Hydrometallurgy最新文献

{"title":"A comparison of batch and semi-batch reactors for leaching battery cathodes (LiCoO2) under controlled addition of HCl and H2O2","authors":"Maria del Mar Cerrillo-Gonzalez,&nbsp;Maria Villen-Guzman,&nbsp;Alvaro Rivas-Bascon,&nbsp;Jose Miguel Rodriguez-Maroto,&nbsp;Juan Manuel Paz-Garcia","doi":"10.1016/j.hydromet.2024.106334","DOIUrl":"10.1016/j.hydromet.2024.106334","url":null,"abstract":"<div><p>Recovery of cobalt and lithium from end-of-life Li-ion battery wastes have been evaluated in batch and semi-batch leaching systems. In this preliminary study, HCl and H₂O₂ were used as leaching and reducing agents, respectively. The comparison of batch and semi-batch processes was carried out, obtaining an improvement from 40% to 70% in the metal mass extracted (<em>i.e.</em> Co and Li) for semi-batch experiments under the same experimental conditions. Effects of the initial concentration of reducing and leaching agents were evaluated for a semi-batch system in which the acid was continuously fed to maintain a constant pH value. From experimental results, it was found that the concentration of H₂O₂ plays an important role in the leaching process in terms of selectivity. For the experiments carried out using 0.1 M of HCl and 1 M of H₂O₂, the percentage of Li and Co extracted was 90% for a leaching time of 30 min. The double-controlled addition of HCl and H₂O₂ to the semi-batch system allows the reduction of the H₂O₂ concentration to 0.5 M. The optimization of reactants entails not only the decrease of their consumption but also maximize the selectivity of the reactions desired, which represents promising results for the environmental sustainability of the process. Further work will examine the fate of chloride ions in the process.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"227 ","pages":"Article 106334"},"PeriodicalIF":4.7,"publicationDate":"2024-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0304386X24000744/pdfft?md5=3e6d24b99504ffed2e4c55717b4a0d2c&pid=1-s2.0-S0304386X24000744-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141037721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recovery of valuable metals from manganese purification sludge (SPS) containing Mn-Ni-Co sulfide and preparation of battery-grade Ni-Co-Mn sulfate solution","authors":"Leiting Yue ,&nbsp;Mingyu Wang ,&nbsp;Jia Li ,&nbsp;Wenjuan Guan ,&nbsp;Qinggang Li ,&nbsp;Zuoying Cao ,&nbsp;Shengxi Wu ,&nbsp;Guiqing Zhang","doi":"10.1016/j.hydromet.2024.106331","DOIUrl":"https://doi.org/10.1016/j.hydromet.2024.106331","url":null,"abstract":"<div><p>The manganese production industry produces a large amount of sulfide purification sludge (SPS) every year, representing a hazardous solid waste but also a valuable secondary resource for Ni, Co, and Mn. In this paper, the recovery of Ni, Co, and Mn from the SPS was achieved by (i) leaching with a solution of hydrogen peroxide, (ii) selectively extracting nickel, cobalt and manganese, (iii) solvent extraction for zinc removal, and finally obtained the battery-grade Ni-Co-Mn sulfate solution. During the hydrogen peroxide solution leaching stage, the leaching efficiency of Co, Mn, and Ni reached 98.5%, 98.6%, and 95.6%, respectively. A synergistic extraction system (SES) consisting of decyl 4-picolinate and dinonylnaphthalene sulfonic acid was used to selectively extract Ni, Co, and part of Mn, and the extraction of Ni and Co was &gt;99.8% and 95.5%, respectively. The loaded organic was subjected to four-stage countercurrent scrubbing using a 5 g/L H₂SO₄ solution, resulting in nearly 100% removal of Ca and Mg. After that, 150 g/L H₂SO₄ was used to strip Ni, Co, and Mn from the loaded organic to obtain a crude Ni-Co-Mn sulfate solution. Finally, D2EHPA was utilized for the extraction of impurity Zn from the stripping solution to obtain a battery-grade Ni-Co-Mn sulfate solution with &lt;5 × 10⁻⁴ g/L of Zn. Compared to traditional technology, the novel process not only enables the recovery of valuable Ni, Co, and Mn in SPS but also facilitates their direct preparation into battery-grade nickel‑cobalt‑manganese sulfate solution, which has the advantages of a short process and high added value.