EnergiesPub Date : 2024-10-09DOI: 10.3390/en17195012
Wei Zhang, Zhilin Qi, Jie Tian, Fang Xu, Deyu Kong, Mingda Dong, Shenyao Yang, Wende Yan
{"title":"Influence of Reaction Conditions on the Yield of Supercritical Multicomponent Thermal Fluids","authors":"Wei Zhang, Zhilin Qi, Jie Tian, Fang Xu, Deyu Kong, Mingda Dong, Shenyao Yang, Wende Yan","doi":"10.3390/en17195012","DOIUrl":"https://doi.org/10.3390/en17195012","url":null,"abstract":"Supercritical multicomponent thermal fluid (scMCTF) is a novel medium with great potential for heavy oil thermal recovery. The production rate of scMCTF will affect the injection efficiency of thermal fluid, and then affect the development effect of thermal recovery. However, at present, there are few reports on the production rate of each component of scMCTF, and their understanding is not clear. According to the existing production rate data of supercritical water (scH2O) gasification products, based on the generation mechanism of scMCTF, the production rate of thermal fluid generation products under different generation conditions was calculated, and its influencing factors were identified. The results show the following: (1) The factors affecting the production rate of scMCTF generation products can be divided into three categories: reaction raw material factors, reaction condition factors, and catalytic factors. (2) The hydrocarbon number of raw material, reaction temperature, reaction time, and catalyst concentration were positively correlated with the production rate of the product. (3) The concentration of the reaction raw material is negatively correlated with the production rate of the product. The higher the concentration of the raw material is, the lower the concentration of H2O is, and the steam reforming reaction is inhibited, which leads to the decrease in the production rate. (4) The effect of reaction pressure and catalyst load on the product is not significant. (5) The reaction product production rate increased first and then decreased with the ratio of H2O to oil in the raw material emulsion and the ratio of preheated H2O to raw material discharge. (6) The effect of metal salt catalysts is relatively stable, and the catalytic effect of simple metal catalysts is significantly different under the action of different types of accelerators, so it is necessary to study the degree of synergization of different accelerators on the catalytic effect. The results can lay a foundation for the subsequent experimental and theoretical research design.","PeriodicalId":11557,"journal":{"name":"Energies","volume":"17 19","pages":"5012-5012"},"PeriodicalIF":0.0,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/1996-1073/17/19/5012/pdf?version=1728458173","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147905792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigation of Cotton Stalk-Derived Hydrothermal Bio-Oil: Effects of Mineral Acid/Base and Oxide Additions","authors":"Libo Zhang, Jianing Wang, Hui Ming, Hanjun Hu, Xintong Dou, Yepeng Xiao, Lihua Cheng, Zhun Hu","doi":"10.3390/en17194854","DOIUrl":"https://doi.org/10.3390/en17194854","url":null,"abstract":"Hydrothermal liquefaction technology (HTL) is a promising thermochemical method to convert biomass into novel liquid fuels. The introduction of oxides and inorganic acids/bases during the hydrothermal process significantly impacts the yield and composition of bio-oil. However, systematic research on their effects, especially at lower temperatures, remains limited. In this paper, we examine the effects of acidity and alkalinity on cotton stalk hydrothermal bio-oil by introducing homogeneous acids and bases. Given the operational challenges associated with product separation using homogeneous acids and bases, this paper further delves into the influence of heterogeneous oxide catalysts (possessing varying degrees of acidity and alkalinity, as well as distinct microstructures and pore architectures) on the production of cotton stalk hydrothermal bio-oil. The effects of nanoscale oxides (CeO2, TiO2, ZnO, Al2O3, MgO and SiO2) and homogeneous acid–base catalysts (NaOH, K2CO3, Na2CO3, KOH, HCl, H2SO4, HNO3) on the quality of cotton stalk bio-oil