B. Digvijay, J. Amala, S. Aravind, S. Bhuvaneshwari, P. Mohanraj
{"title":"CuxO/Cu based electrochemical sensor for the detection of CO2 gas","authors":"B. Digvijay, J. Amala, S. Aravind, S. Bhuvaneshwari, P. Mohanraj","doi":"10.1080/00194506.2022.2114947","DOIUrl":"https://doi.org/10.1080/00194506.2022.2114947","url":null,"abstract":"ABSTRACT Industrialization and urbanization have primarily contributed to air pollution, necessitating the need for the development of better sensing devices. Unlike other gases, Carbon dioxide (CO2) is more stable in the environment and poses a serious threat to the environment and health. Thus, the detection of CO2 gas becomes imperative. In the present work, a 3-electrode electrochemical cell was developed to detect CO2 gas. The working electrode (CuxO/Cu) was prepared by anodization of copper foil and the characterization studies has been done using XRD, SEM and FTIR techniques. The quantitative analysis of CO2 gas was performed by electrochemical techniques such as Cyclic Voltammetry (CV) and TAFEL. The potential window for CV was between −0.6 V to 1 V and −2 V to 1 V for NaCl and KCl electrolyte, respectively. The sensor developed has lower response time and could detect CO2 gas of concentrations upto 8000 ppm in both electrolytes. The sensor with KCl electrolyte showed a better response than NaCl, with a reduction current density of 0.016A. GRAPHICAL ABSTRACT","PeriodicalId":13430,"journal":{"name":"Indian Chemical Engineer","volume":"64 1","pages":"479 - 493"},"PeriodicalIF":1.5,"publicationDate":"2022-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46845096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Particle sized distribution simulation for an industrial fluidised bed urea granulator by PNB method considering non-uniform growth rate","authors":"H. Nemati, S. A. Shekoohi","doi":"10.1080/00194506.2022.2110525","DOIUrl":"https://doi.org/10.1080/00194506.2022.2110525","url":null,"abstract":"ABSTRACT The present work is an extension of the PNB method. Contrary to the previous works, it is assumed that the growth rate of particles/granules is not constant along the granulator length and it depends on the granule mass flow rate and molten urea spray mass flowrate. With these assumptions, the governing equations were extracted, and the analytical solution was derived. Since this method is based on the particle number and the measured data are mass-based (defined based on mass fraction distribution), a general procedure was also proposed to transfer between number-based and mass-based quantities. Finally, the results were compared with measured data taken from a large-scale industrial urea granulator and close agreements were observed. This method is introduced as an effective tool for the simulation of other applications, like driers. GRAPHICAL ABSTRACT","PeriodicalId":13430,"journal":{"name":"Indian Chemical Engineer","volume":"65 1","pages":"271 - 284"},"PeriodicalIF":1.5,"publicationDate":"2022-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42223629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Simulation on non-ideal behaviour of plug flow bioreactor based on the growth study of Lactobacillus species","authors":"S. Sarkar, R. Chowdhury","doi":"10.1080/00194506.2021.2008275","DOIUrl":"https://doi.org/10.1080/00194506.2021.2008275","url":null,"abstract":"ABSTRACT The physical properties of a biological system vary with time due to the growth of biomass, and thus the flowability of such a medium inside any bioreactor also changes with time. The present study aims to study the non-ideal behaviour of a plug flow bioreactor (PFBR) under non-reactive conditions for a biological system. Different physical parameters of this study have been incorporated from the batch growth study of Lactobacillus sp. The growth of bacteria culture was simulated using a PVA solution to conduct residence time distribution (RTD) experiments in pulse and step mode. Different parameters of the dispersion model were measured, and the non-zero variance indicated that dispersion always occurred along the path of reaction which led to turbulence and diffusion. The Peclet No was non-infinite; thus, PFBR always deviates from the ideal behaviour of the plug flow reactor. During the velocity distribution study, it had also been established that the Peclet number was decreased with the increase of Reynolds Number at a certain medium viscosity. Moreover, the