Inorganica Chimica Acta最新文献

{"title":"A multifunctional metal–organic complex fluorescent probe for highly sensitive detection of lysine, CrO42-/Cr2O72-, Fe3+ and nitro-aromatic compounds","authors":"Jingze Wang,&nbsp;Yun Zhao,&nbsp;Linhan Fan,&nbsp;Jingyue Zhang,&nbsp;Changyan Sun,&nbsp;Wenjun Li,&nbsp;Zhidong Chang","doi":"10.1016/j.ica.2024.122415","DOIUrl":"10.1016/j.ica.2024.122415","url":null,"abstract":"<div><div>Water contamination caused by organic and inorganic compounds represents an urgent global issue. It is meaningful to detect these compounds. A metal–organic complex (Zn-HTBA) was investigated as a multifunctional fluorescent probe which showed exceptional fluorescence characteristics. The Zn- HTBA can specifically detect lysine in water through fluorescence enhancement, and the detection limit was 0.17 μM. The Zn-HTBA also selectively detect CrO₄^2-/Cr₂O₇^2- and Fe³⁺ with the detection limits of 0.014/0.022 and 0.12 μM through fluorescence quenching. In addition, the Zn-HTBA was found to sensitively detect nitroaromatic compounds in ethanol through fluorescence quenching. The possible detection mechanisms were studied in detail through UV–Vis, PXRD, XPS, etc. The mechanism of Zn-HTBA to detect CrO₄^2-/Cr₂O₇^2-, Fe³⁺ and 2-nitrotoluene was energy competition, and the mechanism of Zn-HTBA to detect lysine was the formation of hydrogen bonds.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"574 ","pages":"Article 122415"},"PeriodicalIF":2.7,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142535076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, general physicochemical behaviour and magnetic studies of the macrocyclic bis-pyridine derivatives [TTDPzM(py)2]·2H2O (M = MnII, CoII, NiII)","authors":"Maria Pia Donzello ,&nbsp;Luca Visentin ,&nbsp;Marcus J. Giansiracusa ,&nbsp;Ida Pettiti ,&nbsp;Andrea Angelucci ,&nbsp;Claudio Ercolani ,&nbsp;Keith S. Murray","doi":"10.1016/j.ica.2024.122409","DOIUrl":"10.1016/j.ica.2024.122409","url":null,"abstract":"&lt;div&gt;&lt;div&gt;In our extensive work on phthalocyanine-like macrocycles carrying peripherally attached strongly electron-withdrawing 1,2,5-thia/selenodiazol rings we recently reported on the Fe&lt;sup&gt;II&lt;/sup&gt; species of formula [TTDPzFe(py)&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;.&lt;/sup&gt;2H&lt;sub&gt;2&lt;/sub&gt;O (TTDPz = tetrakis(thiadiazole)porphyrazinato dianion). The present work deals with the synthesis and extended physicochemical studies of the series of related macrocycles [TTDPzM(py)&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;.&lt;/sup&gt;2H&lt;sub&gt;2&lt;/sub&gt;O (M = Mn&lt;sup&gt;II&lt;/sup&gt;, Co&lt;sup&gt;II&lt;/sup&gt;, Ni&lt;sup&gt;II&lt;/sup&gt;). The diffractograms of three solid samples of the Ni&lt;sup&gt;II&lt;/sup&gt; complex [TTDPzNi(py)&lt;sub&gt;2&lt;/sub&gt;]·2H&lt;sub&gt;2&lt;/sub&gt;O, obtained from different synthetic procedures, indicate that the species is reproducibly obtained. All three samples are isomorphous with each other as shown by their X-ray powder diffractograms. Based on the comparison of the IR spectra of [TTDPzNi(py)&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;.&lt;/sup&gt;2H&lt;sub&gt;2&lt;/sub&gt;O and the related desolvated [TTDPzNi], the IR absorption peaks belonging to the pyridine molecules could be identified. The systematic presence of the two water molecules in all three species suggests that forms of contact do exist in the form of hydrogen bonds between them and the S and N atoms present peripherally in the thiadiazole groups of the macrocyclic units. As regard to the elimination of water, the thermograms (in inert atmosphere in the range 25–600 °C) indicate in all cases that loss of water occurs below 100 °C but loss of pyridine occurs over a broad range 100–300 °C for the Mn&lt;sup&gt;II&lt;/sup&gt; and Co&lt;sup&gt;II&lt;/sup&gt; species whereas for the Ni&lt;sup&gt;II&lt;/sup&gt; complex it takes place in the narrow range 200–220 °C. In relation to the parallel series of metallophthalocyanines, i.e. [PcM] (M = Mn&lt;sup&gt;II&lt;/sup&gt;, Fe&lt;sup&gt;II&lt;/sup&gt;, Co&lt;sup&gt;II&lt;/sup&gt;), it is noted that the Ni&lt;sup&gt;II&lt;/sup&gt; analog has not been reported in the literature and in a direct experiment it has been proved that [PcNi] heated in pyridine is obtained unchanged, the different behavior for the Ni&lt;sup&gt;II&lt;/sup&gt; TTDPz derivative due to the electron withdrawing effect of the external thiadiazole substituents, which makes favorable axial pyridine coordination in the complex&lt;strong&gt;.