International Journal of Electrochemical Science最新文献_第2页

Retraction notice to “Effect of titanium dioxide nanogel surface charges and particle size on anti-corrosion performances of epoxy coatings” [Int. J. Electrochem. Sci. 12(2) (2017) pp. 959–974] “二氧化钛纳米凝胶表面电荷和粒径对环氧涂料防腐性能的影响”[j]。j . Electrochem。科学通报，12(2)(2017)pp. 959-974]

IF 2.4 4区化学

International Journal of Electrochemical Science Pub Date : 2026-05-01 Epub Date: 2026-03-12 DOI: 10.1016/j.ijoes.2026.101352

Mohamed H. Wahby, Ayman M. Atta , Hamad A. Al-Lohedan , Ashraf M. El-saeed , Ahmed M. Tawfeek

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Retraction notice to ‘Adsorption characteristics and corrosion inhibition efficiency of ethoxylated octadecylamine ionic liquid in aqueous acid solution' [Intern. J. Electrochem. Sci., 11/2 (2016) Pages 882–898] 乙氧基十八胺离子液体在酸性水溶液中的吸附特性及缓蚀效率研究[j]。j . Electrochem。科学。， 11/2（2016）页882-898]

IF 2.4 4区化学

International Journal of Electrochemical Science Pub Date : 2026-05-01 Epub Date: 2026-03-10 DOI: 10.1016/j.ijoes.2026.101349

Ayman M. Atta , Gamal A. El-Mahdy , Hamad A. Allohedan , Mahmood M.S. Abdullah

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Retraction notice to ‘Corrosion protective coating based on alkyd resins derived from recycled poly (ethylene terephthalate) waste for carbon steel’ [Intern. J. Electrochem. Sci., 8/4 (2013) Pages 5136–5152] 关于“基于从回收的聚对苯二甲酸乙酯废料中提取的醇酸树脂的碳钢防腐涂层”的撤回通知[实习生]。j . Electrochem。科学。， 8/4（2013）页5136-5152]

IF 2.4 4区化学

International Journal of Electrochemical Science Pub Date : 2026-05-01 Epub Date: 2026-03-10 DOI: 10.1016/j.ijoes.2026.101350

Ayman M. Atta , Rasha A. El-Ghazawy , Ashraf M. El-Saeed

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Retraction notice to ‘Corrosion inhibition of mild steel in acidic medium by magnetite myrrh nanocomposite’ [Int. J. Electrochem. Sci. 9/12(2014) 8446–8457] “磁铁矿没药纳米复合材料在酸性介质中对低碳钢的缓蚀作用”[j]。j . Electrochem。科学通报，9/12(2014)8446-8457]

IF 2.4 4区化学

International Journal of Electrochemical Science Pub Date : 2026-05-01 Epub Date: 2026-03-10 DOI: 10.1016/j.ijoes.2026.101356

Ayman M. Atta , Gamal A. El-Mahdy , Hamad A. Al-Lohedan , Sami A. Al-Hussain

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Recent advances in carbon dot-driven nanomaterials for photoelectrochemical-based degradation of contaminants: A review 碳点驱动纳米材料光电降解污染物的研究进展

IF 2.4 4区化学

International Journal of Electrochemical Science Pub Date : 2026-04-01 Epub Date: 2026-01-14 DOI: 10.1016/j.ijoes.2026.101297

Abera Demeke Ambaye , Temesgen Girma Kebede , Naledi Raleie , Simiso Dube , Mkhulu Mathe , Mathew Muzi Nindi , Seshibe Makgato , Touhami Mokrani