non-ideality of PFBR further increased due to the change of physical properties of the medium. Here, a polynomial relation had been established between the Peclet number and medium viscosity. Therefore, the current study might be a value addition towards the designing of the plug flow bioreactor. GRAPHICAL ABSTRACT","PeriodicalId":13430,"journal":{"name":"Indian Chemical Engineer","volume":"64 1","pages":"379 - 389"},"PeriodicalIF":1.5,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41905280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigating the tolerance of nano-filtration for the treatment of wastewater","authors":"K. Maheshwari, M. Agarwal, A. Ghosh","doi":"10.1080/00194506.2022.2101147","DOIUrl":"https://doi.org/10.1080/00194506.2022.2101147","url":null,"abstract":"ABSTRACT The textile industries generate highly concentrated and toxic waste streams which are disposed of without any pretreatment leading to environmental imbalances. Therefore, such waste streams need to be treated before directly discharging. This study explores the nano-filtration (NF) approach for dye effluent remediation. Congo red dye is the widely used chemical that imparts red colour to fabric and is highly toxic when emitted in a very minute amount of 3 mg/L. Therefore, a polyamide-based NF HFT-150 was implemented for the removal of Congo red dye (CD), noting the influences of feed pressure (1–12 kg/cm2) and inlet concentration (10–100 mg/L) used for examining the permeate flux in the process. It was reported that 99.7% removal was obtained at a feed pressure of 6 kg/cm2 with permeate flux of 7.9 mL/min cm2 for an initial concentration of 10 mg/L. Moreover, the samples from a small scale textile industry from Pali, Rajasthan, were collected, and the physicochemical properties were evaluated, revealing the total dissolved salts of 8560 mg/L. The collected sample was treated by NF HFT-150, indicating that potentially strong discolouration was reported at 6 kg/cm2 feed pressure. Therefore, it can be suggested that nano-filtration could be efficiently implemented for textile effluent treatment. Highlights A polyamide-based NF HFT-150 was implemented for the removal of Congo red dye. A strong efficacy of 99.7% was obtained at a feed pressure of 6 kg/cm2. Wastewater samples from a small-scale textile industry from Pali, Jaipur Rajasthan, were collected. NF HFT-150 membrane resulted in strong discolouration of wastewater sample at 6 kg/cm2 feed pressure. GRAPHICAL ABSTRACT","PeriodicalId":13430,"journal":{"name":"Indian Chemical Engineer","volume":"65 1","pages":"213 - 220"},"PeriodicalIF":1.5,"publicationDate":"2022-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48671961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kevin Joseph Sam, Maya Suresh Nair, S. Velmurugan, R. Rajarathinam, L. Arumugam
{"title":"Extraction of lutein/zeaxanthin from Arthrospira Platensis and optimisation of the saponification process using the response surface methodology","authors":"Kevin Joseph Sam, Maya Suresh Nair, S. Velmurugan, R. Rajarathinam, L. Arumugam","doi":"10.1080/00194506.2022.2101146","DOIUrl":"https://doi.org/10.1080/00194506.2022.2101146","url":null,"abstract":"ABSTRACT This study explores the extraction of lutein and zeaxanthin from Arthrospira Platensis (spirulina), with traditional protocols as a reference and response surface methodology as a tool for optimisation. An enhanced extraction procedure was developed for obtaining higher lutein concentration. The extraction process is further optimised using the central composite method, with the aid of design software tools. Methanol was used as the extracting solvent in a fixed ratio with dry spirulina powder. Saponification and hydrolysis using KOH, water and ethyl acetate/dichloromethane were done for isolating lutein and zeaxanthin from its ester. Ultraviolet–visible spectrophotometry was used for analysing the absorbance of the lutein sample at a wavelength of 445 nm. Using the Response Surface Methodology, trials of various combinations are run for finding optimum conditions of saponification. The major variables were reaction time, reaction temperature and concentration of KOH. Temperature range of 45–75°C, the reaction time of 45–70 min and KOH concentrations ranging from 2% to 10% are observed as the optimum range. The sample is filtered using a PVDF membrane and stored in acetone or isopropyl alcohol. GRAPHICAL ABSTRACT","PeriodicalId":13430,"journal":{"name":"Indian Chemical Engineer","volume":"65 1","pages":"249 - 259"},"PeriodicalIF":1.5,"publicationDate":"2022-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47019444","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yasmin Thalji Cusin, W. Silvestre, G. Pauletti, L. Muniz