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"227 ","pages":"Article 106331"},"PeriodicalIF":4.7,"publicationDate":"2024-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140822217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multiscale modeling of reactive flow in heterogeneous porous microstructures","authors":"Akhilesh Paspureddi ,&nbsp;Rafael Salazar-Tio ,&nbsp;Ganapathi Raman Balasubramanian ,&nbsp;Abhijit Chatterjee ,&nbsp;Bernd Crouse","doi":"10.1016/j.hydromet.2024.106333","DOIUrl":"10.1016/j.hydromet.2024.106333","url":null,"abstract":"<div><p>This paper presents a multiscale reactive flow model to simulate in-situ leaching of copper in heterogeneous porous microstructures. The introduced workflow combines fluid flow simulation with advection-diffusion-reaction simulation, both required to model reactive flow. The proposed workflow can include the fluid flow in resolved and unresolved pore structures and utilizes required parameters from molecular simulation (ionic diffusivity) and reaction databases (reaction rate parameters). The modeling approach is validated by comparing results to other open-source codes for a model calcite dissolution on acid injection. This model is applied to copper mining by leaching to analyze the reactive flow through a fractured digital rock model of a subsurface sample. Results are analyzed by tracking the concentration distribution along the pore space structure and calculating the outlet concentration of copper to conform the leaching path. Several sensitivity studies are performed to show the robustness of the modeling framework as well as to investigate the importance of each of these parameters on copper production. The complexity of the model is systematically increased from a single scale surface reaction model, to consider the influence of competitive bulk solution reactions, and finally to include flow through porous media to model multiscale reactive flow. This study shows that a multi-scale flow model with homogeneous bulk and heterogeneous surface reactions is required to accurately model copper leaching.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"228 ","pages":"Article 106333"},"PeriodicalIF":4.7,"publicationDate":"2024-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141252933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Extraction and separation of strategic precious Ag from low-grade Mn-Ag ores in China: A short review of co-leaching and selective leaching processes","authors":"Bingbing Liu ,&nbsp;Chunyu Han ,&nbsp;Yizhuang Wang ,&nbsp;Shengpeng Su ,&nbsp;Yanfang Huang ,&nbsp;Hu Sun ,&nbsp;Guihong Han","doi":"10.1016/j.hydromet.2024.106316","DOIUrl":"https://doi.org/10.1016/j.hydromet.2024.106316","url":null,"abstract":"<div><p>Silver-bearing manganese ore (Mn-Ag ore) is an important resource for the extraction of the precious metal Ag. However, the efficient and economical utilization of low-grade Mn-Ag ore poses challenges due to its polymetallic co-occurrence, complex associated mineral structures, and lower Ag grade compared to an industrial Ag grade of 80 g/t. In contrast, the Ag grade of commercially viable concentrate, achieved through physicochemical beneficiation, generally exceeds 1000 g/t. This work briefly discusses the metallogeny and resource characteristics and the processing technologies of Mn-Ag ore to produce high grade Ag concentrates. Based on the metallogeny characteristics of Mn-Ag deposits, this work delves into the challenges and difficulties in the physical separation of Ag and Mn. By regulating the differences in the chemical properties of Mn and Ag constituents, chemical beneficiation processes, including unit operations of pyrometallurgy and hydrometallurgy, result in favorable Ag and Mn enrichment and separation. The chemical principles, technical parameters, Mn-Ag separation efficiency, and advantages and disadvantages of chemical beneficiation (blast furnace smelting, chlorination roasting, one-step leaching, and two-step leaching) were systematically summarized and discussed. This work can provide theoretical and technical guidance for the effective treatment of low-grade Mn-Ag ores.