{"title":"Recent advances in carbon dot-driven nanomaterials for photoelectrochemical-based degradation of contaminants: A review","authors":"Abera Demeke Ambaye , Temesgen Girma Kebede , Naledi Raleie , Simiso Dube , Mkhulu Mathe , Mathew Muzi Nindi , Seshibe Makgato , Touhami Mokrani","doi":"10.1016/j.ijoes.2026.101297","DOIUrl":"10.1016/j.ijoes.2026.101297","url":null,"abstract":"<div><div>Carbon dots (CDs) have attracted increasing attention due to their unique physicochemical and photophysical properties, such as strong photoluminescence, high crystallinity, and excellent dispersibility. This review focuses on the synthesis, characterization, and application of CD-based nanostructures in photoelectrochemical (PEC) degradation systems for the removal of pollutants. The commonly employed synthesis methods, such as hydrothermal, solvothermal, and others, are comprehensively discussed along with their advantages, limitations, and scalability potential. In addition, the review highlights the basic principles of photoelectrochemical degradation, emphasizing the role of CDs as efficient light-harvesting and charge-transfer materials. The characterization techniques used to evaluate the structural, optical, and electronic properties of CDs are briefly summarized. Moreover, recent innovations in the design and functionalization of CD-based composites for enhanced photocatalytic activity are reviewed. Particular attention is given to degradation mechanisms, interfacial charge dynamics, and strategies for improving quantum efficiency and stability. Finally, the current challenges and research gaps are outlined, with perspectives on future directions aimed at developing sustainable, low-cost, and high-performance CD-based PEC technologies for environmental remediation.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"21 4","pages":"Article 101297"},"PeriodicalIF":2.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146172238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Machine learning in corrosion electrochemistry: A critical review of prediction and corrosion-type identification 腐蚀电化学中的机器学习：预测和腐蚀类型识别的重要回顾

IF 2.4 4区化学

International Journal of Electrochemical Science Pub Date : 2026-04-01 Epub Date: 2026-02-11 DOI: 10.1016/j.ijoes.2026.101324

Ruinan Guo , Junxiang Rong

{"title":"Machine learning in corrosion electrochemistry: A critical review of prediction and corrosion-type identification","authors":"Ruinan Guo , Junxiang Rong","doi":"10.1016/j.ijoes.2026.101324","DOIUrl":"10.1016/j.ijoes.2026.101324","url":null,"abstract":"<div><div>Recent progress in data driven approaches is reshaping corrosion electrochemistry by enabling quantitative interpretation of complex electrochemical responses that involve interactions among environmental variables, alloy composition and surface chemistry. This review examines research published after 2010 that applies machine learning methods such as artificial neural networks, support vector regression and ensemble learning to predict corrosion rates from multivariate electrochemical and environmental datasets. These studies demonstrate that data driven models can reproduce current density evolution, mass loss behaviour and other electrochemical indicators with improved accuracy compared with traditional empirical relations while also revealing mechanistic patterns such as the contribution of alloying elements or the influence of moisture controlled wet and dry cycles. Parallel developments in corrosion type identification have used supervised learning and unsupervised learning to analyse electrochemical noise data, in situ images and microscopy based measurements, allowing automated recognition of uniform attack, pitting initiation and deposit controlled localized degradation. A central point of debate is whether models trained on limited electrochemical conditions can generalize to new regimes. This issue is addressed through hybrid approaches that incorporate physics informed parameters, electrochemical rate expressions or structural constraints that enhance interpretability and improve extrapolation beyond the original training domain. By integrating evidence from more than one hundred peer reviewed studies, this review clarifies the demonstrated capabilities of machine learning in electrochemical corrosion research and highlights the methodological and data related challenges that must be resolved for widespread adoption in scientific and industrial practice.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"21 4","pages":"Article 101324"},"PeriodicalIF":2.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146172236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

3D multiphysics modeling and design optimization of a 25-layer Z-type SOFC stack 25层z型SOFC叠层的三维多物理场建模与设计优化

IF 2.4 4区化学

International Journal of Electrochemical Science Pub Date : 2026-04-01 Epub Date: 2026-02-10 DOI: 10.1016/j.ijoes.2026.101320

