International Journal of Ceramic Engineering & Science最新文献

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Oxide Ceramic Large-scale Integration Device for Putting the Brakes on Global Boiling Accelerated by Artificial Intelligence Age Computers 人工智能时代计算机加速全球沸腾的氧化物陶瓷大规模集成装置
International Journal of Ceramic Engineering & Science Pub Date : 2025-06-13 DOI: 10.1002/ces2.70011
Shunpei Yamazaki, Tatsuya Onuki, Satoru Saito, Shoki Miyata, Kazuma Furutani, Kazuki Tsuda, Hiromichi Godo, Takanori Matsuzaki, Kenichi Okazaki, Hidekazu Miyairi, Motomu Kurata, Yasuhiro Jinbo, Fumito Isaka, Yuji Egi, Yoshinori Ando, Tsutomu Murakawa, Ryota Hodo, Toshikazu Ohno, Ryosuke Motoyoshi, Yuichi Yanagisawa, Yukinori Shima, Masami Jincho, Yasutaka Nakazawa, Masahiro Watanabe, Kayo Kumakura, Masataka Nakada, Ami Sato, Shinya Fukuzaki, Toshiki Sasaki, Nobuharu Ohsawa, Yuto Yakubo
{"title":"Oxide Ceramic Large-scale Integration Device for Putting the Brakes on Global Boiling Accelerated by Artificial Intelligence Age Computers","authors":"Shunpei Yamazaki,&nbsp;Tatsuya Onuki,&nbsp;Satoru Saito,&nbsp;Shoki Miyata,&nbsp;Kazuma Furutani,&nbsp;Kazuki Tsuda,&nbsp;Hiromichi Godo,&nbsp;Takanori Matsuzaki,&nbsp;Kenichi Okazaki,&nbsp;Hidekazu Miyairi,&nbsp;Motomu Kurata,&nbsp;Yasuhiro Jinbo,&nbsp;Fumito Isaka,&nbsp;Yuji Egi,&nbsp;Yoshinori Ando,&nbsp;Tsutomu Murakawa,&nbsp;Ryota Hodo,&nbsp;Toshikazu Ohno,&nbsp;Ryosuke Motoyoshi,&nbsp;Yuichi Yanagisawa,&nbsp;Yukinori Shima,&nbsp;Masami Jincho,&nbsp;Yasutaka Nakazawa,&nbsp;Masahiro Watanabe,&nbsp;Kayo Kumakura,&nbsp;Masataka Nakada,&nbsp;Ami Sato,&nbsp;Shinya Fukuzaki,&nbsp;Toshiki Sasaki,&nbsp;Nobuharu Ohsawa,&nbsp;Yuto Yakubo","doi":"10.1002/ces2.70011","DOIUrl":"https://doi.org/10.1002/ces2.70011","url":null,"abstract":"<p>One factor that is considered to be a cause of global boiling, which is becoming a serious social problem, is the rapid progress and widespread use of artificial intelligence (AI). We focus on an oxide ceramic with an extremely low off-state current (<i>I</i><sub>off</sub>) of 1 zA/µm to 1 yA/µm and a very large on/off ratio of 17 digits, and we aim to achieve AI with an ultra-low power consumption using the large-scale integration of oxide semiconductors (OSs). Field effect transistors (FETs) that include crystal indium oxide (IO) as a channel material exhibit an off-state current (<i>I</i><sub>off</sub>) equivalent to that of the FETs that contain indium gallium zinc oxide (IGZO) and an on-state current (<i>I</i><sub>on</sub>) that is higher than that of the FETs that contain IGZO. Single crystal IO is shown to be a promising material for improving performance and reducing the variation in the characteristics of OS devices. This report introduces the latest trends in the use of oxide ceramics. We expect that the development of these technologies will achieve AI with ultra-low power consumption in the future, which will be an important remediation against global boiling.</p>","PeriodicalId":13948,"journal":{"name":"International Journal of Ceramic Engineering & Science","volume":"7 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ces2.70011","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144281361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Valorization of Mine Tailings for Sustainable Geopolymer Production 可持续地聚合物生产中尾矿的增值研究
International Journal of Ceramic Engineering & Science Pub Date : 2025-06-10 DOI: 10.1002/ces2.70014
Pozhhan Mokhtari, Joey Lin, Prapassorn Numkiatsakul, Babak Koohestani, Waltraud M. Kriven