under moderate hydrothermal conditions (220 °C, 4 h) were investigated. Characterization techniques including infrared spectroscopy, thermogravimetric analysis, elemental analysis, and GC-MS were employed. The results revealed that CeO2 and NaOH achieved the highest bio-oil yield due to Ce3+/Ce4+ redox reactions, OH-LCC disruption, and ionic swelling effects. Nano-oxides enhanced the formation of compounds like N-ethyl formamide and aliphatic aldehydes while suppressing nitrogen-containing aromatics. The total pore volume and average pore width of oxides negatively correlated with their catalytic efficiency. CeO2 with low pore volume and width exhibited the highest energy recovery. The energy recovery of cotton stalk bio-oil was influenced by both acid and base sites on the oxide surface, with a higher weak base content favoring higher yields and a higher weak acid content inhibiting them. The findings of this research are expected to provide valuable insights into the energy utilization of agricultural solid waste, such as cotton stalks, as well as to inform the design and development of highly efficient catalysts.","PeriodicalId":11557,"journal":{"name":"Energies","volume":"17 19","pages":"4854-4854"},"PeriodicalIF":0.0,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/1996-1073/17/19/4854/pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147898194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
EnergiesPub Date : 2024-09-24DOI: 10.3390/en17194769
Osama A. Marzouk
{"title":"Portrait of the Decarbonization and Renewables Penetration in Oman’s Energy Mix, Motivated by Oman’s National Green Hydrogen Plan","authors":"Osama A. Marzouk","doi":"10.3390/en17194769","DOIUrl":"https://doi.org/10.3390/en17194769","url":null,"abstract":"The aim of this study is to quantitatively describe the anticipated change in the energy mix of the Sultanate of Oman (Oman) as the country moves forward in its national plan for green hydrogen, in order to become a global producer and exporter. This aim is achieved by curating recent data about energy projects in Oman that are either operating or planned (in a construction or pre-construction stage). Then, these data are processed further to extract useful insights about how the energy mix would change if the planned projects are realized and added to the operating ones. This reveals the serious commitment of the country to accomplish its national plan for green hydrogen (GH), where the green hydrogen production ambition for 2030 is about 1.125 million tons per annum (Mtpa), using a renewable energy capacity of approximately 18 GW. This ambition increases to about 3.5 Mtpa with approximately 70 GW of renewables in 2040, and increases further to about 8 Mtpa with approximately 180 GW of renewables in 2050. As a portrait of Oman’s energy mix with the assumption of successfully completing all planned energy projects, we found that the country is expected to have a total capacity of 83.1271 GW, with the share of renewables (solar and wind) reaching 83.133% (as compared to 15.0711 GW with an 8.907% renewables share for operating projects). Nearly all (precisely 99.571%) of the 68.0560 GW planned national energy capacity additions are based on solar or wind energy, while the traditional oil–gas energy is gradually phased out. Green hydrogen production dominates this surge in renewables penetration within the Omani energy mix, with 84.659% of the planned 34.3140 GW solar capacity additions linked with green hydrogen production, for operating water electrolyzers. Similarly, 98.804% of the planned 33.4500 GW wind capacity additions are linked with green hydrogen production.","PeriodicalId":11557,"journal":{"name":"Energies","volume":"17 19","pages":"4769-4769"},"PeriodicalIF":0.0,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147912379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Highly Efficient Layer-by-Layer Organic Photovoltaics Enabled by Additive Strategy","authors":"Yuheng Ni, Hongyue Tian, R.H. Gong, Hang Zhou, Wenjing Xu, Jian Wang, Xiaoling Ma, Fujun Zhang","doi":"10.3390/en17164022","DOIUrl":"https://doi.org/10.3390/en17164022","url":null,"abstract":"In this work, layer-by-layer organic photovoltaics (LbL OPVs) were prepared by sequentially spin-coating PM1 and L8-BO solutions. The solvent additive 1,8-diiodooctane (DIO), which has a high boiling point, and solid additive l,3,5-trichlorobenzene (TCB), which has a high volatile, were deliberately selected to incorporate with the L8-BO solutions. The power conversion efficiency (PCE) of LbL OPVs was considerably enhanced from 17.43% to 18.50% by employing TCB as the additive, profiting by the concurrently increased short-circuit current density (JSC) of 26.74 mA cm−2 and a fill factor (FF) of 76.88%. The increased JSCs of LbL OPVs with TCB as additive were ascribed to the tilted-up absorption edge in the long wavelength range and the external quantum-efficiency spectral difference between LbL OPVs with and without TCB as an additive. The molecular arrangement of L8-BO and the PM1 domain was enhanced with TCB as an additive, which was most likely responsible for the increased charge mobilities in the layered films processed with additives. It was indicated that the dynamic film-forming process of the acceptor layers plays a vital role in achieving efficient LbL OPVs by employing additive strategy. Over 6% PCE improvement of the LbL OPVs with PM1/L8-BO as the active layers can be achieved by employing TCB as additive.","PeriodicalId":11557,"journal":{"name":"Energies","volume":"17 16","pages":"4022-4022"},"PeriodicalIF":0.0,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/1996-1073/17/16/4022/pdf?version=1723621434","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147920952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
EnergiesPub Date : 2024-07-29DOI: 10.3390/en17153733
Weilai Zhang, Jianxun Wu, Shuofan Li, Yahe Zhang, Suoqi Zhao, Quan Shi
{"title":"Classification Method of Heavy Oil Based on Chemical Composition and Bulk Properties","authors":"Weilai Zhang, Jianxun Wu, Shuofan Li, Yahe Zhang, Suoqi Zhao, Quan Shi","doi":"10.3390/en17153733","DOIUrl":"https://doi.org/10.3390/en17153733","url":null,"abstract":"Heavy oil resources in the world are extremely abundant, and viscosity is currently the main reference index for heavy oil classification. However, the diversification of practical issues in heavy oil exploitation, and the refinement of processing and utilization urgently require the support of heavy oil classification with more reference indexes. In this study, the macroscopic properties of typical heavy oils in China were analyzed, and the semi-quantitative analysis of the molecular composition of different heavy oils was completed based on high-resolution mass spectrometry. The results show that heavy oils with similar viscosities can exhibit huge differences in macroscopic properties and chemical composition. According to the evaluation of the chemical composition and macroscopic properties of typical Chinese heavy oils, 12 types of compounds belonging to saturates, aromatics, resins, and asphaltenes (SARA) were identified, establishing a connection between the macroscopic fractions and molecular compositions of heavy oils. By summarizing the comparative results, a new classification criterion for heavy oils was established, focusing on the main parameters of H/C ratio and total acid number (TAN), with sulfur content as a supplementary indicator. H/C is the embodiment of the degree of molecular condensation in the macroscopic properties, reflecting the structural characteristics of the main molecules of the heavy oil. Chinese heavy oil is generally characterized by high TAN, which corresponds to the composition of petroleum acids, and it is also an important reference index for the exploitation and processing of heavy oils. Most Chinese heavy oils have a very low sulfur content, but the presence of sulfur compounds in high-sulfur heavy oils can lead to significant differences in the distribution of compound types among the SARA. This new classification method for heavy oil combines the characteristics of chemical composition of heavy oils, which is expected to provide valuable support for the extraction and processing of heavy oil.","PeriodicalId":11557,"journal":{"name":"Energies","volume":"17 15","pages":"3733-3733"},"PeriodicalIF":0.0,"publicationDate":"2024-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/1996-1073/17/15/3733/pdf?version=1722240091","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147892069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
