Geochemistry International最新文献

{"title":"Composition of Methane Cycle Microbial Communities in the Upper Layers of Bottom Sediments of the Kara Sea","authors":"A. L. Bryukhanov,&nbsp;V. S. Sevastyanov,&nbsp;M. D. Kravchishina,&nbsp;S. A. Voropaev,&nbsp;N. V. Dushenko,&nbsp;A. V. Kurakov,&nbsp;V. Yu. Fedulova","doi":"10.1134/S0016702924700277","DOIUrl":"10.1134/S0016702924700277","url":null,"abstract":"<div><p>A study of the distribution of methane cycle microbial communities in the upper layers of bottom sediments above large hydrocarbon reservoirs in the South Kara petroleum region of the West Siberian Province revealed the presence in these layers of both aerobic methanotrophic bacteria and anaerobic methanogenic archaea, as well as numerous heterotrophic microorganisms of various phylogenetic groups. Research was carried out in the Baydaratskaya Bay and in the east of the Pukhuchan Depression (southern part of the Kara Sea). Aerobic methanotrophic bacteria belonged to the families <i>Methyloligellaceae</i>, <i>Methylophagaceae</i> and <i>Methylomonaceae</i> were detected in the surface oxidized layers (0–2 cm, <i>E</i>_<i>h</i> from 60 to 175 mV) of bottom sediments. Moreover, representatives of <i>Methyloligellaceae</i> were found in quite significant amount (1.52–2.61% of all 16S rRNA gene sequence reads) at all studied stations of the Kara Sea. In the subsurface reduced layers (18–20 cm, <i>E</i>_<i>h</i> from –63 to –246 mV), methanogenic archaea were dominated by representatives of the order <i>Methanomassiliicoccales</i> (up to 3.3% of all 16S rRNA gene sequence reads). Methanogenic archaea of the orders <i>Methanofastidiosales</i>, <i>Methanobacteriales</i> and <i>Methanomicrobiales</i> were also discovered. In addition, aerobic/facultative anaerobic methanotrophic bacteria of the families <i>Methylococcaceae</i> and <i>Methylomonadaceae</i> were found on these reduced layers of the bottom sediments, but the relative abundance (in percentage of sequence reads of their total number) of anaerobic methanotrophic archaea was extremely low there. Apparently, the oxidation of methane in bottom sediments of the Kara Sea, where its concentration at most of the studied stations dramatically increased with sediment depth, occurs predominantly under aerobic conditions in the surface layers, where the relative abundance and phylogenetic diversity of methanotrophs are higher.</p></div>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 6","pages":"609 - 617"},"PeriodicalIF":0.7,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141610183","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Applicability Limits of the Maturity Concept in Organic Geochemistry. II Relationships between the Rates of Reactions of Different Type","authors":"M. B. Smirnov,&nbsp;N. A. Vanyukova","doi":"10.1134/S0016702924700265","DOIUrl":"10.1134/S0016702924700265","url":null,"abstract":"<p>The paper considers how different maturity criteria reflect the overall degree of approach to the chemical equilibrium state of OM. The material for this study was OM from carbonate, siliceous–carbonate, carbonate–siliceous, and siliceous rocks of the northern and central regions of the Volga–Ural area (more than 100 samples). The raw data were processed using the apparatus of nonparametric correlation analysis (paired correlation coefficients between 27 parameters and partial correlation coefficients). The strengths of relations between maturity criteria based on reactions of different type (for example, reactions of C–C bond cleavage and isomerization reactions of aromatic compounds) were studied. It is shown that none of the 266 correlation coefficients corresponds to the values characteristic of a functional dependence. The partial correlation coefficients show that there are only thirteen pairs in which the parameters determined by reactions of different type are directly interrelated, and the strength of the relation significantly affects the values of both parameters. Thus, the values we measured in carbonate and silicite rocks cannot be to used to characterize the general approach of their OM to chemical equilibrium. Although the concept of “maturity” may have, technically speaking, the meaning of a general tendency toward equilibrium, it should be admitted that no methods are available so far to measure it. No data can be used to identify the only single parameter whose value is controlled only by the maturity value. Moreover, it is quite probable that there is no such a parameter at all. Nowadays the degree of approach to chemical equilibrium can be characterized only by using a set of parameters determined by reactions of all four types identified in the work.