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"227 ","pages":"Article 106316"},"PeriodicalIF":4.7,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140807938","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Phase diagrams of CoSO4-H2O and CoSO4-H2SO4-H2O systems for CoSO4·nH2O (n = 6,7) recovery by cooling and eutectic freeze crystallization","authors":"Yiqian Ma ,&nbsp;Mohammadreza Akbarkermani ,&nbsp;Michael Svärd ,&nbsp;Xiong Xiao ,&nbsp;Suchithra Ashoka Sahadevan ,&nbsp;James Gardner ,&nbsp;Richard T. Olsson ,&nbsp;Kerstin Forsberg","doi":"10.1016/j.hydromet.2024.106332","DOIUrl":"https://doi.org/10.1016/j.hydromet.2024.106332","url":null,"abstract":"<div><p>This paper reports the solid-liquid phase equilibria of the CoSO₄-H₂O and CoSO₄-H₂SO₄-H₂O systems at low temperatures. Binary and ternary phase diagrams, including the stable solid phases CoSO₄·6H₂O and CoSO₄·7H₂O were established using experimental data and thermodynamic modeling applying the mixed-solvent electrolyte (MSE) model. The results showed that the addition of H₂SO₄ shifts the eutectic temperature and concentration to lower values for cobalt sulfate and ice crystallization. The trends obtained from the experimental data and the modeling are consistent for the binary CoSO₄-H₂O system with good agreement, but the ternary CoSO₄-H₂SO₄-H₂O system shows some deviations. In general, the MSE model is shown to be reliable for inferring and establishing the phase diagram of the low-temperature system. The phase diagrams are helpful for designing the pathways of cooling crystallization and eutectic freeze crystallization and assessing the performance of the low-temperature crystallization process in the production of CoSO₄ hydrates. In addition, some practical examples of cooling crystallization and eutectic freeze crystallization of CoSO₄ solutions are provided.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"227 ","pages":"Article 106332"},"PeriodicalIF":4.7,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0304386X24000720/pdfft?md5=74dc62e7f516b2e7f315451f2c999410&pid=1-s2.0-S0304386X24000720-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141066935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biosorption of gold(III) from leachates of waste printed circuit boards by baker's yeast","authors":"Shunpei Suzuki ,&nbsp;Haruka Iijima ,&nbsp;Yoshio Kobayashi ,&nbsp;Yojiro Yamamoto ,&nbsp;Hiroshi Shiigi ,&nbsp;Norizoh Saitoh ,&nbsp;Yasuhiro Konishi","doi":"10.1016/j.hydromet.2024.106323","DOIUrl":"10.1016/j.hydromet.2024.106323","url":null,"abstract":"<div><p>A microbial method using commercially available baker's yeast was developed for efficiently and selectively collecting aqueous Au(III) ions in aqua regia leachates from waste printed circuit boards (PCBs) through biosorption under air at temperatures ranging from 10 °C to 34 °C. Even when the total concentration of base metals was much higher than the initial Au concentration in the PCB leachate with high acid concentrations of 4.7–5.6 mol/L, commercial dry baker's yeast exhibited an excellent ability to selectively collect aqueous Au ions from the leachate within 60 min. When the biosorption test was repeated as a three-stage batch operation, the percentage biosorption of Au from the PCB leachate increased from 61% to 99% with 36 g/L dry yeast cells at 34 °C. The experimental results for the three-stage batch biosorption test were consistent with theoretical predictions based on the material balance of Au in multistage equilibrium operations and the distribution coefficient of Au. Equilibrium data of the Au biosorption conformed to the linear isotherm, regardless of the yeast concentration and the initial Au concentration in the leachate. The distribution coefficient <em>K</em>_Au at 34 °C decreased by 30%, from 53.7 to 37.3 L/kg-dry cells, as the total base metal concentration in the leachate was increased tenfold, from 1.94 to 16.4–19.1 g/L. Moreover, the distribution coefficient of Au at 10 °C to 34 °C was analyzed to determine thermodynamic parameters according to the van't Hoff equation. The thermodynamic studies indicated that the biosorption of aqueous Au ions by baker's yeast was spontaneous and exothermic.