Asian Journal of Organic Chemistry最新文献

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Photocatalytic Cascade Alkylation/Cyclization of N‐Arylacrylamides with Simple Alkanes: A Convenient Approach to Quaternary C3 Alkylated Oxindoles
IF 2.8 4区 化学
Asian Journal of Organic Chemistry Pub Date : 2025-03-01 DOI: 10.1002/ajoc.202400554
Liang Ye , Haibin Xu , Jiong Yu , Han Yan , Min Wang , Pinhua Li
{"title":"Photocatalytic Cascade Alkylation/Cyclization of N‐Arylacrylamides with Simple Alkanes: A Convenient Approach to Quaternary C3 Alkylated Oxindoles","authors":"Liang Ye ,&nbsp;Haibin Xu ,&nbsp;Jiong Yu ,&nbsp;Han Yan ,&nbsp;Min Wang ,&nbsp;Pinhua Li","doi":"10.1002/ajoc.202400554","DOIUrl":"10.1002/ajoc.202400554","url":null,"abstract":"<div><div>A convenient and efficient protocol for the synthesis of 3,3‐dialkylated oxindoles through photocatalytic aerobic radical‐cascade alkylation/cyclization of <em>N</em>‐arylacrylamides with the alkyl radicals generated from simple alkanes is described. This method features a broad substrate scope, inexpensive alkyl radical precursors, simple conditions and good yields.</div></div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 3","pages":"Article e202400554"},"PeriodicalIF":2.8,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Promising Strategy for Searching High Energy Density Materials Based on 2,4,5‐Trinitro‐Imidazole Functional Backbone
IF 2.8 4区 化学
Asian Journal of Organic Chemistry Pub Date : 2025-03-01 DOI: 10.1002/ajoc.202400719
Wenjun Liu , Xinghui Jin , Fang Yuan , Yuexia Wang , Jianhua Zhou , Qiong Wu
{"title":"A Promising Strategy for Searching High Energy Density Materials Based on 2,4,5‐Trinitro‐Imidazole Functional Backbone","authors":"Wenjun Liu ,&nbsp;Xinghui Jin ,&nbsp;Fang Yuan ,&nbsp;Yuexia Wang ,&nbsp;Jianhua Zhou ,&nbsp;Qiong Wu","doi":"10.1002/ajoc.202400719","DOIUrl":"10.1002/ajoc.202400719","url":null,"abstract":"<div><div>A series of high energy density compounds are designed by altering the triazole, tetrazine, oxadiazole rings and energetic groups (such as −CN, −N<sub>3</sub>, −NH<sub>2</sub>, −NHNH<sub>2</sub>, −NO<sub>2</sub>, −NHNO<sub>2</sub>, −C(NO<sub>2</sub>)<sub>3</sub>, −CH(NO<sub>2</sub>)<sub>2</sub>) into 2,4,5‐trinitro‐imidazole skeleton. Their structures are optimized by density functional theory (DFT) methods at B3LYP/6‐311G (d,p) method. Based on the optimized structures, the impact of different rings and energetic groups on their energy gaps, heats of formation, detonation performance and sensitivities are investigated. The results show that compound F4 possesses the highest values of heats of formation due to their high nitrogen content. However, compound F2 possesses the highest values of detonation pressure and detonation velocity which indicates that the detonation performance are determined by values of density rather than those of heats of formation. Taking both detonation performance and impact sensitivities into consideration, compounds B4, C4, F4, I4, J4 and J8 are screened as high energy density compounds due to their excellent detonation performance and acceptable sensitivities compared to those of RDX. Finally, the distribution of frontier molecular orbital, the electrostatic potential area distribution, thermodynamic properties and weak interactions of the screened compounds are fully investigated.</div></div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 3","pages":"Article e202400719"},"PeriodicalIF":2.8,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ortho‐Selective Suzuki Coupling of Dichlorophenol and Dichlorobenzylalcohol in Water under Palladium Catalysis Directed by Noncovalent Interactions and Computational Analysis
IF 2.8 4区 化学
Asian Journal of Organic Chemistry Pub Date : 2025-03-01 DOI: 10.1002/ajoc.202400581
Shangxun Zhao , Shuo Wen , Hongrun Chen , Kewei Zhan , Jiawei Weng , Danli Ding , Xingwei Cai , Heng Song , Chen Xu
