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Preparation of High Self-Healing Diels–Alder (DA) Synthetic Resin and Its Influence on the Surface Coating Properties of Poplar Wood and Glass 高自愈性双桤木合成树脂的制备及其对杨木和玻璃表面涂层性能的影响
3区 材料科学
Coatings Pub Date : 2025-08-24 DOI: 10.3390/coatings15090988
Yang Dong, Xiaoxing Yan
{"title":"Preparation of High Self-Healing Diels–Alder (DA) Synthetic Resin and Its Influence on the Surface Coating Properties of Poplar Wood and Glass","authors":"Yang Dong, Xiaoxing Yan","doi":"10.3390/coatings15090988","DOIUrl":"https://doi.org/10.3390/coatings15090988","url":null,"abstract":"Self-healing coatings can replace conventional coatings and are capable of self-healing and continuing to protect the substrate after coating damage. In this study, two types of self-healing resins were synthesized as coatings: Type-A via Diels–Alder crosslinking of furfuryl-modified diglycidyl ether bisphenol A with bismaleimide, and Type-B through epoxy blending/curing to form a semi-interpenetrating network. FTIR and Raman spectroscopy confirmed the formation of Diels–Alder (DA) bonds, while GPC tests indicated incomplete monomer conversion. Both resins were applied to glass and wood substrates, with performance evaluated through TGA, colorimetry (ΔE), gloss analysis, and scratch-healing tests (120 °C/30 min). The results showed that Type-A resins had a higher healing efficiency (about 80% on glass substrates and 60% on wood substrates), while Type-B resins had a lower healing rate (about 65% on glass substrates and 55% on wood substrates). However, Type-B is more heat-resistant, has a slower decomposition rate between 300 and 400 °C, higher gloss retention, and less color difference (ΔE) between wood and glass substrates. The visible light transmission of Type-B (74.14%) is also significantly higher.","PeriodicalId":10520,"journal":{"name":"Coatings","volume":"15 9","pages":"988-988"},"PeriodicalIF":0.0,"publicationDate":"2025-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2079-6412/15/9/988/pdf?version=1756026085","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147915040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Hydrophobic, Durable, and Reprocessable PEDOT:PSS/PDMS-PUa/SiO2 Film with Conductive Self-Cleaning and De-Icing Functionality PEDOT:具有导电自清洁和除冰功能的PSS/PDMS-PUa/SiO2薄膜
3区 材料科学
Coatings Pub Date : 2025-08-23 DOI: 10.3390/coatings15090985
Jie Fang, Rongqing Dong, Meng Zhou, Lishan Liang, Mingna Yang, Huakun Xing, Yongluo Qiao, Shuai Chen
{"title":"Hydrophobic, Durable, and Reprocessable PEDOT:PSS/PDMS-PUa/SiO2 Film with Conductive Self-Cleaning and De-Icing Functionality","authors":"Jie Fang, Rongqing Dong, Meng Zhou, Lishan Liang, Mingna Yang, Huakun Xing, Yongluo Qiao, Shuai Chen","doi":"10.3390/coatings15090985","DOIUrl":"https://doi.org/10.3390/coatings15090985","url":null,"abstract":"Poly (3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) stands out as a renowned commercial conducting polymer composite, boasting extensive and promising applications in the realm of film electronics. In this study, we have made a concerted effort to overcome the inherent drawbacks of PEDOT:PSS films (especially, high moisture absorption, mechanical damage vulnerability, insufficient substrate adhesion ability, etc.) by uniformly blending them with polydimethylsiloxane polyurea (PDMS-PUa) and silica (SiO2) nanoparticles through a feasible mechanical stirring process, which effectively harnesses the intermolecular interactions, as well as the morphological and structural characteristics, among the various components. The Si−O bonds within PDMS-PUa and the −CH3 groups attached to Si atoms significantly enhance the hydrophobicity of the composite film (as evidenced by a water contact angle of 132.89° under optimized component ratios). Meanwhile, SiO2 microscopically modifies the surface morphology, resulting in increased surface roughness. This composite film not only maintains high conductivity (1.21 S/cm, in contrast to 0.83 S/cm for the PEDOT:PSS film) but also preserves its hydrophobicity and electrical properties under rigorous conditions, including high-temperature exposure (60–200 °C), ultraviolet (UV) aging (365.0 nm, 1.32 mW/cm2), and abradability testing (2000 CW abrasive paper, drag force of approximately 0.98 N, 40 cycles). Furthermore, the