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 6","pages":"618 - 633"},"PeriodicalIF":0.7,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141610184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Study of the Effects of Different Factors on Crystal Growth from Solution: Data of Atomic Force Microscopy","authors":"N. N. Piskunova","doi":"10.1134/S0016702924700289","DOIUrl":"10.1134/S0016702924700289","url":null,"abstract":"<p>In order to crystallographically reconstruct the growth processes of mineral crystals and to establish fundamental patterns in crystal growth at a nanoscale, the effects of various factors on the characteristics of layer-by-layer crystal growth from solution were modeled using atomic force microscopy (AFM). In an experiment on growth in the area of a scratch, it was shown, using an original method of AFM data processing, that the average rate diagrams indicate a situation of a self-organization process: stable auto-oscillations in the growth rate. Comparison of the results with data on the growth of similar uninfluenced hillocks leads to the conclusion that giant fluctuations and the phenomenon of simultaneous growth and dissolution in local areas are caused by nanoindentation, when the strain from artificially formed defects strongly influences the evolution of the surface. In an AFM experiment on the trapping of foreign solid particles by a growing crystal at the nanoscale, the process of formation of a screw dislocation initiated by a foreign inclusion particle was registered. To theoretically explain the process, a three-stage mechanism is proposed that involves strain relaxation around the inclusion particle by the formation of one or more dislocations prior to the sealing of the inclusion during the first stage, the attachment of edge dislocations to them during the time of overgrowing in the second stage, and the development of a resulting dislocation after the particle has been completely sealed during the third stage. In studying growth in a flow cell, the mechanism of nanoscale reorientation of the growth hillock in the direction of the flow was established at a nanoscale, and the phenomenon of a change in the dominant hillock was registered. The resulting dissolution patterns in the channel are a clear demonstration of Curie’s Symmetry Principle, according to which only those symmetry elements of a body in an environment can be preserved that are shared by the body and the environment.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 6","pages":"634 - 646"},"PeriodicalIF":0.7,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141610185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Methane Fluxes from a Rich Fen: Relations with the Hydrochemistry and the Dissolved Carbon Isotopic Composition","authors":"E. A. Soldatova,&nbsp;V. N. Kolotygina,&nbsp;L. A. Krivenok,&nbsp;V. Ivanov,&nbsp;T. A. Kremleva","doi":"10.1134/S0016702924700290","DOIUrl":"10.1134/S0016702924700290","url":null,"abstract":"<p>In the framework of the eutrophic Ob fen study, methane fluxes were measured by the chamber method, and water was sampled for the analysis of general chemical composition, content of biophilic elements (C, N, and P) and δ¹³C of the dissolved inorganic carbon (δ¹³C-DIC). Samples were taken from open and forested areas within the fen, with the latter having long received discharged domestic wastewaters. The methane emissions positively correlate with the concentrations of nitrogen compounds and dissolved organic carbon (DOC). In both areas, higher methane emissions were observed from waterlogged microdepressions than from dry elevated microlandscape features. The largest emission was observed from the microdepressions in the forested area near the wastewater discharge point, where the extreme values of CH₄ fluxes were almost 30 times higher than the background ones. However, the