Journal of Cultural Heritage最新文献

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Fire-retardant and fire-resistant coatings: From industry to the potential use on cultural heritage 阻燃和防火涂料:从工业到文化遗产的潜在用途
IF 3.5 2区 综合性期刊
Journal of Cultural Heritage Pub Date : 2024-07-01 DOI: 10.1016/j.culher.2024.06.014
Inês Soares , Joana Lia Ferreira , Helena Silva , Maria Paula Rodrigues
{"title":"Fire-retardant and fire-resistant coatings: From industry to the potential use on cultural heritage","authors":"Inês Soares ,&nbsp;Joana Lia Ferreira ,&nbsp;Helena Silva ,&nbsp;Maria Paula Rodrigues","doi":"10.1016/j.culher.2024.06.014","DOIUrl":"https://doi.org/10.1016/j.culher.2024.06.014","url":null,"abstract":"<div><p>Fire is one of the most damaging deterioration agents in a short time of action. It can cause considerable damage, leading to the loss of lives and possessions. Concerning fire safety recommendations, buildings must be protected by an integrated system of passive and active measures. Two passive measures widely used in many industries are fire-retardant and fire-resistant coatings. These systems provide a fire-protective layer to the surfaces of flammable and non-flammable materials, delaying or preventing their ignition, reducing the heat transfer from the source to the substrate and decreasing the flame spread and the release of smoke and toxic gases. When exposed to fire, according to the different mechanisms of action, fire-protective coatings (FPC) can be classified as non-intumescent and intumescent. Despite being widely mentioned in heritage fire safety guidelines, studies on their application in the field are still scarce. Namely, research on the safety and efficacy of their application near collections (in support materials) and systematic studies comparing different formulations. Therefore, this research assembles interdisciplinary studies on the use of FPC to deepen knowledge and theoretically identify the feasibility of their application in collection support/storage materials or exhibition furniture (bookshelves, cabinets, plinths) in heritage environments.</p></div>","PeriodicalId":15480,"journal":{"name":"Journal of Cultural Heritage","volume":"68 ","pages":"Pages 316-327"},"PeriodicalIF":3.5,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1296207424001389/pdfft?md5=a75e85e09c89a1d229da79302fa68842&pid=1-s2.0-S1296207424001389-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141605472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced imaging to recover illegible text in historic documents. The challenge of past chemical treatments for ink enhancement 通过先进的成像技术恢复历史文献中难以辨认的文字。过去对油墨进行化学处理所面临的挑战
IF 3.5 2区 综合性期刊
Journal of Cultural Heritage Pub Date : 2024-07-01 DOI: 10.1016/j.culher.2024.06.013
Lucía Pereira Pardo , Paul Dryburgh , Elizabeth Biggs , Marc Vermeulen , Peter Crooks , Adam Gibson , Molly Fort , Constantina Vlachou-Mogire , Moira Bertasa , John R. Gilchrist , Jon Danskin
{"title":"Advanced imaging to recover illegible text in historic documents. The challenge of past chemical treatments for ink enhancement","authors":"Lucía Pereira Pardo ,&nbsp;Paul Dryburgh ,&nbsp;Elizabeth Biggs ,&nbsp;Marc Vermeulen ,&nbsp;Peter Crooks ,&nbsp;Adam Gibson ,&nbsp;Molly Fort ,&nbsp;Constantina Vlachou-Mogire ,&nbsp;Moira Bertasa ,&nbsp;John R. Gilchrist ,&nbsp;Jon Danskin","doi":"10.1016/j.culher.2024.06.013","DOIUrl":"10.1016/j.culher.2024.06.013","url":null,"abstract":"<div><p>From fires to floods, from invisible inks to redactions, information has been accidentally or intentionally obscured on countless documents, maps and photographs, in collections from archives, libraries, and museums across the world. Removed from catalogues and reading rooms and therefore inaccessible to researchers and the general public, what new knowledge would these obscured documents reveal if we were able to read them? This paper demonstrates that current imaging technologies can be used to unlock this lost content.</p><p>We used High Resolution Multiband Imaging (MBI), Reflectance Imaging Spectroscopy (RIS) and micro X Ray Fluorescence (µXRF) imaging to reveal illegible letter-forms and whole words written in iron gall ink on parchment from medieval documents relevant to the 'Virtual Record Treasury of Ireland' project, a digital reconstruction of archives destroyed in 1922 at the Public Record Office of Ireland at the outset of the Irish Civil War.