在罗丹明B降解过程中,通过非自由基途径在泡沫镍上原位生长CoP以活化过氧单硫酸盐

IF 2.7 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR
Xiaoyu Qiu, Zhimei Li, Jianmei Cen, Hong Tang
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引用次数: 0

摘要

过渡金属基材料是一种很有前途的催化剂,用于过氧单硫酸盐(PMS)的活化去除污染物。然而,纳米材料团聚、高金属离子浸出和低活性氧(ROS)产率等挑战仍然阻碍了它们的实际应用。在这项工作中,成功合成了CoP/NF,将PMS的激活从自由基途径调整为非自由基主导途径,以有效降解有机污染物。磷元素的掺入调节了钴基催化剂的表面电荷状态,诱导了局部电荷密度,提高了催化活性。结果表明,在最佳条件下(催化剂= 1.5 cm2, PMS = 0.3 g/L),在较宽的pH(3.0-9.0)范围内,CoP/NF在2 min内几乎完全去除40 mg/L罗丹明B (RhB),并保持了对NO3−,PO42−,Cl−的较强的抗干扰能力。此外,在CoP/NF + PMS体系中,RhB的降解效率在5个循环后仍保持在98%。活性氧捕获和电子自旋共振(EPR)分析表明,超氧自由基(O2•-)和单重态氧(1O2)是CoP/NF + PMS体系降解的主要机制。这项工作为通过金属磷化物在泡沫镍上的生长来调节PMS活化途径提供了进一步的见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
In situ growth of CoP on nickel foam for peroxymonosulfate activation via non-radical pathways in rhodamine B degradation
Transition metal-based materials have emerged as a promising catalyst for peroxymonosulfate (PMS) activation in pollutant removal. However, challenges such as nano-material agglomeration, high metal ion leaching, and low reactive oxygen species (ROS) yield still hinder their practical application. In this work, the CoP/NF successfully was synthesized to tune PMS activation from a radical pathway to a non-radical dominated pathway for efficient degradation of organic pollutants. The incorporation of phosphorus element modulated the cobalt-based catalyst surface charge state and induced local charge density, facilitating the catalytic activity. Consequently, at optimal conditions (catalyst = 1.5 cm2, PMS = 0.3 g/L), CoP/NF achieved nearly complete removal of 40 mg/L rhodamine B (RhB) within 2 min over a wide pH (3.0–9.0), and maintained a strong anti-interference capacity for NO3, PO42−, Cl. Furthermore, the degradation efficiency of RhB in the CoP/NF + PMS system remained 98 % even after 5 cycles. Impressively, ROS trapping and electron spin resonance (EPR) analyses revealed that the degradation process was dominantly driven by superoxide radicals (O2•–) and singlet oxygen (1O2), which served as the key mechanism for the CoP/NF + PMS system. This work provided further insights into tuning PMS activation pathway via the integration of metal phosphides growth on nickel foam for sustainable water treatment.
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来源期刊
Inorganica Chimica Acta
Inorganica Chimica Acta 化学-无机化学与核化学
CiteScore
6.00
自引率
3.60%
发文量
440
审稿时长
35 days
期刊介绍: Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews. Topics covered include: • chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies; • synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs); • reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models; • applications of inorganic compounds, metallodrugs and molecule-based materials. Papers composed primarily of structural reports will typically not be considered for publication.
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