methane fluxes decrease to the background level at 160 m from the wastewater discharge point, together with the concentrations of almost all nitrogen and carbon compounds dissolved in the fen water. This led us to conclude that wastewater pollution significantly affects the intensity of methane fluxes by increasing ebullitive methane emission near the pollution source. The isotopic composition of the dissolved inorganic carbon (DIC) was heavier in the forested area (δ¹³C-DIC = –9.64 to –9.21‰) than in the open one (–12.83 to –11.24‰). In the open area of the fen, DIC isotopic composition became heavier away from the dry upland, correlating with the increase in the methane fluxes. The obtained data indicate that methane-generating processes are more active in the forested area of the fen than in the open one and become more active in the open area with increasing distance from the dry upland. This highlights the potentialities of using δ¹³C-DIC as a fingerprint of wastewater pollution, at least in the Ob fen area.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 6","pages":"647 - 658"},"PeriodicalIF":0.7,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141610071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ferruginous Mineral Waters of Western Transbaikalia: Formation of Gas, Trace Elements, and Dissolved Organic Matter Composition","authors":"A. V. Ukraintsev,&nbsp;A. M. Plyusnin,&nbsp;M. K. Chernyavskii","doi":"10.1134/S0016702924700307","DOIUrl":"10.1134/S0016702924700307","url":null,"abstract":"<p>The article presents the results of study of ferruginous mineral waters. The waters under consideration are discharged on the territory of Western Transbaikalia and belong to the anoxic sulfide-free and acidic types. The peculiarities of the formation of gas, major and trace elements, and dissolved organic substance composition have been established using modern methods. It has been shown that the chemical composition of the waters is greatly influenced by acid–base conditions. Acidic ferruginous waters contain large amounts of heavy metals; organic matter is mainly represented by low molecular weight organic compounds. The only metals present in significant amounts in ferruginous waters are manganese and zinc. Dissolved organic matter is represented by diverse types of high-molecular weight compounds that are formed as a result of biotic processes.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 6","pages":"659 - 673"},"PeriodicalIF":0.7,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141610072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sulfur Isotopic Composition of Sulfides and Sulfates from Rocks of Carbonatite Complexes of the Devonian Kola Alkaline Province","authors":"E. N. Kozlov,&nbsp;E. N. Fomina,&nbsp;V. N. Reutsky,&nbsp;M. Yu. Sidorov","doi":"10.1134/S0016702924700253","DOIUrl":"10.1134/S0016702924700253","url":null,"abstract":"<p>This study presents the sulfur isotopic characteristics in baryte from carbonatites of the Sallanlatva massif and sulfides (mainly pyrite and pyrrhotite) from carbonatites, phoscorites and products of their contact interaction with the host silicate rocks of most carbonatite-bearing complexes of the Devonian Kola Alkaline Province (KAP). For some complexes (Ozernaya Varaka, Kontozero), these characteristics are reported for the first time. The determined range of δ³⁴S variations of sulfides in one complex does not exceed 4‰, but reaches 20‰ for the entire Kola Alkaline Province. This may be related to the evolution style of carbonatites and associated rocks. It is shown that the δ³⁴S value in sulfides decreases from (1) the least evolved volcanic carbonatites of the Kontozero complex (δ³⁴S_avg. = –1.3‰) through (2) carbonatites and phoscorites of the Kovdor, Ozernaya Varaka, Sokli, and Salmagora massifs towards (3) the rocks of Seblyavr, Vuoriyarvi, and, finally, the carbonatites of Sallanlatva (δ³⁴S_avg. = –14.7‰) massifs, where sulfides differ from those of other KAP carbonatites in their exceptionally low δ³⁴S values. The carbonatite volcanics of Kontozero are almost barren of REE mineralization; carbonatites of the second group contain accessory amounts of REE minerals; the third group is peculiar in the abundance of late carbonatites, where REE