Green Synthesis and Catalysis最新文献_第6页

A H2O2 generation-detection-regulation integrated platform for boosting the efficiency of peroxygenase-catalysed C–H oxidative hydroxylation 提高过氧酶催化C-H氧化羟基化效率的H2O2生成-检测-调控一体化平台

Green Synthesis and Catalysis Pub Date : 2024-08-01 DOI: 10.1016/j.gresc.2023.11.006

{"title":"A H2O2 generation-detection-regulation integrated platform for boosting the efficiency of peroxygenase-catalysed C–H oxidative hydroxylation","authors":"","doi":"10.1016/j.gresc.2023.11.006","DOIUrl":"10.1016/j.gresc.2023.11.006","url":null,"abstract":"<div>The peroxygenases are ideal biocatalysts for the selective oxyfunctionalisation of stable C–H bonds. However, the catalytic efficiency of this approach is limited due to enzyme lability toward oxidant H2O2. Although the reported in-situ H2O2 generation system enables the stable biocatalytic process without deactivating the enzyme, the greatest catalytic potential of peroxygenases still cannot be fulfilled effectively. To address the above issue, a H2O2 generation-detection-regulation platform that integrated an effective organocatalyst-driven H2O2 generation system, a precise electrochemical H2O2 real-time detection device, and a convenient H2O2 regulation strategy was first developed. The suitable range of H2O2 generation rate for maximizing the catalytic efficiency of peroxygenases while minimizing inactivation of the enzyme was firstly obtained by simply adjusting the amount of organocatalyst. According to the determined suitable range, the C–H oxyfunctionalisation efficiency of peroxygenases for each substrate was significantly boosted, achieving ∼3-fold of the reported highest turnover frequency.</div>","PeriodicalId":12794,"journal":{"name":"Green Synthesis and Catalysis","volume":"5 3","pages":"Pages 153-158"},"PeriodicalIF":0.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S266655492300100X/pdfft?md5=1ac9958ba7a3d4adcfa9a5a865502f1e&pid=1-s2.0-S266655492300100X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138512293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ate complexes in organic synthesis: From ate reagents to ate catalysts 有机合成中的金属络合物：从金属试剂到金属催化剂

Green Synthesis and Catalysis Pub Date : 2024-08-01 DOI: 10.1016/j.gresc.2024.04.010

{"title":"Ate complexes in organic synthesis: From ate reagents to ate catalysts","authors":"","doi":"10.1016/j.gresc.2024.04.010","DOIUrl":"10.1016/j.gresc.2024.04.010","url":null,"abstract":"<div>The realm of application of organometallic catalysis to organic synthesis has witnessed a transformative shift in recent years, owing much to the evolution of ate complexes from mere reagents to versatile catalysts. Ate complexes, formed through the coordination of a neutral Lewis acid with an organic anionic base, have emerged as pivotal intermediates that not only facilitate organic transformations but also serve as efficient catalysts in a wide range of chemical reactions. This review presents the fascinating journey of ate complexes, highlighting their development from stoichiometric reagents to active catalysts. Historically, ate complexes were primarily regarded as stoichiometric species essential for various metal-catalyzed transformations. However, constant research has unveiled their potential as catalysts in their own right, reshaping the landscape of modern organic synthesis. In this minireview, we discuss the pivotal role of ate complexes in the evolution of organic synthesis, from their early days as reactive intermediates to their current stature as catalytic pioneers offering a glimpse into the exciting future of this dynamic field.</div>","PeriodicalId":12794,"journal":{"name":"Green Synthesis and Catalysis","volume":"5 3","pages":"Pages 141-152"},"PeriodicalIF":0.0,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S266655492400053X/pdfft?md5=7a4de4c94a8dbec8c809e1e05e1cb03f&pid=1-s2.0-S266655492400053X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141037151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Light-driven enzymatic conversion of mevastatin into pravastatin by coupling P450sca-2 with cyanobacterial photosynthetic system 通过将 P450sca-2 与蓝藻光合系统耦合，光驱动酶法将美伐他汀转化为普伐他汀

Green Synthesis and Catalysis Pub Date : 2024-07-01 DOI: 10.1016/j.gresc.2024.07.001

