Ana-Voica Bojar, Andrzej Pelc, Michael Ernst Böttcher
{"title":"Isotopes as recorders of environmental change. Special issue related to ESIR 2023 - Workshop XVI of the European Society for Isotope Research, Graz, Austria.","authors":"Ana-Voica Bojar, Andrzej Pelc, Michael Ernst Böttcher","doi":"10.1080/10256016.2025.2465449","DOIUrl":"10.1080/10256016.2025.2465449","url":null,"abstract":"","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"1-3"},"PeriodicalIF":1.1,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143557084","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anna-Kathrina Jenner, Rhodelyn Saban, Cátia M Ehlert von Ahn, Patricia Roeser, Iris Schmiedinger, Jürgen Sültenfuß, Anja Reckhardt, Michael Ernst Böttcher
{"title":"Different continuous freshwater contributions to submarine groundwater discharge at a coastal peatland, southern Baltic Sea.","authors":"Anna-Kathrina Jenner, Rhodelyn Saban, Cátia M Ehlert von Ahn, Patricia Roeser, Iris Schmiedinger, Jürgen Sültenfuß, Anja Reckhardt, Michael Ernst Böttcher","doi":"10.1080/10256016.2024.2422864","DOIUrl":"10.1080/10256016.2024.2422864","url":null,"abstract":"<p><p>The impact of freshwater sources like surface river runoff and submarine groundwater discharge (SGD) on coastal waters is currently in focus of intense debate and investigation. One of the ongoing challenges in SGD research is the characterization and quantification of the freshwater endmember contributions to the subsurface mixing zone and their influences on element balance and biogeochemical transformations. Long-term investigations of the sediment porewater composition provide characterization and understanding of the physical, hydrological and biogeochemical processes controlling the substance exchanges. In this study, we focus on the hydrochemical and stable isotope (<i>δ</i><sup>2</sup>H, <i>δ</i><sup>18</sup>O) compositions of sediment porewaters along the coastline of a southern Baltic Sea peatland. Coastal surface water and groundwater dynamics were monitored at two coastal sites using 5-m-long stationary lances over a 5-year period.The vertical compositional gradients were used to extrapolate to zero-salinity (ZS) components applying a binary mixing model on the salinity and water isotope composition. The results characterize a subterranean estuary (STE) with three potential mixing endmembers: two fresh groundwaters and the brackish Baltic Sea. Tritium-helium (<sup>3</sup>H-<sup>3</sup>He) porewater dating gave ages of more than about 20 years for the freshwater components. The ZS components were compared with other SGD sites along the southern Baltic Sea and North Sea and highlight the importance of local SGD studies for a proper groundwater endmember characterization as basis to understand hydrological and biogeochemical developments at the land-ocean continuum in times of current climate change.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"42-60"},"PeriodicalIF":1.1,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142620717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"New chloromethane preparation line for the stable chlorine isotope composition analysis.","authors":"Andrzej Pelc","doi":"10.1080/10256016.2024.2379414","DOIUrl":"10.1080/10256016.2024.2379414","url":null,"abstract":"<p><p>Stable isotopes of chlorine have great application potential due to the widespread occurrence of the chlorine anion in water, minerals, living organisms and the environment. In most studies, the chloride ion from the samples is converted to chloromethane, which is then analysed isotopically using a mass spectrometer. In the present study, a new design for a chloromethane preparation line is proposed. In particular, the new chloromethane preparation line uses a new system for injecting iodomethane into the preparation system, as well as ampoules with Teflon valves and the u-shaped freezers. These improvements reduced the preparation time to about 1 h, and also achieved a decent measurement uncertainty of 0.05 permil.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"92-100"},"PeriodicalIF":1.1,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141758783","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Sulphur and oxygen stable isotopes in acid mine drainage impacted rivers of Meghalaya (India): deciphering the sulphide oxidation pathways.","authors":"Vivek Kumar, Dibyendu Paul, Sudhir Kumar","doi":"10.1080/10256016.2025.2456557","DOIUrl":"10.1080/10256016.2025.2456557","url":null,"abstract":"<p><p>Sulphur and oxygen stable isotopes of sulphate have been used to trace the sources of sulphur into aquatic systems. These isotopes have also been used to understand the transformation and fate of sulphur in the water bodies contaminated by AMD discharge from active and/or abandoned mines. Stable isotopes of oxygen in dissolved sulphate (δ<sup>18</sup>O<sub>SO4</sub>) and water (δ<sup>18</sup>O<sub>H2O</sub>) have helped to decipher the sulphide oxidation pathways and estimate their contributions. The present study is focused on analysing the composition of sulphur and oxygen stable isotopes of sulphate and oxygen stable isotope in