Inorganica Chimica Acta最新文献_第5页

Group 10 metal complexes of the 3,4-bis(dicyclohexylphosphino)thiophene (dcypt) ligand: Synthesis, characterization and catalysis 3,4-双（二环己基膦）噻吩（dcypt）配体的第 10 组金属配合物：合成、表征和催化作用

IF 2.7 3区化学

Inorganica Chimica Acta Pub Date : 2025-03-05 DOI: 10.1016/j.ica.2025.122610

Vincent Fagué , Sonia Mallet-Ladeira , Pascal Guillo , Christophe Fliedel

{"title":"Group 10 metal complexes of the 3,4-bis(dicyclohexylphosphino)thiophene (dcypt) ligand: Synthesis, characterization and catalysis","authors":"Vincent Fagué , Sonia Mallet-Ladeira , Pascal Guillo , Christophe Fliedel","doi":"10.1016/j.ica.2025.122610","DOIUrl":"10.1016/j.ica.2025.122610","url":null,"abstract":"<div><div>The nickel(II) (1), palladium(II) (2) and platinum(II) (3) complexes of the 3,4-bis(dicyclohexylphosphino)thiophene (dcypt) ligand were synthesized and characterized by multinuclear NMR and FT-IR spectroscopic techniques, mass spectrometry and elemental analysis. The nearly perfect square-planar geometry of the three complexes was confirmed by single-crystal X-ray diffraction analysis. Both complexes 1 (Ni) and 2 (Pd) were evaluated towards the Suzuki-Miyaura cross-coupling reaction between aryl halides and aryl boronic acids, a field that was not explored until now for metal complexes of dcypt. While the palladium(II) (pre)catalyst (2) was found very efficient for this transformation, both under “classical” (Cs2CO3 as base, 1,4-dioxane as solvent) and “green” (K3PO4 as base, tert-amyl alcohol (tAA) as solvent) reaction conditions, its nickel(II) analog (1) was only moderately active under the latter conditions (inactive under the former). Complex 2 was tolerant to both the presence of EDGs or EWGs groups on para position of the aryl halide or aryl boronic acid (72–99 %) and allowed the synthesis of polycyclic aromatic compounds. Moreover, the remarkable air-stability of dcypt and of its corresponding palladium(II) complex (2) allowed to perform Suzuki-Miyaura cross-coupling reactions under air and with a non-dried alcoholic solvent (tAA) without loss of activity.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"581 ","pages":"Article 122610"},"PeriodicalIF":2.7,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143627970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesized Tetrakis (2-oxy benzylidene) - hyroanthracen-2-yloxy zinc and cobalt (II) Phthalocyanines: Structural, DFT and SEM-EDS study

IF 2.7 3区化学

Inorganica Chimica Acta Pub Date : 2025-03-04 DOI: 10.1016/j.ica.2025.122614

Seda Erdem Cavdan , Nursel Acar-Selcuki , Dogan Kaya , Ahmet Ekicibil , Sevil Sener

{"title":"Synthesized Tetrakis (2-oxy benzylidene) - hyroanthracen-2-yloxy zinc and cobalt (II) Phthalocyanines: Structural, DFT and SEM-EDS study","authors":"Seda Erdem Cavdan , Nursel Acar-Selcuki , Dogan Kaya , Ahmet Ekicibil , Sevil Sener","doi":"10.1016/j.ica.2025.122614","DOIUrl":"10.1016/j.ica.2025.122614","url":null,"abstract":"<div><div>The Synthesis reaction, structural, spectroscopic, and binding characteristics of new Zn(II) and Co(II) phthalocyanine (Pc) complexes, denoted as Co-Pc (4) and Zn-Pc (5), respectively, containing two (2-oxybenzylidene) anthracene-dione groups, are described. Following the synthesis of 3-[(6-hydroxy-9,10-dihydroanthracen-2-yloxy)phthalonitrile] 3, Zinc Phthalocyanine (Zn-Pc) 4 and Cobalt Phthalocyanine (Co-Pc) 5 were subsequently prepared via chemical reaction with zinc and cobalt salts in dimethylformamide under heat and vacuum conditions. SEM image analysis confirmed homogeneous formation for both Zn-Pc and Co-Pc compounds, with average size of 470 nm and 69 nm, respectively. Compounds 3, 4, and 5 were characterized using elemental analysis, UV–Visible spectroscopy, Fourier Transform-Infrared Spectroscopy, 1H-Nucleer Magnetic Resonans Spectroscopy, and Q-TOF MS. Additionally, Density Functional Theory (DFT) and Time-Dependent Density Functional Theory (TD-DFT) calculations were performed to investigate the structural and electronic properties of compounds 4 and 5. Many phthalocyanine compounds have been synthesized to date, however, the synthesis of Compound 4 with corrosion inhibitors properties is particularly significant in this research.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"581 ","pages":"Article 122614"},"PeriodicalIF":2.7,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143577760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, structural characterization and DFT study of a cobalt(III)/cobalt(II) complex derived from N,O donor reduced Schiff base ligand

