E-journal of Chemistry最新文献_第10页

Influence of Air Annealing and Gamma Ray Irradiation on the Optical Properties of Cl16FePc Thin Films 空气退火和γ射线辐照对Cl16FePc薄膜光学性能的影响

E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/726415

R. Koshy, C. S. Menon

{"title":"Influence of Air Annealing and Gamma Ray Irradiation on the Optical Properties of Cl16FePc Thin Films","authors":"R. Koshy, C. S. Menon","doi":"10.1155/2012/726415","DOIUrl":"https://doi.org/10.1155/2012/726415","url":null,"abstract":"Metal phthalocyanines are one of the most promising candidates to be used in the fabrication of such devices. Among various phthalocyanines, Iron Hexadecachloro Phthalocyanine (Cl16FePc) has received less attention. Basic characteristics of Cl16FePc are not reported in literature. Hexadecacholoro phthalocyanines have attracted interest as possible n-type organic semiconductor with high electron mobility and good stability characteristics. In the present work we investigate the optical band gap of the Cl16FePc thin films from the optical absorption spectrum as a function of air annealing temperatures and their suitability for the fabrication of molecular electronic devices. Some optical properties of the samples were studied as a function of γ-radiation doses also. Optical transition is found to be of direct type and optical band gaps are determined by analyzing the absorption spectrum. Vacuum sublimed thin films of Iron hexadecachloro phthalocyanine were prepared at room temperature onto glass substrates at a base pressure of 10-5 Torr on precleaned glass substrates using Hind Hivac 12A4 coating plant. The optical energy band gap Eg were calculated. The mechanism of optical absorption follow the rule of direct transition. In the present paper we also report refractive index, real and imaginary parts of optical dielectric constant etc. from the reflectance measurements.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":"9 1","pages":"2439-2445"},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/726415","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64347497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 4

Removal of Lead from Synthetic Solutions by Protonated Teleosts Biomass 利用质子化硬骨鱼生物质去除合成溶液中的铅

E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/769180

M. Ashraf, M. J. Maah, I. Yusoff

引用次数: 16

Determination of Mineral Elements of Some Coarse Grains by Microwave Digestion with Inductively Coupled Plasma Atomic Emission Spectrometry 微波消解电感耦合等离子体原子发射光谱法测定某些粗粮中的矿物元素

E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/869297

Li Yang, Qinghua Yan, Yinping Cao, Hui-rong Zhang

{"title":"Determination of Mineral Elements of Some Coarse Grains by Microwave Digestion with Inductively Coupled Plasma Atomic Emission Spectrometry","authors":"Li Yang, Qinghua Yan, Yinping Cao, Hui-rong Zhang","doi":"10.1155/2012/869297","DOIUrl":"https://doi.org/10.1155/2012/869297","url":null,"abstract":"To determinate the mineral elements contents in millet，maise，oat，buckwheat，sorghum and purple rice, microwave digestion procedure optimized was applied for digesting six coarse grains. Nineteen mineral element concentrations were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES). Results displayed the limits of detection (LODs) and the limits of quantification (LOQs) range from 0.0047 to 0.1250 μg/mL and 0.0155 to 0.4125 μg/mL. The relative standard deviations (RSDs) range from 0.83% to 5.03%, which showed that this proposed method was accurate and precise to detect mineral elements in coarse grains simultaneously. Correlation coefficients (r) were calculated in the range of 0.999096-0.999989. The sufficient dada obtained described that the coarse grains selected were abundant in mineral element contents in the human body on daily diet. The success of combining the microwave digestion technology with the ICP-AES was a simple and precise method to determine many mineral elements in coarse grains simultaneously.","PeriodicalId":11519,"journal":{"name":"E-journal of Chemistry","volume":"9 1","pages":"93-98"},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2012/869297","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64362498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 8

Synthesis, Characterization and Spectroscopic Studies of A Novel 2-((E)-((2,4- dichlorophenyl)imino)methyl)phenol Schiff Base and Its Metal Complexes 新型2-((E)-((2,4-二氯苯)亚氨基)甲基)苯酚席夫碱及其金属配合物的合成、表征和光谱研究

E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/928162

E. Shamkhy, I. Al-Karkhi

引用次数: 2

Antibacterial Activity of Macrocyclic Complexes of Cu(II), Ni(II) and VO(II) Derived from o-Aminobenzaldehyde 邻氨基苯甲醛衍生的Cu(II)、Ni(II)和VO(II)大环配合物的抗菌活性

E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/953727

K. Anuradha, R. Rajavel

引用次数: 2

Determination of Energy Characteristic and Microporous Volume by Immersion Calorimetry in Carbon Monoliths 浸没量热法测定碳块体的能量特性和微孔体积

E-journal of Chemistry Pub Date : 2012-01-01 DOI: 10.1155/2012/976275

J. Moreno-Piraján, L. Giraldo, D. P. Vargas