The Chemical Engineering Journal and the Biochemical Engineering Journal最新文献

筛选
英文 中文
Hydrodynamics and mass transfer in a cocurrent packed column: A theoretical study 共流填料柱的流体力学与传质:理论研究
The Chemical Engineering Journal and the Biochemical Engineering Journal Pub Date : 1996-08-01 DOI: 10.1016/0923-0467(96)03080-1
S.A. Beg, M.M. Hassan, M.S.M. Naqvi
{"title":"Hydrodynamics and mass transfer in a cocurrent packed column: A theoretical study","authors":"S.A. Beg,&nbsp;M.M. Hassan,&nbsp;M.S.M. Naqvi","doi":"10.1016/0923-0467(96)03080-1","DOIUrl":"10.1016/0923-0467(96)03080-1","url":null,"abstract":"<div><p>A realistic model has bene developed for the hydrodynamics and mass transfer in a cocurrent packed column. It postulates that the liquid phase is divided into stagnant and dynamic regions. Unlike in other models, the stagnant phase is not completely mixed and its concentration profile is given by a Fickian-type model equation. The model considers axial dispersion in the dynamic phase and mass transfer between the stagnant and dynamic regions of the liquid phase. The resulting partial differential equations are solved numerically by the method of orthogonal collocation. Simulation results highlighting the effects of various parameters for a step input and a step decrease in tracer concentration are also presented. The model predictions for both the downflow and upflow modes of operation are compared with available experimental data and are found to agree well.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"63 2","pages":"Pages 93-103"},"PeriodicalIF":0.0,"publicationDate":"1996-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-0467(96)03080-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80090337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Development of adaptive neural networks for flexible control of batch processes 批量过程柔性控制的自适应神经网络研究
The Chemical Engineering Journal and the Biochemical Engineering Journal Pub Date : 1996-08-01 DOI: 10.1016/0923-0467(96)03078-3
J.-L. Dirion, M. Cabassud, M.V. Le Lann, G. Casamatta
{"title":"Development of adaptive neural networks for flexible control of batch processes","authors":"J.-L. Dirion,&nbsp;M. Cabassud,&nbsp;M.V. Le Lann,&nbsp;G. Casamatta","doi":"10.1016/0923-0467(96)03078-3","DOIUrl":"10.1016/0923-0467(96)03078-3","url":null,"abstract":"<div><p>This paper deals with the application of a neural controller for temperature control of a batch reactor. The term “neural controller” is used to refer to a multilayer neural network which computes the control values to be applied to the process.</p><p>We present the design and the development of the neural network: architecture, learning database and learning procedure. In a first step, the learning phase consists in teaching the neural network to map the dynamics of a classical adaptive controller (generalized predictive control with double model reference) implemented on the process. Although the neural controller performance is good for operating conditions included in the learning set (interpolation), it exhibits limitations on extrapolation. In this work, two methods for the on-line adaptation of the network's weights are developed: one of them is the “specialized” learning technique, whereas the other uses another neural network in order to model the reactor dynamics. Several results are shown and prove the good capacities of neural networks for controlling batch processes.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"63 2","pages":"Pages 65-77"},"PeriodicalIF":0.0,"publicationDate":"1996-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-0467(96)03078-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78239853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
A new solution technique of moving boundary problems for gas-solid reactions; application to half-order volume reaction model 气固反应移动边界问题的一种新的求解方法半阶体积反应模型的应用
The Chemical Engineering Journal and the Biochemical Engineering Journal Pub Date : 1996-08-01 DOI: 10.1016/0923-0467(96)03079-5
E. Jamshidi, H. Ale Ebrahim