</p><p>The readability of text in historic documents with faded iron gall ink and/or parchment obscured by damp stains and ingrained dirt was successfully enhanced with MBI techniques, such as UV-induced visible luminescence (UVL) and UV reflected (UVR) imaging, which were able to recover the contrast of the ink. However, visualising text in documents showing chemical damage caused by the application of reagents for ink enhancement in the 19<sup>th</sup> century (a practice known as “galling”) was more challenging because of the similar composition of the ink and the staining. RIS proved helpful to read documents with moderate to severe chemical damage, particularly after applying Principal Component Analysis (PCA). Text in documents that were severely damaged by galling was also recoverable with µXRF imaging of the distribution of iron from the ink. This also posed several challenges, such as minimising movement of the parchment during overnight scans and separating the data corresponding to iron on the front of the parchment which was combined with the signal from the back. Through subtraction of elemental maps during post-processing, we managed to tackle the latter issue. The combination of these different imaging techniques enabled palaeographers and medieval records specialists to identify individual characters and whole words, thereby recovering the meaning of texts that were previously indecipherable.</p><p>Further research will adapt the methodology to the broad range of causes of information loss, including other reagents historically used for ink enhancement, as well as the variety of document media and temporalities, which require an extensive and multi-faceted approach of advanced imaging and post-processing techniques, in balance with the preservation needs of these fragile and invaluable historic materials.</p></div>","PeriodicalId":15480,"journal":{"name":"Journal of Cultural Heritage","volume":"68 ","pages":"Pages 342-353"},"PeriodicalIF":3.5,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141630245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A study on the laser-induced phenomena of commercial dammar, ketone-based and poly(isobutyl methacrylate) resin artists’ varnishes upon Er:YAG laser irradiation 关于商用达玛、酮基和聚甲基丙烯酸异丁酯树脂艺术家清漆在 Er:YAG 激光照射下的激光诱导现象的研究
IF 3.5 2区 综合性期刊
Journal of Cultural Heritage Pub Date : 2024-07-01 DOI: 10.1016/j.culher.2024.06.012
Chiara Chillè , Charis Theodorakopoulos , Marianne Odlyha
{"title":"A study on the laser-induced phenomena of commercial dammar, ketone-based and poly(isobutyl methacrylate) resin artists’ varnishes upon Er:YAG laser irradiation","authors":"Chiara Chillè ,&nbsp;Charis Theodorakopoulos ,&nbsp;Marianne Odlyha","doi":"10.1016/j.culher.2024.06.012","DOIUrl":"10.1016/j.culher.2024.06.012","url":null,"abstract":"<div><p>This research aims to comprehensively analyse the interaction between a 2940 nm wavelength Er:YAG laser and several commercial varnishes commonly used in the mid-twentieth century. A selection of triterpenoid, poly(cyclohexanone), poly(cyclohexanol) and poly(isobutyl methacrylate) resins was chosen to make dammar, Ketone Resin N, MS2A and Paraloid B67 varnishes. Before creating varnish films, thermogravimetric analysis (TGA) was performed to determine the thermal stability of the resins as received from the manufacturer. The resins were measured at six different heating rates, and the kinetic activation energies (<em>E<sub>a</sub></em>) were calculated using the Flynn-Wall-Ozawa method. Also, differential scanning calorimetry (DSC) was performed to determine the resins' glass transition temperatures (<em>Tg</em>). After a 170.6 klux·h dose of radiation (λ&gt;310 nm) simulating daylight through window glass of approximately 53 museum years, the varnish films were irradiated with an Er:YAG laser. The laser was used in the Very Short Pulse (VSP ≃ 100 µs) and Short Pulse (SP ≃ 300 µs) modes. The 2940 nm laser beam with a 4 mm diameter was fired onto dry and prewetted varnishes using a working distance of 20 cm. Single laser pulses with fluences ranging between 0.5 and 2.7 J/cm<sup>2</sup> were used. A prewetting solution of 1 % v/v Tween®20 surfactant in deionised water was applied to the varnish films. Er:YAG transmission through the aged varnishes was monitored in real time and showed that the transmitted energy increased almost linearly with fluence, except for the Paraloid B67 films which did not interact with the laser. Chemical changes were monitored using Attenuated Total Reflectance/Fourier Transform Infrared (ATR/FT-IR) spectroscopy. A reduction in hydroxy groups and carbon-hydrogen bonding was observed as a function of fluence for dammar and Ketone N films, while no change was observed for the dry and prewetted MS2A films. FTIR was also employed to experimentally determine the absorption coefficient of the varnish films. Optical Microscopy and low-vacuum Scanning Electron Microscopy (SEM) in the Backscattered Electron (BSE) mode were used to compare the dry and prewet irradiated spot areas. These analyses revealed that laser spots were less noticeable on prewetted varnishes than on dry-irradiated films.</p></div>","PeriodicalId":15480,"journal":{"name":"Journal of Cultural Heritage","volume":"68 ","pages":"Pages 328-341"},"PeriodicalIF":3.5,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141622667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical simulation of the evolution of carbonation process in aerial lime mortar 气泡石灰砂浆碳化过程演变的数值模拟
