Greenhouse Gases: Science and Technology最新文献

{"title":"Aminated ZIF-8 to facilitate CO2 sieving through polyvinyl alcohol/ionic liquid membranes","authors":"Chia-Huey Hong,&nbsp;Choe Peng Leo,&nbsp;Nor Naimah Rosyadah Ahmad,&nbsp;Abul Latif Ahmad","doi":"10.1002/ghg.2308","DOIUrl":"https://doi.org/10.1002/ghg.2308","url":null,"abstract":"<p>CO₂ separation technology at low pressure is most desirable in carbon capture projects to mitigate global warming. Facilitated transport membranes offer selective and effective CO₂ permeation using a wide range of carbon carriers at low pressure. Porous fillers were recently included as they can carry abundant fixed carriers besides offering open channels for CO₂ permeation. This study investigates the effects of amine-modified zeolitic imidazolate framework-8 (ZIF-8) with well-defined micropores and gas sieving ability in polyvinyl alcohol (PVA) membranes containing an ionic liquid that worked as mobile carriers. The effects of amine-modified ZIF-8 and silica nanoparticles on membrane properties and separation performance were also compared. Fourier transform infrared spectra confirmed the incorporation of ZIF-8, secondary amine, IL anions, and silica nanoparticles in PVA membranes. Energy dispersive analysis showed the good dispersion of inorganic fillers. The amine-modified silica nanoparticles resulted in higher thermal stability compared to the amine-modified ZIF-8 in PVA membranes containing [bmin][Ac] ionic liquid, as shown in the thermogravimetric analysis. However, the CO₂ separation performance of PVA membranes containing [bmim][Ac] ionic liquid was improved more significantly by the amine-modified ZIF-8 with microporous structure. A CO₂/N₂ ideal selectivity of 85.65 and CO₂ permeance up to 4,502.91 GPU were attained. Unlike the CO₂/N₂ ideal selectivity, the CO₂ permeance was not significantly affected either using [bmin][Ac] or [bmin][BF₄]. The humid gas greatly enhanced the CO₂ permeance without much changes in the CO₂/N₂ ideal selectivity due to the promotion of facilitated transport. © 2024 Society of Chemical Industry and John Wiley &amp; Sons, Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"14 6","pages":"995-1007"},"PeriodicalIF":2.7,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142861728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A bio-reactive transport model for biomethanation in hydrogen underground storage sites","authors":"Jean Donald Minougou,&nbsp;Siroos Azizmohammadi,&nbsp;Raoof Gholami,&nbsp;Holger Ott","doi":"10.1002/ghg.2307","DOIUrl":"https://doi.org/10.1002/ghg.2307","url":null,"abstract":"<p>Underground biomethanation, which relies on the subsurface microbial activity to convert hydrogen and carbon dioxide into methane, is a promising approach to support carbon capture, utilization, and storage technology. The process involves injecting hydrogen with captured CO₂ into depleted oil and gas reservoirs or aquifers colonized by hydrogenotrophic methanogens that can convert these two substrates into methane. Despite the attractiveness of this technology, there are still uncertainties about the efficiency of the conversion process, particularly the impact of microbial parameters. To investigate the efficiency of the hydrogen conversion process, we relied on a bio-reactive transport model that can mimic microbial growth and decay, consumption of substrates, and transport of reactants and products. It was found that the methane concentration peaks near the injection well when the hydrogen fraction is in the range of 75% to 80% of the injected gas composition. In addition, a noticeable hydrogen sulfide concentration can be produced due to sulfide ions in the brine. Using the Kozeny-Carman relation, an attempt was made to correlate microbial growth with reduced porosity and permeability. It was then revealed that substrate consumption by microbes leads to a drastic increase in the microbial population in the subsurface, which can reduce the petrophysical properties of the reservoir, especially in the near wellbore area. The results obtained from a series of parametric analyses showed that the hydrogen concentration in the injected gas, pressure, well spacing, and injection rate are some of the most important parameters contributing to the biomethanation process. © 2024 Society of Chemical Industry and John Wiley &amp; Sons, Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"14 6","pages":"977-994"},"PeriodicalIF":2.7,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ghg.2307","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142861182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Solid-phase