Jehangir Ijaz, Wajid Ali, Said Muhammad, Hayat Ullah, Danish Ather, Imran Ud Din
{"title":"Annual effective dose estimation of radon in drinking water sources of Nizampur basin, North Western Pakistan.","authors":"Jehangir Ijaz, Wajid Ali, Said Muhammad, Hayat Ullah, Danish Ather, Imran Ud Din","doi":"10.1080/10256016.2023.2276218","DOIUrl":"10.1080/10256016.2023.2276218","url":null,"abstract":"<p><p>This study assessed radon (<sup>222</sup>Rn) levels in drinking water sources in the Nizampur basin and their potential health risks for the local community. We analyzed 48 water samples on-site using RAD7. Additionally, we measured pH, temperature (T), total dissolved solids (TDS), redox potential (ORP), and electrical conductivity (EC) with a multiparameter analyzer. Results showed pH, T, TDS, ORP, and EC ranging from 7.2 to 8, 17 to 26 °C, 333 to 1130 mg/l, -56 to 284 mV, and 469 to 2370 <i>µ</i>S/cm. <sup>222</sup>Rn levels varied significantly (0.7-107 Bq/l, mean 23 ± 21, median = 17 Bq/l), with about 65 % exceeding the EPA's limit of 11.1 Bq/l, indicating health risks likely due to local geological conditions. The annual effective doses for ingestion (Ew<sub>Ing</sub>) were 0.87 ± 0.01, 0.35 ± 0.006, and 0.13 ± 0.002 <i>µ</i>Sv/a for adults, infants, and children, respectively. Exposure risk via the inhalation (Ew<sub>Inh</sub>) route ranged from 1.75 to 270 <i>µ</i>Sv/a, with the highest risk in infants, followed by children and adults. Inhalation was the primary exposure route for all age groups. Further, spatial distribution maps and hotspot analysis suggested that the central region characterized by high structural deformation and favorable geology for radon emanation was the area of concern in terms of health risks.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"539-553"},"PeriodicalIF":1.3,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71423601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Differences in <i>δ</i><sup>13</sup>C and <i>δ</i><sup>15</sup>N values for monarch butterflies raised on milkweeds from within and outside of crop fields: implications for inferences about natal origins.","authors":"John M Pleasants","doi":"10.1080/10256016.2023.2257370","DOIUrl":"10.1080/10256016.2023.2257370","url":null,"abstract":"<p><p>Stable isotope (<i>δ</i><sup>2</sup>H, <i>δ</i><sup>13</sup>C) measurements of wing tissue have been used to determine the natal geographic origin of migrant monarch butterflies that overwinter in Mexico. This study examines the possibility of using <i>δ</i><sup>13</sup>C and <i>δ</i><sup>15</sup>N to identify the milkweed habitat used by monarchs in their natal region. Milkweeds were common in corn and soybean fields before herbicide use led to their extirpation around 2006, and the loss of those milkweeds has been proposed as a reason for the monarch population decline. If crop-field monarchs can be identified, then historical samples of monarchs could be examined to test that hypothesis. The <i>δ</i><sup>15</sup>N and <i>δ</i><sup>13</sup>C values of leaves from milkweeds growing in corn fields, soybean fields and non-agricultural habitats were examined as well as monarchs that were raised on those leaves. There were no <i>δ</i><sup>15</sup>N values for leaves or monarchs that were distinctive for crop fields. Milkweeds in corn fields, and monarchs that were raised on those milkweeds, were found to have <i>δ</i><sup>13</sup>C values distinctly lower than those of other habitats and unlike those of locations within the summer breeding range. Thus, it should be possible to identify monarchs that came from cornfields in samples of overwintering monarchs made before ca. 2006.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"476-489"},"PeriodicalIF":1.3,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10362054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Correction.","authors":"","doi":"10.1080/10256016.2023.2224469","DOIUrl":"https://doi.org/10.1080/10256016.2023.2224469","url":null,"abstract":"","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"1"},"PeriodicalIF":1.3,"publicationDate":"2023-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9692796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Regional groundwater flow system characterization of volcanic aquifers in upper Awash using multiple approaches, central Ethiopia.","authors":"Kidist Hailu, Behailu Birhanu, Tilahun Azagegn, Seifu Kebede","doi":"10.1080/10256016.2023.2222221","DOIUrl":"https://doi.org/10.1080/10256016.2023.2222221","url":null,"abstract":"ABSTRACT Characterization of the groundwater flow systems is important for sustainable water resource management decision-making. We have used vertical profiles of electrical conductivity (EC) and water temperature taken at 2 m intervals during drilling of 109 boreholes, and samples for stable isotope analysis (δ 18O, δ 2H) taken from 47 boreholes to characterize groundwater recharge, flow and discharge. 