IF 3.5 2区 综合性期刊
Journal of Cultural Heritage Pub Date : 2024-07-01 DOI: 10.1016/j.culher.2024.05.010
Mateus A. Oliveira , Anna Meneghini , Erika T. Guimarães , José Victor Brasil
{"title":"Numerical simulation of the evolution of carbonation process in aerial lime mortar","authors":"Mateus A. Oliveira ,&nbsp;Anna Meneghini ,&nbsp;Erika T. Guimarães ,&nbsp;José Victor Brasil","doi":"10.1016/j.culher.2024.05.010","DOIUrl":"https://doi.org/10.1016/j.culher.2024.05.010","url":null,"abstract":"<div><p>Aerial lime is one of the oldest binders discovered and used in mortars. In different regions of the world, there is a substantial number of historic masonry constructions comprising binders based on aerial lime. The carbonation process has essential relevance on the behaviour of this material. In this sense, an experimental program done by the research group is adopted to support the numerical simulation of the evolution of carbonation phenomenon. Initially, a strategy modelling presented in literature is adopted. In sequence, an iterative process is done to achieve the set of parameters to fit the experimental data using the results from cylinders tested at three different depths with thermogravimetric analysis at four different ages. With a new set of parameters and functions, the numerical model could reproduce reasonably the data from the thermogravimetric analysis. Then, the modelling strategy with the fitted parameters is used to study the evolution of the carbonation in five series of specimens with different sizes, tested with phenolphthalein indicator. Various values of equivalent reaction degree (<em>R</em>∼20% to <em>R</em>∼60%), in terms of numerical results, were obtained for the phenolphthalein test.</p></div>","PeriodicalId":15480,"journal":{"name":"Journal of Cultural Heritage","volume":"68 ","pages":"Pages 263-275"},"PeriodicalIF":3.5,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141480409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An intelligent epistemological tool for audiovisual analysis and mediation of video art archive 用于视听分析和视频艺术档案调解的智能认识论工具
IF 3.5 2区 综合性期刊
Journal of Cultural Heritage Pub Date : 2024-07-01 DOI: 10.1016/j.culher.2024.06.011
Jana Horakova , Pavel Sikora , Stepan Miklanek , Dusan Barok , Jiri Schimmel , Kamil Riha
{"title":"An intelligent epistemological tool for audiovisual analysis and mediation of video art archive","authors":"Jana Horakova ,&nbsp;Pavel Sikora ,&nbsp;Stepan Miklanek ,&nbsp;Dusan Barok ,&nbsp;Jiri Schimmel ,&nbsp;Kamil Riha","doi":"10.1016/j.culher.2024.06.011","DOIUrl":"https://doi.org/10.1016/j.culher.2024.06.011","url":null,"abstract":"<div><p>This article focuses on the development and application of intelligent software for image and sound recognition to perform iconographic and audiographic analyses of the work of video art pioneers Steina and Woody Vasulka (the Vasulkas). The AI epistemological tool <span>Vasulka Live Archive</span><svg><path></path></svg> is designed to provide unique results that benefit from the synthesis of automatic statistical analysis across the dataset and application of predefined categories that are the results of aesthetic evaluation of the Vasulkas’ videos and inspired by terminology of video art aesthetics (Weibel, Krauss). The advantages of this AI tool reveal themselves particularly when the tool is used for transmedia analysis of the whole dataset (the Vasulkas’ work) as the accuracy and completeness of its results are out of reach of an individual human researcher. We argue that this kind of AI tools can contribute to more exact and data-based findings on media art aesthetics, it can contribute to establishing a new field augmented iconology (Spratt) as well as expanding the sphere of AI tools application towards digital collections of experimental and conceptual art of 20th and 21st centuries.</p></div>","PeriodicalId":15480,"journal":{"name":"Journal of Cultural Heritage","volume":"68 ","pages":"Pages 298-306"},"PeriodicalIF":3.5,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141594617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Connecting palettes — An integrated spectroscopic analysis and UMAP visualisation of Wu Guanzhong's paint palette and his painting 连接调色板--吴冠中调色板及其绘画的综合光谱分析和 UMAP 可视化研究