AMD and Lunar-Lukha River water flowing through the coal mining area of the East Jaintia Hills District, Meghalaya, in order to decipher the sulphide oxidation pathways. The results showed that the sulphur stable isotope of sulphate (δ<sup>34</sup>S<sub>SO4</sub>) ranged between -12.5 and -8.0 ‰ (VCDT). The oxygen isotope of sulphate (δ<sup>18</sup>O<sub>SO4</sub>) ranged between 1.4 and 2.0 ‰ (VSMOW). The oxygen isotope of water (δ<sup>18</sup>O<sub>H2O</sub>) was distributed between -6.2 and -4.2 ‰ (VSMOW). Pyrite oxidation was found to be the dominant source of sulphate in the Lunar-Lukha Rivers. The results of the stoichiometric isotope balance model showed that 68-83 % of sulphate derived Fe<sup>3+</sup> oxidation pathway, with a high portion of sulphate oxygen derived from water. The sulphite-water oxygen exchange model revealed the release of intermediate sulphoxyanions, suggesting the presence of an oxidation pathway of sulphide minerals to sulphate via sulphoxyanions. The results from this study will be helpful in defining effective remediation strategies to mitigate AMD impacts.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"76-91"},"PeriodicalIF":1.1,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143189299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"In memoriam: Dr. Keith Alan Hobson, a pioneer of stable isotope ecology.","authors":"Leonard I Wassenaar","doi":"10.1080/10256016.2024.2434511","DOIUrl":"https://doi.org/10.1080/10256016.2024.2434511","url":null,"abstract":"","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"1-2"},"PeriodicalIF":1.1,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142768968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Matthias Pilecky, Martin J Kainz, Leonard I Wassenaar
{"title":"Exploring hydrogen isotope fractionation in lipid biomolecules of freshwater algae: implications for ecological and paleoenvironmental studies.","authors":"Matthias Pilecky, Martin J Kainz, Leonard I Wassenaar","doi":"10.1080/10256016.2024.2419880","DOIUrl":"10.1080/10256016.2024.2419880","url":null,"abstract":"<p><p>Understanding the stable hydrogen isotope (<i>δ</i><sup>2</sup>H) composition and fractionation in lipid biomolecules of primary producers, such as terrestrial and aquatic plants, is crucial for deciphering past environmental conditions, as well as applying compound-specific stable isotope analysis for the study of metabolic and ecological processes. We conducted a new tracer experiment to explore the <i>δ</i><sup>2</sup>H composition of algal fatty acid biomarkers, focusing on freshwater algae, which form the base of aquatic food webs. We selected a range of algal species widely found in freshwater ecosystems and cultivated them under controlled conditions. First, we added <sup>2</sup>H<sub>2</sub>O to ambient water as a tracer to investigate the net hydrogen isotope fractionation during algal lipid synthesis at isotopic equilibrium, which is particularly informative for paleo-geochemical studies. Then, we conducted kinetic experiments to quantify the time needed for algal fatty acids to achieve isotopic steady-state conditions in response to the change in ambient water <i>δ</i><sup>2</sup>H values. Our findings revealed substantial variability in hydrogen isotope fractionation among different algal taxa and various fatty acids. Based on taxa, different fatty acids exhibited faster integration of water hydrogen than others, but they were not necessarily in the order of the biosynthetic pathway. This experiment underscores the complexity of hydrogen isotope fractionation and the requirement for controlled laboratory studies to properly apply compound-specific stable H isotope analysis techniques in ecological and paleo-environmental studies.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"585-595"},"PeriodicalIF":1.1,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142521954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hannan Younis, Mian Mateen Ullah, Muhammad Adil Khan, Farooq Ahmad, Umair Azeem, Muhammad Waseem, Khurram Mehboob, Muhammad Ajaz, Wazir Muhammad
{"title":"Assessment of natural radioactivity levels in rice samples and their implications for radiological protection.","authors":"Hannan Younis, Mian Mateen Ullah, Muhammad Adil Khan, Farooq Ahmad, Umair Azeem, Muhammad Waseem, Khurram Mehboob, Muhammad Ajaz, Wazir Muhammad","doi":"10.1080/10256016.2024.2412707","DOIUrl":"10.1080/10256016.2024.2412707","url":null,"abstract":"<p><p>This study investigates the levels of natural and artificial radioactivity in rice samples collected from various local markets in Islamabad, Pakistan. The <sup>226</sup>Ra, <sup>232</sup>Th, and <sup>40</sup>K activity concentrations were measured through gamma-ray spectrometry with a NaI(Tl) detector. The average activity concentrations were 1.67 ± 1.19 Bq kg<sup>-1</sup> for <sup>226</sup>Ra, 3.31 ± 1.83 Bq kg<sup>-1</sup> for <sup>232</sup>Th, and 88.51 ± 11.65 Bq kg<sup>-1</sup> for <sup>40</sup>K. Calculated radium equivalent (Ra<sub>eq</sub>) values ranged from 7.35 to 18.08 Bq kg<sup>-1</sup>, with a mean value of 11.11 Bq kg<sup>-1</sup>, all below the