{"title":"A new solution technique of moving boundary problems for gas-solid reactions; application to half-order volume reaction model","authors":"E. Jamshidi,&nbsp;H. Ale Ebrahim","doi":"10.1016/0923-0467(96)03079-5","DOIUrl":"10.1016/0923-0467(96)03079-5","url":null,"abstract":"<div><p>Mathematical modelling of a non-catalytic gas-solid reaction in a porous pellet, where both diffusion and chemical reaction are important, is represented by a pair of coupled partial differential equations. When the kinetics are half-order with respect to solid concentration, no analytical solution exists. Therefore numerical solutions or approximate methods have been used.</p><p>In this work a new incremental analytical method of solution has been developed. The results of this method in comparison with the existing numerical and approximate solutions show high accuracy and good fitting. The method is very simple to handle with small calculators and also gives some analytical expressions for gas and solid concentrations.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"63 2","pages":"Pages 79-83"},"PeriodicalIF":0.0,"publicationDate":"1996-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-0467(96)03079-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73156549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
Measurement of the rate of energy dissipation around an oscillating grid by an energy balance approach 用能量平衡法测量振荡网格周围的能量耗散率
The Chemical Engineering Journal and the Biochemical Engineering Journal Pub Date : 1996-08-01 DOI: 10.1016/0923-0467(96)03077-1
D.H. Bache, E. Rasool
{"title":"Measurement of the rate of energy dissipation around an oscillating grid by an energy balance approach","authors":"D.H. Bache,&nbsp;E. Rasool","doi":"10.1016/0923-0467(96)03077-1","DOIUrl":"10.1016/0923-0467(96)03077-1","url":null,"abstract":"<div><p>An experimental study was carried out to evaluate ϵ around an oscillating grid producing zero-mean shear flow. The spatial average <span><math><mtext>ϵ</mtext></math></span> throughout the mixing vessel was determined by the mesurement of the net power input of the grid, this complying with a relationship of the form <span><math><mtext>ϵ</mtext></math></span>α<em>f</em><sup>3</sup><sub>D</sub><em>S</em><sup>3</sup> Re<sup>−<span><math><mtext>1</mtext><mtext>2</mtext></math></span></sup> <em>h</em><sup>−1</sup>, in which f<sub>D</sub> is the driving frequency, <em>S</em> is the stroke length, Re the grid Reynolds number and <em>h</em> the depth of the mixing column. From mesurements of the power spectrum using laser Doppler anemometry, spectral collapse of the power spectra in the domain of the energy containing eddies at different distances from the grid was demonstrated using <em>u</em><sup>2</sup> (<em>u</em> as the turbulence r.m.s. velocity) and τ<sub>E</sub> (Eulerian time integral scale) as the scaling parameters. From a balance of the power input and the energy losses, together with the feature of spectral collapse, it was shown that ϵ could be estimated by ϵ = γ<sub>1</sub><em>u</em><sup>2</sup>/τ<sub>E</sub> in this domain of the power spectrum with γ<sub>1</sub> as a multiplying coefficient independent of distance from the grid.</p><p>From the spatial dependence of the turbulence parameters it was evident that within about 1.5 mesh lengths of the grid there was a transition region beyond which it was found that spatial variations were consistent with the dependences <em>u</em>α<em>z</em><sup>−1</sup>, τ<sub>E</sub>α<em>z</em><sup>2</sup>, and ϵα<em>z</em><sup>−4</sup>, where <em>z</em> is the distance from the grid.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"63 2","pages":"Pages 105-115"},"PeriodicalIF":0.0,"publicationDate":"1996-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-0467(96)03077-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84114726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 15
Abrasion and breakage phenomena in mechanically stirred crystallizers 机械搅拌结晶器中的磨损和断裂现象
The Chemical Engineering Journal and the Biochemical Engineering Journal Pub Date : 1996-08-01 DOI: 10.1016/0923-0467(96)03082-5
B. Biscans , P. Guiraud , C. Laguérie , A. Massarelli , B. Mazzarotta