film demonstrates enhanced resistance to both acidic (1 mol/L, 24 h) and alkaline (1 mol/L, 24 h) environments, along with excellent self-cleaning and de-icing capabilities (−6 °C), and satisfactory adhesion (Level 2). Notably, the dried composite film can be re-dispersed into a solution with the aid of isopropanol through simple magnetic stirring, and the sequentially coated films also exhibit good surface hydrophobicity (136.49°), equivalent to that of the pristine film. This research aims to overcome the intrinsic performance drawbacks of PEDOT:PSS-based materials, enabling them to meet the demands of complex application scenarios in the field of organic electronics while endowing them with multifunctionality.","PeriodicalId":10520,"journal":{"name":"Coatings","volume":"15 9","pages":"985-985"},"PeriodicalIF":0.0,"publicationDate":"2025-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2079-6412/15/9/985/pdf?version=1755934294","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147912560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Mechanistic Investigation of the Corrosion Behavior of Organic Zn14Al1.4 Composite Coating Under Simulated Tropical Marine Atmospheric Conditions 模拟热带海洋大气条件下Zn14Al1.4有机复合涂层腐蚀机理研究
3区 材料科学
Coatings Pub Date : 2025-08-22 DOI: 10.3390/coatings15090981
Hao Zhang, Hao Yu, Chang Liu, Yesheng Huang, Haoyu Wu, Pan Yi, Kui Xiao, Jin Gao
{"title":"Mechanistic Investigation of the Corrosion Behavior of Organic Zn14Al1.4 Composite Coating Under Simulated Tropical Marine Atmospheric Conditions","authors":"Hao Zhang, Hao Yu, Chang Liu, Yesheng Huang, Haoyu Wu, Pan Yi, Kui Xiao, Jin Gao","doi":"10.3390/coatings15090981","DOIUrl":"https://doi.org/10.3390/coatings15090981","url":null,"abstract":"The coupled factors of high temperature, high humidity, and high salinity in tropical marine atmospheres severely threaten the long-term service performance of power transmission and transformation infrastructure. This paper establishes an accelerated cyclic testing protocol (salt spray → drying → damp heat → drying) to evaluate performance and elucidate the dynamic corrosion failure mechanisms of the organic Zn14Al1.4 composite coating. By integrating multiphysical characterization techniques (SEM, EDS, XPS) with electrochemical analysis, this study for the first time elucidates the dynamic transformation of corrosion products: initially dominated by Zn(OH)2, progressing to complex passive phases such as Zn5(OH)8Cl2·H2O, Zn5(OH)6(CO3)2, and Zn6Al2(OH)16CO3 in the mid-term, and ultimately dominated by Fe-based products (FeO, Fe2O3, Fe3O4, FeOOH) that drive interfacial failure. And a four-stage corrosion evolution model was defined: incubation period, accelerated degradation phase, substrate nucleation stage, and catastrophic failure phase. The investigation reveals a shift in the coating/substrate interface failure mechanism from purely physical barrier effects to electrochemical synergy, providing a theoretical framework for the optimized design and service-life prediction of anticorrosive coatings for transmission and transformation equipment in tropical environments.","PeriodicalId":10520,"journal":{"name":"Coatings","volume":"15 9","pages":"981-981"},"PeriodicalIF":0.0,"publicationDate":"2025-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2079-6412/15/9/981/pdf?version=1755860657","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147909610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Multifunctional PDMS Composite Coating for Advanced Anti-Icing with Concurrent Mechanical Durability and Corrosion Protection 同时具有机械耐久性和防腐性能的先进防冰多功能PDMS复合涂层
3区 材料科学
Coatings Pub Date : 2025-08-21 DOI: 10.3390/coatings15080979
Zaixiang Zheng, Shutong Wu, Jiawei Luo, Shengnan Yang, Junnan Cui, Zhimin Cao, Pan Cao