EnergiesPub Date : 2024-06-28DOI: 10.3390/en17133195
WenLong Gao, Liwei Sun, Miao Li, 憲司 小野, Qingchun Gao, DongLiang Kong, JunPu An, Kuobo Wang, Fan Yang
{"title":"Synthesis and Performance Evaluation of Modified Polyaspartic-Acid-Based Scale Inhibitor","authors":"WenLong Gao, Liwei Sun, Miao Li, 憲司 小野, Qingchun Gao, DongLiang Kong, JunPu An, Kuobo Wang, Fan Yang","doi":"10.3390/en17133195","DOIUrl":"https://doi.org/10.3390/en17133195","url":null,"abstract":"This paper focuses on the selection and application of scale inhibitor by studying the problem of pipeline scaling in geothermal well development. Adding scale inhibitor can effectively reduce the treatment cost and achieve a good scale resistance effect, but the commonly used polyaspartic acid scale inhibitor has problems such as poor scale inhibition effect and large use limitations. Therefore, a new modified polyaspartic acid scale inhibitor (His-Tyr-SA-PASP) was prepared using polysuccinimide (PSI) as the raw material and histidine (His), tyrosine (Tyr), and sulfonic acid (SA) as the modification reagent. When the dosage of His-Tyr-SA-PASP was 8 mg/L, the scale inhibition rate of CaCO3 was 94.40%. In addition, the scale inhibition effect of His-Tyr-SA-PASP on CaCO3 was better than that of PASP. At the same time, under the condition of a static experiment at 75 °C, according to the ion concentration of water samples in different scale zones, this paper also identified the ratio of four composite scale inhibitors. When the dosage of compound scale inhibitor was 100 mg/L, Sodium of Polyaspartic Acid–Diethylene Triamine Penta (Methylene Phosphonic Acid)–2-Phosphonobutane-1,2,4-Tricarboxylic Acid–Amino Trimethylene Phosphonic Acid–Copolymer of Maleic and Acrylic Acid = (10:10:5:1:9), (15:10:5:2.5:2.5), (12.5:5:10:1:6.5), and (15:5:10:4:1) and the scale inhibition rate was more than 95%. Under the condition of a dynamic experiment, the optimized composite scale inhibitor still showed a scale inhibition rate of more than 90%. It provides a useful reference for the practical application of water treatment in geothermal wells and has the prospect of industrial application.","PeriodicalId":11557,"journal":{"name":"Energies","volume":"17 13","pages":"3195-3195"},"PeriodicalIF":0.0,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/1996-1073/17/13/3195/pdf?version=1720175206","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147920103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
EnergiesPub Date : 2024-06-27DOI: 10.3390/en17133172
Maierhaba Abudoureheman, Lanzhen He, Kunpeng Liu, Bo Wei, Jia Lv, Jianjiang Wang, Quan Zhu
{"title":"Understanding the Competition Mechanism between Na2O and CaO for the Formation of the Initial Layer of Zhundong Coal Ash","authors":"Maierhaba Abudoureheman, Lanzhen He, Kunpeng Liu, Bo Wei, Jia Lv, Jianjiang Wang, Quan Zhu","doi":"10.3390/en17133172","DOIUrl":"https://doi.org/10.3390/en17133172","url":null,"abstract":"The contents of alkali and alkaline earth metals are higher in Zhundong coal, and there are serious problems of slagging and fouling during the combustion process. Therefore, it is of great significance to reveal the mechanism of slagging and fouling in the boiler of Zhundong coal. In this paper, first-principle calculations based on density functional theory are used to study the competition mechanism of alkaline metal oxides during the combustion process in Zhundong coal by establishing the Na2O(110)/CaO(100)-SiO2(100) double-layer interface model. The results show that the bond lengths of the surface of Na2O(110) and CaO(100) with SiO2(100) after adsorption were generally lengthened and the value of bond population became smaller, which formed a stable binding energy during the reaction. The electron loss of Na is 0.05 e, the electron loss of Ca is 0.03 e, and the electron loss of Na2O is greater than that of CaO. The charge transfer on the surface of Na2O with SiO2 is obviously higher than that of CaO and the orbital hybridization