ACS Central Science最新文献

筛选
英文 中文
IF 12.7 1区 化学
ACS Central Science Pub Date : 2025-07-23
Xiang-Qian Xie, Wen Guo, Yin-Zheng Xia, Li-Juan Liao, Meng-Xin Sun, Jing-Xue Wang, Jiang-Tao Gao*, Hong-Wei Yao* and Huan Wang*, 
{"title":"","authors":"Xiang-Qian Xie, Wen Guo, Yin-Zheng Xia, Li-Juan Liao, Meng-Xin Sun, Jing-Xue Wang, Jiang-Tao Gao*, Hong-Wei Yao* and Huan Wang*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"11 7","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":12.7,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acscentsci.5c00569","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Entropy Drives the Predictive Discovery of an Optimal Cleavable Comonomer for ROMP 熵驱动ROMP最佳可切割共聚体的预测发现
IF 10.4 1区 化学
ACS Central Science Pub Date : 2025-07-23 DOI: 10.1021/acscentsci.5c00521
Kwangwook Ko, Piper L. MacNicol, Mingming Zhu, Lei Zhang, Saifudin M. Abubakar and Jeremiah A. Johnson*, 
{"title":"Entropy Drives the Predictive Discovery of an Optimal Cleavable Comonomer for ROMP","authors":"Kwangwook Ko,&nbsp;Piper L. MacNicol,&nbsp;Mingming Zhu,&nbsp;Lei Zhang,&nbsp;Saifudin M. Abubakar and Jeremiah A. Johnson*,&nbsp;","doi":"10.1021/acscentsci.5c00521","DOIUrl":"https://doi.org/10.1021/acscentsci.5c00521","url":null,"abstract":"<p >Ring-opening metathesis polymerization (ROMP) of norbornene derivatives enables access to polymeric materials for applications ranging from targeted drug delivery to high-performance thermosets; however, the carbon–carbon backbones of ROMP-derived poly(norbornenes) resist deconstruction under mild, selective conditions. Cleavable comonomers (CCs) have been introduced to address this limitation, yet their implementation has been hindered by prohibitive costs and/or suboptimal reactivity. Moreover, the discovery of existing CCs has been largely empirical, lacking clear design principles. Here, we identify the entropy of ring-opening as one of the key determinants of ROMP copolymerization behavior of the best-performing CCs reported to date. Guided by this insight, we establish predictive design criteria and introduce <b>Me</b><sub><b>4</b></sub><b>Si</b><sub><b>2</b></sub><b>O9</b>, a CC that exhibits near-ideal room temperature copolymerization with a broad range of norbornene-based (macro)monomers. <b>Me</b><sub><b>4</b></sub><b>Si</b><sub><b>2</b></sub><b>O9</b> is significantly less expensive than leading silyl ether-based CCs and enables uniform incorporation of cleavable linkages into polymer backbones at low loadings. Beyond delivering a cost-effective and high-performance CC, this work provides fundamental insights into ROMP copolymerization that will enable predictive CC development and expand the functional scope of deconstructable polymeric materials.</p><p >A novel predictive workflow and entropy-maximizing design enabled the development of a cost-effective cleavable comonomer─<b>Me</b><sub><b>4</b></sub><b>Si</b><sub><b>2</b></sub><b>O9</b>─that uniformly embeds deconstructable bonds in ROMP-derived polymers.</p>","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"11 8","pages":"1408–1416"},"PeriodicalIF":10.4,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acscentsci.5c00521","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144902052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 12.7 1区 化学
ACS Central Science Pub Date : 2025-07-23
{"title":"","authors":"","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"11 7","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":12.7,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/ocv011i007_1962666","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 12.7 1区 化学
ACS Central Science Pub Date : 2025-07-23
Zhangyi Xiong, Shitao Wu, Liang Gu, Mengyang Zhai, Yuke Pan, Yanhang Ma* and Zhijie Chen*, 