{"title":"Multifunctional PDMS Composite Coating for Advanced Anti-Icing with Concurrent Mechanical Durability and Corrosion Protection","authors":"Zaixiang Zheng, Shutong Wu, Jiawei Luo, Shengnan Yang, Junnan Cui, Zhimin Cao, Pan Cao","doi":"10.3390/coatings15080979","DOIUrl":"https://doi.org/10.3390/coatings15080979","url":null,"abstract":"Ice accretion on critical transportation infrastructure presents serious operational risks and economic challenges, highlighting the need for sustainable anti-icing solutions. This study develops a strong PDMS-based composite coating on aluminum by incorporating carbon nanotubes (CNTs) and carbon powder, effectively merging passive superhydrophobicity with photothermal capabilities. We systematically assess how different ratios of CNTs to carbon powder (3:1, 1:1, 1:3) influence surface morphology, wettability, anti-icing performance, mechanical durability, and corrosion resistance. The morphological analysis shows the formation of hierarchical micro/nano-structures, with the optimal 1:3 ratio (designated as P13) resulting in dense, porous agglomerates of intertwined CNTs and carbon powder. P13 demonstrates high-performing superhydrophobicity, with a contact angle of 139.7° and a sliding angle of 9.4°, alongside a significantly extended freezing delay of 180 s at −20 °C. This performance is attributed to reduced water–surface interaction and inhibited ice nucleation. Mechanical abrasion tests indicate remarkable durability, as P13 retains a contact angle of 132.5° and consistent anti-icing properties after enduring 100 abrasion cycles. Electrochemical analysis reveals exceptional corrosion resistance, particularly for P13, which achieves a notable 99.66% corrosion inhibition efficiency by creating a highly tortuous diffusion barrier that protects against corrosive agents. This multifunctional coating effectively utilizes the photothermal properties of CNTs, the affordability of carbon powder, the low surface energy of PDMS, and the thermal conductivity of aluminum, presenting a robust and high-performance solution for anti-icing applications in challenging environments.","PeriodicalId":10520,"journal":{"name":"Coatings","volume":"15 8","pages":"979-979"},"PeriodicalIF":0.0,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2079-6412/15/8/979/pdf?version=1755832681","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147331469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of Biomimetical TiO2@PVDF Composite Membrane with Omniphobicity via In-Situ Growth and Its Anti-Fouling Performance 原位生长制备仿生全疏水性TiO2@PVDF复合膜及其防污性能
3区 材料科学
Coatings Pub Date : 2025-08-19 DOI: 10.3390/coatings15080965
Wei Zhang, Xuran Zhu, Baoan Li, Boyang Hu, Leyu Shen, Yuebo Meng, Haifeng Gao
{"title":"Fabrication of Biomimetical TiO2@PVDF Composite Membrane with Omniphobicity via In-Situ Growth and Its Anti-Fouling Performance","authors":"Wei Zhang, Xuran Zhu, Baoan Li, Boyang Hu, Leyu Shen, Yuebo Meng, Haifeng Gao","doi":"10.3390/coatings15080965","DOIUrl":"https://doi.org/10.3390/coatings15080965","url":null,"abstract":"Commercial hydrophobic membranes encounter severe problems such as membrane wetting and membrane fouling under extreme conditions, which affect membrane separation performance. To enhance the anti-fouling abilities of hydrophobic membranes, a composite membrane with omniphobic characteristics was fabricated successfully in this paper. Titanium dioxide (TiO2) nanoparticles were in-situ grown via the hydrothermal synthesis method, and then fluorosilane with low surface energy was grafted on polyvinylidene fluoride (PVDF) membranes. Subsequently, the morphologies, chemical compositions, wetting properties and structural parameters of composite membranes were characterized systematically. Various contaminants were added to the feed to investigate the anti-fouling and anti-wetting performances of the composite membrane in membrane distillation tests. The results showed that butyl titanate was first hydrolyzed to form titanium hydroxide (Ti(OH)4) and then it was dehydrated to form TiO2 in the hydrothermal environment. TiO2 crystals continued to grow and formed rough morphology with micro-nano synergistic distribution, which is similar to a “sunflower” disk composed of cubic clusters and nanopillars. Meanwhile, fluorosilane successfully was grafted onto TiO2. The contact angles of deionized water, 0.4 mM sodium dodecyl sulfate (SDS) solution and 0.2% v/v mineral oil emulsion on the composite membrane surface were 167.3°, 162.0° and 158.5°, respectively, endowing the composite membrane with excellent omniphobic features. In direct contact membrane distillation (DCMD) tests, the composite membrane exhibited a relatively stable membrane permeate flux, and the salt rejection rate almost reached 100%. The mixture, consisting of inorganic salts, organic substances, surfactants and