Judith Straathof, Zuzana Bohrerova, Natalie M. Hull
{"title":"Impact of flocculated and softened particles on UV254 inactivation of indigenous spores","authors":"Judith Straathof, Zuzana Bohrerova, Natalie M. Hull","doi":"10.1002/aws2.70010","DOIUrl":"https://doi.org/10.1002/aws2.70010","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <p>US regulatory ultraviolet (UV) disinfection credit is typically granted when turbidity is ≤1 NTU. However, studies show turbidity does not always correlate well with UV dose responses. This study examined the impact of worst-case high turbidity scenarios at drinking water treatment plants on UV<sub>254</sub> inactivation of indigenous spores from unfiltered source water and unsettled flocculation and softening steps. Flocculated water (turbidity = 6.49–164 NTU) had the lowest dose response with a significantly lower Geeraerd-tail maximum inactivation rate (<i>k</i><sub>max</sub> = 0.021 cm<sup>2</sup>/mJ) and higher residual population density (<i>N</i><sub>res</sub> = 7.081 SFU/mL). Raw source water (<i>k</i><sub>max</sub> = 0.027 cm<sup>2</sup>/mJ, <i>N</i><sub>res</sub> = 1.168 SFU/mL, turbidity = 0.978–215 NTU) and softened water (<i>k</i><sub>max</sub> = 0.030 cm<sup>2</sup>/mJ, <i>N</i><sub>res</sub> = 0.216 SFU/mL, turbidity = 318–495 NTU) had similar dose responses despite significantly different water quality. Particle size and the degree of particle-associated spores best explained the differences in dose responses. Almost all spores were associated with flocculated particles instead of free-floating, which increased tailing and negatively impacted UV inactivation. Based on regulatory reduction equivalent dose bias factors and UV sensitivities of spiked <i>Bacillus subtilis</i> spores, <i>Cryptosporidium</i> would be 4-log inactivated in these raw, flocculated, or softened waters if UV transmission were ≥65%, 90%, or 80%, respectively, even though turbidity was grossly >1 NTU. Depending on particle characteristics, partial inactivation credit when turbidity is >1 NTU should be considered to avoid high-tier violations while still protecting public health.</p>\u0000 </section>\u0000 </div>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"6 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aws2.70010","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143118150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Julie A. Korak, Philip J. Brandhuber, Joseph E. Goodwill
{"title":"Lithium in drinking water: Review of chemistry, analytical methods, and treatment technologies","authors":"Julie A. Korak, Philip J. Brandhuber, Joseph E. Goodwill","doi":"10.1002/aws2.70009","DOIUrl":"https://doi.org/10.1002/aws2.70009","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <p>Lithium was included in the fifth Unregulated Contaminants Monitoring Rule, signaling the Environmental Protection Agency's interest in regulating lithium. Many questions regarding occurrence, health effects, and treatability of lithium exist. This review primarily focuses on the relationship between lithium chemistry and treatability. Sampling indicates nationwide lithium occurrence in drinking water. Yet, lithium is not included in the Integrated Risk Information System, reflecting a lack of censuses regarding its health effects. Aqueous lithium is a monovalent cation with size, charge density, and solubility properties that present treatment challenges. Lithium's growing economic value is stimulating new extraction and isolation technologies, but these may not be transferable to drinking water treatment. Currently, reverse osmosis is the only full-scale drinking water treatment technology that can reliably remove significant levels (>50%) of lithium. Focusing future research efforts on electrodialysis and inorganic ion sieves may yield significant gains in effectiveness and readiness for the drinking water industry.</p>\u0000 </section>\u0000 </div>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"6 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142861636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hari Seshan, Michael J. Adelman, Paige J. Russell, Joseph Quicho, Daniel Daft, Thomas Watson
{"title":"A pilot-scale study of potable reuse impacts on surface water treatment","authors":"Hari Seshan, Michael J. Adelman, Paige J. Russell, Joseph Quicho, Daniel Daft, Thomas Watson","doi":"10.1002/aws2.70008","DOIUrl":"https://doi.org/10.1002/aws2.70008","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <p>Interest is growing in direct potable reuse where advanced-treated water and raw water are blended and fed directly to a water treatment plant (WTP). However, the impacts of raw water augmentation on treatability at drinking water treatment plants have not been studied extensively. A pilot-scale treatment system, consisting of coagulation, flocculation, sedimentation, and filtration, was set up at a WTP to treat potential future blends of advanced-treated water and current raw water. The pilot plant was run with blends from 20% to 100% advanced-treated water at a range of filtration rates (2–9 gpm/sf) and coagulant doses. Under all conditions, filterable water was produced, achieving acceptable turbidity removal. Turbidity removal by sedimentation was variable (30%–90%). Filtration performance was more consistent, exceeding 90% turbidity reduction under all conditions and achieving lower headloss accumulation rates at higher advanced-treated water share. These results are optimistic for potable reuse schemes featuring raw water augmentation.</p>\u0000 </section>\u0000 </div>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"6 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142860013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Theresa J. Boehmer, Erin K. Hamilton, Srdjan Lesaja, Bertram Thomas, Lorena Espinoza, Rachel Kaufmann, Chandresh N. Ladva