222Rn measurements and piezometric evidence were used to complement results from the EC and stable isotopes. The converging evidence shows that groundwater in the study area is characterized by a mix of two different groundwater flow systems: i) the deep groundwater systems are connected to the regional groundwater flow originating from the highlands, outside the surface water basin, ii) the shallow groundwater systems get recharge from local rains. The local recharge zones are located in highly urbanized and industrialized zones posing risk to recharge reduction and pollution. Therefore, attention should be given to protect groundwater resources from contamination and increase groundwater resilience to climate change.","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":"59 3","pages":"269-289"},"PeriodicalIF":1.3,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10496657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pharahilda M Steur, Dennis Botter, Hubertus A Scheeren, Heiko Moossen, Michael Rothe, Harro A J Meijer
{"title":"Preventing drift of oxygen isotopes of CO<sub>2</sub>-in-air stored in glass sample flasks: new insights and recommendations.","authors":"Pharahilda M Steur, Dennis Botter, Hubertus A Scheeren, Heiko Moossen, Michael Rothe, Harro A J Meijer","doi":"10.1080/10256016.2023.2234594","DOIUrl":"https://doi.org/10.1080/10256016.2023.2234594","url":null,"abstract":"<p><p>It is known that the oxygen isotope composition of CO<sub>2</sub>-in-air, when stored over longer time periods in glass sample flasks, tends to drift to more negative values while the carbon isotope composition remains stable. The exact mechanisms behind this drift were still unclear. New experimental results reveal that water already inside the flasks during sampling plays a major role in the drift of the oxygen isotopes. A drying method to remove any water sticking to the inner walls by evacuating the flasks for more than 72 h while heating to 60 °C significantly decreases drift of the oxygen isotopes. Moreover, flasks not dried with this method showed higher differences among drift rates of individual flasks. This is explained through the buildup of H<sub>2</sub>O molecules sticking to the inner walls. Humidity of the air samples in the flasks as well as surface characteristics will lead to differences among flasks. Results also show that permeability of water is higher through Viton O-ring flask seals than through polychlorotrifluoroethylene (PCTFE) shaft seals, and that the stability of flasks sealed with the latter is significantly better over time.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":"59 3","pages":"309-326"},"PeriodicalIF":1.3,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10134064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tetsuya Endo, Osamu Kimura, Masaru Terasaki, Shotaro Nakagun, Yoshihisa Kato, Yukiko Fujii, Koichi Haraguchi, C Scott Baker
{"title":"Carbon, nitrogen, and oxygen stable isotope ratios of striped dolphins and short-finned pilot whales stranded in Hokkaido, northern Japan, compared with those of other cetaceans stranded and hunted in Japan.","authors":"Tetsuya Endo, Osamu Kimura, Masaru Terasaki, Shotaro Nakagun, Yoshihisa Kato, Yukiko Fujii, Koichi Haraguchi, C Scott Baker","doi":"10.1080/10256016.2023.2234590","DOIUrl":"https://doi.org/10.1080/10256016.2023.2234590","url":null,"abstract":"<p><p>Strandings of striped dolphins (SD) and short-finned pilot whales (PW) in Hokkaido, northern Japan, are rare but have recently increased, probably due to global warming. We quantified <i>δ</i><sup>13</sup>C, <i>δ</i><sup>15</sup>N, and <i>δ</i><sup>18</sup>O in muscles of SD (<i>n</i> = 7) and PW (<i>n</i> = 3) stranded in Hokkaido and compared these values with those in muscles (red meat products) of hunted SD and PW in three areas of central and southern Japan. <i>δ</i><sup>18</sup>O in stranded SD, except for the calf, decreased with increasing body length (BL), whereas <i>δ</i><sup>13</sup>C increased, with no BL-related changes in <i>δ</i><sup>15</sup>N. The variability of <i>δ</i><sup>18</sup>O (range of maximum and minimum) was larger in the stranded SD (7.5 ‰) than of the hunted SD in three areas (0.9, 1.9, and 1.4 ‰), whereas that of <i>δ</i><sup>15</sup>N was smaller in the stranded SD than in the hunted SD. Similarly, the variability of <i>δ</i><sup>18</sup>O was larger in the stranded PW in Hokkaido (3.3 ‰) than in the hunted PW in central Japan (1.4 ‰). The larger variability of <i>δ</i><sup>18</sup>O and smaller variability of <i>δ</i><sup>15</sup>N in stranded SD imply long-term sojourning in coastal waters and feeding on small amounts of limited prey species at low trophic levels before death.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":"59 3","pages":"230-247"},"PeriodicalIF":1.3,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10199429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Leonard I Wassenaar, Cedric Douence, Susan Fortson, Douglas S Baer
{"title":"Automated rapid triple-isotope (<i>δ</i><sup>15</sup>N, <i>δ</i><sup>18</sup>O, <i>δ</i><sup>17</sup>O) analyses of nitrate by Ti(III) reduction and N<sub>2</sub>O laser spectrometry.","authors":"Leonard I Wassenaar, Cedric Douence, Susan Fortson, Douglas S Baer","doi":"10.1080/10256016.2023.2222222","DOIUrl":"https://doi.org/10.1080/10256016.2023.2222222","url":null,"abstract":"<p><p>The nitrogen and oxygen (<i>δ</i><sup>15</sup>N, <i>δ</i><sup>18</sup>O, <i>δ</i><sup>17</sup>O) stable isotopic compositions of nitrate (<math><mrow><mi>N</mi></mrow><msubsup><mrow><mi>O</mi></mrow><mn>3</mn><mtext>-</mtext></msubsup></math>) are crucial tracers of nutrient N sources and dynamics in aquatic and atmospheric systems. Methods to reduce aqueous <math><mrow><mi>N</mi></mrow><msubsup><mrow><mi>O</mi></mrow><mn>3</mn><mtext>-</mtext></msubsup></math> to N<sub>2</sub>O gas (microbial or Cd method) before <sup>15</sup>N and <sup>18</sup>O isotope analyses require multi-step conversion or toxic chemicals, and <sup>17</sup>O in N<sub>2</sub>O cannot be disentangled by IRMS due to isobaric interferences. This technical note describes the automation of the stable-isotope analyses of nitrate by coupling the new Ti method with a headspace autosampler and an N<sub>2</sub>O triple-isotope laser analyzer based on off-axis integrated cavity output spectroscopy. The automation yielded accurate and precise results for routine determinations of <i>δ</i><sup>15</sup>N, <i>δ</i><sup>18</sup>O, and <i>δ</i><sup>17</sup>O values for aqueous nitrate in environmental waters. Systematic corrections were required for cavity pressure, N<sub>2</sub>O concentration and water vapour content to obtain the highest precision for all three isotopic ratios. For the first time, an automated laser-based system facilitates routine low-cost triple isotope analyses in studies where high-temporal resolution isotope analyses of NO<sub>3</sub><sup>-</sup> are required but have been, until now, cost-prohibitive and time-consuming (e.g. atmospheric N pollution).</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":"59 3","pages":"297-308"},"PeriodicalIF":1.3,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10143568","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Karina Pfrimer, Roberto Botelho Ferraz Branco, Tom Preston, Márcia Sv Salles, Luiz C Roma-Junior, Eduardo Ferriolli
{"title":"Intrinsic labelling of common beans with <sup>2</sup>H<sub>2</sub>O to enable estimates of protein digestibility.","authors":"Karina Pfrimer, Roberto Botelho Ferraz Branco, Tom Preston, Márcia Sv Salles, Luiz C Roma-Junior, Eduardo Ferriolli","doi":"10.1080/10256016.2023.2234592","DOIUrl":"https://doi.org/10.1080/10256016.2023.2234592","url":null,"abstract":"<p><strong>Background: </strong>The use of plant protein intrinsically labelled with stable isotopes provides an innovative solution to assess the efficiency of protein intake by humans. Here, the incorporation of <sup>2</sup>H has been applied to intrinsically labelled plant protein in the common bean. This study aimed to evaluate which is the best phenological phase of seed maturation to incorporate the heavy hydrogen isotope <sup>2</sup>H into seed amino acids. Common beans (<i>Phaseolus vulgaris</i> L.) were grown in pots, then, after 50 days sowing, <sup>2</sup>H<sub>2</sub>O dissolved in irrigation water was applied, then again at an interval of either 3, 6, 9, and 12 days.