{"title":"Valorization of Mine Tailings for Sustainable Geopolymer Production","authors":"Pozhhan Mokhtari,&nbsp;Joey Lin,&nbsp;Prapassorn Numkiatsakul,&nbsp;Babak Koohestani,&nbsp;Waltraud M. Kriven","doi":"10.1002/ces2.70014","DOIUrl":"https://doi.org/10.1002/ces2.70014","url":null,"abstract":"<p>The sustainable production of geopolymers requires innovative approaches to raw material utilization. This study investigates the valorization of sulfidic coal mine tailings as a partial substitute for metakaolin in geopolymer synthesis. A comprehensive protocol involving mechanical grinding, particle size reduction (&lt;5 µm), and thermal treatment at 800°C was applied to enhance the reactivity of the aluminosilicate phases and eliminate harmful sulfidic content. Unlike earlier studies that only demonstrated low substitution levels or required blending with multiple precursors, this research uniquely demonstrates that thermally valorized coal tailings can replace up to 60 wt.% of metakaolin without compromising mechanical performance—geopolymers with 50 wt.% tailing substitution achieved compressive and flexural strengths of 43.3 MPa and 8.9 MPa, respectively. These are comparable to pure metakaolin-based formulations and significantly superior to untreated tailing mixes. The findings are supported by extensive mineralogical analysis (XRD, EDS, TGA, XRF) and confirm that valorized mine tailings can serve as a cost-effective, environmentally sustainable, raw materials for geopolymer production. This approach transforms hazardous waste into valuable construction materials and supports the global transition to low-carbon building technologies.</p>","PeriodicalId":13948,"journal":{"name":"International Journal of Ceramic Engineering & Science","volume":"7 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ces2.70014","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144255808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Commercially Viable Manufacturing of High Entropy Carbide Feedstocks 商业上可行的高熵碳化物原料制造
International Journal of Ceramic Engineering & Science Pub Date : 2025-06-09 DOI: 10.1002/ces2.70010
Kevin Kaufmann, James Vecchio, Kenneth S. Vecchio
{"title":"Commercially Viable Manufacturing of High Entropy Carbide Feedstocks","authors":"Kevin Kaufmann,&nbsp;James Vecchio,&nbsp;Kenneth S. Vecchio","doi":"10.1002/ces2.70010","DOIUrl":"https://doi.org/10.1002/ces2.70010","url":null,"abstract":"<p>High-entropy materials have attracted considerable research interest owing to the significant increase in potential compositions and the unique combinations of properties in many of the known systems. High-entropy carbides (HECs) are one such subclass of high-entropy materials where numerable interesting material compositions have been identified. However, significant barriers exist toward the scale-up of HEC fabrication beyond the pilot research and development scale. Currently, all reported fabrications of HEC materials uses processes that are not amenable to manufacturing HECs on the scale a materials supply company requires. For example, the most commonly reported synthesis routes require high energy ball milling to reduce the diffusion lengths before producing a bulk HEC article. Herein, two commercially viable routes to producing HEC feedstocks are demonstrated. The first method, cold crucible induction melting (CCIM), is a direct route to synthesize a nearly homogeneous HEC bar that can be milled into a granular powder. The second method, spray drying, produces agglomerated spherical particles that can undergo further homogenization or be used directly. The consolidation of the as-spray dried HEC feedstock into a bulk HEC article is demonstrated using spark plasma sintering (SPS). Chemistry mapping coupled with several additional analyses of the cold crucible bar, spray dried particles, and SPS densified sample are utilized to verify the products of each processing route. The future manufacturing and high-throughput screening of other high entropy ceramic materials, such as oxides, nitrides, and borides, is expected to benefit from this demonstration of rapid and commercially relevant HEC feedstock production methods.</p>","PeriodicalId":13948,"journal":{"name":"International Journal of Ceramic Engineering & Science","volume":"7 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ces2.70010","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144245034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of substitution and processing on the morphology and dielectric properties of Pr2/3Cu3Ti4O12 (PCTO) ceramic 取代和加工对Pr2/3Cu3Ti4O12 (PCTO)陶瓷形貌和介电性能的影响
