ChemSusChem最新文献_第2页

Amino-Sulfonated Graphene as a Catalyst for Efficient Production of Biodiesel from Fatty Acids and Crude Vegetable Oils. 氨基磺化石墨烯催化脂肪酸和粗植物油高效生产生物柴油。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-04-08 DOI: 10.1002/cssc.202402488

Aby Cheruvathoor Poulose, Hugo Bares, Dagmar Zaoralová, Ivan Dědek, Michal Otyepka, Aristides Bakandritsos, Radek Zboril

{"title":"Amino-Sulfonated Graphene as a Catalyst for Efficient Production of Biodiesel from Fatty Acids and Crude Vegetable Oils.","authors":"Aby Cheruvathoor Poulose, Hugo Bares, Dagmar Zaoralová, Ivan Dědek, Michal Otyepka, Aristides Bakandritsos, Radek Zboril","doi":"10.1002/cssc.202402488","DOIUrl":"https://doi.org/10.1002/cssc.202402488","url":null,"abstract":"Climate change and the depletion of fossil fuels increase the demand for sustainable energy. Biodiesel, synthesized with heterogeneous acid catalysts, is a promising chemical carrier of clean energy, adhering to circular carbon economy . Here, we report the particularly effective synthesis of biodiesel using a reusable, solid-state acid graphene catalyst functionalized with a natural aminosulfonic acid. Experimental and theoretical studies unveil the key role of the functionalities containing simultaneously an amino and sulfonate group, ascribing superior acidity. Excellent activity and selectivity for oleic acid conversion to oleic acid methyl esters (a sustainable biofuel) were obtained, offering a strategy for achieving improved catalytic performance compared to earlier or benchmark catalysts in the field. Notably, the catalyst is also highly effective in converting commonly available vegetable oils to biodiesel through trans-esterification, and in carbohydrate dehydration to value-added chemicals, demonstrating its general applicability. Two more variants of aminosulfonic acid‑functionalized graphenes demonstrated very similar activities, validating the key role of such functionalities on the high acidity and activity. The development of such potent, recyclable catalysts is crucial since acid catalysis is arguably the most general and versatile approach for organic reactions, ubiquitous in an extraordinary range of biological and synthetic transformations.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e202402488"},"PeriodicalIF":7.5,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Solvent-Swing CO2 Capture with Aralkylamines. 溶剂振荡CO2捕集与芳烷基胺。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-04-08 DOI: 10.1002/cssc.202500112

Ryo Murakami, Hiroto Tanishima, Risa Otsuka, Ayaka Uchida, Narumi Iwamoto, Fuyuhiko Inagaki

引用次数: 0

Efficient One-Step Synthesis of Lactide with High Yield and Selectivity Using Brønsted Acid Catalysis. Brønsted酸催化一步高效合成高产选择性丙交酯。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-04-08 DOI: 10.1002/cssc.202500100

Yingjie Zhao, Wenqi Qiu, Yukang Liu, Yufei Zhang, Xiaotao Wang, Yuman Guo, Hui Liu, Canbin Ouyang, Zongxia Guo

引用次数: 0

Electrostatic Self-Assembly of NiTiO3 on Carbon Nitride as a Photocatalyst for Visible-Light-Driven Overall Water Splitting. 氮化碳上NiTiO3静电自组装作为可见光驱动整体水分解光催化剂。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-04-07 DOI: 10.1002/cssc.202500338

Long Wang, Haihua Wu, Yifan Lin, Mingyue Wang, Zilong Wang, Wandong Xing, Sibo Wang, Yuanxing Fang

{"title":"Electrostatic Self-Assembly of NiTiO3 on Carbon Nitride as a Photocatalyst for Visible-Light-Driven Overall Water Splitting.","authors":"Long Wang, Haihua Wu, Yifan Lin, Mingyue Wang, Zilong Wang, Wandong Xing, Sibo Wang, Yuanxing Fang","doi":"10.1002/cssc.202500338","DOIUrl":"https://doi.org/10.1002/cssc.202500338","url":null,"abstract":"Achieving intimate contact is crucial for the efficiency of a photocatalyst that includes both reduction and oxidation compartments, as it directly influences charge carrier transfer between them. However, traditional metal oxide-based photocatalysts often face intrinsic limitations in integrating these two functional components due to the difficulty in adjusting their surfaces. Herein, protonated polymeric carbon nitride nanosheets (CNNS) with controlled electrostatic property was integrated with NiTiO3 (NTO). Among them, CNNS functions as the hydrogen evolution photocatalyst (HEP), and NTO nanoparticles served as the oxygen evolution photocatalyst (OEP), resulting in a photocatalytic system for OWS. The system exhibits H₂ and O₂ evolution rates of 35.6 and 17.7 μmol·h⁻¹, respectively, and the corresponding apparent quantum yield is 2.7% at an incident wavelength of 365 nm, outperforming those of individual photocatalysts. This study introduces an applicable electrostatic self-assembly strategy for using carbon nitride to construct redox-mediator-free heterojunctions, thereby advancing applications in various fields, particularly the hydrogen evolution reaction via photocatalytic OWS.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e202500338"},"PeriodicalIF":7.5,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143794107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