on the surface of CaO with SiO2 is weaker than that on the surfaces of Na2O with SiO2. Na2O is easier to react with SiO2 than CaO. The adsorption energies on the surface of Na2O and CaO with SiO2 are −5.56 eV and −0.72 eV, respectively. The adsorption energy of Na2O is higher than that of CaO, indicating that Na2O is more prone to adsorption reactions and formation of Na-containing minerals and other minerals, resulting in more serious slagging. In addition, the XRD analyses at different temperatures showed that Na-containing compounds appeared before Ca-containing ones, and the reaction activity of Na2O is stronger than that of CaO in the reaction process. The experimental results have good agreement with the calculation results. This provides strong evidence to reveal the slagging and fouling of Zhundong coal.","PeriodicalId":11557,"journal":{"name":"Energies","volume":"17 13","pages":"3172-3172"},"PeriodicalIF":0.0,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/1996-1073/17/13/3172/pdf?version=1720489816","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147897317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Transient Flow-Induced Stress Investigation on a Prototype Reversible Pump–Turbine Runner","authors":"Dehao Zhang, Qiang Quan, Xingxing Huang, Zhengwei Wang, Biao Wang, Yunfeng Xiao","doi":"10.3390/en17123026","DOIUrl":"https://doi.org/10.3390/en17123026","url":null,"abstract":"Pump–turbine units with high heads are subjected to strong pressure pulsations from the unsteady transient flow in fluid channels, which can produce severe vibrations and high stresses on the pump–turbine structural components. Therefore, reducing transient flow-induced stresses on prototype reversible pump–turbine units is an important measure for ensuring their safe and efficient operation. A high-head prototype reversible pump–turbine with a rated head of 440 m was used to investigate the transient flow characteristics and the flow-induced-stresses in this study. First, the flow passages of the pump–turbine unit and the structure of the reversible pump–turbine runner were constructed with CAD tools. Next, CFD simulations at the full load were performed to investigate the pressure pulsation characteristics of the pump turbine in both the time domain and the frequency domain. After this, the pressure files calculated by the CFD were exported and applied to a finite element model of the pump–turbine runner to calculate the transient flow-induced dynamic stresses. The results show that the pressure pulsations in the flow passage are closely related to the rotational speed, the guide vane number, and the runner blade number of the pump–turbine unit. The maximum flow-induced stresses on the pump–turbine runner at the full load were below 2 MPa and lower than the allowable value, which reveals that the designs of the pump–turbine runner and the flow passage are acceptable. The conclusions can be used as a reference to evaluate the design of high-head pump–turbines units. The approaches used to carry out the transient flow-induced stress calculations can be applied not only to pump–turbines units but also to other types of fluid turbomachinery such as pumps, turbines, fans, compressors, turbochargers, etc.","PeriodicalId":11557,"journal":{"name":"Energies","volume":"17 12","pages":"3026-3026"},"PeriodicalIF":0.0,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/1996-1073/17/12/3026/pdf?version=1718802595","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147893229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ion-Exchange Strategy Enabling Direct Reformation of Unreliable Perfluorinated Cationic Polymer for Robust Proton Exchange Membrane towards Hydrogen Fuel Cells","authors":"Xuqiu Xie, Wenjing Jia, Changyuan Liu, Yongzhe Li, Anhou Xu, Xundao Liu","doi":"10.3390/en17122954","DOIUrl":"https://doi.org/10.3390/en17122954","url":null,"abstract":"Perfluorosulfonated anionic ionomers are known for their robust ion conductivity and chemical and mechanical stability. However, the structure and transport property degradation of perfluorinated cationic polymers (PfCPs) are not well understood. Herein, we propose an ion-exchange strategy to