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Synthesis and Characterization of Dodecylbenzene Sulfonic Acid doped Tetraaniline via Emulsion Polymerization 乳液聚合法制备十二烷基苯磺酸掺杂四苯胺
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/692853
K. Basavaiah, K. T. Rao, A. Rao
{"title":"Synthesis and Characterization of Dodecylbenzene Sulfonic Acid doped Tetraaniline via Emulsion Polymerization","authors":"K. Basavaiah, K. T. Rao, A. Rao","doi":"10.1155/2012/692853","DOIUrl":"https://doi.org/10.1155/2012/692853","url":null,"abstract":"In this work, we report preparation and characterization of dodecylbenzene sulfonic acid (DBSA) doped tetraaniline via micelles assisted method using ammonium per sulphate (APS) as an oxidant. Here, DBSA act as dopant as well as template for tetraaniline nanostructures. The synthesized DBSA doped tetraaniline have been well characterized by X-ray diffraction patterns, Fourier transform infrared spectroscopy, UV-Visible spectroscopy, Scanning electron microscopy and thermogravimetry. The morphologies of tetraaniline were found to be dependent on molar ratios of N-phenyl-1, 4-phenylenediamine to DBSA. The spectroscopic data indicated that DBSA doped tetraaniline. Thermogravimetry studies revealed that the DBSA doping improved the thermal stability of tetraaniline.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/692853","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64343974","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Ionic Liquid-Mediated, Rapid N-Alkylation of Heterocyclic Compounds with Trialkyl Phosphites in the Presence of Dialkyl Acetylenedicarboxylates 离子液体介导的杂环化合物与三烷基亚磷酸酯在二烷基乙炔二羧酸盐存在下的快速n -烷基化反应
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/786024
A. Hassanabadi, M. Mosslemin, M. Anary‐Abbasinejad, Azadeh Kalantarinejad, Mozhdeh Jerjisi Shirazi
{"title":"Ionic Liquid-Mediated, Rapid N-Alkylation of Heterocyclic Compounds with Trialkyl Phosphites in the Presence of Dialkyl Acetylenedicarboxylates","authors":"A. Hassanabadi, M. Mosslemin, M. Anary‐Abbasinejad, Azadeh Kalantarinejad, Mozhdeh Jerjisi Shirazi","doi":"10.1155/2012/786024","DOIUrl":"https://doi.org/10.1155/2012/786024","url":null,"abstract":"Ionic liquids such as 1,3-dialkylimidazolium bromides and make excellent solvents for N-alkylation of heterocyclic compounds such as saccharin and rhodanine with trialkyl phosphites in the presence of dialkyl acetylenedicarboxylates.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/786024","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64352722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Co(II) Complex of Mefloquine Hydrochloride: Synthesis, Antimicrobial Potential, Antimalaria and Toxicological Activities 盐酸甲氟喹Co(II)配合物的合成、抑菌潜力、抗疟及毒理学活性
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/940258
Adediji J. Femi, O. J. Ayoola
{"title":"Co(II) Complex of Mefloquine Hydrochloride: Synthesis, Antimicrobial Potential, Antimalaria and Toxicological Activities","authors":"Adediji J. Femi, O. J. Ayoola","doi":"10.1155/2012/940258","DOIUrl":"https://doi.org/10.1155/2012/940258","url":null,"abstract":"Transition metal complex of Co(II) with Mefloquine hydrochloride (antimalaria drug) was synthesized using template method. Chemical analysis including conductivity measurements and spectroscopic studies were used to propose the geometry and mode of binding of the ligand to metal ion. From analytical data, the stoichiometry of the complex has been found to be 1:1. Infrared spectral data also suggest that the ligand (mefloquine hydrochloride) behaves as a tridentate ligand with N:N:O donor sequence towards the metal ion. The complex generally showed octahedral coordinate geometry. Conductivity measurement of 10-2 mol dm-3 methanol solution of the complex indicated non-electrolytic nature of metal complex. It also revealed that the ligand anions were covalently bonded to the complex. In-vivo evaluation of antimicrobial studies of the metal complex showed greater activities when compared to the free mefloquine.The complex was screened against malarial parasites (Plasmodium yoelii nigeriensis): It was evident from the results obtained that Co(II) mefloquine has highest clearance of about 80% parasitaemia reduction compared to the free mefloquine. The ligand and metal complex were screened for their toxicological activities at the dose of 0.60 mg/Kg body weight twice daily for seven days on the alkaline phosphatase (ALP), alanine aminotranferase (ALT), and aspartate aminotransferase (AST) activities of rat serum, liver and kidney. Overall, it was revealed that both mefloquine and its metal complex do not showed toxicity particularly on the liver and kidney.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/940258","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64369968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Temperature Dependent Ultrasonic Study in Scandium Antimonide Semiconductor 锑化钪半导体温度相关超声研究