permissible maximum of 370 Bq kg<sup>-1</sup>. The absorbed dose rates ranged from 6.85 to 16.39 nGy h<sup>-1</sup>, with an average of 10.64 nGy h<sup>-1</sup>, falling below the acceptable limit of 51 nGy h<sup>-1</sup>. The outdoor and indoor radiation hazard indices (H<sub>ex</sub> and H<sub>in</sub>) had mean values of 0.03, both below the threshold value of one. The external and internal hazard indices (<i>I<sub>γ</sub></i> and <i>I<sub>α</sub></i>) were both 0.088, also below the critical value of one. The excess lifetime cancer risk (ELCR) ranged from 0.28 to 0.11, with a mean value of 0.18, which is less than the critical value of one. Overall, the radioactivity levels in the analyzed rice samples are within the acceptable limits set by the International Commission on Radiological Protection and are below global averages. These results offer important insights into the radiological safety of rice consumption in the study area.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"615-627"},"PeriodicalIF":1.1,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142500600","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"In memoriam: Dr. Keith Alan Hobson, a pioneer of stable isotope ecology.","authors":"Leonard I Wassenaar","doi":"10.1080/10256016.2024.2434511","DOIUrl":"https://doi.org/10.1080/10256016.2024.2434511","url":null,"abstract":"","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":"60 6","pages":"555-556"},"PeriodicalIF":1.1,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142836422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Copper and its isotopes: a brief overview of its implications in geology, environmental system, and human health.","authors":"Tanya Srivastava, Nishchal Wanjari","doi":"10.1080/10256016.2024.2410290","DOIUrl":"10.1080/10256016.2024.2410290","url":null,"abstract":"<p><p>Copper, a malleable and ductile transition metal, possesses two stable isotopes. These copper isotopic composition data have recently found diverse applications in various fields and disciplines. In geology, copper isotopes serve as tracers that aid in investigating ore formation processes and the mechanisms of copper deposits Likewise, it has emerged as a valuable tracer in polluted environments. In plant biology, copper acts as an essential micronutrient crucial for photosynthesis, respiration, and growth. Copper isotopes contribute to understanding how plants uptake and dispense copper from the soil within their tissues. Similarly, in animals, copper serves as an essential trace element, playing a vital role in growth, white blood cell function, and enzyme activity. In humans, copper acts as an antioxidant, neutralising harmful free radicals within the body. It also helps in maintaining the nervous and immune system. Furthermore, copper isotopes find medical applications, particularly in cancer diagnostics, neurodegenerative diseases, and targeted radiotherapy. However, excessive copper can have detrimental effects in humans such as it can cause liver damage, nausea, and abdominal pain, whilst in plants it can affect the growth of plants, photosynthesis, and membrane permeability. This review emphasises the significance of copper and its isotopes in geology, the environment, and human health.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"642-667"},"PeriodicalIF":1.1,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142375468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Estimation of radiological health risks due to <sup>226</sup>Ra, <sup>232</sup>Th, and <sup>40</sup>K in foods consumed in Iraqi Kurdistan Region.","authors":"Dedawan Salam Saleh, Hemn Salh, Jahfer Majeed Smail, Saddon T Ahmad, Sarmad Raheem Kareem","doi":"10.1080/10256016.2024.2411360","DOIUrl":"10.1080/10256016.2024.2411360","url":null,"abstract":"<p><p>This study investigates the activity concentration of natural radionuclides in a diverse range of food samples in the Koya district markets food baskets, including both domestic and imported products. The samples cover annual crops (e.g. coffee, tea, kidney beans), tree nuts (e.g. almonds, pistachios), and other items (e.g. beef, fish, milk) by using a high-purity germanium (HPGe) detector. This research addresses a notable gap by providing baseline data on radionuclide concentrations and assessing potential health risks. Average activity concentrations for ²²⁶Ra, ²³²Th, and ⁴⁰K were 0.943, 0.367, and 191.8 Bq kg<sup>-1</sup>, respectively. Radium equivalent activity values ranged from 2.88-58.48 Bq kg<sup>-1</sup>, all below the safety limit. The average excess lifetime cancer risk (ELCR) was 0.154 mSv a<sup>-1</sup>, indicating safety for most samples, though coffee and tea showed higher levels. This study provides new data crucial for future research and regulatory monitoring, underscoring the need for further investigation into geological impacts on radionuclide levels.</p>","PeriodicalId":14597,"journal":{"name":"Isotopes in Environmental and Health Studies","volume":" ","pages":"628-641"},"PeriodicalIF":1.1,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142375469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}