{"title":"","authors":"Zhangyi Xiong,&nbsp;Shitao Wu,&nbsp;Liang Gu,&nbsp;Mengyang Zhai,&nbsp;Yuke Pan,&nbsp;Yanhang Ma* and Zhijie Chen*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"11 7","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":12.7,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acscentsci.5c00567","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 12.7 1区 化学
ACS Central Science Pub Date : 2025-07-23
Lauren M. Orr, Sydney J. Tomlinson, Hannah R. Grupe, Melissa Lim, Emily Ho, Halime Yilmaz, Grace Zhou, Barbara Leon, James A. Olzmann* and Daniel K. Nomura*, 
{"title":"","authors":"Lauren M. Orr,&nbsp;Sydney J. Tomlinson,&nbsp;Hannah R. Grupe,&nbsp;Melissa Lim,&nbsp;Emily Ho,&nbsp;Halime Yilmaz,&nbsp;Grace Zhou,&nbsp;Barbara Leon,&nbsp;James A. Olzmann* and Daniel K. Nomura*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"11 7","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":12.7,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acscentsci.5c00959","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 12.7 1区 化学
ACS Central Science Pub Date : 2025-07-23
Brian Choi, Toby G. Johnson, Arthur Acuña, Hader E. Elashal and A. James Link*, 
{"title":"","authors":"Brian Choi,&nbsp;Toby G. Johnson,&nbsp;Arthur Acuña,&nbsp;Hader E. Elashal and A. James Link*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"11 7","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":12.7,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acscentsci.5c00408","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 12.7 1区 化学
ACS Central Science Pub Date : 2025-07-23
Hyejin Lee, Hongjun Jang, Hwan Myung, Angela Rivera, Anna F. Averette, Joseph Heitman, Jiyong Park, Deukjoon Kim, Hyoungsu Kim and Jiyong Hong*, 
{"title":"","authors":"Hyejin Lee,&nbsp;Hongjun Jang,&nbsp;Hwan Myung,&nbsp;Angela Rivera,&nbsp;Anna F. Averette,&nbsp;Joseph Heitman,&nbsp;Jiyong Park,&nbsp;Deukjoon Kim,&nbsp;Hyoungsu Kim and Jiyong Hong*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"11 7","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":12.7,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acscentsci.5c00332","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 12.7 1区 化学
ACS Central Science Pub Date : 2025-07-23
Maria Sara Raju, Maxime Aragon-Alberti, Kevin Cardenas, Ivan Breslavetz, Geert L. J. A. Rikken, Cyrille Train and Matteo Atzori*, 
{"title":"","authors":"Maria Sara Raju,&nbsp;Maxime Aragon-Alberti,&nbsp;Kevin Cardenas,&nbsp;Ivan Breslavetz,&nbsp;Geert L. J. A. Rikken,&nbsp;Cyrille Train and Matteo Atzori*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"11 7","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":12.7,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acscentsci.5c00772","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 12.7 1区 化学
ACS Central Science Pub Date : 2025-07-23
Suman Mandal, Minh Dang Nguyen, Nikhil Ranjan Jana* and T. Randall Lee*, 
{"title":"","authors":"Suman Mandal,&nbsp;Minh Dang Nguyen,&nbsp;Nikhil Ranjan Jana* and T. Randall Lee*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"11 7","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":12.7,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acscentsci.5c00519","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 12.7 1区 化学
ACS Central Science Pub Date : 2025-07-23
Shucheng Song, Chenyang Wang, Wenjing Bao, Zhenchuang Xu, Jian Wu, Liang Lin* and Yanchuan Zhao*, 
{"title":"","authors":"Shucheng Song,&nbsp;Chenyang Wang,&nbsp;Wenjing Bao,&nbsp;Zhenchuang Xu,&nbsp;Jian Wu,&nbsp;Liang Lin* and Yanchuan Zhao*,&nbsp;","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"11 7","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":12.7,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acscentsci.5c00498","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678385","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信