&lt;/strong&gt; Completely insoluble in water, the triad of TTDPz derivatives is extremely low-soluble in non-donor or low donor solvents. This precluded any attempt to isolate single crystals for single-crystal X-ray work. Their UV–visible spectra show essential similarities in whatever organic solvent is used with clearly positioned Soret (300–400 nm) and Q-band absorptions (630–650 nm). Variable temperature magnetic susceptibility and magnetization studies reveal that the [TTDPzM(py)&lt;sub&gt;2&lt;/sub&gt;]&lt;sup&gt;.&lt;/sup&gt;2H&lt;sub&gt;2&lt;/sub&gt;O complexes all show paramagnetism with ground state spins of 3/2 (Mn&lt;sup&gt;II&lt;/sup&gt;), ½ (Co&lt;sup&gt;II&lt;/sup&gt;) and 1 (Ni&lt;sup&gt;II&lt;/sup&gt;), supported by fitting the data to spin Hamiltonian formalism, &lt;em&gt;vide infra&lt;/em&gt;. Comparisons are made with the magnetism of","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"575 ","pages":"Article 122409"},"PeriodicalIF":2.7,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142586672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Activation of persulfate by MOF-derived MnFeOx to efficiently degrade sulfadiazine: Synergistic effects from free radicals and singlet oxygen","authors":"Ruifu Han,&nbsp;Wenhao Zhao,&nbsp;Jiawei Wei,&nbsp;Chenglong Ge,&nbsp;Denghui Zhang,&nbsp;Wenqiang Jiang","doi":"10.1016/j.ica.2024.122407","DOIUrl":"10.1016/j.ica.2024.122407","url":null,"abstract":"<div><div>In this study, a facile hydrothermal approach was used to synthesize the MOFs materials [Mn-doped MIL-101(Fe)]. These materials were subsequently subjected to high temperature annealing process via calcination to generate the MOFs derivatives (MnFeO_x). The synthesized materials were utilized for the removal of sulfadiazine (SDZ) removal through activated peroxymonosulfate (PMS). At the optimum Mn doping, the removal ratio of SDZ could reach 98.9 % (at natural pH) within 20 min. In addition, the study investigated the influence of PMS dosage, catalyst dosage, initial pH, various inorganic anions, and humic acid (HA) on the degradation of SDZ. The activation processes of both free and non-free radicals in the MnFeO_x/PMS system were examined by free radical quenching experiments and electron paramagnetic resonance (EPR) techniques. The analysis of the degradation products of SDZ was conducted by using high performance liquid chromatography-mass spectrometry (HPLC-MS), and the breakdown pathways of SDZ in the MnFeO_x/PMS system were proposed.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"574 ","pages":"Article 122407"},"PeriodicalIF":2.7,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142535074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"AIE active Schiff base derived Pd(II) complex as a ratiometric sensor for fluoride ion","authors":"Indu Bala ,&nbsp;Kiran Singh ,&nbsp;Kiran ,&nbsp;Ramesh Kataria ,&nbsp;Jayant Sindhu","doi":"10.1016/j.ica.2024.122411","DOIUrl":"10.1016/j.ica.2024.122411","url":null,"abstract":"<div><div>A tripodal AIE active Schiff base (<strong>L4</strong>) was synthesized and utilized along with pyridine for the synthesis of Pd(II) metal complex (<strong>MH1</strong>) using a two-step process. X-ray diffraction studies were performed to establish the molecular geometry of the synthesized ligand (<strong>L4</strong>) and its metal complex (<strong>MH1</strong>), which revealed square planar geometry for the Pd(II) complex. DFT studies revealed a reduction in HOMO-LUMO gap upon complexation of the ligand with Pd(II) ion. The compound <strong>L4</strong> displayed aggregation induced emission and viscosity induced emission enhancement was observed in <strong>MH1</strong>. The developed metal complex was utilized for the sensitive and selective recognition of F⁻ ion through a ligand exchange reaction. A ratiometric “<em>turn-off</em>” response along with colorimetric change are the characteristic features of the Pd(II) complex (<strong>MH1</strong>). The probe revealed a binding constant of 1.4 * 10⁷ M⁻¹ as calculated using Benesi-Hildebrand equation. Moreover, the binding stoichiometry in the <strong>MH1</strong>-F⁻ complex was found to be 1:1. The sensing mechanism was established using mass spectrometry as the presence of fluoride incorporated complex was noticed. The structure of the resulting complex was also established using DFT based studies.