{"title":"Ocean singularity analysis and global heat flow prediction reveal anomalous bathymetry and heat flow","authors":"Yang Zhang , Qiuming Cheng , Tao Hong , Junjie Ji","doi":"10.1016/j.gsf.2025.102013","DOIUrl":"10.1016/j.gsf.2025.102013","url":null,"abstract":"<div><div>The investigations of physical attributes of oceans, including parameters such as heat flow and bathymetry, have garnered substantial attention and are particularly valuable for examining Earth’s thermal structures and dynamic processes. Nevertheless, classical plate cooling models exhibit disparities when predicting observed heat flow and seafloor depth for extremely young and old lithospheres. Furthermore, a comprehensive analysis of global heat flow predictions and regional ocean heat flow or bathymetry data with physical models has been lacking. In this study, we employed power-law models derived from the singularity theory of fractal density to meticulously fit the latest ocean heat flow and bathymetry. Notably, power-law models offer distinct advantages over traditional plate cooling models, showcasing robust self-similarity, scale invariance, or scaling properties, and providing a better fit to observed data. The outcomes of our singularity analysis concerning heat flow and bathymetry across diverse oceanic regions exhibit a degree of consistency with the global ocean spreading rate model. In addition, we applied the similarity method to predict a higher resolution (0.1° × 0.1°) global heat flow map based on the most recent heat flow data and geological/geophysical observables refined through linear correlation analysis. Regions displaying significant disparities between predicted and observed heat flow are closely linked to hydrothermal vent fields and active structures. Finally, combining the actual bathymetry and predicted heat flow with the power-law models allows for the quantitative and comprehensive detection of anomalous regions of ocean subsidence and heat flow, which deviate from traditional plate cooling models. The anomalous regions of subsidence and heat flow show different degrees of anisotropy, providing new ideas and clues for further analysis of ocean topography or hydrothermal circulation of mid-ocean ridges.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102013"},"PeriodicalIF":8.5,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143642828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Gentili , G.D. Chiappetta , G. Petrillo , P. Brondi , J. Zhuang
{"title":"Forecasting strong subsequent earthquakes in Japan using an improved version of NESTORE machine learning algorithm","authors":"S. Gentili , G.D. Chiappetta , G. Petrillo , P. Brondi , J. Zhuang","doi":"10.1016/j.gsf.2025.102016","DOIUrl":"10.1016/j.gsf.2025.102016","url":null,"abstract":"<div><div>In this study, the advanced machine learning algorithm NESTORE (Next STrOng Related Earthquake) was applied to the Japan Meteorological Agency catalog (1973–2024). It calculates the probability that the aftershocks will reach or exceed a magnitude equal to the magnitude of the mainshock minus one and classifies the clusters as type A or type B, depending on whether this condition is met or not. It has been shown useful in the tests in Italy, western Slovenia, Greece, and California. Due to Japan’s high and complex seismic activity, new algorithms were developed to complement NESTORE: a hybrid cluster identification method, which uses both ETAS-based stochastic declustering and deterministic graph-based selection, and REPENESE (RElevant features, class imbalance PErcentage, NEighbour detection, SElection), an algorithm for detecting outliers in skewed class distributions, which takes in account if one class has a larger number of samples with respect to the other (class imbalance).</div><div>Trained with data from 1973 to 2004 (7 type A and 43 type B clusters) and tested from 2005 to 2023 (4 type A and 27 type B clusters), the method correctly forecasted 75% of A clusters and 96% of B clusters, achieving a precision of 0.75 and an accuracy of 0.94 six hours after the mainshock. It accurately classified the 2011 Tōhoku event cluster. Near-real-time forecasting was applied to the sequence after the April 17, 2024 M6.6 earthquake in Shikoku, correctly classifying it as a “Type B cluster”. These results highlight the potential for the forecasting of strong aftershocks in regions with high seismicity and class imbalance, as evidenced by the high recall, precision and accuracy values achieved in the test phase.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102016"},"PeriodicalIF":8.5,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143550693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sameera Maha Arachchige , Biswajeet Pradhan , Hyuck-Jin Park
