Journal of Chemical Natural Resources最新文献

{"title":"Utilization of Used Polystyrene As Adhesive In Polymer Emulsion Asphalt","authors":"B. Wirjosentono","doi":"10.32734/jcnar.v3i2.9343","DOIUrl":"https://doi.org/10.32734/jcnar.v3i2.9343","url":null,"abstract":"The utilization of used polystyrene as adhesive material for emulsion polymer asphalt has been carried out. Polystyrene foam was dissolved in toluene at the ratio of 30:70 mL, then the solution was mixed with aquadest at ratios of 90: 10 mL, 70: 30 mL, 50: 50 mL, 30:70 mL, and 10: 90 mL. Then added with 10 mL of Sodium Dodecyl Sulfate solution at concentrations of 10%, 20%, and 30%. The most stable latex polystyrene was mixed with 200 g of sand aggregate at volume ratios of 10 mL, 20 mL, 30 mL, 40 mL, and 50 mL. Then the mixture was pressed into a hotpress at 150ºC for 20 minutes. The mixture obtained was characterized using tensile strength testing, water absorption, and SEM spectroscopy. The results showed that the mixture of sand aggregate with 50 mL latex polystyrene has the best compressive strength and water absorption, at a load of 1606 Kg.f, a stroke of 14.93 mm/minutes, and a water absorption percentage of 18%. The morphology result showed that the surface of sand aggregate with 50 mL of latex polystyrene mixture contains smaller and least holes than the surface of sand aggregate with 10 mL of latex polystyrene mixture.","PeriodicalId":15309,"journal":{"name":"Journal of Chemical Natural Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79382058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Study on Analysis of Vitamin C and β-Carotene Levels From Tamarillo (Solanum betaceaum Cav.) Fruit Produced Between Shoot Grafting of Tamarillo with Lancing Plant (Solanum mauritianum)","authors":"E. Zaidar","doi":"10.32734/jcnar.v3i2.9342","DOIUrl":"https://doi.org/10.32734/jcnar.v3i2.9342","url":null,"abstract":"Research on studies analysis levels of vitamin C and β-carotene of the Tamarillo fruit shoot grafting between the Tamarillo plant and Lancing plant has been conducted. Analysis of vitamin C level was performed by iodometric method, and analysis of β- carotene levels were calculated using UV-Vis spectrophotometer. The research result showed that the level of vitamin C of Tamarillo fruit was 1.596%, the level of vitamin C of Lancing fruit was 0.401%, and the level of vitamin C of Tamarillo fruit grafting outcomes was 1.202%. While the level of β-carotene of Tamarillo fruit was 208.95 ppm, the level of β-carotene of Lancing fruit was 36.11 ppm and the level of - carotene of Tamarillo fruit grafting outcomes was 253.64 ppm. It can be concluded that the vitamin C levels of Tamarillo fruit grafting outcomes decreased slightly. While the β-carotene levels of Tamarillo fruit grafting outcomes increased.","PeriodicalId":15309,"journal":{"name":"Journal of Chemical Natural Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74824030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Determination of Level of Ag, Cu, and Fe in the Mineral Rock Coming from Jambu Dolok Hamlet Toba Samosir District.","authors":"S. Alva","doi":"10.32734/jcnar.v3i2.9349","DOIUrl":"https://doi.org/10.32734/jcnar.v3i2.9349","url":null,"abstract":"A study on the determination of Ag, Cu, and Fe contents in mineral rocks has been conducted. The sample was randomly taken from the surface of the hill at Dusun Jambu Dolok Kabupaten Toba Samosir. Ovens destroyed the sample at 900°C. For the determination of Ag and Cu, the sample was dissolved by using concentrated HNO3. For the determination of Fe, it was dissolved by using concentrated HNO3 and concentrated HCl. The determination of Ag, Cu, and Fe was carried out using Atomic Absorption Spectrophotometer. The wavelength is 328.1 nm for Ag, 324.7 nm for Cu, and 248.3 nm for Fe. The results obtained show that the content of Ag, Cu, and Fe in the sample are 2.1590 mg/Kg, 21,311.4754 mg/Kg, and 150,000.0000 