International Journal of Ceramic Engineering & Science Pub Date : 2025-05-07 DOI: 10.1002/ces2.70004
Bradley Arnold, Ching Hua Su, Fow-Sen Choa, Brian Cullum, Tagide deCarvalho, Narsimha S. Prasad, Lauren N. Gower, Anna C. Darden, Krishna S. Machuga, Narsingh Bahadur Singh
{"title":"Effect of substitution and processing on the morphology and dielectric properties of Pr2/3Cu3Ti4O12 (PCTO) ceramic","authors":"Bradley Arnold,&nbsp;Ching Hua Su,&nbsp;Fow-Sen Choa,&nbsp;Brian Cullum,&nbsp;Tagide deCarvalho,&nbsp;Narsimha S. Prasad,&nbsp;Lauren N. Gower,&nbsp;Anna C. Darden,&nbsp;Krishna S. Machuga,&nbsp;Narsingh Bahadur Singh","doi":"10.1002/ces2.70004","DOIUrl":"https://doi.org/10.1002/ces2.70004","url":null,"abstract":"<p>Low-cost, large dielectric constant, and resistivity materials have wide range of applications for radio frequency systems, flash memory devices to ferroelectric switches, and energy storage applications. The paper reports on the development and characterization of high-resistivity Pr<sub>2/3</sub>Cu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> (PCTO) ceramics developed by doping with Ca<sup>2+</sup> and Sr<sup>2+</sup> ions under various processing conditions. In particular, synthesis and growth were performed at 1173 and 1273 K resulting in significant difference in both electrical and morphological properties. To alter the distortion and polarity of ceramics, low concentration (0.15 mole fraction) of Ca<sup>2+</sup> and Sr<sup>2+</sup> hetero-valent ions with different size were substituted for Pr<sup>3+</sup>. The evolution and sizes of non-spherical, non-faceted grains altered to facet shapes due to changes in the anisotropy developed with increased copper concentration in the grains. The morphology analysis at these low processing temperatures revealed that grain growth occurs by engulfment of smaller grains by larger grains, necking process, and channel formation, with particles growing in nanometer size to greater than 10 µm and forming new layers on top of grains. The migration of copper-rich phases above 1173 K from boundaries to grains causes faceted morphology in both pure and substituted PCTO. Finally, by substituting Ca<sup>2+</sup> and Sr<sup>2+</sup> into the ceramics, altering the processing temperature, resistivity, and dielectric constant significantly increased. The substituted ceramics showed a higher dielectric constant at applied frequencies of 100‒100 000 Hz and did not vary at bias voltages of 50‒1000 mV, indicating no breakdown of the ceramics.</p>","PeriodicalId":13948,"journal":{"name":"International Journal of Ceramic Engineering & Science","volume":"7 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ces2.70004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143919366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, Optical, and Electrical Investigations of MgO Nanostructure Under the Pressure Effect 压力效应下MgO纳米结构的结构、光学和电学研究
International Journal of Ceramic Engineering & Science Pub Date : 2025-05-07 DOI: 10.1002/ces2.70007
Y. Al-Douri, M. Ameri, A. Bouhemadou
{"title":"Structural, Optical, and Electrical Investigations of MgO Nanostructure Under the Pressure Effect","authors":"Y. Al-Douri,&nbsp;M. Ameri,&nbsp;A. Bouhemadou","doi":"10.1002/ces2.70007","DOIUrl":"https://doi.org/10.1002/ces2.70007","url":null,"abstract":"<p>MgO nanostructure is prepared using pulsed laser deposition (PLD) at different oxygen pressure. The prepared MgO nanostructure is characterized and analyzed by scanning electron microscopy (SEM), UV–visible (UV–vis) spectrophotometry and electrical characteristics, respectively. The correlation between grain size and pressure is inversely. The structural studies are presented in terms of varying pressures, focusing on the properties of MgO nanostructures at pressures ranging from 50 to 300 mbar. The grain size varies from 12.5 nm at 50 mbar to 3.9 nm