IF 2.7 3区化学

Inorganica Chimica Acta Pub Date : 2025-03-04 DOI: 10.1016/j.ica.2025.122618

Rabi Sankar Sarkar , Snehasis Banerjee , Shouvik Chattopadhyay

{"title":"Synthesis, structural characterization and DFT study of a cobalt(III)/cobalt(II) complex derived from N,O donor reduced Schiff base ligand","authors":"Rabi Sankar Sarkar , Snehasis Banerjee , Shouvik Chattopadhyay","doi":"10.1016/j.ica.2025.122618","DOIUrl":"10.1016/j.ica.2025.122618","url":null,"abstract":"<div><div>The present work descries the strategic design and synthesis of a dinuclear mixed-valence Co(III)/Co(II) complex, [(N3)CoIIILr(μ-O2CR1)CoII(N3)]·CH3OH, which has been synthesized using an N2O4 donor compartmental ligand, H2Lr {(2,2-dimethyl-1,3-propanediyl)bis(iminomethylene)bis(6-ethoxyphenol)}, CoCl2·6H2O, benzoic acid (R1CO2H) and NaN3 in 1: 2: 1: 2 ratio. Single crystal X-ray diffraction structure confirms the presence of a Co2O2 core in the complex. Co(III) center is present in the inner N2O2 donor pocket and cobalt(II) center is trapped in the outer O2O′2 donor pocket, as confirmed by bond length consideration and BVS calculation. Experimental effective magnetic moment supports the presence of three unpaired electron in the complex. DFT calculation is performed to confirm th oxidation state of The high spin configuration is 28.2 kcal/mol more stable than the low spin configuration at the CAM-B3LYP/Lanl2DZ/6-31G(d) level of theory, thus supporting the quadruplet nature of the complex.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"581 ","pages":"Article 122618"},"PeriodicalIF":2.7,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143563297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A “naked-eye” Naphthalimide based Chemosensor for CN− ion detection: Investigating its application as test-strips, Smartphone Analysis & Molecular Logic gate and its TD-DFT study