mg/Kg, respectively.","PeriodicalId":15309,"journal":{"name":"Journal of Chemical Natural Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87177682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Isolation of Flavonoid Compounds from Salam (Syzygium polyantha Wight) Leaves","authors":"A. Pasaribu","doi":"10.32734/jcnar.v3i2.9345","DOIUrl":"https://doi.org/10.32734/jcnar.v3i2.9345","url":null,"abstract":"Isolation of flavonoid compounds from Salam (Syzygium polyantha Wight) leaves has been done by maceration technique with methanol solvent. Methanol extract obtained was evaporated and dissolved with ethyl acetate. The solution was then concentrated and evaporated. The ethyl acetate fraction was dissolved with methanol and partitioned with n-hexane solvent. The methanol layer was evaporated and then tested with Benedict’s reagent and then acidified with HCl 6% while heated. It was then extracted partition with chloroform. The chloroform layer was separated using Column Chromatography with silica gel as the stationary phase and n-hexane: ethyl acetate 90:10, 80:20, 70:30, and 60:40 v/v, respectively as the mobile phase. The pure compound was paste, brownish red, mass = 8.5 mg, and Rf=0.60. It was a positive reaction with flavonoid compound reagents. The compound was further identified by using UV-Visible, FT-IR, and 1H-NMR spectroscopy. Spectroscopy data obtained indicated that the compound is a flavonoid.","PeriodicalId":15309,"journal":{"name":"Journal of Chemical Natural Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85738766","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Determination of Potassium in Empty Bunches Palm Oil (Elaeis guineensis Jacq.) Using Flame Photometry Method","authors":"S. Alva","doi":"10.32734/jcnar.v3i2.9348","DOIUrl":"https://doi.org/10.32734/jcnar.v3i2.9348","url":null,"abstract":"Research on the determination of potassium in empty bunches palm oil have been done with the flame photometry method. The samples were taken randomly from five areas in Northen Sumatera with various heights in the range of < 25- 400 m above sea level. The first sampling was of Datuk Bandar district at Tanjung Balai < 25 m, Meranti district at Kisaran 50 to 100 m, Bosar Maligas district at Simalungun 150-200 m, Simarimbun district at Pematang Siantar 250 to 300 m, and the last Sari Matondang district at Sidamanik 350-400 m. The sample was digested using concentrated nitric aid and 30% hydrogen peroxide then heated with the addition of nitric acid concentrated. Potassium content was measured with a flame photometer at specific 767.5 nm by using calibration methods. The result obtained that potassium contents in the samples were 11.83%; 17.56%; 21.89%; 24.68%, and 25.14% for Tanjung Balai, Kisaran, Simalungun, Pematang Siantar, and Sidamanik respectively. The data obtained showed the higher area of the sea, the lower the temperature so the content of potassium increased in the palm oil empty bunches.","PeriodicalId":15309,"journal":{"name":"Journal of Chemical Natural Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78641438","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of Cationic Surfactant N, N-(2-Laurate-Ethyl) Stearamidium Chloride","authors":"I. Nainggolan, A. Sembiring","doi":"10.32734/jcnar.v3i2.9362","DOIUrl":"https://doi.org/10.32734/jcnar.v3i2.9362","url":null,"abstract":"The cationic surfactant of N, N-(2-Lauric-Ethyl) Stearamidium Chloride had been successfully synthesized. It is long-chain alkyl surfactant derivative from ammonium salt with amide. Cationic surfactants that are synthesized from fatty acid derivatives are stearic acid and lauric acid. Stearic acid is used as stearamide-making material which is the product of methyl stearate amidation with diethanolamine use methoxide sodium catalyst. Lauric acid was used as esterification material with stearamide thus obtaining N, N-(2-Lauric-Ethyl) Stearamide of alcanolamide ester. Alcanolamide ester continued by salting reaction use HCl gas