synthesis of silicalite-1 molecular sieve based on fly ash and its CO2 adsorption performance","authors":"Xianglian Wu,&nbsp;Aisha Nulahong,&nbsp;Conghui Miao,&nbsp;Qinghua Liu,&nbsp;Jiangyuan Li,&nbsp;Changmin Tuo","doi":"10.1002/ghg.2306","DOIUrl":"https://doi.org/10.1002/ghg.2306","url":null,"abstract":"<p>In this work, an alkali melting-pickling assisted solid phase synthesis method of S-1 zeolite molecular sieve with excellent adsorption properties for CO₂ was successfully developed by using solid waste fly ash. SiO₂ with a purity of up to 97.84% was successfully extracted by using alkaline fusion activation, high temperature calcination and pickling. The CO₂ adsorption capacity of the prepared SiO₂ was 0.51 mmol/g at 298 K and 1 bar. Silicalite-1 molecular sieve was prepared by solid phase synthesis method using SiO₂ extracted from fly ash as silicon source. The results showed that the prepared Silicalite-1 had good morphology and relatively high crystallinity. The specific surface area is 623.30 m²/g, and the total pore volume is 0.31 cm³/g. In addition, the adsorption capacity of CO₂ was 2.05 mmol/g at 298 K and 1 bar. Compared with the prepared SiO₂, the adsorption capacity of CO₂ by Silicalite-1 molecular sieve increased by four times. Moreover, under the test condition of 298 K, it has a high selectivity coefficient for CO₂/N₂ mixed gas, and after 10 times of adsorption-desorption cycle tests, the adsorption capacity of Silicalite-1 molecular sieve for CO₂ does not change significantly, and its adsorption rate can still be as high as 89.31%. The results indicate that Silicalite-1 molecular sieve prepared by solid phase synthesis method has good adsorption selectivity and adsorption–desorption cycle regeneration stability, and can be used in the field of CO₂ adsorption, separation and purification. © 2024 Society of Chemical Industry and John Wiley &amp; Sons, Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"14 6","pages":"954-976"},"PeriodicalIF":2.7,"publicationDate":"2024-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142860249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Core-flooding experiments of various concentrations of CO2/N2 mixture in different rocks: II. Effect of rock properties on residual water","authors":"Yi Li,&nbsp;Xiangyang Li,&nbsp;Zhikai Hu,&nbsp;Ruiting Suo,&nbsp;Liang Xue,&nbsp;Qingchun Yu","doi":"10.1002/ghg.2305","DOIUrl":"https://doi.org/10.1002/ghg.2305","url":null,"abstract":"<p>During CO₂ storage in deep saline aquifers, the presence of residual water has an important influence on the storage efficiency and safety. In this study, natural rock cores taken from deep reservoirs in the Ordos Basin and Fukang, Xinjiang are used as research objects. Nine groups of core-flooding experiments are performed under different CO₂/N₂ gas mixture ratios to study the influence of rock properties (mineral composition, permeability, porosity and pore structure) on the residual water. Furthermore, the geophysical and chemical properties of rock cores are analyzed by X-ray diffraction, electron microscopy, field emission scanning electron microscopy and piezoelectric mercury method. The results show that residual water saturation is a quantitative power function of drainage time. The residual water saturation is positively correlated with the total amount of quartz and feldspar and increases with increasing permeability. Moreover, both the average and median pore throat radius show a strong inverse correlation with irreducible residual water saturation; as these radius increase, the residual water saturation decreases. In contrast, the porosity and maximum pore throat radius display a weaker correlation with irreducible residual water saturation. This study is of great value for engineering practices such as the site selection of CO₂ storage projects in saline aquifer and improvement of CO₂ storage efficiency. © 2024 Society of Chemical Industry and John Wiley &amp; Sons, Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"14 5","pages":"871-886"},"PeriodicalIF":2.7,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142430229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development of a multicomponent counter-current flow model to evaluate the impact of oxygen and water vapor on CO2 removal performance in a hollow fiber membrane contactor","authors":"Qiang Yang,&nbsp;Qianguo Lin,&nbsp;Cheng Tung Chong,&nbsp;Yuyang