identify the structural degradation, ion transport mechanisms, and architectural reformation of PfCPs. Particularly, we demonstrate that the utility of a –SO2–N+ strategy employing the Menshutkin reaction cannot yield reliable PfCPs and anion-exchange membranes, but can yield an unreliable zwitterionic intermediate (cations–anions molar ratio is approximately 7.6%). Moreover, the degradation products were efficiently reformed as proton exchange membranes (PEMs), and the as-reformed PEMs achieved an ion-exchange capacity (IEC) value (0.89 mmol g−1), meanwhile retaining more than 94.7% of their initial capacity. Furthermore, the fuel cell assembled with reformed PEMs displayed a power density of 0.91 Wcm−2 at 2.32 A cm−2, which was 90.1% of that of the robust perfluorosulfonic acid PEMs. Our combined findings shed some fresh light on the state of understanding of the structure–property relationship in PfCPs.","PeriodicalId":11557,"journal":{"name":"Energies","volume":"17 12","pages":"2954-2954"},"PeriodicalIF":0.0,"publicationDate":"2024-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/1996-1073/17/12/2954/pdf?version=1718443954","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147911646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
EnergiesPub Date : 2024-05-29DOI: 10.3390/en17112625
Yuejie Wang, Wei Zheng, Hongyou Zhang, Chenyang Tang, Jun Zhang, Dengfei Yu, Xuanfeng Lu, Gang Li
{"title":"The Role of Amphiphilic Nanosilica Fluid in Reducing Viscosity in Heavy Oil","authors":"Yuejie Wang, Wei Zheng, Hongyou Zhang, Chenyang Tang, Jun Zhang, Dengfei Yu, Xuanfeng Lu, Gang Li","doi":"10.3390/en17112625","DOIUrl":"https://doi.org/10.3390/en17112625","url":null,"abstract":"Heavy oil accounts for a considerable proportion of the world’s petroleum resources, and its exploitation helps to mitigate reliance on conventional oil resources and diversify energy supply. However, due to the high viscosity and high adhesion characteristics of heavy oil, conventional methods such as thermal recovery, emulsification, and dilution have significant limitations and cannot meet the growing demands for heavy oil production. In this study, 3-propyltrimethoxysilane (MPS) was used to modify and graft amphiphilic surfactants (AS) onto nanosilica to prepare a salt-resistant (total mineralization > 8000 mg/L, Ca2+ + Mg2+ > 1000 mg/L) and temperature-resistant (250 °C) nanosilicon viscosity reducer (NSD). This article compares amphiphilic surfactants (AS) as conventional viscosity-reducing agents with NSD. FTIR and TEM measurements indicated successful bonding of 3-propyltrimethoxysilane to the surface of silica. Experimental results show that at a concentration of 0.2 wt% and a mineralization of 8829 mg/L, the viscosity reduction rates of thick oil (LD-1) before and after aging were 85.29% and 81.36%, respectively, from an initial viscosity of 38,700 mPa·s. Contact angle experiments demonstrated that 0.2 wt% concentration of NSD could change the surface of reservoir rock from oil-wet to water-wet. Interfacial tension experiments showed that the interfacial tension between 0.2 wt% NSD and heavy oil was 0.076 mN/m. Additionally, when the liquid-to-solid ratio was 10:1, the dynamic and static adsorption amounts of 0.2 wt% NSD were 1.328 mg/g-sand and 0.745 mg/g-sand, respectively. Furthermore, one-dimensional displacement experiments verified the oil recovery performance of NSD at different concentrations (0.1 wt%, 0.15 wt%, 0.2 wt%, 0.25 wt%) at 250 °C and compared the oil recovery efficiency of 0.2 wt% NSD with different types of demulsifiers. Experimental results indicate that the recovery rate increased with the increase in NSD concentration, and 0.2 wt% NSD could improve the recovery rate of heavy oil by 22.8% at 250 °C. The study of nano-demulsification oil recovery systems can effectively improve the development efficiency of heavy oil.","PeriodicalId":11557,"journal":{"name":"Energies","volume":"17 11","pages":"2625-2625"},"PeriodicalIF":0.0,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/1996-1073/17/11/2625/pdf?version=1716984563","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147912905","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}