All Electrochemical Synthesis of Performic Acid Starting from CO2, O2 and H2O. 从CO2， O2和H2O开始的所有电化学合成甲酸。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-04-07 DOI: 10.1002/cssc.202500180

Ida Dinges, Markus Pyschik, Julian Schütz, Selina Schneider, Elias Klemm, Siegfried R Waldvogel, Markus Stöckl

{"title":"All Electrochemical Synthesis of Performic Acid Starting from CO2, O2 and H2O.","authors":"Ida Dinges, Markus Pyschik, Julian Schütz, Selina Schneider, Elias Klemm, Siegfried R Waldvogel, Markus Stöckl","doi":"10.1002/cssc.202500180","DOIUrl":"https://doi.org/10.1002/cssc.202500180","url":null,"abstract":"Driven by anthropogenic climate change, innovative approaches to defossilise the chemical industry are required. With this study, the first all-electrochemical feasibility study for the complete electrosynthesis of the strong oxidiser and effective disinfectant performic acid is presented. Its synthesis was achieved solely from CO2, O2 and H2O in a two-step process. Initially, CO2 is electrochemically reduced to formate employing Bi2O3 based gas diffusion electrodes in a phosphate buffered electrolyte. Thereby, high formate concentration (500.7 ± 0.6 mmol L-1) and high Faradaic efficiency (86.3 ± 0.3%) were achieved at technically relevant current density (150 mA cm-2). Subsequently, the formate acts as (storable) feed electrolyte for the second electrolysis step. Employing carbon based gas diffusion electrodes, O2 is reduced to H2O2 and performic acid is directly formed in-situ. As before, high H2O2 concentration (1.27 ± 0.06 mol L-1) and high Faradaic efficiency (85.3 ± 5.4%) were achieved. Furthermore, performic acid concentration suitable for disinfection was obtained (82 ± 11 mmol L-1). In summary, this innovative feasibility study highlights the potential of combining electrochemical CO2 reduction with H2O2 electrosynthesis, which could provide sustainable access to performic acid in the future.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e202500180"},"PeriodicalIF":7.5,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143794273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Phosphorus-Modified High-Entropy Layered Double Hydroxide for Enhanced Electrocatalytic Oxygen Evolution via d-Band Center Modulation. 磷修饰的高熵层状双氢氧化物通过d波段中心调制增强电催化析氧。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-04-07 DOI: 10.1002/cssc.202500350

Xingjie Cheng, Hong Li, Jinchen Fan, Weiju Hao, Qingyuan Bi, Guisheng Li

{"title":"Phosphorus-Modified High-Entropy Layered Double Hydroxide for Enhanced Electrocatalytic Oxygen Evolution via d-Band Center Modulation.","authors":"Xingjie Cheng, Hong Li, Jinchen Fan, Weiju Hao, Qingyuan Bi, Guisheng Li","doi":"10.1002/cssc.202500350","DOIUrl":"https://doi.org/10.1002/cssc.202500350","url":null,"abstract":"Developing cost-effective, high-performance electrocatalysts for the oxygen evolution reaction (OER) is crucial but challenging. High-entropy layered double hydroxides (HE-LDHs) show promise due to their multi-metal synergy and structural complexity, yet their OER performance is limited by electronic and surface properties. This study combines theoretical and experimental methods to enhance OER by incorporating phosphorus (P) atoms in HE-LDHs, optimizing oxygen intermediate adsorption, and boosting OER activity and stability. A P-modified FeNiCoCuZn LDH catalyst (P-FeNiCoCuZn LDH) was synthesized via hydrothermal and low-temperature phosphatization processes, featuring phosphate anion intercalation and surface metal phosphides. The phosphate anions improve conductivity and stability, while surface P atoms adjust the electronic structure of metal sites, particularly Ni and Fe, reducing the energy barrier for the rate-determining step (*O→*OOH). The P-FeNiCoCuZn LDH achieves a low overpotential of 290 mV at 100 mA cm-2 and maintains stability for 100 hours in 1 M KOH. In-situ Raman spectroscopy shows the formation of highly active Ni(Fe)-OOH species during OER. This work offers a novel strategy for designing efficient water-splitting catalysts through in-situ heteroatom modification, advancing high-entropy materials in electrocatalysis.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e202500350"},"PeriodicalIF":7.5,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143794175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Direct Carbonate Reduction on Sn Oxide Surface. 氧化锡表面碳酸盐直接还原。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-04-07 DOI: 10.1002/cssc.202500364