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"574 ","pages":"Article 122411"},"PeriodicalIF":2.7,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142535078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Redox reaction of a RuIII(pic)3 complex with cysteine: Spectral, kinetic and biological studies","authors":"Olga Impert ,&nbsp;Oleksandra Pryshchepa ,&nbsp;Paweł Pomastowski ,&nbsp;Katarzyna Rafińska ,&nbsp;Debabrata Chatterjeec","doi":"10.1016/j.ica.2024.122401","DOIUrl":"10.1016/j.ica.2024.122401","url":null,"abstract":"<div><div>The kinetics of the reduction of [Ru^III(pic)₃] (pic⁻ = picolinate) with cysteine leading to the formation of the corresponding red coloured [Ru^II(pic)₃]⁻ complex (λ_max = 466 nm, ε_max = 12,000 M⁻¹ cm⁻¹) was studied by using stopped-flow and rapid scan spectrophotometry. The time course of the reaction was followed at 466 nm as a function of cysteine concentration, pH and temperature. Kinetic data (k = 291 ± 4 M⁻¹ s⁻¹ at 25 °C and pH 8.4) and activation parameters (ΔH^≠ = 36 ± 1 kJ mol⁻¹ and ΔS^≠ = −78 ± 3 J mol⁻¹ deg⁻¹) are interpreted in terms of a mechanism involving rate-determining outer-sphere electron transfer between Ru(III) and the cysteine. Inhibition of bacterial growth (<em>Klebsiella pneumonia</em> and <em>Staphylococcus aureus</em>) by the [Ru^III(pic)₃] complex both in absence and presence of cysteine has been examined, and the results show a positive effect of cysteine addition on the anti-bacterial activity of the complex for <em>S.<!--> <!-->aureus</em>.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"574 ","pages":"Article 122401"},"PeriodicalIF":2.7,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142535073","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and characterization of 3,5-bis((2-hydroxybenzylidene)amino)-N-(2-hydroxyphenyl)benzamide and Zn(II) complex: Investigation of chromic, fluorescence and DPPH radical scavenging behaviours","authors":"Özlem Güngör","doi":"10.1016/j.ica.2024.122410","DOIUrl":"10.1016/j.ica.2024.122410","url":null,"abstract":"<div><div>Novel amido-Schiff base 3,5-bis((2-hydroxybenzylidene)amino)-<em>N</em>-(2-hydroxyphenyl)benzamide (<strong>2a</strong>) has been obtained by the reaction of Schiff base <strong>1a</strong> with 2-hydroxyaniline in the presence of coupling agent <em>N,N′-</em>dicyclohexylcarbodiimide. Schiff base (<strong>1a</strong>) which serves as the starting compound in amide synthesis was produced from the condensation of 3,5-diaminobenzoic acid with salicylaldehyde in a 1:2 mol ratio. Tetrahedral geometry with 1:1 [M:L] stoichiometry Zn(II) complex (<strong>3a</strong>) was newly synthesized by the complexation reaction of ligand <strong>2a</strong> with zinc(II) nitrate. <strong>1a</strong> and <strong>2a</strong> displayed a broad emission band at λ_em = 456 and 472 nm with a blue fluorescent in pure DMSO, while <strong>3a</strong> emitted a strong greenish-blue fluorescent with the λ_em = 485 nm (λ_exc = 365 nm). The fluorescence efficiency of <strong>1a</strong> was poor compared to the others. The λ_em in aqueous DMSO solution (v/v, 1:1) had ∼8–33 nm red-shift with respect to that of pure solution. The λ_em gave ∼1–15 nm red-shift with very low emission efficiency in acidic DMSO media. The results suggested that the aggregation caused quenching properties of <strong>1a–3a</strong> in pure, aqueous, and acidic DMSO system with a 50 % water fraction. The fluorescence of the compounds appeared to be visibly very bright in basic DMSO media. All the compounds were also screened for antioxidant activity using UV–Vis spectroscopy. They were found to be not effective DPPH radical scavengers in DMSO.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"574 ","pages":"Article 122410"},"PeriodicalIF":2.7,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142445859","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, Characterization, Crystal structure determination and DFT study of a six coordinated Cu (II) complex of a phosphorous based tris-(2-pyridinylamino) phosphene sulphide ligand and its acid catalysed hydrolysis","authors":"Aswini Kalita ,&nbsp;Lakhminandan Goswami ,&nbsp;Pankaj Gogoi ,&nbsp;Subrata Paul","doi":"10.1016/j.ica.2024.122408","DOIUrl":"10.1016/j.ica.2024.122408","url":null,"abstract":"<div><div>One mono nuclear copper(II) complex (Cu-TPPS-OOCCH₃ with structural formula C₁₇H₁₉CuN₆O₃PS) is synthesized using a novel tripodal tetradentate ligand, tris-(2-pyridinylamino)phosphene sulphide (TPPS), which has three pyridinylamino groups attached to a phosphorus atom connected to a sulphur atom (P<img>S). The equatorial positions of the complex are occupied by three amino <em>N</em>-atoms of three aminopyridyl groups and one O-atom of the acetate group. The apical position is occupied by other O-atom of acetate group and one secondary <em>N</em>-atom of the tripodal ligand. The complex has been synthesized and purified as green solid and characterized by various spectroscopic techniques and the structure has been determined by X-ray single crystal diffraction study. The geometry optimizations and calculations of energies of the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) of the compounds are performed by using the hybrid B3LYP density functional theory (DFT) along with the def2TZVP basis set.