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"227 ","pages":"Article 106323"},"PeriodicalIF":4.7,"publicationDate":"2024-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140846098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Waste reduction and high value utilization of jarosite-alunite residue (JAR) produced from the recovery of spent lithium-ion battery","authors":"Wenke Liu ,&nbsp;Ping Li ,&nbsp;Qingwei Qin ,&nbsp;Wei Zhao ,&nbsp;Hailin Zhang ,&nbsp;Yunwu Han ,&nbsp;Feijie Wu ,&nbsp;Qiang Zhang ,&nbsp;Shili Zheng ,&nbsp;Guangqiang Li","doi":"10.1016/j.hydromet.2024.106322","DOIUrl":"10.1016/j.hydromet.2024.106322","url":null,"abstract":"<div><p>The residue known as jarosite-alunite (JAR) is produced when the leach solution of spent lithium-ion battery is neutralized. This residue typically consists of Fe, Al, Na₂SO₄, Ni, Co, and Mn. It is classified as both a hazardous solid waste and a secondary resource. A unique hydrometallurgical technique was implemented to recover Na₂SO₄ and use Al extracted from JAR in high value applications. This extraction process involves phase transformation and NaOH leaching, with the pH adjusted in the range from 10.9 to 14. Initially, the JAR compound underwent dissociation to isolate SO₄²⁻ as Na₂SO₄ by means of NaOH at a moderate pH, while the other metals were preserved as a hydroxide residue. Afterwards, aluminum in the hydroxide residue was selectively leached with NaOH leaving Ni, Co, and Mn in the remaining residue. The results indicated that over 93% of Na₂SO₄ and 86% of Al in JAR were effectively recovered as Na₂SO₄ and high value-added γ-AlOOH, respectively. Additionally, the enriched Ni, Co, and Mn in the alkaline leach residue were selectively recovered by H₂SO₄ leaching. The suggested procedure led to a significant decrease in waste by more than 67%, offering a fresh approach to effectively reduce waste and recover metals from JAR.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"228 ","pages":"Article 106322"},"PeriodicalIF":4.8,"publicationDate":"2024-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140782224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development of a conceptual direct solvent extraction (DSX) route and a flowsheet to produce purified concentrated cobalt and nickel solutions representing sulfuric acid leach liquor of laterite","authors":"Alexandre Silva Guimarães ,&nbsp;Georgio Patrício de Souza Resende ,&nbsp;Iranildes Daniel dos Santos ,&nbsp;Marcelo Borges Mansur","doi":"10.1016/j.hydromet.2024.106321","DOIUrl":"https://doi.org/10.1016/j.hydromet.2024.106321","url":null,"abstract":"<div><p>Direct solvent extraction (DSX) was applied to produce purified concentrated Ni and Co solutions from a synthetic sulfuric liquor containing Ca, Cu, Mg, Mn, and Zn as impurities, which simulates the solution obtained by the sulfation-roasting-leaching process after precipitation of Fe, Al, and Cr. The commercial extractants Versatic 10, Cyanex 272, D2EHPA, TBP were used in 3 solvent extraction circuits. In the first circuit, operated at 40 °C, Versatic 10 (0.5 M) fully extracted Cu, Zn, Ni, and Co in 3 stages at O/A = 2:1, and pH 6.5, leaving remaining Mn (54% was extracted) and most of the Ca and Mg in the raffinate. The co-extracted Ca and Mg were fully scrubbed off the loaded Versatic 10 in 2 stages at O/A = 5:1, and pH 6.5. The other metals were stripped out of the Versatic 10 extract using a synthetic Ni spent electrolyte (60 g/L Ni, 2 M H₂SO₄) in 2 stages at O/A = 9:1. This loaded strip liquor was subjected to a second circuit with Cyanex 272 (0.64 M) operated at 50 °C. Three stages were required to fully extract Co, Cu, Mn, and Zn (O/A = 2:1, pH 4), whereas the raffinate containing 82 g/L Ni was deemed suitable for electrowinning. The co-extracted Ni(II) was fully scrubbed off the loaded Cyanex 272 in only 1 stage at O/A = 5:1, and pH 4. All Co, Cu, Mn, and Zn were stripped out from the scrubbed loaded Cyanex 272 in 2 stages at O/A = 10:1 using a synthetic Co spent electrolyte (45 g/L Co, 1 M H₂SO₄). The raffinate containing 58.4 g/L Co was submitted to a third circuit using a D2EHPA (0.6 M) + TBP (0.73 M) synergistic system operated at 50 °C. Zinc(II) was fully extracted by the D2EHPA + TBP system in 2 stages at pH 2 and O/A = 1:3, while Mn(II) and Cu(II) were fully extracted from the Zn-depleted raffinate in 2 stages at pH 3.5 and O/A = 2:1. The raffinate containing 58.3 g/L Co was deemed suitable for electrowinning. Copper(II), Mn(II), and Zn(II) were stripped out from the loaded D2EHPA + TBP in 3 stages at O/A = 2.5:1 using 1 M H₂SO₄. The real number of moles of extractants involved in the extractions and apparent equilibrium constants were estimated for all circuits. A flowsheet of the purification conceptual route is presented.