{"title":"Abrasion and breakage phenomena in mechanically stirred crystallizers","authors":"B. Biscans ,&nbsp;P. Guiraud ,&nbsp;C. Laguérie ,&nbsp;A. Massarelli ,&nbsp;B. Mazzarotta","doi":"10.1016/0923-0467(96)03082-5","DOIUrl":"https://doi.org/10.1016/0923-0467(96)03082-5","url":null,"abstract":"<div><p>Attrition experiments lasting several hours were carried out for low concentration crystal suspensions (3 kg m<sup>−3</sup>) at two different stirring rates (960 and 1154 rev min<sup>−1</sup>). The size distributions were measured at fixed time intervals by continuously circulating the suspension through the cell of a laser particle sizer. Monosized sodium chloride crystals (500−560 μm), after attrition, gave rise to a bimodal size distribution with a higher peak in the parent crystal region and a much lower one below 32 μm: the amount of fine fragments increased continuously throughout the run.</p><p>The size distributions of the particles present in the crystallizer at each time were successfully modelled by superimposing the effects of abrasion and breakage fracture mechanisms. At the beginning of the run, abrasion largely prevails, being responsible for more than 98% of the fracture, but its importance rapidly declines with time and at the end of the run (8–12 h) the contributions of abrasion and breakage mechanisms to attrition appear comparable.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"63 2","pages":"Pages 85-91"},"PeriodicalIF":0.0,"publicationDate":"1996-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-0467(96)03082-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91759390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
Abrasion and breakage phenomena in mechanically stirred crystallizers 机械搅拌结晶器中的磨损和断裂现象
The Chemical Engineering Journal and the Biochemical Engineering Journal Pub Date : 1996-08-01 DOI: 10.1016/0923-0467(96)03082-5
B. Biscans, P. Guiraud, C. Laguerie, A. Massarelli, B. Mazzarotta
{"title":"Abrasion and breakage phenomena in mechanically stirred crystallizers","authors":"B. Biscans, P. Guiraud, C. Laguerie, A. Massarelli, B. Mazzarotta","doi":"10.1016/0923-0467(96)03082-5","DOIUrl":"https://doi.org/10.1016/0923-0467(96)03082-5","url":null,"abstract":"","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"23 1","pages":"85-91"},"PeriodicalIF":0.0,"publicationDate":"1996-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87180127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
Modeling of liquid emulsion membranes facilitated by two carriers 两种载体促进乳化液膜的建模
The Chemical Engineering Journal and the Biochemical Engineering Journal Pub Date : 1996-08-01 DOI: 10.1016/0923-0467(96)03097-7
Young Sun Mok , Won Kook Lee , Yong Kuk Lee
{"title":"Modeling of liquid emulsion membranes facilitated by two carriers","authors":"Young Sun Mok ,&nbsp;Won Kook Lee ,&nbsp;Yong Kuk Lee","doi":"10.1016/0923-0467(96)03097-7","DOIUrl":"https://doi.org/10.1016/0923-0467(96)03097-7","url":null,"abstract":"<div><p>A mathematical model was proposed to describe the behaviour of liquid emulsion membranes for the extraction of penicillin G in a continuous countercurrent mixing column. A polyamine-type surfactant acts non only as carrier but also as surface-stabilizing agent; thus the influence of surfactant on extraction should be considered in mathematical modeling when its effect is significant. The proposed model takes into account the influence of surfactant on mass transfer. The advancing front model was employed for deriving the overall mass transfer coefficient in the emulsion globule, and the axial dispersion model was applied to the external feed phase. The experimental data were compared with the proposed model, the calculations without considering the contribution of the surfactant to extraction, and the calculations without considering diffusion in the emulsion phase.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"63 2","pages":"Pages 127-137"},"PeriodicalIF":0.0,"publicationDate":"1996-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-0467(96)03097-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136603770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of anthraquinone reaction with sodium sulphide 蒽醌与硫化钠反应的研究
The Chemical Engineering Journal and the Biochemical Engineering Journal Pub Date : 1996-07-01 DOI: 10.1016/0923-0467(95)03071-9
F. Rodríguez, J. Revenga, J. Tijero