{"title":"ortho‐Selective Suzuki Coupling of Dichlorophenol and Dichlorobenzylalcohol in Water under Palladium Catalysis Directed by Noncovalent Interactions and Computational Analysis","authors":"Shangxun Zhao ,&nbsp;Shuo Wen ,&nbsp;Hongrun Chen ,&nbsp;Kewei Zhan ,&nbsp;Jiawei Weng ,&nbsp;Danli Ding ,&nbsp;Xingwei Cai ,&nbsp;Heng Song ,&nbsp;Chen Xu","doi":"10.1002/ajoc.202400581","DOIUrl":"10.1002/ajoc.202400581","url":null,"abstract":"<div><div>The use of attractive noncovalent interactions is emerging as a versatile approach to address site‐selectivity challenges. Herein, we report ortho‐selective Suzuki coupling reactions in water of 2,3‐dichloroarenes and 2,4‐dichloroarenes bearing a hydroxy group in the presence of a palladacycle catalyst and directed by noncovalent interactions. Various ortho‐substituted arylphenols and arylbenzyl alcohols were obtained in good to excellent yields with high selectivity. Density functional theory (DFT) calculations and ab initio molecular dynamics (AIMD) simulations suggested that the <em>ortho</em>‐selective Suzuki coupling of dichlorophenols and dichlorobenzyl alcohols occurred through electrostatic interactions and hydrogen bonding interactions, respectively.</div></div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 3","pages":"Article e202400581"},"PeriodicalIF":2.8,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622430","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
FeCl3‐Promoted Conjugate Reduction of Exocyclic α,β‐Unsaturated Ketones with Polymethylhydrosiloxane
IF 2.8 4区 化学
Asian Journal of Organic Chemistry Pub Date : 2025-03-01 DOI: 10.1002/ajoc.202400691
Yulong Zhang , Hang Wang , Bin Gu , Bowen Hu , Dr. Xiaoxue Tang , Prof. Dr. Yushuang Chen
{"title":"FeCl3‐Promoted Conjugate Reduction of Exocyclic α,β‐Unsaturated Ketones with Polymethylhydrosiloxane","authors":"Yulong Zhang ,&nbsp;Hang Wang ,&nbsp;Bin Gu ,&nbsp;Bowen Hu ,&nbsp;Dr. Xiaoxue Tang ,&nbsp;Prof. Dr. Yushuang Chen","doi":"10.1002/ajoc.202400691","DOIUrl":"10.1002/ajoc.202400691","url":null,"abstract":"<div><div>A new iron catalytic conjugate reduction of exocyclic α,β‐unsaturated carbonyl compounds with PMHS has been established for the first time. The reaction utilized PMHS as readily available, non‐toxic, and mild reductant that can be handled in open air. This protocol exhibits high compatibility with various substituents, and gives excellent yields, providing an environmentally benign and efficient access to construct synthetically useful α‐benzyl cyclic ketone scaffolds.</div></div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 3","pages":"Article e202400691"},"PeriodicalIF":2.8,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrostability of Boroxines
IF 2.8 4区 化学
Asian Journal of Organic Chemistry Pub Date : 2025-03-01 DOI: 10.1002/ajoc.202400683
Dr. Kosuke Ono
{"title":"Hydrostability of Boroxines","authors":"Dr. Kosuke Ono","doi":"10.1002/ajoc.202400683","DOIUrl":"10.1002/ajoc.202400683","url":null,"abstract":"<div><div>Boroxines, six‐membered heterocyclic compounds with alternating O and B atoms, are readily formed by dehydration of boronic acids, while it is also known to be readily hydrolyzed to boronic acids under wet conditions. Therefore, hydrolysis is one of major problems for boroxine‐based architectures and materials, although they have self‐healing properties that can be restored simply by dehydration. In recent years, interesting studies have been reported to improve the hydrostability of boroxines, with some boroxines being stable even in water. This review categorizes and summarizes the findings on the enhancement of the hydrostability of boroxines according to the methods used.</div></div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 3","pages":"Article e202400683"},"PeriodicalIF":2.8,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Blue‐LED Self‐Assembly‐Assisted Synthesis of New Photostable Organoboron Esters for Live‐Cell Imaging
IF 2.8 4区 化学
Asian Journal of Organic Chemistry Pub Date : 2025-03-01 DOI: 10.1002/ajoc.202400613
Mónica G. Flores‐Amaro , María C. García‐López , David A. Velázquez Hernández , Horacio Reyes‐Pérez , Valeria Villarreal‐García , Rosa Martha Jiménez‐Barrera , Rodrigo Chan‐Navarro , Vianey González‐Villasana , Diana Reséndez‐Pérez.