{"title":"2015 United States Public Health Service optimal fluoride level adherence and operation among adjusting water systems in 40 states: 2016–2021","authors":"Theresa J. Boehmer, Erin K. Hamilton, Srdjan Lesaja, Bertram Thomas, Lorena Espinoza, Rachel Kaufmann, Chandresh N. Ladva","doi":"10.1002/aws2.70007","DOIUrl":"https://doi.org/10.1002/aws2.70007","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <p>In 2015, the United States Public Health Service (USPHS) set a target fluoride level for drinking water at 0.7 mg/L to maximize oral health benefits while minimizing any potential harms. Using water fluoridation operational data reported by water systems to the Centers for Disease Control and Prevention (CDC) Water Fluoridation Reporting System (WFRS) during 2016–2021, this study assesses how water systems performed around this target. The authors summarize completeness of data reporting, assess the distribution of monthly average fluoride readings (MAFR) values, and evaluate precision in maintaining fluoride levels. About 69% of adjusting systems provided data, with an average completeness of 63.8% among them. MAFR mean was 0.71 mg/L (SD: 0.20 mg/L), indicating that water systems have primarily adopted the USPHS target. About 76% of MAFRs fell ± 0.1 mg/L around the reporting system point's mean, indicating feasibility in maintaining precision around a target. State programs and water systems could work together to improve data quality and educate operators on best practices.</p>\u0000 </section>\u0000 </div>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"6 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142764152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
David G. Wahman, Michael R. Schock, Darren A. Lytle
{"title":"Drinking water buffer intensity simulator (BIS): Development and practical simulations","authors":"David G. Wahman, Michael R. Schock, Darren A. Lytle","doi":"10.1002/aws2.70006","DOIUrl":"https://doi.org/10.1002/aws2.70006","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <p>An established body of research over many decades has identified the importance of both bulk-water and pipe scale surface microenvironment buffering to meet distribution system pH targets and reduce corrosivity toward metallic piping and components. Buffer intensity quantifies the ability of water to resist pH changes, and the greater the buffer intensity, the more resistant the water is to pH changes. To provide a practical tool for exploring buffer intensity, a buffer intensity simulator (BIS) was implemented in open-source R code, incorporating typical chemical species (e.g., carbonate and orthophosphate) that contribute to drinking water buffer intensity along with temperature and ionic strength impacts. The BIS was verified against a parallel spreadsheet implementation and is publicly available at https://github.com/USEPA/BIS. Simulations were conducted to illustrate impacts related to buffer intensity using three practical scenarios: carbonate buffering in drinking waters, temperature impacts, and free ammonia presence from chloramine use and/or source water presence.</p>\u0000 </section>\u0000 </div>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"6 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The role of genus Bacillus in biodegradation of microcystins: Implications for the removal of cyanotoxins from tropical freshwaters","authors":"Madhuni Madhushika Wijesooriya, Kanaji Masakorala, Widana Gamage Shirani Manel Kumari","doi":"10.1002/aws2.70005","DOIUrl":"https://doi.org/10.1002/aws2.70005","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <p>The proliferation of harmful cyanobacterial blooms poses a threat to the ecosystem and human health. Microcystins (MCs) are the most frequently detected cyanotoxin released by cyanobacteria, including <i>Microcystis</i> sp. Our study aimed to isolate potential MC-degrading bacteria in Sri Lankan freshwater and determine their possible MC-degradation pathways. Twenty-two morphologically distinct bacterial strains from 13 freshwater bodies were isolated following the enrichment assay. MC-biodegradation assays further confirmed the MC-degradation potential of 21 strains, with <i>Bacillus</i> being the predominant genus. The strain <i>Bacillus altitudinis</i> BL1, isolated from Beira Lake, showed the highest efficiency in <i>Microcystis</i> sp. cell lysis (80%) and MC-degradation (87%). PCR assay results confirmed the absence of <i>mlr</i>ABCD genes in all strains, indicating the presence of uncharacterized alternative MC-degradation mechanisms that require further exploration. The dual functions of <i>Microcystis</i> sp. cell lysis and MC-degradation in 21 strains support developing efficient bacteria-mediated strategies to remediate microcystins and eradicate <i>Microcystis</i>-blooms in tropical freshwaters.</p>\u0000 </section>\u0000 </div>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"6 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Chlorine conversion impact on activated carbon block filters: Water quality and nitrification risk in chloraminated water","authors":"Horace Jakpa, Katherine Alfredo","doi":"10.1002/aws2.70003","DOIUrl":"https://doi.org/10.1002/aws2.70003","url":null,"abstract":"<p>The effectiveness of a periodic free chlorine conversion period (FClP) as a nitrification mitigation measure has been scrutinized in chloraminated distribution systems, and knowledge about the response of activated carbon block (ACB) point-of-use (POU) filters to this practice is unknown. In this study, three similar filters were monitored bracketing three successive FClPs in the laboratory, aimed at studying the response of ACB POU filters to FClP and the occurrence of nitrification. Results indicate that stagnating filters fostered biofilm growth and increased nitrite concentration (2.5 mg/L-N) above the EPA maximum contaminant level (MCL). Despite FClP being effective at mitigating nitrification and reducing nitrite concentration far below EPA MCL, this was only temporary. Filters that were microbially seeded before an FClP event re-nitrified immediately after chloramination resumed. Successive FClPs induced a microbial community change and failed at controlling nitrification, resulting in elevated nitrite and microbial exposure.</p>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"6 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142525612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Carleigh C. Samson, Sheldon V. Masters, Christian Ley Mathews, Chad J. Seidel