IF 3.5 2区 综合性期刊
Journal of Cultural Heritage Pub Date : 2024-07-01 DOI: 10.1016/j.culher.2024.06.004
King Wai Chiu , Dickson Tik San Sin , May Chui In Long
{"title":"Connecting palettes — An integrated spectroscopic analysis and UMAP visualisation of Wu Guanzhong's paint palette and his painting","authors":"King Wai Chiu ,&nbsp;Dickson Tik San Sin ,&nbsp;May Chui In Long","doi":"10.1016/j.culher.2024.06.004","DOIUrl":"10.1016/j.culher.2024.06.004","url":null,"abstract":"<div><p>A paint palette of the 20th-century Chinese modern artist Wu Guanzhong (1919–2010) was studied with an integrated spectroscopic approach, macro-scale non-invasive techniques hyperspectral imaging (HSI) and macro X-ray fluorescence (MA-XRF), complemented with Raman spectroscopy. The palette is revealed to be comprised of synthetic inorganic and organic pigments, typical of the 20th century modern palette that is dominated by azo and phthalocyanine pigments. HSI datasets of the paint palette and those of Wu's oil painting ‘Xidi Village’ (2001) were then processed within one unsupervised Uniform Manifold Approximation and Projection (UMAP) model, in an attempt to identify connections between the artefact and the artwork, so that known pigment results of the palette may provide preliminary pigment assignment for the painting. This study describes the steps taken to establish this automated assisted pigment analysis workflow, which involves processing multiple HSI datasets within one UMAP model, density clustering, non-negative least square (NNLS) fitting to extract endmembers (EM) spectra and to generate distribution maps. The approach to perform micro-sampling pigment analysis on the artist's palette (or artist's materials) is considered less invasive to the integrity than that from artworks, the results of which have demonstrated to serve as a critical resource to support further pigment analysis studies of the artist's paintings via non-invasive analytical techniques.</p></div>","PeriodicalId":15480,"journal":{"name":"Journal of Cultural Heritage","volume":"68 ","pages":"Pages 354-363"},"PeriodicalIF":3.5,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141728702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating industrial heritage value using cloud theory and Dempster–Shafer theory 利用云理论和 Dempster-Shafer 理论评估工业遗产价值
IF 3.5 2区 综合性期刊
Journal of Cultural Heritage Pub Date : 2024-07-01 DOI: 10.1016/j.culher.2024.07.002
Qi Zhao , Fuying Liu , Wenqi Qiao
{"title":"Evaluating industrial heritage value using cloud theory and Dempster–Shafer theory","authors":"Qi Zhao ,&nbsp;Fuying Liu ,&nbsp;Wenqi Qiao","doi":"10.1016/j.culher.2024.07.002","DOIUrl":"10.1016/j.culher.2024.07.002","url":null,"abstract":"<div><p>This study proposes a systematic approach to evaluate the value of industrial heritage under conditions of uncertainty. This approach primarily incorporates cloud theory and Dempster–Shafer theory (D–S theory), allowing managers to predict the direction of heritage renovation. Moreover, through this method, corresponding renovation measures and management methods can be formulated based on value levels and probabilities. The normal cloud distribution in cloud theory is more associated with people's judgment of things, while the subordinate cloud is employed to describe the basic probability distribution of factors at different value levels. The D–S theory has considerable advantages in terms of integrating information from multiple sources. This study uses the Shenyang Aircraft Factory as a case study to demonstrate the applicability and effectiveness of both theories. The results demonstrate that the combination of these two models can integrate knowledge and data, and the results of the value assessment model are in good agreement with the actual situation. In addition, this study provides a useful tool for dealing with uncertainty, randomness, and fuzziness in decision-making, making it easier for managers to develop appropriate building renovation plans.</p></div>","PeriodicalId":15480,"journal":{"name":"Journal of Cultural Heritage","volume":"68 ","pages":"Pages 364-374"},"PeriodicalIF":3.5,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141847514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ours Elsevier 爱思唯尔熊