{"title":"Blue‐LED Self‐Assembly‐Assisted Synthesis of New Photostable Organoboron Esters for Live‐Cell Imaging","authors":"Mónica G. Flores‐Amaro ,&nbsp;María C. García‐López ,&nbsp;David A. Velázquez Hernández ,&nbsp;Horacio Reyes‐Pérez ,&nbsp;Valeria Villarreal‐García ,&nbsp;Rosa Martha Jiménez‐Barrera ,&nbsp;Rodrigo Chan‐Navarro ,&nbsp;Vianey González‐Villasana ,&nbsp;Diana Reséndez‐Pérez.","doi":"10.1002/ajoc.202400613","DOIUrl":"10.1002/ajoc.202400613","url":null,"abstract":"<div><div>In this work, we report a blue‐LED self‐assembly‐assisted synthesis of novel emissive organoboron esters, achieved in just 30 minutes with quantitative yields. The molecular structure in solution (characterized by <sup>1</sup>H and <sup>11</sup>B NMR, and mass spectrometry) was further confirmed via X‐ray molecular diffraction analysis for compound <strong>3</strong>, where the boron ion adopts a distorted tetrahedral geometry. The photophysical properties of these molecules were analyzed in solution, revealing that <strong>1</strong>, featuring <em>tert</em>‐butyl groups and boron heterocycles with a nitro‐substituent, exhibits superior photostability compared to its derivatives. Photobleaching values showed an inverse correlation with the oxidation potentials of compounds <strong>1</strong>–<strong>3</strong>, except for <strong>4</strong>, used as a reference. Mass spectrometry further revealed greater energetic stability of the molecular ion of <strong>1</strong>. Notably, compound <strong>3</strong> demonstrated good solubility, high photostability, and adequate biocompatibility, making it a promising fluorescent dye for biomedical applications. Cytotoxicity assays in HEK‐293 cells across different concentrations confirmed its non‐toxic nature. Theoretical calculations further supported the high chemical stability of all compounds, attributing it to a synergistic interaction between electronic and steric effects, which protect the fluorophores by substitution of Schiff bases and formation of boron heterocycles. Additionally, <strong>3</strong> exhibited strong, non‐hazardous blue fluorescence when tested on HEK‐293 and MDA‐MB‐231 cells.</div></div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 3","pages":"Article e202400613"},"PeriodicalIF":2.8,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Commercial Copper‐Catalyzed Aerobic Oxidative Synthesis of 4H‐3,1‐Benzoxazine and Their Effects on Anti‐Inflammatory Genes Expression
IF 2.8 4区 化学
Asian Journal of Organic Chemistry Pub Date : 2025-03-01 DOI: 10.1002/ajoc.202400609
Dr. Jira Jongcharoenkamol , Rujiporn Saewa , Atchariya Intasri , Pariya Atawong , Phanupong Changtor , Dr. Kittisak Buddhachat , Dr. Sutthichat Kerdphon
{"title":"Commercial Copper‐Catalyzed Aerobic Oxidative Synthesis of 4H‐3,1‐Benzoxazine and Their Effects on Anti‐Inflammatory Genes Expression","authors":"Dr. Jira Jongcharoenkamol ,&nbsp;Rujiporn Saewa ,&nbsp;Atchariya Intasri ,&nbsp;Pariya Atawong ,&nbsp;Phanupong Changtor ,&nbsp;Dr. Kittisak Buddhachat ,&nbsp;Dr. Sutthichat Kerdphon","doi":"10.1002/ajoc.202400609","DOIUrl":"10.1002/ajoc.202400609","url":null,"abstract":"<div><div>A facile green synthesis of the anti‐inflammatory gene expression of 4<em>H</em>‐3,1‐benzoxazine was developed under a commercial copper catalytic system. Benzoxazines were synthesized from 2‐aminobenzyl alcohols and aromatic aldehydes including heterocyclic aromatic aldehydes using an economical commercially available copper(I)iodide (CuI) as a catalyst in the presence of the base, <sup><em>t</em></sup>BuOK. Target products were achieved in moderate to high yields with up to 75 % isolated yield. 4<em>H</em>‐3,1‐Benzoxazine enabled down‐regulation of inflammatory gene expression including tumor necrosis factor‐α (TNF‐<em>α</em>), inducible nitric oxide synthase (iNOS), cyclooxygenase‐2 (COX‐2), and interleukin‐1<em>β</em> (IL‐1<em>β</em>) in the lipopolysaccharide (LPS)‐stimulated RAW 264.7 macrophage cell line using a real‐time quantitative polymerase chain reaction (RT‐qPCR) comparable to anti‐inflammatory drug, dexamethasone. These results demonstrated that 4<em>H</em>‐3,1‐Benzoxazines possess the potential capability of anti‐inflammation.</div></div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 3","pages":"Article e202400609"},"PeriodicalIF":2.8,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gold(I)‐catalyzed Synthesis of Axially Chiral Indolo[2,3‐c]carbazole Exhibiting Advanced Electrochromic Response
IF 2.8 4区 化学
Asian Journal of Organic Chemistry Pub Date : 2025-03-01 DOI: 10.1002/ajoc.202400695