oil emulsions, was used as feed. In contrast, the commercial PVDF membrane flux decreased drastically and even dropped to 0 due to the membrane fouling and wetting. As for the pristine PVDF membrane, the membrane surface was covered with pollutants and membrane pores were blocked. Therefore, it was proved that the omniphobic composite membrane possesses outstanding anti-fouling and anti-wetting performance.","PeriodicalId":10520,"journal":{"name":"Coatings","volume":"15 8","pages":"965-965"},"PeriodicalIF":0.0,"publicationDate":"2025-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2079-6412/15/8/965/pdf?version=1755610600","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147333542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hygrosensitive Response and Characteristics of Copolymer Coatings with Potential for Humidity Monitoring 具有湿度监测潜力的共聚物涂料的湿敏响应及特性
3区 材料科学
Coatings Pub Date : 2025-08-14 DOI: 10.3390/coatings15080954
Katerina Lazarova, Silvia Bozhilova, Martina Docheva, Ketrin Pavlova, Gergana Alexieva, Darinka Christova, Tsvetanka Babeva
{"title":"Hygrosensitive Response and Characteristics of Copolymer Coatings with Potential for Humidity Monitoring","authors":"Katerina Lazarova, Silvia Bozhilova, Martina Docheva, Ketrin Pavlova, Gergana Alexieva, Darinka Christova, Tsvetanka Babeva","doi":"10.3390/coatings15080954","DOIUrl":"https://doi.org/10.3390/coatings15080954","url":null,"abstract":"Newly developed hygrosensitive poly(vinyl alcohol) derivatives comprising grafted poly(N,N-dimethylacrylamide) chains of varied length and graft density are presented. The optical, sensing, and hydration properties of these copolymer thin films prepared by spin-coating were systematically studied. Refractive indices (n), absorption coefficients (k), and thicknesses (d) were calculated via curve fitting of the reflection spectra. Reflectance measurements across a relative humidity range of 5% to 95% were used to evaluate the humidity sensing behavior. Coating swelling exceeding 100% was observed. Hydration levels under high humidity conditions were studied using a quartz crystal microbalance method. This revealed approximately 24% water content in the polymer with the higher grafting density and shorter PDMA chains compared to around 31% in the copolymer with longer PDMA brushes that were loosely grafted The potential application of these copolymers as responsive materials for advanced humidity sensing is discussed. A combined optical and gravimetric approach for characterizing the humidity sensing properties of thin nanosized coatings is demonstrated, providing opportunities for advanced characterization of new functional materials, thus broadly contributing to the state of the art of sensor technologies.","PeriodicalId":10520,"journal":{"name":"Coatings","volume":"15 8","pages":"954-954"},"PeriodicalIF":0.0,"publicationDate":"2025-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2079-6412/15/8/954/pdf?version=1755169866","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147904216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Photocatalytic Performance of 3D-Printed Triply Periodic Minimal Surface Photocatalytic Reactors 3d打印三周期最小表面光催化反应器的光催化性能
3区 材料科学
Coatings Pub Date : 2025-08-14 DOI: 10.3390/coatings15080953
Xi Chen, Chenxi Zhang, Qi Chen, Xiao Chen, Ningning Li
{"title":"Photocatalytic Performance of 3D-Printed Triply Periodic Minimal Surface Photocatalytic Reactors","authors":"Xi Chen, Chenxi Zhang, Qi Chen, Xiao Chen, Ningning Li","doi":"10.3390/coatings15080953","DOIUrl":"https://doi.org/10.3390/coatings15080953","url":null,"abstract":"To overcome poor catalyst recovery and inefficient mass transfer in photocatalytic water treatment, this study presents novel Triply Periodic Minimal Surface (TPMS) photocatalytic reactors (PCRs) fabricated via Stereolithography (SLA) 3D printing. Five TiO2-loaded reactors (Fischer-Radin-Dunn (FRD), Neovius (N), Diamond (D), I-graph Wrapped Package (IWP), Gyroid (G)) with hierarchical porosity were designed. Using methylene blue (MB) as the target pollutant, the photocatalytic degradation performance of TPMS-PCRs is evaluated and Computational Fluid Dynamics (CFD) hydrodynamic simulations are conducted to analyze their flow characteristics under both horizontal and rotational flow fields. The catalytic efficiency