IF 2.7 3区化学

Inorganica Chimica Acta Pub Date : 2025-03-04 DOI: 10.1016/j.ica.2025.122615

Gurdeep Kaur , Iqubal Singh , Gurpinder Singh , Deepak Kumar

{"title":"A “naked-eye” Naphthalimide based Chemosensor for CN− ion detection: Investigating its application as test-strips, Smartphone Analysis & Molecular Logic gate and its TD-DFT study","authors":"Gurdeep Kaur , Iqubal Singh , Gurpinder Singh , Deepak Kumar","doi":"10.1016/j.ica.2025.122615","DOIUrl":"10.1016/j.ica.2025.122615","url":null,"abstract":"<div><div>It is unanimously known that cyanide (CN−) is one of the most toxic ions because it can interfere with the body's physiological phenomenon causing endocrine disorders, respiratory failure, hypoxia, vascular necrosis, and even death. Therefore, it is essential to develop cost-effective, sensitive, rapid, and efficient methods for sensing CN− ions. The naphthalimide-based highly selective probe 1 was successfully synthesized in a multi-step process. Probe 1 displayed high selectivity and specificity against cyanide (CN−) ion and exhibited naked eye changes accompanied by “turn-off” fluorescence behavior. The introduction of CN− ion into the probe solution shows a visible color change from yellow to blue. Further, the optical methods were employed to determine the sensing performance of probe 1 towards CN− ion. The CN− ion detection limit was 5.47 μM with a binding constant of 1.52 × 105 M−1. The fluorescence quenching efficiency towards cyanide ion was found to be 73.21 %, with the Stern-Volmer quenching constant to be 1.22 × 105 M−1. Job's plot analysis revealed 1:1 stoichiometric binding between probe 1 and CN− ion, further supported by FT-IR analysis, mass analysis, 1H NMR titrations, and TD-DFT study. Probe 1 finds its practical application for detecting CN− ion using the test strip method. In addition, chemically switchable fluorescent dyes provide helpful building blocks for developing intricate molecular devices that communicate via adjustments in their emission characteristics; therefore, probe 1 was also used to establish molecular logic gates.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"581 ","pages":"Article 122615"},"PeriodicalIF":2.7,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143592247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A one-dimensional co-based coordination polymer: Synthesis, crystal structure and nonenzymatic electrochemical sensing for glucose

IF 2.7 3区化学

Inorganica Chimica Acta Pub Date : 2025-03-03 DOI: 10.1016/j.ica.2025.122626

Yonghua Zhang, Cancan Shi, Shuqi Wang, Yufang Wang

{"title":"A one-dimensional co-based coordination polymer: Synthesis, crystal structure and nonenzymatic electrochemical sensing for glucose","authors":"Yonghua Zhang, Cancan Shi, Shuqi Wang, Yufang Wang","doi":"10.1016/j.ica.2025.122626","DOIUrl":"10.1016/j.ica.2025.122626","url":null,"abstract":"<div><div>A new one-dimensional Co-based coordination polymer (CP), namely, [Co(Hbta2−)(L)] (Co-CP) (H3bta = 1,3,5-benzenetricarboxylic acid and L = 4̕ -(4-(1H-imidazol-1-yl)phenyl)-2,2′:6–2″-terpyridine) was successfully prepared through the simple one-step solvothermal method. Co(II) is five-coordinated with two carboxylate oxygen atoms from two different Hbta2− ligands and three nitrogen atoms from one L ligand. Hbta2− and L coordinate with cobalt to form a one-dimensional chain by carboxyl groups bridging, and the one-dimensional chains interconnected by strong hydrogen bonding interactions to generate a two-dimensional layer, which is further extended by π-π stacking interactions into a three-dimensional supramolecular architecture. N-rich L ligands enhance the electrochemical properties of coordination polymer. Cyclic voltammetry (CV) and amperometric investigation exhibited that the Co-CP showed excellent nonenzymatic electrochemical sensing performance toward glucose. The Co-CP modified electrode offered a wide linear range from 20 μM to 19.7 mM in three segments and a low detection limit of 5 μM (S/N = 3). The electrochemical glucose sensor also exhibited excellent stability.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"581 ","pages":"Article 122626"},"PeriodicalIF":2.7,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143551756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Coordination behaviour of a family of o-xylene-based hybrid P,E ligands with platinum(II) and platinum(0)