Zhang","doi":"10.1002/ghg.2304","DOIUrl":"https://doi.org/10.1002/ghg.2304","url":null,"abstract":"<p>Membrane contactor has emerged as a promising technology for flue gas carbon capture as it integrates the advantages of high capture efficiency of absorption technology and compact design of membrane technology. However, the integration performance could be affected by the presence of minor components such as water vapor and residual oxygen in real gas conditions, owing to vapor condensation and dynamic oxidation in gas-liquid transfer interface. Therefore, it remains a need to develop a model that enables the prediction of CO₂ removal performance of membrane contactor under industrial real gas conditions. In the present study, a multicomponent model considering the impact of water vapor and oxygen on CO₂ removal in membrane contactors was developed. The model, based on mass transfer equilibrium, gas reaction kinetics, and diffusion coefficients, describes the transport and reaction dynamics of multicomponent gases within the gas, liquid, and membrane phases. Utilizing the finite element method (FEM) for solution, the model was demonstrated with a case study of CO₂ separation from a quaternary gas mixture by a hollow fiber membrane contactor (HFMC). The results highlight the importance of considering water vapor and oxygen in the design and evaluation of industrial membrane contactor systems, offering valuable insights for enhancing CO₂ separation efficiency in practical applications. © 2024 Society of Chemical Industry and John Wiley &amp; Sons, Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"14 5","pages":"776-790"},"PeriodicalIF":2.7,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142429858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Invasion percolation & basin modelling for CCS site screening and characterization","authors":"Friedemann Baur,&nbsp;Sam Hiebert","doi":"10.1002/ghg.2303","DOIUrl":"https://doi.org/10.1002/ghg.2303","url":null,"abstract":"<p>During the early screening phase of Carbon Capture and Storage (CCS) site evaluations limited time and data are available and hence CO₂ plume evaluations using time and data intensive reservoir simulations are almost never performed. However, there is still a need for early plume evaluations to risk and rank injection sites relative to each other. Therefore, an alternative fluid migration method called invasion percolation is adopted for the CCS screening phase to predict the extent and location of CO₂ plumes in the subsurface. Invasion percolation as part of basin modeling is a rapid method, which requires limited data and is ideal for the early screening phase. Invasion percolation results are compared to uncalibrated reservoir models, typical for the screening phase, revealing that plume location shape and size are very reasonable especially when compared to seismic observed plume outlines. It can be concluded that invasion percolation as part of basin modeling is a fit for purpose method, which can assess multiple opportunities rapidly during the early intake screening phase to risk and rank opportunities relative to each other and to build a CCS injection site portfolio. In addition to the plume evaluation, basin models can provide useful basin-scale or injection site specific pressure and temperature predictions as well as CO₂ density estimates for static volume calculations before detailed reservoir and stratigraphic models are available. © 2024 Society of Chemical Industry and John Wiley &amp; Sons, Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"14 5","pages":"760-775"},"PeriodicalIF":2.7,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142429307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A study on degradation and CO2 capture performance of aqueous amino acid salts for direct air capture applications","authors":"Ali Kiani,&nbsp;Will Conway,&nbsp;Mohamed H. Abdellah,&nbsp;Graeme Puxty,&nbsp;Ann-Joelle Minor,&nbsp;Gerard Kluivers,&nbsp;Robert Bennett,&nbsp;Paul Feron","doi":"10.1002/ghg.2302","DOIUrl":"https://doi.org/10.1002/ghg.2302","url":null,"abstract":"<p>We have previously proposed amino acid salts solutions as potential absorption liquids for direct air capture (DAC) of CO₂ from the atmosphere. However, little is known about their relevant CO₂ solubilities, CO₂ mass transfer rates, and susceptibility to oxidative and thermal degradation under conditions relevant to DAC. We report here on the overall solubility of CO₂ and CO₂ mass transfer rates into a series of amino acid salts solutions. Additionally, the robustness of various amino acid salt solutions to thermal and oxidative degradation has been assessed.