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/130434
Alok Gupta, S. Srivastava, K. Thapa
{"title":"Temperature Dependent Ultrasonic Study in Scandium Antimonide Semiconductor","authors":"Alok Gupta, S. Srivastava, K. Thapa","doi":"10.1155/2012/130434","DOIUrl":"https://doi.org/10.1155/2012/130434","url":null,"abstract":"In this paper analysis of wave propagation of elastic wave in scandium antimonide semiconductor was investigated. In scandium antimonide semiconductor, NaCl structure was found. Ultrasonic properties like ultrasonic attenuation, sound velocities, acoustic coupling constants, and thermal relaxation time have been investigated in cubic scandium antimonide semiconductor. Second and third order elastic constant have been computed for the evaluation of above said ultrasonic properties. Second and third elastic constant was studied at the various temperatures. Longitudinal and shear velocity was calculated by using the elastic constant. Longitudinal and shear velocity increase with increase the temperature. Ultrasonic attenuation either from longitudinal or shear wave propagation in cubic materials increase with increase the temperature.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/130434","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64294836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on Degradation of Dye Acid Red B by Sr2FeMoO6 Synthesized by Microwave Sintering Method 微波烧结法合成Sr2FeMoO6降解染料酸性红B的研究
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/239305
Y. Zhai, Jing Qiao, Man-de Qiu
{"title":"Research on Degradation of Dye Acid Red B by Sr2FeMoO6 Synthesized by Microwave Sintering Method","authors":"Y. Zhai, Jing Qiao, Man-de Qiu","doi":"10.1155/2012/239305","DOIUrl":"https://doi.org/10.1155/2012/239305","url":null,"abstract":"Double perovskite Sr2FeMoO6 was synthesized rapidly by microwave sintering method. The crystal structure of the sample was investigated by XRD. It shows that the as-synthesized sample is Sr2FeMoO6 with tetragonal crystal structure and I4/mmm space group. The test of electrical transport properties shows that the sample exhibits typical semiconductor behavior in the temperature range of 80~300 K. The influence of the dosage of the sample, light irradiation sources, and time on the efficiency of degradation have been studied. The results show Sr2FeMoO6 exhibits excellent degradation activity for dye Acid Red B, the decolorization rate is close to 100% under proper conditions. Meanwhile, a mechanism related to the process of degradation is proposed.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/239305","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64304908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Synthesis and Characterization of Boron Trifluoride Doped High Performance Polyaniline 掺三氟化硼高性能聚苯胺的合成与表征
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/275862
K. Basavaiah, D. Samsonu, A. V. Prasada Rao
{"title":"Synthesis and Characterization of Boron Trifluoride Doped High Performance Polyaniline","authors":"K. Basavaiah, D. Samsonu, A. V. Prasada Rao","doi":"10.1155/2012/275862","DOIUrl":"https://doi.org/10.1155/2012/275862","url":null,"abstract":"We report simple synthesis of boron trifluoride (BF3) doped defect free high performance polyaniline (HPPANI) in two step method. Firstly, HPPANI was prepared via self-stabilization dispersion polymerization method in a heterogeneous reaction medium. Second step involves doping of emeraldine base form of HPPANI with boron trifluoride under reduced vacuum. The resultants BF3 doped HPPANI have been well characterized by using UV-Visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermogravimetry. The spectroscopic data indicated that the interaction between HPPANI and BF3.Thermogravimetry studies revealed that the BF3 doping improved the thermal stability of defects free PANI.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/275862","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64308536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Effect of Magnetite Nano Particles on p-n-Alkyl Benzoic Acid Mesogens 磁性纳米颗粒对对正烷基苯甲酸介生的影响
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/878049
S. Sastry, S. S. Begum, T. V. Kumari, V. Murthy, S. Ha
{"title":"Effect of Magnetite Nano Particles on p-n-Alkyl Benzoic Acid Mesogens","authors":"S. Sastry, S. S. Begum, T. V. Kumari, V. Murthy, S. Ha","doi":"10.1155/2012/878049","DOIUrl":"https://doi.org/10.1155/2012/878049","url":null,"abstract":"The magnetite (Fe3O4) nanoparticles (0.5 wt%) of size less than 20 nm doped in p-n-alkyl benzoic acids where n varies from heptyl (7) to nonyl (9) are prepared and the presence of Fe","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/878049","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64363883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Synthesis and Characterization of a Novel Class of Lewis Acid Doped Tetraaniline 一类新型Lewis酸掺杂四苯胺的合成与表征