{"title":"A critical review of hurricane risk assessment models and predictive frameworks","authors":"Sameera Maha Arachchige , Biswajeet Pradhan , Hyuck-Jin Park","doi":"10.1016/j.gsf.2025.102012","DOIUrl":"10.1016/j.gsf.2025.102012","url":null,"abstract":"<div><div>Hurricanes are one of the most destructive natural disasters that can cause catastrophic losses to both communities and infrastructure. Assessment of hurricane risk furnishes a spatial depiction of the interplay among hazard, vulnerability, exposure, and mitigation capacity, crucial for understanding and managing the risks hurricanes pose to communities. These assessments aid in gauging the efficacy of existing hurricane mitigation strategies and gauging their resilience across diverse climate change scenarios. A systematic review was conducted, encompassing 94 articles, to scrutinize the structure, data inputs, assumptions, methodologies, perils modelled, and key predictors of hurricane risk. This review identified key research gaps essential for enhancing future risk assessments. The complex interaction between hurricane perils may be disastrous and underestimated in the majority of risk assessments which focus on a single peril, commonly storm surge and flood, resulting in inadequacies in disaster resilience planning. Most risk assessments were based on hurricane frequency rather than hurricane damage, which is more insightful for policymakers. Furthermore, considering secondary indirect impacts stemming from hurricanes, including real estate market and business interruption, could enrich economic impact assessments. Hurricane mitigation measures were the most under-utilised category of predictors leveraged in only 5% of studies. The top six predictive factors for hurricane risk were land use, slope, precipitation, elevation, population density, and soil texture/drainage. Another notable research gap identified was the potential of machine learning techniques in risk assessments, offering advantages over traditional MCDM and numerical models due to their ability to capture complex nonlinear relationships and adaptability to different study regions. Existing machine learning based risk assessments leverage random forest models (42% of studies) followed by neural network models (19% of studies), with further research required to investigate diverse machine learning algorithms such as ensemble models. A further research gap is model validation, in particular assessing transferability to a new study region. Additionally, harnessing simulated data and refining projections related to demographic and built environment dynamics can bolster the sophistication of climate change scenario assessments. By addressing these research gaps, hurricane risk assessments can furnish invaluable insights for national policymakers, facilitating the development of robust hurricane mitigation strategies and the construction of hurricane-resilient communities. To the authors’ knowledge, this represents the first literature review specifically dedicated to quantitative hurricane risk assessments, encompassing a comparison of Multi-criteria Decision Making (MCDM), numerical models, and machine learning models. Ultimately, advancements in hurricane risk assessmen","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102012"},"PeriodicalIF":8.5,"publicationDate":"2025-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143480627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Delcy R. Nazareth , Maria Judith Gonsalves , Nitisha Sangodkar
{"title":"Influence of ambient geochemical and microbiological variables on the bacterial diversity in a cold seep ecosystem in North Indian Ocean","authors":"Delcy R. Nazareth , Maria Judith Gonsalves , Nitisha Sangodkar","doi":"10.1016/j.gsf.2025.102015","DOIUrl":"10.1016/j.gsf.2025.102015","url":null,"abstract":"<div><div>Cold seeps are oases for biological communities on the sea floor around hydrocarbon emission pathways. Microbial utilization of methane and other hydrocarbons yield products that fuel rich chemosynthetic communities at these sites. One such site in the cold seep ecosystem of Krishna-Godavari basin (K-G basin) along the east coast of India, discovered in Feb 2018 at a depth of 1800 m was assessed for its bacterial diversity. The seep bacterial communities were dominated by phylum Proteobacteria (57%), Firmicutes (16%) and unclassified species belonging to the family <em>Helicobacteriaceae</em>. The surface sediments of the seep had maximum OTUs (operational taxonomic units) (2.27 × 10<sup>3</sup>) with a Shannon alpha diversity index of 8.06. In general, environmental parameters like total organic carbon (p < 0.01), sulfate (p < 0.001), sulfide (p < 0.05) and methane (p < 0.01) were responsible for shaping the bacterial community of the cold seep ecosystem in the K-G Basin. Environmental parameters play a significant role in changing the bacterial diversity richness between different cold seep environments in the oceans.