</p><p>CO₂ absorption rates into the amino acid salts solutions were observed to be in the same order of magnitude as aqueous monoethanolamine (MEA), with sarcosinate and lysinate solutions providing the fastest and slowest CO₂ mass transfer rates at 25°C, respectively. Degradation data revealed that all amino acid salt solutions investigated in this study displayed elevated rates of thermal degradation at both 120 and 150°C relative to MEA. The opposite trend was observed with respect to oxidative degradation where all amino acid salt solutions showed a greater resistance to oxidative degradation than that observed for MEA under the conditions investigated here. Considering the degradation, CO₂ absorption capacity, and CO₂ mass transfer rate data, we propose the potassium salts of proline and sarcosine as the most promising amino acid salts (of those considered here) for further evaluation in DAC processes. Overall, this study provides valuable insight into the suitability of various amino acid salt solutions as absorption liquid for DAC. © 2024 The Author(s). <i>Greenhouse Gases: Science and Technology</i> published by Society of Chemical Industry and John Wiley &amp; Sons Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"14 5","pages":"859-870"},"PeriodicalIF":2.7,"publicationDate":"2024-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ghg.2302","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142430031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Validation of cubic EoS mixing rules and multi-fluid helmholtz energy approximation EoS for the phase behaviour modelling of CO2-rich binary mixtures at low temperatures","authors":"Franklin Okoro,&nbsp;Antonin Chapoy,&nbsp;Pezhman Ahmadi,&nbsp;Rod Burgass","doi":"10.1002/ghg.2300","DOIUrl":"https://doi.org/10.1002/ghg.2300","url":null,"abstract":"<p>The transportation of CO₂ from the capture site to the storage location is a crucial phase in carbon capture, utilisation and storage (CCUS) process. For offshore operations, ship transportation is considered a viable alternative, and this would entail operations at low temperatures (down to 223.15 K). A review of the literature revealed that there is limited experimental data on CO₂-rich systems at low temperatures, thus, the need to investigate the phase behaviour of CO₂-rich systems at these conditions. This study validated and compared the accuracies of Peng–Robinson (PR) equation of state (EoS) with three different mixing rules (the classical with original and adjusted binary interaction parameters, the Wong–Sandler, and the Orbey–Wong–Sandler mixing rules) against the multi-fluid helmholtz energy approximation (MFHEA - with original and adjusted binary-specific reducing parameters) EoS in the prediction of bubble points of CO₂-rich binary systems (CO₂-CH₄, CO₂–O₂, CO₂–Ar, and CO₂–N₂) for CCUS applications. The experimental studies used for the validation of the models were conducted at low temperatures (228.15–273.15 K with overall uncertainties of 0.14 K) and for five different CO₂ mole ratios (99.5, 99, 98.5, 98 and 95% with overall uncertainties of 0.032%) using the constant composition expansion method. The overall uncertainty of the pressure measurements was 0.03 MPa. From the study, it was observed that there was a significant effect of binary interaction parameters (BIP) adjustment on the performance of PR-EoS with classical mixing rule, especially for the CO₂–N₂ system. For all the systems, the predictions of PR-EoS with the classical mixing rules and the adjusted BIPs were the most accurate in terms of the average absolute deviations from the experimental data. The model also predicted the literature data well in comparison with the other models (with less than 5% deviations for all the data points). Further analysis also proved that the model dew point predictions were in reasonable agreement with the available literature data at the considered conditions. As a result, the model could be adopted to fill the existing knowledge gaps of the studied systems at conditions (143.15–223.15 K) where experimental studies were not feasible. © 2024 The Author(s). <i>Greenhouse Gases: Science and Technology</i> published by Society of Chemical Industry and John Wiley &amp; Sons Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"14 5","pages":"829-858"},"PeriodicalIF":2.7,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ghg.2300","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142430069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advancements