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/392718
K. Basavaiah, A. Rao
{"title":"Synthesis and Characterization of a Novel Class of Lewis Acid Doped Tetraaniline","authors":"K. Basavaiah, A. Rao","doi":"10.1155/2012/392718","DOIUrl":"https://doi.org/10.1155/2012/392718","url":null,"abstract":"Boron trifluoride (BF3) doped tetraaniline with novel structure were successfully synthesized via two step method. In the first step, emeraldine base form tetraaniline was synthesized via oxidative chemical polymerization of N-phenyl-1, 4-phenylenediamine using ammonium persulphate as oxidant. In the second step involves control BF3 doping of tetraaniline using boron trifluoride etherate. As synthesized BF3 doped tetraaniline have been well characterized by UV-Visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction patterns (XRD), and scanning electron microscopy (SEM) and thermogravimetry. Thermogravimetry studies revealed that the BF3 doping improved the thermal stability of tetraaniline.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/392718","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64318820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Functionalization and Chemical Modification of 2-Hydroxyethyl Methacrylate with Carboxylic Acid 羧酸对2-甲基丙烯酸羟乙酯的功能化及化学改性研究
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/603573
M. H. Nasirtabrizi, L. Zargin, S. Khodabandlou, S. Mansour
{"title":"Functionalization and Chemical Modification of 2-Hydroxyethyl Methacrylate with Carboxylic Acid","authors":"M. H. Nasirtabrizi, L. Zargin, S. Khodabandlou, S. Mansour","doi":"10.1155/2012/603573","DOIUrl":"https://doi.org/10.1155/2012/603573","url":null,"abstract":"Free radical polymerization of the resulting monomers methyl methacrylate (MMA), ethyl methacrylate (EMA), methylacrylate (MA) and ethylacrylate (EA) with 2-hydroxyethyl methacrylate (HEMA) (in 1:1 mole ratio) were carried out using azobis(isoboutyronitrile) (AIBN) as initiator at the temperature ranges 60-70°C. The modification of polymers were carried out by 9-anthracenecarboxylic acid (9-ACA) via the esterification reaction between —OH of poly(HEMA) and —COOH of 9-ACA, in presence of N,N′-dicyclohexyl-carbodiimide (DCC), 4-(dimethylamino) pyridine (DMAP) and N,N-dimethyl formamid (DMF). It was found that the molar ratio acid/alcohol/catalysts= 0.02: 0.02: 0.02 and 0.002, optimal for preparation of the ester. As demonstrated by FT-IR, 1H-NMR and dynamic mechanical thermal analysis (DMTA). The Tg value of methacrylate and acrylate copolymers containing 9-ACA groups was found to increase with incorporation of 9-ACA groups in polymer structures. The presence of 9-ACA groups in the polymer side chains created new polymers with novel modified properties that find some applications in polymer industry. These anthracenic factors could take part in cyclo addition reaction with other factors such as anhydrides and kinons.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/603573","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64336770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation 含非对称四齿状席夫碱配体的新型铂(II)配合物的合成、表征及DFT计算
E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/802529
A. Akbari, I. Sheikhshoaie, L. Saghatforoush, S. Ebrahimipour, Z. Amiri
{"title":"New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation","authors":"A. Akbari, I. Sheikhshoaie, L. Saghatforoush, S. Ebrahimipour, Z. Amiri","doi":"10.1155/2012/802529","DOIUrl":"https://doi.org/10.1155/2012/802529","url":null,"abstract":"The tetra dentate neutral (E)-4-nitro-2-((2-(2-(pyridin-2-yl) ethylthio) ethylimino) methyl) phenol, (pytaO2NSalH), Schiff-base ligand was synthesized using 1-(2-pyridyl)-3-thia-s-aminopentane (pyta) and 5-NO2 salicylaldehyde. Then the related square planar Pt (II) cationic complex, [Pt (NSNO)] Cl, was synthesized using PtCl2 (SMe2)2 as precursor complex. The nature of the pytaO2NSalH and its platinum complex were determined by the elemental analysis, molar conductivity and spectrochemical (IR, UV–vis, 1HNMR) techniques. In addition, the fully optimized geometries and vibration frequencies of them together were calculated using the ADF 2009.01 package. Structural parameters are in good agreement with the experimental data. The calculated and experimental results confirmed the suggested structures for the ligand and complex.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/802529","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64353995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
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