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102015"},"PeriodicalIF":8.5,"publicationDate":"2025-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143519652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ashar Awan , Mustafa Kocoglu , Mohammad Subhan , Mohammed Shakib , Nora Yusma bte Mohamed Yusoff
{"title":"Do energy intensity, resource abundance and inequality drive energy poverty? Evidence from developing countries","authors":"Ashar Awan , Mustafa Kocoglu , Mohammad Subhan , Mohammed Shakib , Nora Yusma bte Mohamed Yusoff","doi":"10.1016/j.gsf.2025.102014","DOIUrl":"10.1016/j.gsf.2025.102014","url":null,"abstract":"<div><div>Energy poverty in developing countries is a critical issue characterized by the lack of access to modern energy services, such as electricity and clean cooking facilities, as marked in SDG 7. This study explores the correlations between energy poverty, energy intensity, resource abundance, and income inequality, as these factors have been theorized to play important roles in influencing energy poverty in developing countries. By observing that the dataset is heterogeneous across the countries and over the time frame, we use the Method of Moments Quantile Regression (MMQR) to analyze our developing countries’ data from 2000 to 2019. Our findings indicate that energy intensity is a significant factor influencing energy poverty, suggesting that higher energy consumption relative to the sample countries can exacerbate this issue. Additionally, we observe that income inequality within the sample countries is a critical determinant of energy poverty levels, highlighting the dynamics between economic disparity and access to energy resources. Interestingly, our study reveals that resource abundance acts as a blessing rather than a curse in terms of energy poverty, implying that countries rich in natural resources may have better opportunities to combat energy deprivation. Finally, we emphasize the vital role of financial markets in addressing energy poverty on a global scale, suggesting that robust financial systems can facilitate investments and innovations aimed at improving energy access for vulnerable populations. The results from the robustness supports the empirical results obtained from the main estimation. The empirical findings of the present study advance important comprehensions for policymakers to adopt energy policies that address the complex challenges of energy poverty and promote inclusive energy access.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102014"},"PeriodicalIF":8.5,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143480628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pengpeng Yu , Yuan Liu , Hanyu Wang , Xi Chen , Yi Zheng , Wei Cao , Yiqu Xiong , Hongxiang Shan
{"title":"Machine learning of pyrite geochemistry reconstructs the multi-stage history of mineral deposits","authors":"Pengpeng Yu , Yuan Liu , Hanyu Wang , Xi Chen , Yi Zheng , Wei Cao , Yiqu Xiong , Hongxiang Shan","doi":"10.1016/j.gsf.2025.102011","DOIUrl":"10.1016/j.gsf.2025.102011","url":null,"abstract":"<div><div>The application of machine learning for pyrite discrimination establishes a robust foundation for constructing the ore-forming history of multi-stage deposits; however, published models face challenges related to limited, imbalanced datasets and oversampling. In this study, the dataset was expanded to approximately 500 samples for each type, including 508 sedimentary, 573 orogenic gold, 548 sedimentary exhalative (SEDEX) deposits, and 364 volcanogenic massive sulfides (VMS) pyrites, utilizing random forest (RF) and support vector machine (SVM) methodologies to enhance the reliability of the classifier models. The RF classifier achieved an overall accuracy of 99.8%, and the SVM classifier attained an overall accuracy of 100%. The model was evaluated by a five-fold cross-validation approach with 93.8% accuracy for the RF and 94.9% for the SVM classifier. These results