in covalent organic framework-based nanocomposites: Pioneering materials for CO2 reduction and storage","authors":"Pallavi Singh,&nbsp;Pragnesh N Dave","doi":"10.1002/ghg.2297","DOIUrl":"https://doi.org/10.1002/ghg.2297","url":null,"abstract":"<p>The persistent increase in atmospheric carbon dioxide (CO₂) concentration poses a significant contemporary challenge. Contemporary chemistry is heavily focused on sustainable solutions, particularly the photo-/electrocatalytic reduction of CO₂ and its utilization for energy storage. Despite promising prospects, efficient chemical CO₂ conversion faces obstacles such as ineffective CO₂ uptake/activation and catalyst mass transport. Covalent organic frameworks (COFs) have emerged as potential catalysts due to their precise structural design, functionalizable chemical environments, and robust architectures. COF-based materials, especially those incorporating diverse active sites like single metal sites, metal nanoparticles, and metal oxides, hold promise for CO₂ conversion and energy storage. This review sheds light on CO₂ photoreduction/electroreduction and storage in Li-CO₂ batteries catalyzed by COF-based composites, focusing on recent advancements in integrating COFs with nanoparticles for CO₂ reduction. It discusses design principles, synthesis methods, and catalytic mechanisms driving the enhanced performance of COF-based nanocomposites across various applications, including electrochemical reduction, photocatalysis, and lithium CO₂ batteries. The review also addresses challenges and prospects of COF-based catalysts for efficient CO₂ utilization, aiming to steer the development of innovative COF-based nanocomposites, thus advancing sustainable energy technologies and environmental stewardship. © 2024 Society of Chemical Industry and John Wiley &amp; Sons, Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"14 5","pages":"914-938"},"PeriodicalIF":2.7,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142429974","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Comprehensive review of experimental studies, numerical modeling, leakage risk assessment, monitoring, and control in geological storage of carbon dioxide: Implications for effective CO2 deployment strategies","authors":"Abobakr Sori,&nbsp;Jafarsadegh Moghaddas,&nbsp;Hasan Abedpour","doi":"10.1002/ghg.2295","DOIUrl":"https://doi.org/10.1002/ghg.2295","url":null,"abstract":"<p>The geological storage of carbon dioxide (CO₂) represents a promising strategy for mitigating climate change by securely sequestering CO₂ emissions. This review article aims to provide a comprehensive overview of the current state of research and development in the field of geological carbon dioxide (CO₂) sequestration. We systematically examined a wide range of recent literature, focusing on advancements in numerical simulations, experimental studies, risk assessments, and monitoring techniques related to CO₂ sequestration. Literature was selected based on relevance, recency, and contribution to the understanding of key challenges and solutions in CO₂ storage, with sources spanning peer-reviewed journals, conference proceedings, and significant technical reports. Our review highlights several key themes: the integration of machine learning and advanced numerical models in predicting CO₂ behavior in subsurface formations; innovative experimental approaches to understanding the physicochemical interactions between CO₂, brine, and geological substrates; and the development of robust risk assessment frameworks to address potential leakage and induced seismicity. We also explore recent advancements in monitoring technologies, emphasizing their critical role in ensuring the long-term integrity and effectiveness of CO₂ storage sites. Overall, this review synthesizes the latest findings and identifies gaps in current knowledge, providing a roadmap for future research directions. Our aim is to enhance the understanding of CO₂ sequestration processes, support the development of safer and more efficient storage methods, and contribute to the global effort in mitigating climate change through effective carbon management strategies. © 2024 Society of Chemical Industry and John Wiley &amp; Sons, Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"14 5","pages":"887-913"},"PeriodicalIF":2.7,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142429994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}