Jun Wang, Lijuan Chen, Lan Huang, Tengfei Chen, Juqin Zeng, Wenbo Ju

引用次数: 0

Coupling Agents in Lithium Batteries: Impact on Enhancing Interfacial Bonding and Stability. 锂电池中的偶联剂：对增强界面结合和稳定性的影响。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-04-07 DOI: 10.1002/cssc.202500347

Wen Yan, Chi Wang, Xiaoyue Li, Ying Jiang

{"title":"Coupling Agents in Lithium Batteries: Impact on Enhancing Interfacial Bonding and Stability.","authors":"Wen Yan, Chi Wang, Xiaoyue Li, Ying Jiang","doi":"10.1002/cssc.202500347","DOIUrl":"https://doi.org/10.1002/cssc.202500347","url":null,"abstract":"Lithium-ion and lithium metal batterie are the cornerstone of modern energy storage but face significant challenges related to interfacial stability, including solid-electrolyte interphase (SEI) formation, lithium dendrite growth, and electrode degradation. Coupling agents offer a promising solution to address these issues by enhancing interfacial bonding, improving compatibility, and reducing resistance. This review provides a comprehensive overview of the role of coupling agents in optimizing battery interfaces, focusing on their functions as adhesion promoters, protective surface layers, and precursors for electrode material synthesis. We also discuss their applications in composite solid electrolytes, gel polymer electrolytes, and protective coatings for metallic lithium anodes and current collectors. The impacts of coupling agents on interfacial bonding and stability, as well as the interaction mechanisms, are examined at the molecular level. By highlighting recent advancements and challenges, this review aims to guide future research in interfacial engineering for high-performance composite materials and optimized interfaces in batteries.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e202500347"},"PeriodicalIF":7.5,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Garnets Initiate Grafting of Methyl Methacrylate Brushes onto Fluoropolymers for Electrochemically Stable and Fast-Ion-Conducting Composite Solid-State Electrolytes. 石榴石引发甲基丙烯酸甲酯刷接枝到含氟聚合物上制备电化学稳定和快速离子导电的复合固态电解质。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-04-07 DOI: 10.1002/cssc.202500044

Long Pan, Xiong Xiong Liu, Pengcheng Yuan, Haotian Zhang, Yuan Zhang, Mufan Cao, Min Gao, Yaping Wang, Tomasz Wejrzanowski, Wei Zhang, ZhengMing Sun

{"title":"Garnets Initiate Grafting of Methyl Methacrylate Brushes onto Fluoropolymers for Electrochemically Stable and Fast-Ion-Conducting Composite Solid-State Electrolytes.","authors":"Long Pan, Xiong Xiong Liu, Pengcheng Yuan, Haotian Zhang, Yuan Zhang, Mufan Cao, Min Gao, Yaping Wang, Tomasz Wejrzanowski, Wei Zhang, ZhengMing Sun","doi":"10.1002/cssc.202500044","DOIUrl":"https://doi.org/10.1002/cssc.202500044","url":null,"abstract":"Fluoropolymer-based solid-state electrolytes (SSEs) promise next-generation all-solid-state Li metal batteries but suffer poor stability against Li metal anodes and sluggish Li+ transport. Here, we propose garnet-type Li6.4La3Zr1.4Ta0.6O12 (LLZTO) as a bifunctional mediator to enable the in-situ grafting and compositing for poly(vinylidene fluoride-co-hexafluoropropylene) (PVH), aiming at electrochemically stable and superionic SSEs. The LLZTO not only induces the formation of C=C bonds as active sites for effectively grafting methyl methacrylate (MMA) brush chains to PVH, but also acts as an ion-conducting filler to enhance mechanical properties and ion transport. In addition, the grafted MMA brush chains improve electrochemical stability against Li metal anodes and weaken polymer crystallinity to create amorphous domains for Li+ transport. Therefore, the resulting composite SSEs, PVH-graft-MMA/LLZTO (PVHML), achieves an impressive ionic conductivity of 0.94 mS cm-1 at 25 °C, high mechanical strength (2.02 MPa), and exceptional cycling stability in Li symmetric cells (2800 h at 0.1 mA cm-1, 25 °C). Furthermore, PVHML-based all-solid-state LiFePO4|Li full cells demonstrate superior cyclability with 89.8% capacity retention at 0.2C after 200 cycles (25 °C). This strategy provides an efficient solution to the challenges of fluoropolymer-based SSEs, paving the way for their practical applications in high-performance all-solid-state lithium metal batteries.","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":" ","pages":"e202500044"},"PeriodicalIF":7.5,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

BODIPY-coumarin triad as acceptor for ternary Non-Fullerene Solar Cells with over 15% Efficiency. bodipy -香豆素三元体作为三元非富勒烯太阳能电池的受体，效率超过15%。

IF 7.5 2区化学

ChemSusChem Pub Date : 2025-04-07 DOI: 10.1002/cssc.202500570

Ganesh D Sharma, Pengfei Li, Tingting Gu, Yi Fu, Xu Liang, Haijun Xu, Rahul Singhal

引用次数: 0