Chenyuan Hong, Yongyang Fan, Zitian Luo, Daifen Chen

{"title":"3D multiphysics modeling and design optimization of a 25-layer Z-type SOFC stack","authors":"Chenyuan Hong, Yongyang Fan, Zitian Luo, Daifen Chen","doi":"10.1016/j.ijoes.2026.101320","DOIUrl":"10.1016/j.ijoes.2026.101320","url":null,"abstract":"<div><div>To address the performance and reliability requirements for high-power solid oxide fuel cell (SOFC) stacks, a three-dimensional coupled flow-thermal-electrochemical numerical model has been established to optimize a 25-layer Z-type SOFC stack design, The synergistic effects of Z-type inlet/outlet manifold layout and air flow distributing geometry over single-cell on the flow, temperature, and pressure distribution characteristics are systematically investigated. Preliminary results indicate that for a 25-layer medium-scale stack with a 2in1out configuration, the Z-type structure combined with a hybrid configuration of 7 square air flow channels and ribs could ensure good distributing qualities of both flow and oxygen within the stack. This provides critical structural design guidance for constructing high-performance, high-reliability modular high-power SOFC systems. The results show that without increasing the length of the current collection path, the contact area of the rib airway and cathode of the Z-type SOFC stack using square ribs increased by 17 % (5 square) and 22.7 % (7 square) respectively, and the optimized oxygen distribution range increased. The optimized structure demonstrates overall velocity enhancement, with maximum velocity increases of 2.2 m/s (7 square) and 3.4 m/s (5 square)，and verifies the effectiveness of structural adjustment in enhancing the uniformity of the flow field.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"21 4","pages":"Article 101320"},"PeriodicalIF":2.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146172243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Internal heating of lithium-ion batteries at low temperatures based on electro-thermal modeling 基于电热模型的低温锂离子电池内部加热

IF 2.4 4区化学

International Journal of Electrochemical Science Pub Date : 2026-04-01 Epub Date: 2026-02-02 DOI: 10.1016/j.ijoes.2026.101316

Yankong Song , Kehao Yin , Chao Lyu , Xiao Liang , Wei Li

{"title":"Internal heating of lithium-ion batteries at low temperatures based on electro-thermal modeling","authors":"Yankong Song , Kehao Yin , Chao Lyu , Xiao Liang , Wei Li","doi":"10.1016/j.ijoes.2026.101316","DOIUrl":"10.1016/j.ijoes.2026.101316","url":null,"abstract":"<div><div>Lithium-ion batteries (LIBs) are highly sensitive to operating temperature and experience particularly severe performance degradation at low temperature (here define as temperature below 0 °C). Preheating of LIBs represents an effective strategy to mitigate these adverse effects prior to operation under such conditions. Among various preheating techniques, the internal heating method has garnered increasing attention due to its advantages in temperature uniformity and operational simplicity. However, the application of excessively high current amplitudes during heating will induce capacity rapidly fade. To address this issue, this paper proposes a constrained pulse heating method that limits the current amplitude. Based on a thermal coupling simplified electrochemical model (TC-SEM), the criterion for preventing lithium plating is translated into current amplitude constraints across varying temperature and states of charge (SOC). Moreover, this study developed an experimental platform capable of delivering adjustable pulsed currents is constructed, incorporating these predefined current constraints to dynamically regulate the heating process and minimize degradation. Validation experiments demonstrate that no significant capacity degradation is observed following 100 heating cycles. In contrast, a control group subjected to heating with current amplitudes exceeding the prescribed heating current limits exhibited a capacity loss of approximately 2.1 % after only 30 cycles.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"21 4","pages":"Article 101316"},"PeriodicalIF":2.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146122707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Application of a UiO-67 metal-organic framework for the sensitive electrochemical detection of omeprazole in the biological samples UiO-67金属有机骨架在生物样品中奥美拉唑灵敏电化学检测中的应用