at 300 mbar. Additionally, UV–vis optical investigations are conducted to understand the behavior of MgO nanostructures under different pressures. Transmittance is measured between 300 and 1100 nm across different pressures, 50–300 mbar to show high transmittance over 80% at pressures ranging from 200 to 300 mbar. The bandgap investigation, which is related to transmittance, reveals that at 200 mbar, the bandgap exhibits a direct inter-band transition, attributed to non-stoichiometry of the deposited layer. The electrical properties are investigated in terms of <i>I</i>–<i>V</i>, <i>J</i>–<i>V</i>, <i>C</i>–<i>V</i> characteristics, photo-current, short circuit current, open circuit voltage, spectral responsivity, and quantum efficiency.</p>","PeriodicalId":13948,"journal":{"name":"International Journal of Ceramic Engineering & Science","volume":"7 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ces2.70007","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143919367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Effect of Deposition Process Parameters on the Microstructure and Mechanical Properties of Nanostructured Thermal Barrier Coatings 沉积工艺参数对纳米热障涂层微观结构和力学性能的影响
International Journal of Ceramic Engineering & Science Pub Date : 2025-05-04 DOI: 10.1002/ces2.70006
Shahnaz Bashir Bhat, Atikur Rahman, Mukund Dutt Sharma
{"title":"The Effect of Deposition Process Parameters on the Microstructure and Mechanical Properties of Nanostructured Thermal Barrier Coatings","authors":"Shahnaz Bashir Bhat,&nbsp;Atikur Rahman,&nbsp;Mukund Dutt Sharma","doi":"10.1002/ces2.70006","DOIUrl":"https://doi.org/10.1002/ces2.70006","url":null,"abstract":"<p>Nanostructured thermal barrier coatings (TBCs, Cr/CoAlY/8 wt% Y<sub>2</sub>O<sub>3-</sub>ZrO<sub>2</sub> ceramic top coatings) were deposited on superni-718 substrates by the magnetron sputtering method on different process parameters. The effect of magnetron sputtering power on microstructure and mechanical properties of TBC was studied in the present research work. The structural properties of the deposited TBC coatings were characterized by X-ray diffraction (XRD) and field emission scanning electron microscope (FE-SEM) and chemical composition of thermal barrier coatings was characterized by energy dispersive X-ray spectroscopy (EDS). XRD results showed that the coatings deposited at a low power has much more amorphous nature as compared to coatings deposited at a high power has crystalline nature.The XRD analysis revealed the tetragonal phase which is the stable phase in TBC coating, since the temperature is constant in both depositions. Mechanical properties of the TBC coatings were studied by nano indentation. The results revealed that coatings deposited at lower power exhibited 50% increase in hardness values as compared to coating deposited as higher power. Furthermore, coating thickness has enhanced from 957 nm to 1.34 µm thus there has been 28% enhancement in coating thickness in changing process parameters specifically power of magnetron.</p>","PeriodicalId":13948,"journal":{"name":"International Journal of Ceramic Engineering & Science","volume":"7 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ces2.70006","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143905210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improvement of mechanical properties of biomimetic-layered Si3N4 ceramics with TiN as the interface layer TiN为界面层的仿生层状Si3N4陶瓷力学性能的改善
International Journal of Ceramic Engineering & Science Pub Date : 2025-04-28 DOI: 10.1002/ces2.10248
Xinghua Shen, Tongyang Li, Lizhi Zhang, Lujie Wang, Yuan Yu, Huaguo Tang, Zhuhui Qiao