{"title":"Extraction of Citrus deliciosa Tenore petitgrain (leaf) essential oil by steam distillation under different operating pressures","authors":"Yasmin Thalji Cusin, W. Silvestre, G. Pauletti, L. Muniz","doi":"10.1080/00194506.2022.2101148","DOIUrl":"https://doi.org/10.1080/00194506.2022.2101148","url":null,"abstract":"ABSTRACT This work aimed to evaluate the effect of system absolute pressure on the yield and composition of petitgrain essential oil of Citrus deliciosa Tenore, extracted by steam distillation. The extractions were carried out at the absolute pressures of 760, 610, 460, and 310 Torr, for 1 h. The chemical composition of the essential oil was determined by GC/MS and GC-FID. According to the results, the reduction of pressure reduced essential oil yield, from 0.6% v/w at 760 Torr to 0.3% v/w at 310 Torr. Regarding the chemical composition, there was an increase in methyl N-methylanthranilate content with the reduction of system pressure, from 88.3 wt.% at 760 Torr to 97.6 wt.% at 310 Torr. However, it was observed a reduction in extraction efficiency due to the lower steam temperature. On the other hand, lower temperatures may imply a smaller degradation of thermolabile compounds. This process may be an alternative to other deterpenation techniques because it couples in a sole stage the extraction and purification/separation of essential oil components. GRAPHICAL ABSTRACT","PeriodicalId":13430,"journal":{"name":"Indian Chemical Engineer","volume":"65 1","pages":"260 - 270"},"PeriodicalIF":1.5,"publicationDate":"2022-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41823425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Mahalingam, Sofia Rani Shaik, L. Kaushik, M. Palanisamy, P. Kalita
{"title":"Design and Life Cycle Assessment of small-scale medical waste incinerator equipped with Porous Radiant Burner for remote areas","authors":"A. Mahalingam, Sofia Rani Shaik, L. Kaushik, M. Palanisamy, P. Kalita","doi":"10.1080/00194506.2022.2098180","DOIUrl":"https://doi.org/10.1080/00194506.2022.2098180","url":null,"abstract":"ABSTRACT In this paper, the design of a Small-scale Medical Waste Incinerator (SMWI) equipped with an LPG-operated Porous Radiant Burner (PRBLPG) is presented as a solution for disposing of medical waste generated in remote areas. Based on simple mass and heat balance analysis, SMWI having primary and secondary chambers with a volume of 1 and 0.754 m3 is designed. The proposed SMWI is evaluated for its environmental impact by performing a Life Cycle Assessment (LCA) and compared with an SMWI equipped with an Electric Heater (SMWI–EH). The total primary energy required for the construction of SMWI is 48285.56 MJ. It is found that the damage caused by the operation of PRBLPG in SMWI is lesser when compared to that of an Electric Heater (EH). In SMWI–PRB, LPG consumption contributed to about 17488.27 kg CO2−eq in the global warming category, whereas in the case of SMWI–EH, electricity consumption contributed to about 243766.11 kg CO2−eq. The operation of SMWI–PRB showed a reduction of about 54% in the resource utilisation category in comparison with SMWI–EH. The results obtained from the LCA study indicated that PRBLPG is a better option as an auxiliary heating device in SMWI than EH due to its environmental superiority. GRAPHICAL ABSTRACT","PeriodicalId":13430,"journal":{"name":"Indian Chemical Engineer","volume":"64 1","pages":"494 - 507"},"PeriodicalIF":1.5,"publicationDate":"2022-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44746991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Response surface methodology for optimisation of glycyrrhizic acid extraction from Glycyrrhiza glabra in the aqueous two-phase system","authors":"Kavita J. Lanjekar, V. Rathod","doi":"10.1080/00194506.2022.2085194","DOIUrl":"https://doi.org/10.1080/00194506.2022.2085194","url":null,"abstract":"ABSTRACT Glycyrrhizic acid (GA) is a natural sweetener obtained from Licorice (Glycyrrhiza glabra) and has numerous biological activities. In the present study, partitioning of GA in the polyethylene glycol (PEG)-salt aqueous two-phase system (ATPS) was optimised