IF 2.4 4区化学

International Journal of Electrochemical Science Pub Date : 2026-04-01 Epub Date: 2026-02-08 DOI: 10.1016/j.ijoes.2026.101317

Mohammadreza Belali, Seyed Karim Hassaninejad-Darzi, Haniyeh Shafiei

{"title":"Application of a UiO-67 metal-organic framework for the sensitive electrochemical detection of omeprazole in the biological samples","authors":"Mohammadreza Belali, Seyed Karim Hassaninejad-Darzi, Haniyeh Shafiei","doi":"10.1016/j.ijoes.2026.101317","DOIUrl":"10.1016/j.ijoes.2026.101317","url":null,"abstract":"<div><div>A novel electrochemical sensor based on a UiO-67 metal-organic framework (MOF) modified with a carbon paste electrode (UiO-67/CPE) was developed for the sensitive and selective quantification of omeprazole (OM). The UiO-67/CPE exhibited remarkable electrocatalytic activity toward OM oxidation vs. bare CPE. Also, the improved electrochemical behavior can be ascribed to the remarkable textural properties of UiO-67, namely its high surface area and porous architecture. Experimental conditions, including UiO-67 amount in the UiO-67/CPE and pH of buffer solution were optimized through a one variable at a time. The results indicated that the optimal conditions were at 0.03 g of UiO-67 and a pH of 3.0. The resulting UiO-67/CPE sensor offered a broad linear response (0.15–224.83 µM), a low detection limit of 0.15 µM and excellent precision (RSD = 3.83 % for reproducibility and 3.27 % for repeatability). The UiO-67/CPE sensor enabled sensitive determination of OM concentrations in human plasma samples, with results confirming its high reliability through excellent recoveries (98–105 %) and high selectivity against potential interferences.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"21 4","pages":"Article 101317"},"PeriodicalIF":2.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146172241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Approximate analytical modeling of nonlinear CO₂ adsorption kinetics 非线性CO₂吸附动力学的近似解析建模

IF 2.4 4区化学

International Journal of Electrochemical Science Pub Date : 2026-04-01 Epub Date: 2026-02-11 DOI: 10.1016/j.ijoes.2026.101323

V. Kamala Priyatharshini , S.Shyamala Malini , R. Nalini , A. Meena , L. Rajendran

{"title":"Approximate analytical modeling of nonlinear CO₂ adsorption kinetics","authors":"V. Kamala Priyatharshini , S.Shyamala Malini , R. Nalini , A. Meena , L. Rajendran","doi":"10.1016/j.ijoes.2026.101323","DOIUrl":"10.1016/j.ijoes.2026.101323","url":null,"abstract":"<div><div>Heterogeneous CO₂ adsorption kinetics on solid amine sorbents are analyzed using a Toth-type isotherm to describe equilibrium behavior, leading to a nonlinear ordinary differential equation governing the temporal evolution of surface coverage. The nonlinear adsorption rate, formulated in terms of the driving force between equilibrium and instantaneous coverages, is solved analytically using the Rajendran–Joy method (RJM), yielding closed-form expressions for transient adsorption uptake over a wide time domain. The analytical solutions are validated against numerical simulations and quantitatively benchmarked against established Toth-based kinetic models, demonstrating comparable predictive accuracy with significantly reduced computational cost and enhanced parametric transparency. Sensitivity analysis elucidates the influence of kinetic and isotherm parameters on adsorption dynamics and identifies limiting regimes where the model reduces to linear or pseudo-order kinetics. The model limitations, including its validity range under strongly nonlinear adsorption conditions, are discussed. Beyond gas–solid capture systems, the developed kinetic framework is also applicable to electrochemical interfaces where CO₂ adsorption on amine-functionalized electrodes or catalytic surfaces governs interfacial reaction rates, such as in electrochemical CO₂ reduction processes.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"21 4","pages":"Article 101323"},"PeriodicalIF":2.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146172237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0