carbonates are frequently major minerals. Thus, the greater the volume of REE minerals in carbonatites of the complex, the lower the δ³⁴S value in sulfides from its carbonatites and associated rocks. For the first time in the KAP, the sulfur isotopic composition of associated baryte–pyrite pairs was studied in the Sallanlatva carbonatites. The sulfur isotopic characteristics are shown to correspond to the final low-temperature (250–350°C) stage of carbonatite evolution in oxidized conditions, which satisfies the parameters of baryte crystallization. Since the studied samples of the Sallanlatva carbonatites are explosive breccias, the oxidized composition of fluids may indicate their phreatomagmatic nature, i.e., formation due to the interaction of intruded hot matter (melt/fluid) with meteoric waters.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 6","pages":"561 - 573"},"PeriodicalIF":0.7,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141610182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Erratum to: Geochemical Markers of the Norilsk Ore-Bearing Intrusions: Case Study of the Maslovsky Deposit","authors":"Yu. A. Kostitsyn,&nbsp;N. A. Krivolutskaya,&nbsp;A. V. Somsikova,&nbsp;M. O. Anosova,&nbsp;I. V. Kubrakova,&nbsp;N. D. Tolstykh,&nbsp;B. I. Gongalsky,&nbsp;I. A. Kuzmin","doi":"10.1134/S0016702924980015","DOIUrl":"10.1134/S0016702924980015","url":null,"abstract":"","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 6","pages":"674 - 674"},"PeriodicalIF":0.7,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142411271","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mineralogical, Geochemical and Nd Isotopic Study of the Meta-Clastic Rocks of the Paleoproterozoic Mahakoshal Basin, Central Indian Tectonic Zone: Implications for Provenance Characterization, Paleoweathering Conditions and Tectonic Setting","authors":"Kamaal Parvez,&nbsp;M. E. A. Mondal,&nbsp;Iftikhar Ahmad,&nbsp;Waliur Rahaman,&nbsp;Anil D. Shukla,&nbsp;Wamiq Mohammed Khan","doi":"10.1134/S0016702924700472","DOIUrl":"10.1134/S0016702924700472","url":null,"abstract":"<p>The present study focuses on the petrographic studies, XRD patterns, whole-rock geochemical data and Nd isotopic data of the clastic rocks of the Paleoproterozoic Mahakoshal Basin which includes meta-argillites, meta-greywackes and quartzites to characterize their provenance, tectonic setting, weathering intensity, and paleoclimate condition. Geochemically, the rock samples of meta-argillite and meta-greywacke in the bivariate plot Log Na₂O/K₂O vs. Log SiO₂/Al₂O₃ are classified as litharenite and greywacke. The samples of quartzite fall in the fields from the sublitharenite to quartzarenite. The weathering indices such as CIA, <span>(alpha _{{{text{Ca}}}}^{{{text{Al}}}})</span>, <span>(alpha _{{{text{Na}}}}^{{{text{Al}}}})</span>, <span>(alpha _{{text{K}}}^{{{text{Al}}}})</span>, <span>(alpha _{{{text{Sr}}}}^{{{text{Al}}}})</span>, <span>(alpha _{{{text{Ba}}}}^{{{text{Al}}}})</span> and Th/U suggest that the clastic rocks have undergone moderate to intense chemical weathering and show K-metasomatism. Chondrite normalized REE patterns, discriminant diagrams of La–Th–Sc and Ni–V–10*Th and various transition elements ratio such as Cr/Th, Th/Co, Th/Sc, and La/Sc support the mixing of the mafic, intermediate and felsic sources. The Eu anomaly is highly variable and ranges from 0.29 to 1.08 and supports that the sediments have been derived from the heterogeneous source. T_CHUR model ages are consistent with 1.98–2.92 Ga possible provenance. εNd(t) and <i>f</i>(Sm/Nd) values overlap with the arc and the Archean crust signatures indicating that the sediments are derived from a Paleoproterozoic arc and older Archean crust (TTG gneisses and Archean granite). The opening of the Mahakoshal Basin is characterized by the retreating accretionary orogen and the closure of the basin is due to switching retreating accretionary orogen into advancing accretionary orogen which is contemporaneous to the assembly of the Columbia Supercontinent (∼1.8 Ga).