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"574 ","pages":"Article 122408"},"PeriodicalIF":2.7,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142445861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The crystal structures of Imine-Enamine ‘tautomerism’ in solid state and “turn on” sensing for Zn2+: spectroscopy, DFT and cell imaging studies","authors":"Gopal C. Das ,&nbsp;Bhriguram Das ,&nbsp;Urmila Saha ,&nbsp;Surya Kanta Dey ,&nbsp;Sujata Maiti Choudhury ,&nbsp;Paula Brandao ,&nbsp;Asma A. Alothman ,&nbsp;Saikh M. Wabaidur ,&nbsp;Malay Dolai","doi":"10.1016/j.ica.2024.122404","DOIUrl":"10.1016/j.ica.2024.122404","url":null,"abstract":"<div><div>The crystallographically established ligand 2-((E)-(benzyl imino)methyl)-4-bromophenol (HL) (existing keto at 296 K and enol at 120 K in the solid state), which is in equilibrium of interconversion (ΔE) = 4.39Kcal) with its tautomer, showed weak emission in the excited state, due to the fact of PET but in the presence of Zn²⁺, PET was blocked and chelation-enhanced fluorescence (CHEF) was set up. It exhibits 'turn on' sensor with the coordination of Zn²⁺. Among various metal ions, the synthesised probe HL selectively detected Zn²⁺ and LOD was about to ∼ 1.63 µM. The Zn(II) coordinated complex and the relative stabilities of the tautomers of HL were thoroughly calculated by spectroscopic and computational studies. Furthermore, cell imaging was also performed to validate the sensing property as well as cyto-toxicity of the probe.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"574 ","pages":"Article 122404"},"PeriodicalIF":2.7,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142445860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"An overview of the synthesis, structure and different applications of hetero-nuclear complexes of different transition metals and sodium with salen type compartmental ligands","authors":"Puspendu Middya ,&nbsp;Sougata Das ,&nbsp;Shouvik Chattopadhyay","doi":"10.1016/j.ica.2024.122405","DOIUrl":"10.1016/j.ica.2024.122405","url":null,"abstract":"<div><div>Salen-type compartmental ligands, prepared by the 1:2 condensation of a diamine and a salicylaldehyde derivative, have been used in the synthesis of a variety of hereto-nuclear complexes with several transition and non-transition metals. This review focuses light on the synthesis of different hetero-nuclear transition metal/Na complexes with these ‘salen type’ compartmental Schiff base ligands. The X-ray structures, properties and different applications of these complexes are also discussed. The less explored area is also highlighted.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"574 ","pages":"Article 122405"},"PeriodicalIF":2.7,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142535077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Formation of zinc tetraammine difluoride and dinitrate and conversion to zinc oxide and zinc hydroxyfluoride under ambient conditions","authors":"Jacqueline Cuen,&nbsp;Andrew Witty,&nbsp;Minkyeong Choi,&nbsp;Nathan Shtilerman,&nbsp;Trinanjana Mandal,&nbsp;Marc Walters","doi":"10.1016/j.ica.2024.122402","DOIUrl":"10.1016/j.ica.2024.122402","url":null,"abstract":"<div><div>The zinc tetraammine complexes [Zn(NH₃]₄]F₂ (ZAF) and [Zn(NH₃]₄](NO₃)₂ (ZAN) have been isolated from methanolic ammonia and characterized by single crystal X-ray diffraction and Raman spectroscopy. As determined from Raman data, the tetrahedral structure of the zinc tetraammine cation complex is sustained in solutions that contain high concentrations of ammonia. Dilution of ZAF or ZAN solutions in bulk water results in the deposition of ZnO as determined by X-ray powder diffraction (XRD). Lower dilution, as when aqueous ZAF is applied to wet surfaces, results in Zn(OH)F deposition as identified by XRD. These mineral products are readily obtained from zinc tetraammine solutions under ambient conditions and lend themselves to biomedical and materials applications.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"574 ","pages":"Article 122402"},"PeriodicalIF":2.7,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142535079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}