Shanmin Zheng, Zhengquan Gao, Yuanyuan Jiang, Jiawei Guo, Fangyuan Cheng, Xuan Wang, Hao-Bing Yu, Bo Hu, Chunxiao Meng, Shengying Li, Xingwang Zhang

引用次数: 0

Synthesis of 1,4-oxathiins via [3+3] annulation of pyridinium 1,4‐zwitterionic thiolates with iodonium ylides 通过吡啶鎓-1,4-齐聚物硫醇盐与碘鎓酰化物的[3+3]环化反应合成 1,4-氧硫杂质

Green Synthesis and Catalysis Pub Date : 2024-07-01 DOI: 10.1016/j.gresc.2024.07.002

Zhibin Niu, C. Pi, Yangjie Wu, Xiuling Cui

引用次数: 0

Electrochemical selective deuterium labelling of N-heteroarenes N-teroarenes 的电化学选择性氘标记

Green Synthesis and Catalysis Pub Date : 2024-06-24 DOI: 10.1016/j.gresc.2024.06.003

Feiyu Qiu, Yi Chen, Peiqin Liao, Yuan Gao, Mian Guo, Heng Zhang, Aiwen Lei, Wu Li

引用次数: 0

Transformation of ambient CO2 in air into cyclic carbonates mediated by a phosphorus-nitrogen PN3-pincer iron complex 在磷-氮 PN3-钳铁复合物的介导下，将空气中的二氧化碳转化为环状碳酸盐

Green Synthesis and Catalysis Pub Date : 2024-06-17 DOI: 10.1016/j.gresc.2024.06.002

Li Yang, Priyanka Chakraborty, Pradip K. Das, Dongya Zhang, Kuo-Wei Huang

引用次数: 0

Electrophilic aryl spiroannulation induced by diaryliodonium salts： efficient synthesis of [5,5]-spiro lactone-lactam scaffolds from α-cyanocarboxylates 二月桂碘鎓盐诱导的亲电芳基螺烷化作用：从α-氰基羧酸酯高效合成[5,5]-螺内酯-内酰胺支架

Green Synthesis and Catalysis Pub Date : 2024-06-01 DOI: 10.1016/j.gresc.2024.05.009

Zhiyuan Bao, Yifei Li, Zhengsen Yu, Chao Chen

引用次数: 0

Synthesis of naphtho[1,2-b]furan-2-carbaldehydes and naphtho[2,1-b]furan-2-carbaldehydes via electrocatalytic 3,3-rearrangement/cyclization of propargylic aryl ethers under mild conditions 在温和条件下通过电催化丙炔基芳基醚的 3,3-重排/环化合成萘并[1,2-b]呋喃-2-羰基醛和萘并[2,1-b]呋喃-2-羰基醛

Green Synthesis and Catalysis Pub Date : 2024-06-01 DOI: 10.1016/j.gresc.2024.05.008

Kaili Cen, Mixia Ouyang, Guojun He, Zhouting Zeng, Qiaolin Wang, Xin Yu, Feng Zhao, Jinhui Cai

引用次数: 0

Stereoselective oxidative C3-N bond dehydrogenation and aromatization of 1-carboxyl substituted tetrahydroisoquinolines employing pipecolate oxidase 利用哌啶醇氧化酶对 1-羧基取代的四氢异喹啉进行立体选择性 C3-N 键氧化脱氢和芳香化反应

Green Synthesis and Catalysis Pub Date : 2024-06-01 DOI: 10.1016/j.gresc.2024.06.001

Shuyun Ju, Xiaoshu Zhou, Huanhuan Jin, Yang Yang, Lirong Yang, Jianping Wu

引用次数: 0

Photocatalyzed chemodivergent aerobic oxidation of naturally occurring Viridicatin and derivatives 光催化化学发散有氧氧化天然维甲酸及其衍生物

Green Synthesis and Catalysis Pub Date : 2024-06-01 DOI: 10.1016/j.gresc.2024.05.010

Yingxian Li, Hui Wang, Xuemin Jia, Bing Guo, Yuanyong Yang, Lei Tang, Zhiyong Jiang

引用次数: 0