until obtained cationic surfactant of N, N-(2-Lauric-Ethyl) Stearimidium Chloride. Each compound analyzed function groups by FT-IR spectrophotometric with the analyzed change of melting points, and a part compound analyzed surface tension characteristic with measuring Critical Micelle Concentration (CMC) with use Du Nouy ring method. The analysis product obtained shows that methyl stearate by yield in the amount of 91.66% shows that melting point of 40.5°C, stearamide with yield in the amount of 87.6% show that melting point as 185°C by CMC value 0.133 mol/ L in 40.7 dyne/cm surface tension. Alcanolamide ester with a yield in the amount of 84.7% has a melting point of 55°C by a CMC value of 0.067 mol/L in 36.1 dyne/cm surface tension, and cationic surfactant has a melting point of 45°C by CMC value 0.055 mol/L in 31,1 dyne/cm surface tension. stearamide with a yield in the amount of 87.6% show that melting point of 185°C by a CMC value of 0.133 mol/L in 40.7 dyne/cm surface tension. Alcanolamide ester with a yield in the amount of 84.7% has a melting point of 55°C by a CMC value of 0.067 mol/L in 36.1 dyne/cm surface tension, and cationic surfactant has melting point as 45°C by CMC value 0.055 mol/L in 31,1 dyne/cm surface tension. stearamide with a yield in the amount of 87.6% show that melting point of 185°C by a CMC value of 0.133 mol/L in 40.7 dyne/cm surface tension. Alcanolamide ester with a yield in the amount of 84.7% has a melting point of 55°C by a CMC value of 0.067 mol/L in 36.1 dyne/cm surface tension, and cationic surfactant has a melting point of 45°C by CMC value 0.055 mol/L in 31,1 dyne/cm surface tension.","PeriodicalId":15309,"journal":{"name":"Journal of Chemical Natural Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82570774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fabrication of Biodegraded Composite from Polypropylene, Polypropylene Grafted Maleic Anhydride, and Chempedak Seed (Artocarpus integer) Starch","authors":"D. Nasution","doi":"10.32734/jcnar.v3i2.9344","DOIUrl":"https://doi.org/10.32734/jcnar.v3i2.9344","url":null,"abstract":"Fabrication of biodegraded composite from polypropylene, polypropylene grafted maleic anhydride, and chempedak seed (Artocarpus integer) starch has been conducted. The stages were prepared starch of Cempedak seed, grafting process of maleic anhydride on polypropylene, and fabrication of composite with a composition ratio of PP: PP-g-MA: starch of chempedak seed (9.5:0.5:0.1)g, (9.5:0.5:0.2)g, (9.5:0.5:0.3)g, (9.5:0.5:0.4)g, (9.5:0.5:0.5) g, and PP: starch of chempedak seed (10:2)g. The composites obtained were characterized using tensile strength and elongation testing, surface morphology analysis by SEM, analysis in nature with the ability to decompose by biodegradable test, and functional groups analysis by FTIR spectroscopy. The results showed that the biodegradable composites have the best properties in the ratio of PP: PP-g-MA: starch of chempedak seed (9.5:0.5:0.1)g with the test results of tensile strength was 28.743 N/m2, and also the SEM results show that flat surface and improved homogeneity, and strong group interactions as well as having good biodegradable properties.","PeriodicalId":15309,"journal":{"name":"Journal of Chemical Natural Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85095250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fabrication and Characterization of Glucosamine Hydrochloride from Chitin of Horseshoe Crab Shell (Tachypleus gigas)","authors":"Aurora Khairani Nasution","doi":"10.32734/jcnar.v3i2.9350","DOIUrl":"https://doi.org/10.32734/jcnar.v3i2.9350","url":null,"abstract":"Preparation of glucosamine hydrochloride from the chitin of horseshoe crab shells using the chemical hydrolysis method has been done using HCl concentration variation ratios of 7%, 9%, 11%,14 % with a ratio of 9:1 (v/w) for 4 hours at a temperature of 90ºC. Determination of glucosamine hydrochloride characteristics was characterized