IF 3.5 2区 综合性期刊
Journal of Cultural Heritage Pub Date : 2024-07-01 DOI: 10.1016/S1296-2074(24)00166-3
{"title":"ours Elsevier","authors":"","doi":"10.1016/S1296-2074(24)00166-3","DOIUrl":"10.1016/S1296-2074(24)00166-3","url":null,"abstract":"","PeriodicalId":15480,"journal":{"name":"Journal of Cultural Heritage","volume":"68 ","pages":"Page iv"},"PeriodicalIF":3.5,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1296207424001663/pdfft?md5=bb949ea0bb70e5a6b96b3cb00a22aae0&pid=1-s2.0-S1296207424001663-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142021299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
What kind of corrosion products are “black spots”? —Effects of reduced sulfur compounds on corrosion of bronze artefacts 什么样的腐蚀产物是 "黑斑"?-还原硫化合物对青铜器腐蚀的影响
IF 3.5 2区 综合性期刊
Journal of Cultural Heritage Pub Date : 2024-07-01 DOI: 10.1016/j.culher.2024.06.010
Akinobu Yanagida , Soichiro Wakiya , Rika Kigawa , Yoshinori Sato , Satoshi Shiga , Yoshihide Koizumi , Tadashi Uchino , Yumi Yasuki , Yohsei Kohdzuma
{"title":"What kind of corrosion products are “black spots”? —Effects of reduced sulfur compounds on corrosion of bronze artefacts","authors":"Akinobu Yanagida ,&nbsp;Soichiro Wakiya ,&nbsp;Rika Kigawa ,&nbsp;Yoshinori Sato ,&nbsp;Satoshi Shiga ,&nbsp;Yoshihide Koizumi ,&nbsp;Tadashi Uchino ,&nbsp;Yumi Yasuki ,&nbsp;Yohsei Kohdzuma","doi":"10.1016/j.culher.2024.06.010","DOIUrl":"https://doi.org/10.1016/j.culher.2024.06.010","url":null,"abstract":"<div><p>While deterioration due to the generation of “black spots” is reported, consensus on the specific corrosion products comprising black spots and underlying deterioration mechanisms is lacking. This study investigated the deterioration of copper objects by analysing the black spots that appeared on them and proposes environmental conditions to suppress the appearance of black spots. Bronze artefacts excavated from a marine archaeological site, on which black spots were generated, were closely observed, and investigated. First, X-ray fluorescence and micro-X-ray diffraction analyses were performed on a bronze artefact, from which the black spots were removed, to determine the composition of the artefact. Second, to investigate the composition of the black spots, fine structure analysis of the black spots on the fine fragments of the bronze artefacts was conducted using scanning and transmission electron microscopy, energy dispersive X-ray spectroscopy, and electron diffraction (ED) analysis. The results indicate that the black spots were partially composed of metallic copper and a fine particle mixture of Cu<sub>2</sub>S and CuSO<sub>4</sub>. These results imply that the transformation of copper sulfide to metallic copper may have played an important role in the initiation and propagation of black spots. In this study, ED analysis was performed on the microscopic area of the black spots; no amorphous phases were detected, and all observed phases were identified as crystalline materials. To determine the sources of gas-phase sulfur compounds that cause black spots, H<sub>2</sub>S and carbonyl sulfide (COS) emissions from a spherical clay artefact (a cannon ball with gunpowder excavated from an underwater archaeological site) which was exhibited in the same showcase with the bronze artefacts were analysed via gas chromatography. The concentrations of H<sub>2</sub>S and COS were 0.462 and 8.636 ppb, respectively; these are significantly higher than those in the lower troposphere. These results indicate that deterioration by black spots occurred because of H<sub>2</sub>S and COS, which were emitted from the spherical clay artefact excavated from an underwater archaeological site in the exhibition case. In addition, it was confirmed that the inclusion of deoxygenating and dehumidifying agents (RP-AN) in the plastic bag in which the spherical clay artefact was inserted resulted in a significant decrease in the concentration of H<sub>2</sub>S and COS.</p></div>","PeriodicalId":15480,"journal":{"name":"Journal of Cultural Heritage","volume":"68 ","pages":"Pages 307-315"},"PeriodicalIF":3.5,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1296207424001341/pdfft?md5=1a23d5c8752d932bda91c80692211e16&pid=1-s2.0-S1296207424001341-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141594619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design & study of cost-effective conservation of watercolor paper 水彩纸成本效益保护设计与研究
IF 3.1 2区 综合性期刊
Journal of Cultural Heritage Pub Date : 2024-06-18 DOI: 10.1016/j.culher.2024.06.005
Woon Lam Ng, Huanlong Hu, Zeyan Zhuang
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