{"title":"Improvement of mechanical properties of biomimetic-layered Si3N4 ceramics with TiN as the interface layer","authors":"Xinghua Shen,&nbsp;Tongyang Li,&nbsp;Lizhi Zhang,&nbsp;Lujie Wang,&nbsp;Yuan Yu,&nbsp;Huaguo Tang,&nbsp;Zhuhui Qiao","doi":"10.1002/ces2.10248","DOIUrl":"https://doi.org/10.1002/ces2.10248","url":null,"abstract":"<p>In order to synergistically improve the strength and toughness of Si<sub>3</sub>N<sub>4</sub> ceramic. We imitate the structure of shell nacre and use Si<sub>3</sub>N<sub>4</sub> as the matrix layer, TiN is used as the interface layer. During the experiment, the samples were prepared by dry lamination and discharge plasma sintering techniques. In the process of the study, ceramic samples with different microstructures were obtained by adjusting the amount of TiN addition and sintering temperature. The fracture toughness and flexural strength were improved by the layered ceramics modeled after the micro-nano structure was regulated by the nacre, the toughness can reach to 17.04 ± 1.32 MPa·m<sup>1/2</sup>. At the same time, the bending strength can reach 322 ± 3.2 MPa. Bio-inspired layered ceramics with high toughness can be better choice for industrial equipment in the aerospace field and daily life.</p>","PeriodicalId":13948,"journal":{"name":"International Journal of Ceramic Engineering & Science","volume":"7 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ces2.10248","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143880123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance alumina composite ceramics with brick-and-mortar structure derived from microsphere 由微球衍生而成的高性能陶瓷复合材料
International Journal of Ceramic Engineering & Science Pub Date : 2025-03-16 DOI: 10.1002/ces2.70002
Yedong Rong, Shihui Zhao, Qifan Zhang, Jianli Qiao, Guolong Sang, Xiaoqing Xi, Jinlong Yang
{"title":"High-performance alumina composite ceramics with brick-and-mortar structure derived from microsphere","authors":"Yedong Rong,&nbsp;Shihui Zhao,&nbsp;Qifan Zhang,&nbsp;Jianli Qiao,&nbsp;Guolong Sang,&nbsp;Xiaoqing Xi,&nbsp;Jinlong Yang","doi":"10.1002/ces2.70002","DOIUrl":"https://doi.org/10.1002/ces2.70002","url":null,"abstract":"<p>A series of alumina composite ceramics with a brick-and-mortar structure were successfully prepared by coating with different contents of ZrO<sub>2</sub> and alumina sol on Al<sub>2</sub>O<sub>3</sub> microspheres and hot pressing. By changing the process parameters, the influence of hot pressing on the mechanical properties of the material was explored. The synergistic effect of brick-and-mortar structure toughening, phase transformation toughening, and alumina sol self-toughening improves the mechanical properties of the alumina composite ceramics. The samples coated with ZrO<sub>2</sub> and alumina sol achieved the best performance when hot pressing pressure is 30 MPa and the temperature is 1540°C, with a fracture toughness of 7.4 MPa·m<sup>1/2</sup> and a flexural strength of 671 MPa. The ZrO<sub>2</sub> content of this sample is only 2 wt%. Compared with the control group of Al<sub>2</sub>O<sub>3</sub> solid microspheres directly hot pressed, the fracture toughness increased by 17% and 26%, respectively. Self-toughening Al<sub>2</sub>O<sub>3</sub> ceramics were successfully prepared by coating alumina sol. Its fracture toughness is 6.8 MPa·m<sup>1/2</sup> and its flexural strength is 600 MPa. This method is not only suitable for toughening alumina composite ceramics, but also maintains their high strength, with the potential for industrial production.</p>","PeriodicalId":13948,"journal":{"name":"International Journal of Ceramic Engineering & Science","volume":"7 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ces2.70002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143629838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Calculation model by Voronoi network and verification of zinc oxide varistor considering conduction mechanism 考虑导通机理的氧化锌压敏电阻Voronoi网络计算模型及验证
International Journal of Ceramic Engineering & Science Pub Date : 2025-02-24 DOI: 10.1002/ces2.70001
Xiao Lei, Xin Ning, Peng Liu, Pengfei Meng, Yue Yin, Jingke Guo