IF 2.7 3区化学

Inorganica Chimica Acta Pub Date : 2025-03-03 DOI: 10.1016/j.ica.2025.122622

Kathryn M. Allan , John L. Spencer

{"title":"Coordination behaviour of a family of o-xylene-based hybrid P,E ligands with platinum(II) and platinum(0)","authors":"Kathryn M. Allan , John L. Spencer","doi":"10.1016/j.ica.2025.122622","DOIUrl":"10.1016/j.ica.2025.122622","url":null,"abstract":"<div><div>The coordination chemistry of a family of hybrid P,E ligands of the type, o-C6H4(CH2PBut2)(CH2E) (E = SBut (1), S(=O)But (2), NMe2 (3)), with Pt(II) and Pt(0) precursors has been investigated. Both monodentate and chelating bonding modes were observed, along with a number of examples of hemilabile behaviour. Chelated [PtCl2(P,S)] and [PtCl2(P,N)] complexes have been synthesised, and unusual reactivity between [PtCl2(1,5-hexadiene)] and ligand 2 or 3 has been observed, resulting in σ:η2-bound phosphonium complexes. Three [PtH2(P,E)2] complexes were prepared, and in the case of ligand 1, derivatised to a number of [PtHL(P,S)2]CH(SO2CF3)2 complexes (L = CO, NCMe, 1,3,5-triaza-7-phosphaadamantane). One of these complexes, [PtH(NCMe)(P,S)2]CH(SO2CF3)2, undergoes reversible dissociation of MeCN resulting in chelation of one of the P,S ligands. Reactions with Pt(0) precursor complexes resulted in the first examples of chelated [Pt(alkene)(P,S)] and [Pt(alkene)(P,S=O)] complexes, and 14-electron [Pt(P,E)2] complexes of all three ligands.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"581 ","pages":"Article 122622"},"PeriodicalIF":2.7,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143577964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Encapsulating Rhodamine 6G in a new anionic in-based metal-organic framework to realize pure white light emission

IF 2.7 3区化学

Inorganica Chimica Acta Pub Date : 2025-03-02 DOI: 10.1016/j.ica.2025.122619

Hao-Yu Zhu , Suo Peng , Li-Jun Xue , Yi Zhang , Wei-Min Chen , Lu Xue , Fang-Ming Wang , Li-Li Wen

引用次数: 0

Construction of dual-ligand samarium(III)-MOF fluorescent sensor: An efficient platform for selectivity detection of antibiotic tetracycline

IF 2.7 3区化学

Inorganica Chimica Acta Pub Date : 2025-03-02 DOI: 10.1016/j.ica.2025.122624

Pengchao Wu , Hongxi Li , Xiaoyang Zhao , Wenyuan Zhao

{"title":"Construction of dual-ligand samarium(III)-MOF fluorescent sensor: An efficient platform for selectivity detection of antibiotic tetracycline","authors":"Pengchao Wu , Hongxi Li , Xiaoyang Zhao , Wenyuan Zhao","doi":"10.1016/j.ica.2025.122624","DOIUrl":"10.1016/j.ica.2025.122624","url":null,"abstract":"<div><div>The proliferation of antibiotic resistance associated with tetracycline (TC) has emerged as a significant threat to global public health and safety. Therefore, the accurate quantification of TC concentrations and assessment of its environmental impact are critical steps in evaluating pollution risks. However, the development of portable and practical methods for detecting tetracycline (TC) in aquatic environments remains a significant challenge. Herein, a samarium-based metal-organic framework (Sm-MOF) was constructed through a solvothermal approach, utilizing pyromellitic acid (H4BTEC) and nicotinic acid (HNTCA) as dual ligands. The resulting 3D framework was stabilized through a synergistic interplay of coordination bonds and hydrogen bonding interactions, endowing the structure with exceptional stability for functional applications. Notably, the Sm-MOF exhibited a distinct fluorescence quenching response upon selective recognition of TC, even in the presence of multiple interfering species, highlighting its potential for precise detection in complex environments. The experimental results demonstrated that the Sm-MOF exhibited significant potential as a highly effective sensor material for TC detection, characterized by its rapid response time, exceptional anti-interference performance, and excellent recyclability. Moreover, DFT calculations revealed that the fluorescence quenching mechanism of Sm-MOF for TC was primarily governed by fluorescence resonance energy transfer (FRET) and photoinduced electron transfer (PET).</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"581 ","pages":"Article 122624"},"PeriodicalIF":2.7,"publicationDate":"2025-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143577753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Syntheses, crystal structures, and magnetic properties of cyanido-bridged one- and two-dimensional Ln(III)-Fe(III) coordination polymers

IF 2.7 3区化学

Inorganica Chimica Acta Pub Date : 2025-03-01 DOI: 10.1016/j.ica.2025.122621

Hao-Yi Huang , Hong Li , Xingwei Cai , Shuyang Chen , Shaojun Zheng , Lulu Li , Peipei Cen , Lei Chen

