respectively. The systemic exposure dosage values for these metals in the products were below their respective provisional tolerable daily intake and/or recommended daily intake values. The margin of safety values were higher than 100 which exhibited that the concentrations of metals observed in these products do not cause substantial health risk to the users.","PeriodicalId":15742,"journal":{"name":"Journal of Environmental and Analytical Toxicology","volume":"12 1","pages":"1-3"},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82632632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mechanisms and Influencing Factors of Electro-Kinetic Enhanced Phytoextraction for the Recovery of Metal-Polluted Soils","authors":"X. Mao, Xu Yang, Hengji Qin, X. Shao, Zhanyu Zhang, Jing Li","doi":"10.4172/2161-0525.1000586","DOIUrl":"https://doi.org/10.4172/2161-0525.1000586","url":null,"abstract":"Soil contamination with various toxic metals has become a serious global concerned issue due to the potential risks to the environmental ecology and human health. So far, numerous in-situ and ex-situ methods have been developed and electro-kinetic (EK) enhanced phytoremediation is widely accepted as a sustainable alternative for the decontamination. The integrated technique contains the application of a low intensity electric field adjoined to growing plants in contaminated soil. So far, many efforts have been made while there is a clear lack of this technology in both laboratorial and field applications. Limitations such as low phytoavailaibility of target metals, unsatisfactory metal's tolerance and translocation ability of plants and undesirable soil pH environment might the main reasons that responsible for the low remediation efficiency. In order to figure out the current focusing phenomena, the possible mechanisms of phytoextraction, EKR and EKR-enhanced phytoextraction were discussed, respectively. In addition, influencing factors such as metal speciation, plant selection and electro-kinetic parameters were also discussed. The contents summarized in the present paper are believed to be an useful guideline for further investigation and optimization of EK-enhanced phytoextraction.","PeriodicalId":15742,"journal":{"name":"Journal of Environmental and Analytical Toxicology","volume":"262 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79673231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Organic Chemical Concentrations in Eggs and Nestlings of Cavity Nesting Birds at and around Los Alamos National Laboratory","authors":"S. Gaukler, Charles D. Hathcock, J. Fair","doi":"10.4172/2161-0525.1000549","DOIUrl":"https://doi.org/10.4172/2161-0525.1000549","url":null,"abstract":"In 1943, Los Alamos National Laboratory (LANL) was established as part of the Manhattan project to design atomic weapons. LANL now operates as a multidisciplinary research institution. As part of an ongoing assessment of siterelated ecological risk, organochlorine pesticides, their metabolites, polycyclic aromatic hydrocarbons, polychlorinated biphenyls (PCBs), and 2,3,7,8-tetrachlorodibenzo-p-dioxin toxic equivalents (TEQs) were evaluated in western bluebird (Sialia mexicana) and ash-throated flycatcher (Myiarchus cinerascens) eggs relative to a developed but non-industrial reference area; PCBs and TEQs were also evaluated in nestlings. Chemicals were below detection limits in the majority of samples. Western bluebird eggs collected from the study area had significantly lower concentrations of dieldrin, oxychlordane, and trans-nonachlor when compared with eggs from the reference area. No differences were observed in concentrations of dichlorodiphenyldichloroethylene (DDE), dichlorodiphenyltrichloroethane (DDT), and heptachlor epoxide. Ash-throated flycatcher eggs contained higher total TEQ concentrations when compared with western bluebird eggs; however, no differences in concentrations of DDE, DDT, dieldrin, or total PCBs were observed. No differences were observed in total PCBs or TEQs in nestlings between the two species. Western bluebird eggs contained higher levels of total PCBs and TEQs when compared with nestlings; no differences were observed in total PCBs or TEQs between ash-throated flycatcher eggs and nestlings. Chemical concentrations detected in eggs of both species were below levels that are associated with adverse effects reported in the scientific literature, suggesting that concentrations of organic chemicals observed here appear to be at levels causing negligible risks to local bird populations.","PeriodicalId":15742,"journal":{"name":"Journal of Environmental and Analytical Toxicology","volume":"211 1","pages":"1-9"},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77488024","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Pollution from Small and Medium Size Enterprises: Less Understood and Neglected Sources in Nigerian Environment","authors":"Sridhar Mkc, Coker Ao, C. Achi","doi":"10.4172/2161-0525.1000558","DOIUrl":"https://doi.org/10.4172/2161-0525.1000558","url":null,"abstract":"Small and Medium Size Enterprises (SMEs) are encouraged by Nigerian Government to develop and sustain the economy and promote employment. They range from process industries, fabrication workshops, service centres, food and drink premises, and several others. A majority of these sprawled up in urban areas though they are also seen in peripheral and rural areas. These centres play significant role in the national economy. At the same time, they also produce a variety of end products and byproducts in solid, liquid or gaseous forms which affect the environment negatively by polluting air, water and soil. This has resulted in eutrophication of water bodies, contamination of groundwater, soil and affected quality of life in the cities. There are well laid out pollution control regulations and guidelines in the country. The Federal Ministry of Environment, The National Environmental Standards and Regulations Enforcement Agency (NESREA) with five Zonal offices