</p><p><strong>Results: </strong>Applications of <sup>2</sup>H<sub>2</sub>O at 6, 9, and 12 days after the first application, in the full-flowering stage, were the best treatments for enriching protein-bound amino acids in the bean seed with <sup>2</sup>H.</p><p><strong>Conclusion: </strong>All treatments resulted in enrichment above 500 ppm, so the treatments (quantity and timing of <sup>2</sup>H<sub>2</sub>O addition) were deemed successful for enriching bean seeds. This makes the intrinsically labelled seeds suitable for preparing test meals to assess the digestion and essential amino acid absorption of common bean amino acids in human subjects.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":"59 3","pages":"290-296"},"PeriodicalIF":1.3,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10146234","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Isotopic niches of the Northern shoveler <i>Spatula clypeata</i> in spring migratory stopover sites in the Marais breton, France.","authors":"Axelle Moreau, Pierrick Bocher, Pascal Bonnin, Sébastien Farau, Christine Dupuy","doi":"10.1080/10256016.2023.2208865","DOIUrl":"https://doi.org/10.1080/10256016.2023.2208865","url":null,"abstract":"<p><p>The Northern shoveler, <i>Spatula clypeata</i>, makes several migratory stopovers to reach its breeding site in the best conditions. These stopovers allow the species to replenish their reserves. Therefore, feeding efficiency at such sites is essential. Despite its importance, few studies have been conducted on the spring ecology of the shoveler, particularly on its diet at stopover sites. Therefore, this study focused on the Northern shoveler's feeding habit during its spring migratory stopover in the Marais breton (MB), a wetland situated in Vendée (France, Atlantic coast). The shoveler's plasma and potential food resources were studied using a stable carbon and nitrogen isotope analysis. The study showed that the shoveler feeds primarily on microcrustaceans, especially Cladocera and Copepoda; Chironomidae larvae, Corixidae, Hydrophilidae larvae, and particulate organic matter. This last food source, the POM, had never been highlighted before.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":"59 3","pages":"217-229"},"PeriodicalIF":1.3,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10496653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nimisha Singh, Rohit Pradhan, Raghavendra P Singh, Praveen K Gupta
{"title":"The role of continental evapotranspiration on water vapour isotopic variability in the troposphere.","authors":"Nimisha Singh, Rohit Pradhan, Raghavendra P Singh, Praveen K Gupta","doi":"10.1080/10256016.2023.2212834","DOIUrl":"https://doi.org/10.1080/10256016.2023.2212834","url":null,"abstract":"<p><p>Rainforests play an important role in hydrological and carbon cycles, both at regional and global scales. They pump large quantities of moisture from the soil to the atmosphere and are major rainfall hotspots of the world. Satellite-observed stable water isotope ratios have played an essential role in determining sources of moisture in the atmosphere. Satellites provide information about the processes involving vapour transport in different zones of the world, identifying sources of rainfall and distinguishing moisture transport in monsoonal systems. This paper focuses on major rainforests of the world (Southern Amazon, Congo and Northeast India) to understand the role of continental evapotranspiration in influencing tropospheric water vapour. We have used satellite measurements of <sup>1</sup>H<sup>2</sup>H<sup>16</sup>O/<sup>1</sup>H<sub>2</sub><sup>16</sup>O from Atmospheric InfraRed Sounder (AIRS), evapotranspiration (ET), solar-induced fluorescence (SIF), precipitation (P), atmospheric reanalysis-derived moisture flux convergence (MFC) and wind to discern the role of ET in influencing water vapour isotopes. A global map of the correlation between <i>δ</i><sup>2</sup>H<sub>v</sub> and ET-P flux indicates that densely vegetated regions in the tropics show the highest positive correlation (r > 0.5). Using mixing models and observations of specific humidity and isotopic ratio over these forested regions, we discern the source of moisture in pre-wet and wet seasons.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":"59 3","pages":"248-268"},"PeriodicalIF":1.3,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10143039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}