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"227 ","pages":"Article 106321"},"PeriodicalIF":4.7,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140645016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Simultaneous extraction of molybdenum and silicon from sulphate leach solution of spent catalyst using trialkylamine (N235) and recovery of pure ammonium molybdate","authors":"Wenhui Shi ,&nbsp;Jian Li ,&nbsp;Yaobin Lai ,&nbsp;Hui Zhang ,&nbsp;Huadong Zhang ,&nbsp;Xuxia Zhang ,&nbsp;Kejia Liu ,&nbsp;Tao Qi","doi":"10.1016/j.hydromet.2024.106308","DOIUrl":"10.1016/j.hydromet.2024.106308","url":null,"abstract":"<div><p>Spent catalyst of molybdenum with silicon dioxide, commonly used as the carrier, is an important secondary resource for recovery of molybdenum. This work proposes a process to recycle molybdenum and remove silicon simultaneously by solvent extraction. The sulfuric acid leachate of the spent catalyst was contacted with the trialkylamine N235 (R₃N, R = C₈–C₁₀), to extract molybdenum and silicon. Several vital parameters were investigated to explore the influence on extraction and stripping. The extraction efficiencies of molybdenum and silicon were up to 99.6% and 77.1% after three-stage countercurrent extraction under optimized condition. The extraction reactions were determined by maximum loading capacity and FT-IR. The peak at 802.1 cm⁻¹ was caused by the stretching vibration of Si-O-Si, indicating the co-extraction of silicon. Molybdenum and silicon in the loaded organic phase can be stripped by the mixture of solution containing 7.00 mol/L NH₄OH and 0.80 mol/L (NH₄)₂CO₃, and the stripping efficiencies were &gt;99.0%. Ammonium molybdate was prepared by removing silicon and evaporating, and the purity was 99.9%.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"227 ","pages":"Article 106308"},"PeriodicalIF":4.7,"publicationDate":"2024-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140780541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Behavior of calcium lignosulfonate under oxygen pressure acid leaching condition","authors":"Sijie Yang,&nbsp;Yuhu Li,&nbsp;Yudong Yang,&nbsp;Ran Liu,&nbsp;Yi Zhao","doi":"10.1016/j.hydromet.2024.106317","DOIUrl":"10.1016/j.hydromet.2024.106317","url":null,"abstract":"<div><p>The behavior of calcium lignosulfonate (CLS) in the oxygen pressure acid leaching process of ZnS concentrate was investigated using total organic carbon assessment (TOC), UV–visible spectrophotometry, Fourier transform infrared spectroscopy (FTIR), and gas chromatography-coupled mass spectrometry (GC–MS) as characterization methods. The effect of the CLS degradation products on zinc electrowinning was also discussed. The results showed that the temperature was positively correlated with the degradation of CLS, while the initial acidity had only significant effects in the range of 0–50 g/L and oxygen partial pressure range of 0–0.1 MPa. At an oxygen partial pressure of 0.2 MPa, an acidity of 160 g/L, and a reaction temperature of 150 °C, about 82.4% of CLS was degraded. In the oxygen pressure acid leaching process, CLS underwent polymerization and decomposition reactions, and its aromatic rings and side chain groups were damaged to varying degrees. At 120 °C, CLS was partially converted into sulfonic acids, phenols, and esters of higher molecular weights. At 150 °C, CLS further degraded into lower-molecular-weight aromatic ethers and sulfonic acids with shorter carbon chains. These organics were relatively stable and were the main sources of organic compounds during the oxygen pressure leaching process of zinc concentrates. The addition of CLS had a significant negative impact on zinc electrowinning, which was related to the adsorption of CLS on the cathode surface, enhancing cathodic polarization and inhibiting zinc reduction kinetics.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"227 ","pages":"Article 106317"},"PeriodicalIF":4.7,"publicationDate":"2024-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140759755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}