demonstrate the strong feasibility of pyrite classification, supported by a relatively large, balanced dataset and high accuracy rates. The classifier was employed to reveal the genesis of the controversial Keketale Pb-Zn deposit in NW China, which has been inconclusive among SEDEX, VMS, or a SEDEX-VMS transition. Petrographic investigations indicated that the deposit comprises early fine-grained layered pyrite (Py1) and late recrystallized pyrite (Py2). The majority voting classified Py1 as the VMS type, with an accuracy of RF and SVM being 72.2% and 75%, respectively, and confirmed Py2 as an orogenic type with 74.3% and 77.1% accuracy, respectively. The new findings indicated that the Keketale deposit originated from a submarine VMS mineralization system, followed by late orogenic-type overprinting of metamorphism and deformation, which is consistent with the geological and geochemical observations. This study further emphasizes the advantages of Machine learning (ML) methods in accurately and directly discriminating the deposit types and reconstructing the formation history of multi-stage deposits.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102011"},"PeriodicalIF":8.5,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143420929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dillon A. Brown , Martin Hand , Laura J. Morrissey , Justin L. Payne , Andrew W. McNeill
{"title":"Warm continental subduction initiated by back-arc collapse: Evidence from remote south-west Tasmania","authors":"Dillon A. Brown , Martin Hand , Laura J. Morrissey , Justin L. Payne , Andrew W. McNeill","doi":"10.1016/j.gsf.2025.102009","DOIUrl":"10.1016/j.gsf.2025.102009","url":null,"abstract":"<div><div>The Tasmanian microcontinent, situated along the East Gondwana accretionary margin during the late Neoproterozoic and early Palaeozoic, contains an unequivocal high-pressure metamorphic record comprising key information pertaining to the geodynamics of subduction along the margin. Subduction of the Tasmanian microcontinent is interpreted by some as a response to back-arc basin inversion prior to ophiolite obduction and high-pressure metamorphism during the Cambrian Tyennan Orogeny. However, thermobarometric evidence in support of such a model from rocks once positioned on the subducting continental margin is lacking. Despite occurrences of eclogite-facies mineral assemblages in the strongly deformed Tyennan Region of western Tasmania, garnet-bearing quartzofeldspathic assemblages documented in metasedimentary lithologies from the remote south-west coast of Tasmania have been interpreted as an expression of low- to moderate-pressure metamorphism. We report a strongly overprinted chlorite-quartz-garnet-bearing assemblage from the southern Tyennan Region (Nye Bay) which shows evidence for high-pressure metamorphism. Coarse-grained garnet porphyroblasts contain inclusions of kyanite, muscovite, and rutile, and yield in-situ Lu–Hf dates of c. 520 Ma. The cm-scale garnet porphyroblasts are zoned in the major and trace elements, preserving core-rim compositional gradients reflecting garnet growth up-pressure. Aided by mineral equilibria forward modelling, the garnet rim compositions and the Zr content of Cambrian rutile constrain peak metamorphic conditions of ∼ 17.5–19 kbar and ∼ 780–820 °C, equivalent to warm subduction thermal gradients between 410–470 °C/GPa. Garnet core compositions and the Ti content of quartz inclusions in the garnet cores constrain the pressures and temperatures for garnet nucleation to ∼ 6–7 kbar and ∼ 560–580 °C, corresponding to relatively high prograde thermal gradients between 800–965 °C/GPa. The thermal gradients determined from the south-west Tasmanian metamorphic record provide a direct window into the progressive evolution of the thermal state of the Cambrian subduction system, with the physical conditions of garnet nucleation potentially reflecting those of subduction initiation. The corresponding warm thermal gradients provide evidence for subduction initiation driven by the collapse of a pre-orogenic back-arc. This interpretation is consistent with an existing tectonic model for the Tyennan Orogeny which proposes a back-arc basin origin for the protoliths to the western Tasmanian sub-ophiolitic metamorphic sole.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 3","pages":"Article 102009"},"PeriodicalIF":8.5,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143420930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Alcindo Neckel , Emanuelle Goellner , Marcos L.S. Oliveira , Paloma Carollo Toscan , Alana Urio , Guilherme Peterle Schmitz , Giana Mores , Brian William Bodah , Eduardo Nuno Borges Pereira