</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 13","pages":"1378 - 1404"},"PeriodicalIF":0.7,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141586094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Studying the Influence of Soil Characteristics on Selenium Distribution in Bas-Chellif Soils Algeria and Predicting Speciation Patterns","authors":"M. Ait Mechedal,&nbsp;H. Laoufi,&nbsp;K. Ouamer-ali,&nbsp;K. Djili,&nbsp;Y. Daoud,&nbsp;D. B. Sims","doi":"10.1134/S0016702924700460","DOIUrl":"10.1134/S0016702924700460","url":null,"abstract":"<p>Knowledge of the geochemistry of selenium (Se) is crucial for understanding its behavior in the environment. While numerous studies have explored selenium geochemistry, there is a notable inadequacy, especially in extreme soil conditions such as saline soils, which are widespread globally. This study focuses on characterizing the geochemistry of selenium in saline soils, with a specific focus on the El Hamadna perimeter in Bas-Cheliff, Algeria. This location was chosen due to its diverse salinity levels and selenium content. Utilizing Phreeqc software, the study examines selenium’s chemical speciation. In the arid soils of this region, predicted selenium (IV) concentrations range from 0.19 to 3.05 mg kg^–1, and selenium (VI) concentrations range from 0.54 to 5.58 mg kg^–1. A significant negative correlation was observed between total selenium and Se(VI) concentrations with pH, whereas Se(IV) showed a positive and significant correlation with pH. No correlation was found between selenium concentrations and the salinity gradient in the studied soils. Non-significant correlations were observed between selenium levels and CaCO₃, clay, and organic matter in the soils, suggesting that these soil properties do not influence the distribution of selenium concentrations in the examined soils. Only the pH and the presence of the main form MgSeO₃ control the representation of selenium in the soil profile.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 8","pages":"897 - 907"},"PeriodicalIF":0.7,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141586138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"REE Distribution in the Water and Bottom Sediments of Small Lakes within the Ukok Plateau and the Ulagan Depression (Russian Altai)","authors":"V. D. Strakhovenko,&nbsp;E. A. Ovdina,&nbsp;G. I. Malov,&nbsp;V. I. Malov","doi":"10.1134/S001670292470037X","DOIUrl":"10.1134/S001670292470037X","url":null,"abstract":"<p>The contemporary scientific investigations delves into the mechanisms of migration, distribution, and fractionation of rare earth elements and yttrium (REE + Y) in aqueous environments characterized by humid and arid sedimentogenesis. This particular facet has been employed to solve numerous fundamental inquiries pertaining to lithology and paleolimnology. The manner in which REE + Y behave in water bodies within the cryolithozone remains largely unexplored. By evaluating the concentration levels and distribution patterns of REE + Y in the waters and sediments of the lakes situated in the Ukok Plateau and the Ulagan depression, under the prevailing conditions of cryolithogenesis as the primary geochemical process transforming rocks, soils, and sediments, we were able to augment the existing comprehension of nival sedimentation. In all the lakes examined, the content of REE + Y in the water exhibits a similar magnitude as that of small lakes in other landscape zones of the southern Western Siberia, while the content level of REE + Y is greater in the bottom sediments. The concentrations, distribution and fractionation of REE + Y vary from lake to lake and are determined by several factors: the chemical properties of REE + Y in solutions, the intensity of transformation of host rocks and the mineral forms of the REE + Y in the rocks (minerals). The concentrations, distribution and fractionation of REE + Y in bottom sediments vary slightly from lake to lake except for the contents of Eu, Y, La. The content of Eu, Y, La in the bottom sediment of the lake is influenced by a combination of factors, including their concentrations in the water, the redox conditions of diagenesis, and the mineral composition of the bottom sediment, particularly the amount of accessory minerals.</p>","PeriodicalId":12781,"journal":{"name":"Geochemistry International","volume":"62 7","pages":"772 - 791"},"PeriodicalIF":0.7,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141192614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}