Prof. Dr. Takanori Suzuki , Dr. Wataru Nojo , Yuiki Kawada , Soichiro Sugiyama , Takaya Ikeuchi , Prof. Dr. Yusuke Ishigaki , Prof. Dr. Hiroaki Ohno
{"title":"Gold(I)‐catalyzed Synthesis of Axially Chiral Indolo[2,3‐c]carbazole Exhibiting Advanced Electrochromic Response","authors":"Prof. Dr. Takanori Suzuki ,&nbsp;Dr. Wataru Nojo ,&nbsp;Yuiki Kawada ,&nbsp;Soichiro Sugiyama ,&nbsp;Takaya Ikeuchi ,&nbsp;Prof. Dr. Yusuke Ishigaki ,&nbsp;Prof. Dr. Hiroaki Ohno","doi":"10.1002/ajoc.202400695","DOIUrl":"10.1002/ajoc.202400695","url":null,"abstract":"<div><div>The Wurster's Blue skeleton embedded in an axially chiral indolo[2,3‐<em>c</em>]carbazole framework can act as a key chromophore to realize three‐way‐output electrochromic response (UV‐Vis‐near IR absorption, fluorescence, and circular dichroism) upon reversible electrochemical interconversion with the corresponding neutral electron donor, which was effectively synthesized by gold(I)‐catalyzed cascade cyclization of 2‐azidophenyl‐1,3‐butadiyne with a 2‐phenyl‐1‐naphthyl terminal group.</div></div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 3","pages":"Article e202400695"},"PeriodicalIF":2.8,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harnessing the Ketene Chemistry by Transition-Metal-Catalyzed C−H Functionalization 通过过渡金属催化的 C-H 功能化利用烯酮化学性质
IF 2.8 4区 化学
Asian Journal of Organic Chemistry Pub Date : 2025-02-17 DOI: 10.1002/ajoc.202400768
Zhiming Feng, Yushan Xie, Lili Wu, Prof. Chengming Wang
{"title":"Harnessing the Ketene Chemistry by Transition-Metal-Catalyzed C−H Functionalization","authors":"Zhiming Feng,&nbsp;Yushan Xie,&nbsp;Lili Wu,&nbsp;Prof. Chengming Wang","doi":"10.1002/ajoc.202400768","DOIUrl":"https://doi.org/10.1002/ajoc.202400768","url":null,"abstract":"<p>Transition-metal-catalyzed C−H functionalization has become a cornerstone of modern organic synthesis, enabling the efficient formation of various C−C and C-heteroatom bonds. Ketenes, a class of highly reactive and versatile molecules, have recently been harnessed as powerful substrates for C−H functionalization reactions, unlocking new possibilities for the construction of complex molecular frameworks. This review provides a comprehensive overview of the latest advances in transition-metal-catalyzed C−H functionalization with ketenes, encompassing the design of novel catalytic systems, elucidation of reaction mechanisms, and exploration of synthetic applications. By highlighting the current state of the art, challenges, and future prospects, this concept aims to inspire further research and innovation in this rapidly evolving field, ultimately expanding the frontiers of transition-metal-catalyzed C−H functionalization with ketenes.</p>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 4","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143845822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quinazoline, Imidazoline, and Azetidine Heterocycles via Oxidative Sulfonamidation of Camphene
IF 2.8 4区 化学
Asian Journal of Organic Chemistry Pub Date : 2025-02-16 DOI: 10.1002/ajoc.202400671
Mikhail Yu. Moskalik, Ivan A. Garagan, Tatyana N. Borodina, Sergei V. Zinchenko, Bagrat A. Shainyan
{"title":"Quinazoline, Imidazoline, and Azetidine Heterocycles via Oxidative Sulfonamidation of Camphene","authors":"Mikhail Yu. Moskalik,&nbsp;Ivan A. Garagan,&nbsp;Tatyana N. Borodina,&nbsp;Sergei V. Zinchenko,&nbsp;Bagrat A. Shainyan","doi":"10.1002/ajoc.202400671","DOIUrl":"https://doi.org/10.1002/ajoc.202400671","url":null,"abstract":"<p>The NBS-induced reaction of camphene with sulfonamides in acetonitrile in the presence of cesium carbonate and with three-fold excess of NBS results in the formation of the Ritter type solvent interception products with spiro-joined imidazoline ring and the unrearranged camphene framework (major products, up to 70 %), and the rearranged products with fused azetidine and camphene rings (minor products, up to 28 %). With equimolar amount of NBS, only the rearranged products of the quinazoline type with fused tetrahydropyrimidine and camphene rings are formed in up to 74 % yield. The azetidine derivatives of monoterpenes represent practically unknown class of compounds, their structure was proved by X-ray analysis, and the mechanism of formation of all three types of products is discussed.</p>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 4","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143845995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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