{"title":"Syntheses, crystal structures, and magnetic properties of cyanido-bridged one- and two-dimensional Ln(III)-Fe(III) coordination polymers","authors":"Hao-Yi Huang , Hong Li , Xingwei Cai , Shuyang Chen , Shaojun Zheng , Lulu Li , Peipei Cen , Lei Chen","doi":"10.1016/j.ica.2025.122621","DOIUrl":"10.1016/j.ica.2025.122621","url":null,"abstract":"<div><div>Two new heterometallic coordination polymers, [Dy(TPA)Fe(CN6)(H2O)2]·4H2O (1-Dy) and [Gd2(TPA)2Fe2(CN6)2(CH3OH)2]·8.5H2O (2-Gd) were synthesized by reacting DyCl3·6H2O with K3[Fe(CN)6] and tri[(2-pyridyl)methyl]amine (TPA). The structures of both complexes were established by single crystal X-ray diffraction. Polymer 1-Dy exhibits a one-dimensional (1D) chain structure formed by [Fe(CN)6]3− bridging the [Dy(TPA)(H2O)2]3+ units. For polymer 2-Gd, each [Fe(CN)6]3− unit is connected to three [Gd(TPA)(CH3OH)]3+ units through three nearly coplanar CN groups, forming a near-rectangular grid Gd2Fe2. These Gd2Fe2 extend to generate a 2-dimensional (2D) monolayered topology, which represents a cyclic formation of a novel grid structure. Hydrogen bonding interactions via water molecules stabilize both structures. Magnetic susceptibility measurements indicate weak antiferromagnetic interactions between Ln(III) and Fe(III) ions, with Fe(III) and Ln(III) centers behaving as nearly isolated magnetic entities.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"581 ","pages":"Article 122621"},"PeriodicalIF":2.7,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143563296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Water-phase synthesis of nano-hierarchical porous metal–organic frameworks for removal of uranium (VI) from aqueous solution

IF 2.7 3区化学

Inorganica Chimica Acta Pub Date : 2025-03-01 DOI: 10.1016/j.ica.2025.122623

Kai Zheng , Kaikai Zhao , Weibiao Guo , Xuquan Liu , Yu Liang , Kuan Liang , Qianjun Deng , Hongxia Xi , Pengfei Yang , Xuejiao Sun , Chongxiong Duan

{"title":"Water-phase synthesis of nano-hierarchical porous metal–organic frameworks for removal of uranium (VI) from aqueous solution","authors":"Kai Zheng , Kaikai Zhao , Weibiao Guo , Xuquan Liu , Yu Liang , Kuan Liang , Qianjun Deng , Hongxia Xi , Pengfei Yang , Xuejiao Sun , Chongxiong Duan","doi":"10.1016/j.ica.2025.122623","DOIUrl":"10.1016/j.ica.2025.122623","url":null,"abstract":"<div><div>With the increasing reliance on nuclear energy and the potential environmental release of uranium radionuclides, public concern regarding uranium pollution has steadily grown. Metal-organic frameworks (MOFs), known for their abundant active sites and unique porous structures, exhibit significant promise in addressing uranium-related challenges. In this study, a nano-hierarchical porous structure of Cu-BTC (NH-Cu-BTC) was synthesized at room temperature and atmospheric pressure, utilizing N,N-dimethylethylenediamine as a templating agent in the aqueous phase. The impact of activation on the porosity characteristics of NH-Cu-BTC was investigated. The as-synthesized NH-Cu-BTC possessed micropores, mesopores, and macropores, with crystal sizes approximately 150 nm. Through simulation calculations, the electrostatic potential and orbital energies of the templating agent molecule were analyzed to elucidate the synthesis mechanism. Various factors influencing the adsorption of uranium (VI) by NH-Cu-BTC, including pH, contact time, and temperature, were explored, and the underlying adsorption mechanisms were elaborated. Compared to C-Cu-BTC, NH-Cu-BTC exhibited a 32.8 % enhancement in its adsorption capacity for uranium (VI). This investigation furnishes precious comprehension regarding the fabrication and utilization of porous substances, proffering a novel tactic for proficiently eliminating uranium (VI) from aqueous mediums.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"581 ","pages":"Article 122623"},"PeriodicalIF":2.7,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143551757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0