{"title":"Study of anthraquinone reaction with sodium sulphide","authors":"F. Rodríguez,&nbsp;J. Revenga,&nbsp;J. Tijero","doi":"10.1016/0923-0467(95)03071-9","DOIUrl":"10.1016/0923-0467(95)03071-9","url":null,"abstract":"<div><p>The reduction of anthraquinone (AQ) with sodium sulphide in alkaline medium has been studied by measuring conversion as a function of time at various temperatures, sodium sulphide concentrations, initial radii of anthraquinone particles and sodium hydroxide concentrations. The reduced product is the disodium salt of 9,10-dihydroxyanthracene. The kinetic data were fitted to the isothermal shrinking core model (SCM) for cylindrical particles without porous solid product layer formation. The results indicate that the surface chemical reaction is the controlling step of the overall process rate. AQ reduction is of first order with respect to sodium sulphide concentration. The activation energy was obtained from the Arrhenius law and was found to be 68.81 kJ mol<sup>−1</sup> for the investigated temperature range.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"63 1","pages":"Pages 37-43"},"PeriodicalIF":0.0,"publicationDate":"1996-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-0467(95)03071-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83177904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Transitional mixing in multiple-turbine agitated tanks 多涡轮搅拌槽内的过渡混合
The Chemical Engineering Journal and the Biochemical Engineering Journal Pub Date : 1996-07-01 DOI: 10.1016/0923-0467(95)03072-7
Jorge M.T. Vasconcelos, Jorge M. Barata, S.S. Alves
{"title":"Transitional mixing in multiple-turbine agitated tanks","authors":"Jorge M.T. Vasconcelos,&nbsp;Jorge M. Barata,&nbsp;S.S. Alves","doi":"10.1016/0923-0467(95)03072-7","DOIUrl":"10.1016/0923-0467(95)03072-7","url":null,"abstract":"<div><p>Blending of viscous newtonian liquids was studied in dual- and triple-turbine agitated tanks. The dimensionless power, mixing and interstage flow numbers were all found to be dependent on the Reynolds number as long as the full development of turbulence was inhibited by viscosity (Re &lt; 2 × 10<sup>4</sup>) and they were found to be constant above that limit. The complexity of the transitional regime makes it adverse for simple correlation, but, surprisingly, modelling of mixing in the upper transition region (Re &gt; 400) could still be achieved using a compartment model developed elsewhere for turbulent mixing simulation in this geometry. The model corresponds to a simplified physical representation of the hydrodynamics of the tank</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"63 1","pages":"Pages 53-58"},"PeriodicalIF":0.0,"publicationDate":"1996-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-0467(95)03072-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89118277","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Liquid—solid mass transfer in packed beds of variously shaped particles at low Reynolds numbers: experiments and model 低雷诺数下不同形状颗粒填充床的液固传质:实验与模型
The Chemical Engineering Journal and the Biochemical Engineering Journal Pub Date : 1996-07-01 DOI: 10.1016/0923-0467(96)03073-4
Dominique Seguin, Agnès Montillet, Danielle Brunjail, Jacques Comiti
{"title":"Liquid—solid mass transfer in packed beds of variously shaped particles at low Reynolds numbers: experiments and model","authors":"Dominique Seguin,&nbsp;Agnès Montillet,&nbsp;Danielle Brunjail,&nbsp;Jacques Comiti","doi":"10.1016/0923-0467(96)03073-4","DOIUrl":"10.1016/0923-0467(96)03073-4","url":null,"abstract":"<div><p>The cathodic reduction of ferricyanide ions is used to characterize liquid—solid mass transfer in porous electrodes in the creeping flow regime. Our study deals with packed beds of spheres, long cylinders and plates of low height-to-side ratio. Correlations are proposed and compared with predictive equations based on the association of the capillary representation of the porous medium with the analytical solution for mass transfer at a pipe wall, for fully developed laminar flow in short tubes.</p><p>The model leads to satisfying values of the mass transfer coefficient in the case of beds packed with spheres and parallelepipedal particles.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"63 1","pages":"Pages 1-9"},"PeriodicalIF":0.0,"publicationDate":"1996-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-0467(96)03073-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72948787","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 38
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信