implement these regulations. But in spite of these, SMEs sector which is mostly private driven escapes from being questioned on their poor environmental upkeep and disposal of untreated waste products. This paper has drawn examples from selected major urban areas in Nigeria and highlights some of the issues, challenges and possible mitigation measures to safeguard the fragile Nigerian environment.","PeriodicalId":15742,"journal":{"name":"Journal of Environmental and Analytical Toxicology","volume":"18 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77605970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effects of Tropospheric Ozone (O3) on Yield and Nutritional Quality of Mung Bean (Vigna radiata Cv. MN 98): Evidence from Pakistan","authors":"I. Jan","doi":"10.4172/2161-0525.1000567","DOIUrl":"https://doi.org/10.4172/2161-0525.1000567","url":null,"abstract":"The effects of ambient ozone concentrations on the yield and nutritional quality of Mung bean (MN-98) grown in Northern Pakistan was assessed using EDU. Passive samplers results revealed that ozone was significantly lower (24.2 ppb) in April compared to May, June (49 ppb). The mean pods number/plants, length/plant, and biomass of both fresh and dry weight of EDU and NEDU treated plants were all significantly not different. The mean biomass for EDU leaves was (4.0 g) and significantly reduced compared to NEDU (2.8 g). The mean root length and shoot biomass of EDU plants compared to NEDU treated plants remained unchanged. However, the total biomass of EDU plants were significantly higher (10.0 g) compared to NEDU (7.3 g). The overall plant biomass was 30% significantly higher than N-EDU plants. The nutritional quality parameters (Ash, Moisture, Fats, Fiber and Protein) reduced significantly in NEDU seeds compared to EDU. The %moisture contents of seeds was (F=0.017; p<0.05), %Ash (F=3.987; p<0.05), %Protein (F=3.467; p<0.05) %Fats (F=2.574; p<0.05), %Fiber content was positively affected by EDU treatment. It was concluded that ozone is directly affecting the growth and quality of summer crops grown in Pakistan that can affect the future food security of the region.","PeriodicalId":15742,"journal":{"name":"Journal of Environmental and Analytical Toxicology","volume":"12 1","pages":"1-5"},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74222088","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
P. Mulati, E. Kitur, C. Taracha, Justus Kurgat, S. Raina, J. Irungu
{"title":"Evaluation of Neonicotinoid Residues in Hive Products from Selected Counties in Kenya","authors":"P. Mulati, E. Kitur, C. Taracha, Justus Kurgat, S. Raina, J. Irungu","doi":"10.4172/2161-0525.1000577","DOIUrl":"https://doi.org/10.4172/2161-0525.1000577","url":null,"abstract":"","PeriodicalId":15742,"journal":{"name":"Journal of Environmental and Analytical Toxicology","volume":"4 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84619299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Quantification of Some Physico-Chemical Characteristics of Waste Water Effluent from Batu Tannery Industry at Different Batch, Addis Ababa, Ethiopia","authors":"Tadesu Hailu, Alemayehu Abebaw, Daniel Minilu","doi":"10.4172/2161-0525.1000592","DOIUrl":"https://doi.org/10.4172/2161-0525.1000592","url":null,"abstract":"","PeriodicalId":15742,"journal":{"name":"Journal of Environmental and Analytical Toxicology","volume":"141 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78552981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Glyphosate Substitution for Glycine During Protein Synthesis as a Causal Factor in Mesoamerican Nephropathy","authors":"S. Seneff, L. Orlando","doi":"10.4172/2161-0525.1000541","DOIUrl":"https://doi.org/10.4172/2161-0525.1000541","url":null,"abstract":"Mesoamerican Nephropathy (MeN), also known as Chronic Kidney Disease of unknown etiology (CKDu), is an unusual form of kidney disease affecting agricultural workers in Central America. Its prevalence is alarmingly high among young male sugarcane workers in Nicaragua and El Salvador. The absence of known etiologies for CKD, such as hypertension and diabetes, has led researchers to explore a number of potential risk factors, though none adequately explain the timing and epidemic nature of the disease. In this paper, we explore the idea that glyphosate, an herbicide routinely used on sugarcane, could play a significant causal role in MeN, mediated by its property as an analogue of the coding amino acid glycine. Glyphosate is a glycine molecule with a methyl phosphonyl group attached to its nitrogen atom. Its substitution in place of glycine could disrupt multiple proteins critical for kidney health. Here, we first present prior evidence from the research literature that glyphosate may be substituting erroneously for glycine. In particular, multiple species of both bacteria and plants have mutated to remove a highly conserved glycine residue in the enzyme in the shikimate pathway that is disrupted by glyphosate, and this mutation has caused the enzyme to be completely insensitive to glyphosate. We have identified multiple proteins with key roles related to kidney function, whose disruption by glyphosate substitution for critical glycine residues could explain most of the unique features of MeN. Specifically, glycine substitution in aquaporin, chloride channels, cytochrome C oxidase and collagen, among others, could contribute to dehydration, increased urinary acidification, renal fibrosis, rhabdomyolysis and mitochondrial dysfunction. While the hypothesis that glyphosate could be disrupting protein synthesis is not yet proven, it is remarkable how well it explains multiple features of MeN. Investigations to verify whether glyphosate is in fact disrupting protein synthesis are urgently needed.","PeriodicalId":15742,"journal":{"name":"Journal of Environmental and Analytical Toxicology","volume":"165 1","pages":"1-9"},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80425030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}