using the central composite design of response surface methodology (RSM). Effects of different operational parameters, such as salt concentration, pH, molecular weight of PEG, and concentration were studied to recover GA. The RSM predicted optimised conditions comprised 15.65% (w/v) of PEG 4000, 19.69% (w/v) of Sodium citrate and pH 8.0, yielding 28.39 mg/g GA. The close resemblance of the predicted and experimental yield of GA outlined the successful validation of the response model. In addition, the ATPS method offered lower energy, process time, cost economics and solvent consumption over conventional Soxhlet extraction. GRAPHICAL ABSTRACT","PeriodicalId":13430,"journal":{"name":"Indian Chemical Engineer","volume":"65 1","pages":"38 - 50"},"PeriodicalIF":1.5,"publicationDate":"2022-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45457016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Harshavardhana Krishna Kuruganti, V. Ramasubbaiah, J. Sreenivasulu, D. K. Behara
{"title":"Dairy waste scum as a potential feedstock for bio-diesel production: optimisation, quality and reliability studies","authors":"Harshavardhana Krishna Kuruganti, V. Ramasubbaiah, J. Sreenivasulu, D. K. Behara","doi":"10.1080/00194506.2022.2085193","DOIUrl":"https://doi.org/10.1080/00194506.2022.2085193","url":null,"abstract":"ABSTRACT Dairy waste scum obtained from the downstream milk production process is a potential source to produce biodiesel. It’s a less dense floating solid mass that primarily consists of triglycerides and fatty acids, which are important constituents for fuel. The present study aims to produce biodiesel using dairy waste scum by a transesterification process using NaOH/KOH catalysts. The present work identifies the better catalyst between two alkaline catalysts NaOH and KOH, using low-cost methodologies. The preliminary confirmation characteristics, such as density, calorific value, Kinematic Viscosity, Specific Gravity, Flash Point, and Fire Point will support the formation of synthesised biodiesel via the proposed methodology. The experimental results lead to a yield of 89.02% of biodiesel using NaOH catalyst with optimised process parameters of the temperature of 55°C, the reaction time of 120 min, and catalyst loading of 1 wt./wt.%. Finally, biodiesel was tested for emission and combustion characteristics in a CI engine. To optimise the process parameters, the response surface methodology (RSM) along with Bootstrap estimation has been performed using MINITAB19. Furthermore, the experimental and predicted yields obtained from ANOVA were reported.","PeriodicalId":13430,"journal":{"name":"Indian Chemical Engineer","volume":"65 1","pages":"25 - 37"},"PeriodicalIF":1.5,"publicationDate":"2022-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42332682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Leandro G. Gutierrez, P. Mancini, M. Kneeteman, C. Ferretti
{"title":"Transesterification of methyl salicylate with isoamyl alcohol assisted by microwave irradiation and promoted by acid-basic catalysts","authors":"Leandro G. Gutierrez, P. Mancini, M. Kneeteman, C. Ferretti","doi":"10.1080/00194506.2022.2085192","DOIUrl":"https://doi.org/10.1080/00194506.2022.2085192","url":null,"abstract":"ABSTRACT A procedure was studied for synthesising isoamyl salicylate by transesterifying methyl salicylate with isoamyl alcohol. The transesterification reaction was evaluated using catalysts with different acid-base properties in microwave irradiation or conventional heating. The amounts of methyl salicylate and isoamyl salicylate in samples were analysed by Gas Chromatography. Acids and neutral catalysts showed zero or shallow catalytic activity, while the most actives were the basic catalysts. Methyl salicylate conversions (higher than 60%) were obtained at 120°C in 4 h of reaction under the Microwave irradiation procedure, using 1% wt. Ca(OH)2, MeONa, or LiOH as catalysts. Under these optimised conditions, using LiOH as a catalyst, it could obtain yields of isoamyl salicylate of 98% in 4 h. Finally, under experimental conditions of isoamyl salicylate synthesis, LiOH did not present catalytic homogeneous contribution. GRAPHICAL ABSTRACT","PeriodicalId":13430,"journal":{"name":"Indian Chemical Engineer","volume":"65 1","pages":"90 - 100"},"PeriodicalIF":1.5,"publicationDate":"2022-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41754526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}