{"title":"Geospatial applicability optics of the TROPOspheric monitoring instrument (TROPOMI) on a global scale: An overview","authors":"Alcindo Neckel , Emanuelle Goellner , Marcos L.S. Oliveira , Paloma Carollo Toscan , Alana Urio , Guilherme Peterle Schmitz , Giana Mores , Brian William Bodah , Eduardo Nuno Borges Pereira","doi":"10.1016/j.gsf.2025.102008","DOIUrl":"10.1016/j.gsf.2025.102008","url":null,"abstract":"<div><div>Studies arising from literature reviews are important as they facilitate specific understanding about the use of the Sentinel-5P satellite developed by the European Space Agency (ESA) to detect the concentration levels of atmospheric pollutants on a global scale. The objective of this literature review is to analyze the application of the geospatial optics of the Sentinel-5P satellite; coupled with the Tropospheric Monitoring Instrument (TROPOMI) in the detection of NO<sub>2</sub> and CO over the period beginning in May 2018 and lasting through May 2024. This was accomplished using manuscripts published in the ScienceDirect databases. The study employed the rigorous Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) method, using the specific search term ‘sentinel TROPOMI satellite’, which yielded 555 results published between 2018 and 2024. Subsequently, 274 manuscripts were selected, and 85 were classified for analysis after a concise review. The Content Analysis Method (CAM) was used to understand the absolute frequency, with the use of the MAXQDA software (version 24.2.0) in this analysis. The purpose of using TROPOMI in the 85 manuscripts analyzed is significant. The manuscripts studied focused on air quality monitoring (30.1%), COVID-19 impact detection (24.3%), assessment of pollution sources (23.3%), support for decision makers (13.6%) and the development of methods and tools (8.7%). In this context, 38.5% of the examined studies focused on Asia, followed Europe (29.2%), North and South America (25.1%) and Africa (7.3%). TROPOMI data makes it possible to contribute to creating future government public policies on both the local and global scale.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 2","pages":"Article 102008"},"PeriodicalIF":8.5,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143145347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yinlei Hao , Hui Zhou , Xingxing Kuang , Qinghua Gong , Yuqing Feng , Meizhuang Zhu , Nianqing Li , Xiaoyan Shi
{"title":"Lithium isotopes in the geothermal waters of the India–Asia continental convergent margin: Source and evolution","authors":"Yinlei Hao , Hui Zhou , Xingxing Kuang , Qinghua Gong , Yuqing Feng , Meizhuang Zhu , Nianqing Li , Xiaoyan Shi","doi":"10.1016/j.gsf.2025.102001","DOIUrl":"10.1016/j.gsf.2025.102001","url":null,"abstract":"<div><div>Lithium (Li) in geothermal waters along the India–Asia continental convergent margin is a potential Li resource and plays an important role in the Li budget and Li isotopic composition (<em>δ</em><sup>7</sup>Li) of rivers and oceans. However, its origins and behavior remain unclear. Here, we systematically investigated the <em>δ</em><sup>7</sup>Li, water (<em>δ</em><sup>18</sup>O and <em>δ</em><sup>2</sup>H) and helium (<sup>3</sup>He/<sup>4</sup>He) isotopes of 21 geothermal water samples as well as a series of shallow groundwater and river water samples from southern Tibet and the Himalayas. The <em>δ</em><sup>7</sup>Li values of geothermal waters vary from +1.0‰ to +14.3‰ and are negatively correlated with the Li concentration (0.006–35.0 mg/L). For geothermal water with Li concentrations >5 mg/L, Li is sourced mainly from magmatic fluids exsolving from granitic magma chambers in the crust rather than the mantle, with contributions of 49.5% ± 3.2% to 85.5% ± 1.0%. The <em>δ</em><sup>7</sup>Li values of these Li-rich geothermal waters are relatively homogeneous and comparable to those of bulk granitic rocks. They are mainly controlled by the Li isotopic compositions of granitic magmatic fluids (−2.6‰ to +5.6‰), and the dissolution of primary minerals and the precipitation of secondary minerals with minimal Li isotopic fractionation during high-temperature (174 ± 5 °C to 315 ± 6 °C) water–granite interactions at deep geothermal reservoirs (4.4–7.9 km). For geothermal waters with Li concentrations <5 mg/L, Li originates primarily from water–granitic rock interactions (dominated by biotite dissolution) at 106 ± 3 °C to 207 ± 10 °C, contributing approximately 85% ± 16% of the total Li. An integrated dissolution–precipitation–mixing model suggests that high <em>δ</em><sup>7</sup>Li values in Li-depleted samples result from preferential incorporation of <sup>6</sup>Li into secondary minerals at lower reservoir temperatures within shallower reservoirs (2.7–5.2 km) and mixing of shallow groundwater during the ascent of geothermal waters. This study provides new insights into the fluid geochemistry of crustal granitic magma chambers and highlights that Li-rich geothermal waters in Tibet are controlled by the existence of crustal granitic magma chambers and the scale of faults.