of TPMS reactors is influenced not only by pore characteristics, specific surface area, and inter-pore connectivity, but also by the flow velocities on both the reactor surface and within its internal channels. The FRD-type TPMS-PCR loaded with 2.5 wt% TiO2 exhibited optimal photocatalytic performance, achieving 95.36% degradation efficiency under rotational flow within 2.5 h, compared to 88.2% under horizontal flow. Remarkably, after five degradation cycles, its efficiency further improved to 96.7%, demonstrating its excellent stability. The rotational flow field enhanced the average flow velocity by approximately sixfold compared to horizontal flow, with the D-type reactor reaching a maximum surface velocity of 5.3 × 10−2 m/s.","PeriodicalId":10520,"journal":{"name":"Coatings","volume":"15 8","pages":"953-953"},"PeriodicalIF":0.0,"publicationDate":"2025-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2079-6412/15/8/953/pdf?version=1755218884","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147332587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Construction and Performance Optimization of a Multifunctional CHP-Ti-MAO Composite Coating: Antibacterial Activity, Controlled Drug Release, and Corrosion Resistance 多功能CHP-Ti-MAO复合涂层的构建与性能优化:抗菌活性、药物控释和耐蚀性
3区 材料科学
Coatings Pub Date : 2025-08-13 DOI: 10.3390/coatings15080948
Liting Mu, Yiqi Lian, Shiyu Zheng, Shuo Chang, Ximeng Li, Changhai Sun, Hongbing Qiu
{"title":"Construction and Performance Optimization of a Multifunctional CHP-Ti-MAO Composite Coating: Antibacterial Activity, Controlled Drug Release, and Corrosion Resistance","authors":"Liting Mu, Yiqi Lian, Shiyu Zheng, Shuo Chang, Ximeng Li, Changhai Sun, Hongbing Qiu","doi":"10.3390/coatings15080948","DOIUrl":"https://doi.org/10.3390/coatings15080948","url":null,"abstract":"Titanium and its alloys are widely used in orthopedics because of their excellent mechanical properties and biocompatibility; however, their bioinert surface results in sluggish osseointegration and renders implants susceptible to bacterial infection. This study innovatively constructed a “CHP-Ti-MAO” composite coating, which aims to simultaneously improve early osseointegration and antibacterial performance. CHP micron coatings coated with hydroxyapatite (HA) and curcumin (Cur) at different PLGA concentrations (50%, 100%, and 150%) were deposited on the basis of calcium–phosphorus ceramic coatings prepared by micro-arc oxidation (MAO) following the emulsification-solvent volatilization method. It was found that increasing the concentration of PLGA can increase the particle size of the coating, enhance the hydrophilicity, and significantly improve the sustained release performance of the drug. Among them, the 100% PLGA concentration group performed the best: the drug-release half-life reached 75 h, and the corrosion current density was the lowest (9.5 × 10−9 A/cm2), showing the best corrosion resistance. This group of coatings has a strong and long-term antibacterial effect on Escherichia coli, with an antibacterial rate of more than 95% at 24 h and more than 99% by day 17. The hemolysis rate of all coatings was lower than 5%, indicating good biocompatibility. This study confirmed that 100% CHP-Ti-MAO composite coating successfully solved the limitations of excessive pore size and insufficient antibacterial persistence of an MAO layer and also had excellent slow-release, corrosion resistance, and high-efficiency antibacterial capabilities, which provided an important basis for the development of a new generation of multifunctional titanium-based implants.","PeriodicalId":10520,"journal":{"name":"Coatings","volume":"15 8","pages":"948-948"},"PeriodicalIF":0.0,"publicationDate":"2025-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2079-6412/15/8/948/pdf?version=1755082298","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147908788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Study of Polyhedral Oligomeric Silsesquioxane-Modified Superwetting Transparent Coating for Anti-Fogging, Stain Resistance, Self-Cleaning and Anti-Biological Application 多面体低聚硅氧烷改性防雾、耐污、自洁、抗生物超湿透明涂料的研究
3区 材料科学
Coatings Pub Date : 2025-08-11 DOI: 10.3390/coatings15080936
Weibiao Zhu, Jinxin He, Xia Dong