{"title":"Calculation model by Voronoi network and verification of zinc oxide varistor considering conduction mechanism","authors":"Xiao Lei,&nbsp;Xin Ning,&nbsp;Peng Liu,&nbsp;Pengfei Meng,&nbsp;Yue Yin,&nbsp;Jingke Guo","doi":"10.1002/ces2.70001","DOIUrl":"https://doi.org/10.1002/ces2.70001","url":null,"abstract":"<p>This paper investigates the impact of the microstructure of zinc oxide varistor ceramics on their electrical properties. The microstructure of varistor was characterized by Voronoi network, and the relationship between microstructure and electrical properties was studied by experiments. The results of the calculations indicate that the reduction of grain size leads to a linear increase in voltage gradient but also reduces the energy handling capacity and current-carrying capacity. An increase in grain nonuniformity causes a decrease in voltage gradient and leakage current, while the nonlinear coefficient and residual voltage ratio increase. The variation of grain resistivity significantly affects the residual voltage ratio, and the two are almost proportional. When the grain resistivity reaches 50 Ω·m, the residual voltage ratio is as high as 2.37. The influence of grain resistivity on flow capacity has an obvious inflection point and reaches the maximum value at about 1 Ω·m, about 5000 A. The increase in sample diameter size leads to a decrease in the varistor voltage gradient and nonlinear coefficient. The results can better characterize the effect of the changes of the structure of the varistor on the electrical properties.</p>","PeriodicalId":13948,"journal":{"name":"International Journal of Ceramic Engineering & Science","volume":"7 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ces2.70001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143481475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of gibbsite in lithomargic clay on the mechanical and physical properties of limestone calcined clay cement 石煤粘土中三水铝石对石灰石煅烧粘土水泥力学和物理性能的影响
International Journal of Ceramic Engineering & Science Pub Date : 2025-02-24 DOI: 10.1002/ces2.70000
Clement Nyarko Opoku, Anthony Andrews, Martinson Addo Nartey, Eric Kwame Asare
{"title":"Effect of gibbsite in lithomargic clay on the mechanical and physical properties of limestone calcined clay cement","authors":"Clement Nyarko Opoku,&nbsp;Anthony Andrews,&nbsp;Martinson Addo Nartey,&nbsp;Eric Kwame Asare","doi":"10.1002/ces2.70000","DOIUrl":"https://doi.org/10.1002/ces2.70000","url":null,"abstract":"<p>Cement, a non-renewable yet essential commodity in the construction industry remains the most used material despite the high CO<sub>2</sub> emissions associated with the production. To address this, several attempts such as pozzolans have been used to replace cementitious materials. Currently, limestone calcined clay cement (LC<sup>3</sup>) has gained prominence as a solution to ensure sustainability in the construction industry. To this end, this work investigated the effect of gibbsite in lithomargic clay on the physical and mechanical properties of LC<sup>3</sup>. The gibbsite and kaolinite fractions in lithomargic clay were separated using the 90 µm mesh. Geotechnical analysis was performed on &lt;90 µm clay to ascertain its suitability as supplementary cementitious material and further calcined at 800°C for 1 h. Paste cubes were produced from LC<sup>3</sup> and cured at 7, 14, and 28 days. The compressive strength results for all gibbsite-containing formulations after 28 days were above 20 MPa; thus, can be classified as type M masonry cement. Furthermore, the density of LC<sup>3</sup> cubes, which has a relationship with compressive strength was seen to increase as curing age increased, thus corresponding to an increase in compressive strength, which has the potential to enhance the resistance of LC<sup>3</sup> paste cube specimens to harsh environmental conditions.</p>","PeriodicalId":13948,"journal":{"name":"International Journal of Ceramic Engineering & Science","volume":"7 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ces2.70000","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143481474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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