using Fourier transform-infra red (FT-IR) spectroscopy, in which the characteristics of glucosamine hydrochloride obtained in the OH group of glucosamine hydrochloride were 3446 cm-1 (s), 3448 cm-1 (s), 3450 cm-1 (s), 3448 cm-1 (s), respectively. For NH group of glucosamine hydrochloride were 1557 cm-1 (s), 1559 cm-1 (s), 1556 cm-1 (s), 1560 cm-1 (s), respectively. For CN group of glucosamine hydrochloride were 1379 cm-1 (m), 1379 cm-1 (m), 1379 cm-1 (m), 1379 cm-1 (m), respectively. While the glycoside bond of glucosamine hydrochloride 1073 cm-1 (w), 1074 cm-1 (w), 1074 cm-1 (w), 1074 cm-1 (w), respectively. Determination of the concentration of glucosamine hydrochloride with Ultraviolet Spectrophotometer analysis at a maximum wavelength of 197 nm with a standard solution of N-acetyl glucosamine in a solution of phosphate acid 0.005%, in which obtained the concentration of glucosamine hydrochloride 7% = 33.67 ppm, 9% = 36.35 ppm, 11% = 40.16 ppm, 14% = 43.97 ppm.","PeriodicalId":15309,"journal":{"name":"Journal of Chemical Natural Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84038103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Analysis of Potassium Ion (K+), Sodium Ion (Na+), and Proteins from Coconut Water Variety of Coconut and Hybrid Coconut","authors":"S. Alva","doi":"10.32734/jcnar.v3i1.9340","DOIUrl":"https://doi.org/10.32734/jcnar.v3i1.9340","url":null,"abstract":"Analysis of potassium ion (K+), sodium ion (Na+), and proteins of Dalam coconut varieties water and Hybrid coconut varieties water have been done. The sample is green coconut which was taken simple random from Deli Tua Barat village in the regency of Deli Tua. Analysis of potassium ion (K+) and sodium ion (Na+) was determined by Atomic Absorption Spectrophotometry method (AAS) and analysis of protein was determined by the Kjeldahl method. From the result analysis of Dalam coconut varieties water contain amount potassium ion 321.60 mg/100 mL + 0,77 mg/100 mL, sodium ion 33.17 mg/100 mL + 1.85 mg/100 mL, and protein 0,18 % + 0.05 %. Whereas Hybrid coconut varieties water contain amount potassium ion 278.67 mg/100 mL + 1.53 mg/100 mL, sodium ion 31.33 mg/100 mL + 0.83 mg/100 mL, and protein 0.48 % + 0.3 %.","PeriodicalId":15309,"journal":{"name":"Journal of Chemical Natural Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91539856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Analysis of Copper (Cu), Chromium (Cr), and Manganese (Mn) Levels from Liquid Waste of The Steel Industry with Atomic Absorption Spectrophotometry (AAS) Method","authors":"Syarifah Aini, Z. Alfian, H. Agusnar","doi":"10.32734/jcnar.v3i1.9338","DOIUrl":"https://doi.org/10.32734/jcnar.v3i1.9338","url":null,"abstract":"Liquid waste from the steel industry processing, washing machine, and kitchenware foundry contained the elements of copper (Cu), chromium (Cr), and manganese (Mn). The effluent samples were destructed using concentrated HNO3. Then determined the concentration of the elements copper (Cu), chromium (Cr), and manganese (Mn) using an Atomic Absorption Spectrophotometer with a calibration curve. The results obtained for the level of copper (Cu) on the sample inlet was 0.9714 mg/L to 0.9719 mg/L, and the sample outlet was 3.9990 mg/L to 4.0002 mg/L. Levels of the element chromium (Cr) on sample inlet was 0.0295 mg/L to 0.0297 mg/L, the sample outlet was 0.0399 mg/L to 0.0400 mg/L. Meanwhile, the level of manganese (Mn) in the sample inlet was 0.1269 mg/L to 0.1271 mg/L in a sample outlet was 2.9699 mg/L to 2.9701 mg/L. Then the steel industry wastewater for elemental copper (Cu) and manganese (Mn) exceeded the limits that have been instituted by the Minister of Environment Decree No. 51, 1995, regarding the Liquid Waste Quality Standard for Industrial Activity.","PeriodicalId":15309,"journal":{"name":"Journal of Chemical Natural Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91189967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}