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 2","pages":"Article 102001"},"PeriodicalIF":8.5,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143319068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Matee Ullah , Urs Klötzli , Christian Rentenberger , Jiří Sláma , Muhammad Younas , Muhammad Khubab , Mohammad Goudarzi , Tanveer Ahmad
{"title":"Unravelling the geochemical and geochronological diversities of the pre-collisional magmatism: Implications for the subduction dynamics in the Kohistan island arc and Karakorum block, Pakistan","authors":"Matee Ullah , Urs Klötzli , Christian Rentenberger , Jiří Sláma , Muhammad Younas , Muhammad Khubab , Mohammad Goudarzi , Tanveer Ahmad","doi":"10.1016/j.gsf.2025.102003","DOIUrl":"10.1016/j.gsf.2025.102003","url":null,"abstract":"<div><div>The magmatic arcs in the north-west region of Pakistan comprises of numerous volcanic and plutonic bodies of different ages and compositions evolved during the subduction of the Neo- Tethys Ocean under the Eurasian supercontinent. This study focusses on the examination of the granitoids of the Kohistan batholith (a part of Kohistan-Ladakh Island Arc; KLIA) and the Khunjerab pluton, concentrating on their petrological traits, mineral chemistry, in-situ zircon U-Pb geochronology, and whole-rock major and trace element geochemistry. According to zircon U-Pb dating, the Kohistan batholith granitoid was emplaced around 91.7 ± 0.3 Ma, while zircons of the Khunjerab pluton yield ages of 106.4 ± 0.4 Ma and 106.4 ± 1.0 Ma. All the samples from both magmatic units have calcic to calc-alkaline (Na<sub>2</sub>O + K<sub>2</sub>O: 3.6–10.6 wt.% and SiO<sub>2</sub>: 60–73 wt.%), metaluminous to peraluminous properties (Aluminum Saturation Index (ASI): 0.9–1.2). Notably, Nb, Ta, and Ti show depletion, while large ion lithophile elements like Cs, Rb, and K have been enriched. Additionally, we find that SiO<sub>2</sub> and P<sub>2</sub>O<sub>5</sub> have a negative correlation while Rb and Th have a positive correlation, which confirm an I-type arc magmatism. Together with the published literature, TEM analysis, and thermal modelling, our zircon U-Pb results point to a period of continuous magmatic activity from the Late Jurassic to the Late Cretaceous (between 150 Ma and 91 Ma) in the Kohistan Island arc region while the Khunjerab pluton (part of Karakorum block/Eurasian plate) experienced widespread magmatism around 120 Ma to 106 Ma. With SiO<sub>2</sub> concentrations ranging from 67.5–73.3 wt.% and 60–71.4 wt.% and relatively low alkali (Na<sub>2</sub>O + K<sub>2</sub>O) contents between 3.6–10.6 wt.% and 5.1–7.4 wt.% in the Kohistan batholith and Khunjerab pluton respectively, showing clear signs of acidity. The whole rock as well as the mineral geochemical analysis and the elevated water contents (8–10 wt.% and 3.1–3.5 wt.%) inferred from amphibole and biotite chemistry respectively, indicates that the Kohistan batholith was most likely formed through partial melting of a (hydrous) magma originating from a more or less altered metasomatized mantle wedge. Likewise, the Khunjerab pluton whole rock geochemistry also indicates its origin through partial melting of magma originating from an altered metasomatized mantle wedge. This study also shows that both units are not only different in terms of the nature of magmatism but also in terms of their ages i.e., continental arc magmatism occurred in the Khunjerab (Karakoram) block in the middle Cretaceous (106 Ma) while island arc magmatism occurred on the Kohistan side in the late Cretaceous (91 Ma). Further, this study also investigate why multi-grain U-Pb zircon dating is necessary for studying magmatic rocks by using transmission electron microscopy.</div></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"16 2","pages":"Article 102003"},"PeriodicalIF":8.5,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143145890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}