{"title":"Estimating the impact of the proposed Lead and Copper Rule Improvements","authors":"Carleigh C. Samson, Sheldon V. Masters, Christian Ley Mathews, Chad J. Seidel","doi":"10.1002/aws2.70004","DOIUrl":"https://doi.org/10.1002/aws2.70004","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <p>Lead in drinking water can lead to serious health effects, including neurodevelopmental issues and heart disease. In December 2023, the U.S. Environmental Protection Agency (EPA) proposed the Lead and Copper Rule Improvements (LCRI), which lower the Lead and Copper Rule's (LCR's) lead action level (AL) from 15 parts per billion (ppb) to 10 ppb and require both first- and fifth-liter sampling and 90th percentile compliance calculations based on the highest lead levels at sites with lead service lines. A methodology for estimating the likelihood a system will have an AL exceedance (ALE) under the LCRI was developed using Michigan LCR compliance data and applied to national LCR compliance data. Findings were compared to EPA's estimates, indicating EPA may have underestimated the percent of smaller systems (serving <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mo>≤</mo>\u0000 </mrow>\u0000 <annotation>$$ le $$</annotation>\u0000 </semantics></math> 3300) with ALEs and overestimated the percent of larger systems (serving > 10,000), thus underestimating costs and overestimating the benefits of this rulemaking.</p>\u0000 </section>\u0000 </div>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"6 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aws2.70004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142451256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
David A. Cornwell, George Kamenov, Nancy E. McTigue
{"title":"The use of lead isotopes for determining sources of lead in drinking water","authors":"David A. Cornwell, George Kamenov, Nancy E. McTigue","doi":"10.1002/aws2.70002","DOIUrl":"https://doi.org/10.1002/aws2.70002","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <p>A series of paired samples were analyzed to determine if high-precision lead isotopic fingerprinting could help identify the source of lead in plumbing materials and drinking water. Samples were obtained of plumbing materials (lead service lines, copper pipe with lead solder, galvanized materials, and brass fixtures) from water utilities across the United States. Lead samples were taken from the material itself, from scales, and in some cases from associated water. The lead samples were analyzed to determine the ratios of the four stable lead isotopes present. The results enabled the identification of relationships between various components and further aided in the identification of the source of lead found in water and in pipe scales. Isotopic fingerprinting, as demonstrated in this study, could be used to determine if a galvanized line is a galvanized line requiring replacement (GRR) under the Lead and Copper Rule Improvements (USEPA, 2023).</p>\u0000 </section>\u0000 </div>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"6 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142435327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Matthew Vedrin, Joseph N. S. Eisenberg, Sarah Page, Rebecca Lahr, Brian Steglitz, Rebecca Hardin, Lutgarde Raskin
{"title":"Repeated conventional flushing to improve water quality in a full-scale distribution system","authors":"Matthew Vedrin, Joseph N. S. Eisenberg, Sarah Page, Rebecca Lahr, Brian Steglitz, Rebecca Hardin, Lutgarde Raskin","doi":"10.1002/aws2.70001","DOIUrl":"https://doi.org/10.1002/aws2.70001","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <p>One of the primary ways utilities prevent and address water quality concerns in distribution systems is via regular hydrant flushing, yet rigorous research to evaluate the impact of full-scale flushing programs is limited. This study employed time-series and correlation analyses to evaluate the efficacy of a utility's five-month repeated conventional flushing program to reduce nitrification and improve disinfectant residual concentrations in the distribution system. Short-term water quality improvements during flushes were common across the 16 locations flushed, but lasting improvements were inconsistent as demonstrated by continued nitrification and heterogeneous water quality changes. Flushing frequencies and flow rates may need to be tailored to individual sites, even when similar water quality challenges exist. Water quality monitoring data and related analyses helped to prioritize flush sites, maximize efficiency during and between flushes, and inform decisions to implement additional interventions.</p>\u0000 </section>\u0000 </div>","PeriodicalId":101301,"journal":{"name":"AWWA water science","volume":"6 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aws2.70001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142404530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}