{"title":"Study of Polyhedral Oligomeric Silsesquioxane-Modified Superwetting Transparent Coating for Anti-Fogging, Stain Resistance, Self-Cleaning and Anti-Biological Application","authors":"Weibiao Zhu, Jinxin He, Xia Dong","doi":"10.3390/coatings15080936","DOIUrl":"https://doi.org/10.3390/coatings15080936","url":null,"abstract":"Transparent coatings with superwetting properties (superhydrophilicity or superhydrophobicity) have broad application prospects. Usually, most studies have been carried out separately on superhydrophobic coatings or superhydrophilic coatings. In our work, superhydrophilic transparent coatings were prepared by the four-mercapto and four-polyethylene glycol monomethyl acrylate modified POSS (POSS-(SH)4-(PEGMA)4) (designated as I-coating) as well as superhydrophobic transparent coating (designated as O-coating) were prepared with the mercapto and seven-heptyl decafluoroheptyl acrylate modified POSS (POSS-SH-(DFMA)7). The similarities and differences in anti-fogging, stain resistance, self-cleaning and anti-biological application between superhydrophobic and superhydrophilic coatings were compared systematically. The results show that superhydrophilic coatings performed better at preventing fog and facilitating self-cleaning; nevertheless, superhydrophobic coatings exhibited superior efficacy in the removal of contaminants such as markers and lipsticks. Both superwetting coatings demonstrated proficiency in self-cleaning and in deterring biological adhesion with respect to low-viscosity oil droplets. The relevant research of this paper provided a reference for the subsequent study on the advantages and disadvantages of superhydrophilic and superhydrophobic as well as its specific application.","PeriodicalId":10520,"journal":{"name":"Coatings","volume":"15 8","pages":"936-936"},"PeriodicalIF":0.0,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2079-6412/15/8/936/pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147917982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
SERS and Chiral Properties of Cinnamic Acid Derivative Langmuir-Blodgett Films Complexed with Dyes 肉桂酸衍生物Langmuir-Blodgett膜与染料络合的SERS和手性
3区 材料科学
Coatings Pub Date : 2025-08-01 DOI: 10.3390/coatings15080890
Xingdi Zhao, Xinyu Li, Pengfei Bian, Qingrui Zhang, Yuqing Qiao, Mingli Wang, Tifeng Jiao
{"title":"SERS and Chiral Properties of Cinnamic Acid Derivative Langmuir-Blodgett Films Complexed with Dyes","authors":"Xingdi Zhao, Xinyu Li, Pengfei Bian, Qingrui Zhang, Yuqing Qiao, Mingli Wang, Tifeng Jiao","doi":"10.3390/coatings15080890","DOIUrl":"https://doi.org/10.3390/coatings15080890","url":null,"abstract":"Chiral molecules are crucial in the field of optical devices, molecular recognition, and other novel functional materials due to their unique spatially asymmetric configuration and optical activity. In this study, a chiral molecule, Cholest-3-yl (E)-3-(4-carbamoylphenyl)acrylate (CCA), was combined with dyes containing large conjugated structures, tetramethylporphyrin tetrasulfonic acid (TPPS), and Nickel(II) phthalocyanine-tetrasulfonic acid tetrasodium salt (TsNiPc), and composite LB films of CCA/TPPS and CCA/TsNiPc were successfully prepared by using Langmuir-Blodgett (LB) technology. The circular dichroism (CD) test proved that the CCA/TPPS composite film had a strong CD signal at 300–400 nm, and the composite film showed chirality. This significant optical activity provides a new idea and option for the application of LB films in chiral sensors. In the Surface Enhanced Raman Spectroscopy (SERS) test, the CCA/TPPS composite film was sensitive to signal sensing, in which the enhancement factor EF = 2.28 × 105, indicating that a large number of effective signal response regions were formed on the surface of the film, and the relative standard deviation (RSD) = 12.08%, which demonstrated that the film had excellent uniformity and reproducibility. The high sensitivity and low signal fluctuation make the CCA/TPPS composite LB film a promising SERS substrate material.","PeriodicalId":10520,"journal":{"name":"Coatings","volume":"15 8","pages":"890-890"},"PeriodicalIF":0.0,"publicationDate":"2025-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2079-6412/15/8/890/pdf?version=1754014030","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147881305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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